糖鎖関連試薬糖質データシートカタログ

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3 Table of Contents Table of Contents /...1 The Functional ligosaccharides Chain /...2 TCI Website /...4 Catalog Usage Abbreviations Used in the Catalog /...6 Carbohydrates / Allose...7 Arabinose...8 Erythrose...9 Fructose...10 Fucose...11 Galactose...13 Galactosamine...20 Glucose...22 Glucosamine...38 Gulose...44 Idose...45 Inositol...46 Lyxose...48 Mannose...49 Mannosamine...53 Psicose...54 Rhamnose...55 Ribose...56 Sialic Acids...59 Sorbose...61 Tagatose...62 Talose...63 Xylose...64 Disaccharides...66 Trisaccharides...77 Tetrasaccharides...83 ligosaccharides...85 Polysaccharides...91 thers...95 Reagents for ligosaccharide Synthesis / Applications for Sugar-conjugates / Enzymes / Glycosynthase (Endo-M-N175Q) Endo-M Endo-α Glycohydrolase Lectin, Fucose Specific / L Antibodies / Anti-Glyco Antibodies Secondary Antibodies NMR Data / NMR Product Name Index / Appendix / Basic Structures of Glycolipids / Basic Structures of Glycoproteins / Basic Structures of Proteoglycans / The Physical Properties of the Typical rganic Solvents Freezing Mixtures / Preparation of Reagents and Solutions / Pressure-Temperature Nomograph / TCI Local ffices / TCI Distributors / General Information /

4 The Functional ligosaccharides Chain- We are ready to meet your demand. Feel free to send us any serious inquiry, please refer to our contact information listed on the back cover. 2

5 The Functional ligosaccharides Chain- 3

6 TCI Website 4

7 Reagents for Glyco-Chemistry & Biology 5

8 Catalog Usage M Methoxyphenyl 3--Allyl-4,6--benzylidene- -D-galactopyranoside >98.0%(LC) C 23 H 26 7 = [ ] MFCD mp 228 NMR P. CH 2 1g 5g B0643 Allyl Bromide 25g 500g >98.0%(GC) C3H5Br = [ ] MFCD bp 71 d 1.43 flp 12 Beil. 1,201 MI RTECS UC Ph H CH 3 Br A1651 endo- -N-Acetylglucosaminidase (= Endo-M) Recombinant: from Mucor hiemalis expressed in Candida boidinii [Purity: single band by SDS-PAGE(85KDa)] [ ] MFCD EC munits Product Number Please use the product number with the chemical name when inquiring and ordering. Chemical Name Molecular Formula Molecular Weight CAS Registry Number (Chemical Abstracts Service Registry Number) MDL Number* Quantity Structural Formula Purity Physical Property fp : freezing point( ) / mp : melting point( ) / bp : boiling point( ) / d : specific gravity / flp : flash point( ) from literature, and not necessarily product specification. References Beil. : Beilstein(vol. (suppl.) part, page) / MI14 : Monograph Number from "The Merck Index", 14th edition** / F&F : Fieser & Fieser's "Reagents for rganic Synthesis"; vol, page RTECS Number (Registry of Toxic Effects of Chemical Substances Number) EC Number (Enzyme Commission Number) NMR NMR data are prepared. Chemical Abstracts Service Registry Number * ** *Reproduced with license of MDL Available Chemicals Directory. **Reproduced with permission from The Merck Index, Fourteenth Edition. Copyright 2006 by Merck & Co., Inc., Whitehouse Station, NJ, USA. All rights reserved. << Abbreviations Used in the Catalog >> Ac All Bn Boc Bz Fmoc Gal acetyl allyl benzyl tert-butoxycarbonyl benzoyl (9H-fluoren-9-ylmethoxy)carbonyl galactose Glc glucose MP 4-methoxyphenyl Ph phenyl pnp p-nitrophenyl SDS-PAGE sodium dodecylsulfate-polyacrylamide gel electrophoresis Xyl xylose 6

9 Allose A1982 A1488 Allitol >98.0%(GC) C 6 H 14 6 = [ ] mp 152 Beil. 1(4)2839 RTECS BA D-(+)-Allose >98.0%(LC) C 6 H 12 6 = [ ] MFCD mp 149 Beil. 1(4)4299 MI H 100mg 1g H 100mg H H H H H H CH 2 H H H H H CH 2 H H D2265 1,2:5,6-Di--isopropylidene- -D-allofuranose >98.0%(GC) C 12 H 20 6 = [ ] MFCD mp 75 Beil. 19(5)12,318 CH 3 CH 3 1g 5g H CH 3 CH 3 F Formylphenyl -D-Allopyranoside 5g >98.0%(LC) C 13 H 16 7 = [ ] mp 190 H H H H C H Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 7

10 Arabinose A0513 D-(-)-Arabinose >98.0%(GC) C 5 H 10 5 = [ ] MFCD mp 161 Beil. 1(4)4215 H 25g H H H A0515 L-(+)-Arabinose >98.0%(GC) C 5 H 10 5 = [ ] MFCD mp 156 Beil. 1(4)4218 MI g 250g H H H H A0517 DL-Arabitol >95.0%(GC) C 5 H 12 5 = [ ] MFCD Beil. 1(4)2832 MI H 100mg H H H H relative A0516 D-(+)-Arabitol >98.0%(GC) C 5 H 12 5 = [ ] MFCD mp 103 Beil. 1(4)2832 MI g 25g CH 2 H H H H H H H CH 2 H A0518 L-(-)-Arabitol >97.0%(GC) C 5 H 12 5 = [ ] MFCD mp 103 Beil. 1(4)2832 MI g 25g CH 2 H H H H H H H CH 2 H M1019 Methyl -D-Arabinopyranoside >99.0%(GC) C 6 H 12 5 = [ ] MFCD mp 174 H 100mg H CH 3 H T2695 2,3,4-Tri--acetyl- -L-arabinopyranosyl 2,2,2-Trichloroacetimidate C 13 H 16 Cl 3 N 8 = [ ] NMR P.136 Price on request Ac NH C CCl 3 Ac Ac 8

11 Erythrose D1320 Dithioerythritol >98.0%(T) C 4 H 10 2 S 2 = [ ] MFCD mp 84 Beil. 2(3)2360 RTECS KF HS 5g 25g H SH H E0021 meso-erythritol >99.0%(LC)(T) C 4 H 10 4 = [ ] MFCD mp 120 Beil. 1,525 MI RTECS KF g 500g H H H H E0455 D-Erythronolactone >98.0%(GC) C 4 H 6 4 = [ ] MFCD mp 103 Beil. 18,78 1g 5g 25g H H I0454 2,3--Isopropylidene-D-erythronolactone >98.0%(GC) C 7 H 10 4 = [ ] MFCD mp 68 Beil. 19(5)10,235 1g H 3 C CH 3 Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 9

12 Fructose D3758 2,3:4,5-Di--isopropylidene- -D-fructopyranose 5g 25g >98.0%(GC) C 12 H 20 6 = [ ] MFCD mp 96 Beil. 19(4)6124 CH 3 CH 3 CH 3 CH 3 H F0060 D-(-)-Fructose 25g 500g >98.0%(LC) C 6 H 12 6 = [ ] MFCD Beil. 31,321 MI RTECS LS H H CH 2 H H H F0317 L-(+)-Fructose 100mg 1g >97.0%(LC) C 6 H 12 6 = [ ] MFCD H H H CH 2 H H New T2755 Topiramate >98.0%(LC)(T) C 12 H 21 N 8 S = [ ] MFCD mp 126 MI RTECS LS CH 3 CH 3 1g 5g CH 3 CH 3 S 2 NH 2 10

13 Fucose- D0049 D-(+)-Fucose >98.0%(GC) C 6 H 12 5 = [ ] MFCD mp 137 Beil. 31,76 MI g 5g H CH 3 H H H F0065 L-(-)-Fucose >97.0%(GC) C 6 H 12 5 = [ ] MFCD Beil. 31,78 MI g 10g CH H 3 H H H M1051 Methyl -L-Fucopyranoside 1g C 7 H 14 5 = [ ] MFCD mp 159 CH 3 H H CH 3 H M1050 Methyl -L-Fucopyranoside C 7 H 14 5 = [ ] MFCD mp 123 CH 3 H H 1g CH 3 H M1626 Methyl 2,3,4-Tri--acetyl-1-thio- -L-fucopyranoside >98.0%(LC) C 13 H 20 7 S = [ ] MFCD mp 148 NMR P.137 1g 5g CH 3 SCH 3 Ac Ac Ac M1628 Methyl 2,3,4-Tri--benzyl-1-thio- -L-fucopyranoside >95.0%(LC) C 28 H 32 4 S = [ ] MFCD mp 58 NMR P.138 CH 3 Bn Bn 1g SCH 3 Bn N Nitrophenyl -L-Fucopyranoside 10mg >98.0%(LC) C 12 H 15 N 7 = [ ] MFCD CH 3 H H H N 2 Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 11

14 Fucose- N Nitrophenyl -D-Fucopyranoside 100mg >98.0%(GC) C 12 H 15 N 7 = [ ] mp 184 H CH 3 H H N 2 P1842 Phenyl 2,3,4-Tri--benzyl-1-thio- -L-fucopyranoside >98.0%(LC) C 33 H 34 4 S = [ ] mp 108 1g 5g CH 3 SPh Bn Bn Bn T2207 1,2,3,4-Tetra--acetyl- -L-fucopyranose 1g 5g Ac >98.0%(LC) C 14 H 20 9 = [ ] MFCD mp 94 Beil. 17(3/4)2549 CH 3 Ac Ac Ac 12

15 Galactose- A Aminophenyl -D-Galactopyranoside 1g >95.0%(T) C 12 H 17 N 6 = [ ] MFCD mp 163 Beil. 17(3/4)3409 H H H H NH 2 G [2-(2-Azidoethoxy)ethoxy]ethyl 2,3,4,6-Tetra--acetyl- D-galactopyranoside >96.0%(N) C 20 H 31 N 3 12 = [ ] MFCD Ac Ac Ac Ac 1g 5g N 3 B Bromo-4-chloro-3-indolyl -D-Galactopyranoside [for Biochemical Research] >98.0%(LC)(N) C 14 H 15 BrClN 6 = [ ] MFCD MI H H H H 200mg 1g N H Cl Br B Bromo-6-chloro-3-indolyl -D-Galactopyranoside (contains ca. 10% Ethyl Acetate) [for Biochemical Research] >98.0%(LC) C 14 H 15 BrClN 6 = [ ] MFCD H H 20mg 100mg H H N H Br Cl B Bromo-3-indolyl -D-Galactopyranoside [for Biochemical Research] >98.0%(LC) C 14 H 16 BrN 6 = [ ] MFCD H H 20mg 100mg H H N H Br C Chloro-3-indolyl -D-Galactopyranoside [for Biochemical Research] >98.0%(LC) C 14 H 16 ClN 6 = [ ] MFCD H H 20mg 100mg H H N H Cl D Deoxy-D-galactose 1g C 6 H 12 5 = [ ] MFCD mp 112 H H H H Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 13

16 Galactose- D2555 1,2:3,4-Di--isopropylidene- -D-galactopyranose >92.0%(GC) C 12 H 20 6 = [ ] MFCD bp 133 /0.2mmHg Beil. 19(5)12,366 CH 3 CH 3 5g 25g H CH 3 CH3 G0273 D-Galactal >98.0%(LC) C 6 H 10 4 = [ ] MFCD Beil. 17(5)5,698 1g 5g H H H G0005 Galactitol >98.0%(GC) C 6 H 14 6 = [ ] MFCD mp 189 Beil. 1,544 MI G0008 D-(+)-Galactose Anhydrous >97.0%(LC) C 6 H 12 6 = [ ] MFCD Beil. 1(4)4336 MI RTECS LW g 250g H H H H H H H H CH 2 H H H H H CH 2 H 25g 500g H G0267 L-(-)-Galactose >98.0%(LC) C 6 H 12 6 = [ ] MFCD Beil. 1(4) mg 500mg H H H H H G0010 -D-Galacturonic Acid Hydrate >95.0%(T) C 6 H 10 7 xh 2 = (Anh) [ ] MFCD Beil. 3(4)2000 MI H CH H 5g 25g. xh 2 H H I0328 Isopropyl 1-Thio- -D-galactopyranoside >98.0%(GC) C 9 H 18 5 S = [ ] MFCD MI H H H H 1g 5g S CH 3 CH 3 14

17 Galactose- M Methoxyphenyl 3--Allyl- 2--benzyl-4,6--benzylidene- -D-galactopyranoside >98.0%(LC) C 30 H 32 7 = MFCD mp 177 NMR P.139 Ph Bn 1g CH 3 M Methoxyphenyl 3--Allyl- 4,6--benzylidene- -D-galactopyranoside >98.0%(LC) C 23 H 26 7 = [ ] MFCD mp 228 NMR P.140 Ph H 1g 5g CH 3 M Methoxyphenyl 3--Allyl-4,6-- benzylidene-2--(4-methylbenzoyl)- -D-galactopyranoside Ph 1g >98.0%(LC) C 31 H 32 8 = MFCD NMR P.141 CH 3 CH 3 M Methoxyphenyl 3--Allyl- -D-galactopyranoside >98.0%(LC) C 16 H 22 7 = [ ] MFCD mp 143 NMR P.142 H H H 5g CH 3 M Methoxyphenyl 3--Benzyl- -D-galactopyranoside >98.0%(LC) C 20 H 24 7 = [ ] mp 154 NMR P.143 H Bn H H 1g 5g CH 3 M Methoxyphenyl 4,6--Benzylidene- -D-galactopyranoside Ph Price on request C 20 H 22 7 = [ ] NMR P.144 H H CH 3 M Methoxyphenyl 2,6-Bis--(4-methylbenzoyl)- -D-galactopyranoside >98.0%(LC) C 29 H 30 9 = MFCD NMR P.145 H H 1g CH 3 CH 3 CH 3 Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 15

18 Galactose- M Methoxyphenyl 2,6-Di--benzyl- -D-galactopyranoside >98.0%(LC) C 27 H 30 7 = [ ] MFCD mp 113 NMR P.146 H H Bn Bn 1g CH 3 M Methoxyphenyl 2,6-Di--benzyl- 3,4--isopropylidene- -D-galactopyranoside >98.0%(LC) C 30 H 34 7 = [ ] MFCD mp 105 NMR P.147 CH 3 CH 3 Bn Bn 1g CH 3 M Methoxyphenyl -D-Galactopyranoside >98.0%(LC) C 13 H 18 7 = [ ] MFCD mp 160 Beil. 17(3/4)2984 NMR P.148 H H H H 5g 25g CH 3 M Methoxyphenyl 3,4--Isopropylidene- 2,6-bis--(4-methylbenzoyl)- -D-galactopyranoside >95.0%(LC) C 32 H 34 9 = MFCD NMR P.149 CH 3 CH 3 1g CH 3 CH 3 CH 3 M Methoxyphenyl 3,4--Isopropylidene- -D-galactopyranoside >98.0%(LC) C 16 H 22 7 = [ ] MFCD NMR P.150 CH 3 CH 3 H H 1g CH 3 M Methoxyphenyl 3,4--Isopropylidene- 6--(4-methylbenzoyl)- -D-galactopyranoside >98.0%(LC) C 24 H 28 8 = MFCD NMR P.151 CH 3 CH 3 H CH 3 1g CH 3 M Methoxyphenyl 2,3,4,6-Tetra--acetyl- -D-galactopyranoside >98.0%(LC) C 21 H = [ ] MFCD mp 105 NMR P.152 Ac Ac Ac Ac 5g 25g CH 3 16

19 Galactose- M Methoxyphenyl 2,3,4,6-Tetra--benzyl- -D-galactopyranoside >98.0%(LC) C 41 H 42 7 = [ ] MFCD mp 110 NMR P.153 Bn Bn Bn Bn 5g CH 3 M Methoxyphenyl 2,3,6-Tri--benzyl- -D-galactopyranoside C 34 H 36 7 = [ ] H Bn Price on request Bn Bn CH 3 M Methoxyphenyl 2,4,6-Tri--benzyl- -D-galactopyranoside >98.0%(LC) C 34 H 36 7 = [ ] MFCD mp 94 NMR P.154 Bn H Bn Bn 1g CH 3 M1047 Methyl -D-Galactopyranoside Monohydrate >97.0%(GC) C 7 H 14 6 H 2 = (Anh) [ ] MFCD mp 108 H H 5g 25g H. H CH3 H 2 M1035 Methyl -D-Galactopyranoside >98.0%(GC) C 7 H 14 6 = [ ] MFCD mp 178 Beil. 31,315 H H 1g 5g H H CH 3 M1933 Methyl 2,3,6-Tri--benzoyl- -D-galactopyranoside >98.0%(LC) C 28 H 26 9 = [ ] MFCD mp 143 NMR P.155 5g 25g 250g H Bz Bz Bz CH3 N Nitrophenyl -D-Galactopyranoside [Substrate for -D-Galactosidase] >98.0%(LC) C 12 H 15 N 8 = [ ] MFCD H H 1g 5g 25g H H 2 N Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 17

20 Galactose- N Nitrophenyl -D-Galactopyranoside [Substrate for -D-Galactosidase] >98.0%(LC) C 12 H 15 N 8 = [ ] MFCD mp 168 H H 200mg 1g H H N2 N Nitrophenyl -D-Galactopyranoside [Substrate for -Galactosidase] >98.0%(LC) C 12 H 15 N 8 = [ ] MFCD mp 180 Beil. 17(5)7,55 H H H H 1g 5g N 2 G0247 Penta--acetyl- -D-galactopyranose >97.0%(GC) C 16 H = [ ] MFCD mp 145 Beil. 17(5)7,322 Ac Ac 25g 250g Ac Ac Ac New P2078 Phenyl 2--Acetyl-3,4,6-tri--benzyl- 1-thio- -D-galactopyranoside C 35 H 36 6 S = [ ] NMR P.156 Price on request Bn Bn Bn Ac SPh P1660 Phenyl 3--Allyl-2,4,6-tri--benzyl- 1-thio- -D-galactopyranoside >98.0%(LC) C 36 H 38 5 S = [ ] Bn Bn Bn 1g SPh P1326 Phenyl -D-Galactopyranoside >98.0%(LC) C 12 H 16 6 = [ ] MFCD mp 148 Beil. 17(5)7,47 H H 1g 5g H H Ph P1477 Phenyl 2,3,4,6-Tetra--acetyl-1-thio- -D-galactopyranoside C 20 H 24 9 S = [ ] NMR P.157 Ac Ac 5g 25g Ac Ac SPh 18

21 Galactose- P1679 Phenyl 2,3,4,6-Tetra--benzyl-1-thio- -D-galactopyranoside >98.0%(LC) C 40 H 40 5 S = [ ] MFCD mp 88 NMR P.158 Bn Bn Bn Bn 1g SPh P1680 Phenyl 2,4,6-Tri--acetyl-3--allyl- 1-thio- -D-galactopyranoside >98.0%(LC) C 21 H 26 8 S = NMR P.159 Ac Ac Ac 1g SPh T2295 2,3,4,6-Tetra--acetyl- -D-galactopyranosyl 2,2,2-Trichloroacetimidate >93.0%(LC) C 16 H 20 Cl 3 N 10 = [ ] MFCD mp 122 NMR P.160 T1734 Tri--acetyl-D-galactal >95.0%(GC) C 12 H 16 7 = [ ] MFCD Beil. 17(5)5,700 Ac Ac Ac Ac Ac 1g 5g Ac NH C CCl 3 1g 5g Ac T1932 3,4,6-Tri--benzyl-2-deoxy- D-galactopyranose >98.0%(LC) C 27 H 30 5 = [ ] MFCD Bn Bn 100mg Bn H T1858 Tri--benzyl-D-galactal >98.0%(LC) C 27 H 28 4 = [ ] MFCD mp 55 Beil. 17(5)5,698 Bn Bn 1g Bn T (Triisopropylsilyl)-D-galactal >97.0%(GC) C 15 H 30 4 Si = [ ] H H 200mg Si[CH(CH 3 ) 2 ] 3 Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 19

22 Galactosamine- A1245 N-Acetyl-D-galactosamine Hydrate >98.0%(LC)(N) C 8 H 15 N 6 xh 2 = (Anh) [ ] MFCD Beil. 4(4)2039 H H H 1g 5g. xh2 H A1833 -(2-Azido-4,6--benzylidene-2-deoxy- -D-galactopyranosyl)-N-[(9H-fluoren-9- ylmethoxy)carbonyl]-l-serine tert-butyl Ester Ph 100mg >92.0%(LC) C 35 H 38 N 4 9 = [ ] NMR P.161 H N 3 C(CH3)3 HN Fmoc A1832 -(2-Azido-4,6--benzylidene-2-deoxy- -D-galactopyranosyl)-N-[(9H-fluoren-9-ylmethoxy) carbonyl]-l-threonine tert-butyl Ester >97.0%(LC) C 36 H 40 N 4 9 = [ ] NMR P.162 Ph H 100mg N 3 CH 3 C(CH 3) 3 HN Fmoc New A Azidoethyl 2-Acetamido-2-deoxy- -D-galactopyranoside C 10 H 18 N 4 6 = [ ] MFCD NMR P.163 Price on request H H H N 3 G0007 D-(+)-Galactosamine Hydrochloride >98.0%(LC)(N) C 6 H 13 N 5 HCl = [ ] MFCD MI RTECS LW H H H H 2 N 1g 5g. HCl H M Methoxyphenyl 3--Allyl-2-azido- 4,6--benzylidene-2-deoxy- -D-galactopyranoside >95.0%(LC) C 23 H 25 N 3 6 = [ ] NMR P.164 Ph 1g CH 3 N 3 N Nitrophenyl 2-Acetamido-2-deoxy- -D-galactopyranoside C 14 H 18 N 2 8 = [ ] MFCD mp 207 Beil. 18(5)11,102 Price on request H H H N 2 20

23 Galactosamine- P1643 Phenyl 2-Deoxy-1-thio- 2-(2,2,2-trichloroethoxyformamido)- -D-galactopyranoside C 15 H 18 Cl 3 N 6 S = [ ] NMR P.165 Price on request H H H NH SPh C CH 2 CCl 3 P1642 Phenyl 3,4,6-Tri--acetyl-2-deoxy-1-thio- 2-(2,2,2-trichloroethoxyformamido)- -D-galactopyranoside >98.0%(LC)(N) C 21 H 24 Cl 3 N 9 S = [ ] mp 117 NMR P.166 Ac Ac Ac NH 1g 5g SPh C CH 2 CCl 3 T1731 1,3,4,6-Tetra--acetyl-2-azido-2-deoxy- -D-galactopyranose C 14 H 19 N 3 9 = [ ] MFCD mp 121 Beil. 17(5)6,400 NMR P.167 Ac Ac 100mg Ac N 3Ac Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 21

24 Glucose- New A2253 A Acetyl-5-methoxyphenyl -D-Glucopyranoside C 15 H 20 8 = [ ] mp 83 Beil. 17(4)3020 NMR P Acetyl-2,3,4-tri--benzyl- D-glucopyranose C 29 H 32 7 = [ ] Price on request H H H H Price on request Bn Bn Ac Ac Bn CH 3 H A1074 1,6-Anhydro- -D-glucose >99.0%(GC) C 6 H 10 5 = [ ] MFCD mp 183 1g 5g H H H New A2637 1,6-Anhydro-2,3,4-tri--benzyl- -D-glucopyranose C 27 H 28 5 = [ ] Price on request Bn Bn Bn A0522 Arbutin 5g 25g >95.0%(LC) C 12 H 16 7 = [ ] MFCD mp 198 Beil. 31,210 MI RTECS CE H H H H H A Azidoethyl -D-Glucopyranoside 1g >98.0%(LC) C 8 H 15 N 3 6 = [ ] H H H H N 3 A Azidoethyl 2,3,4,6-Tetra--acetyl- -D-glucopyranoside >92.0%(LC) C 16 H 23 N 3 10 = [ ] mp 115 NMR P.169 Ac Ac Ac Ac 1g 5g N 3 22

25 Glucose- B2835 Baicalin 25g >90.0%(T) C 21 H = [ ] MFCD mp 196 Beil. 18(3/4)5154 RTECS LZ HC H H H H H New New B4170 Benzyl 2,3-Di--benzyl- 4,6--benzylidene- -D-glucopyranoside C 34 H 34 6 = [ ] mp 136 NMR P.170 B4171 Benzyl 2,3,4-Tri--benzyl- -D-glucopyranoside C 34 H 36 6 = [ ] MFCD mp 103 NMR P.171 Price on request Ph Bn Bn Bn H Bn Bn Bn Price on request Bn G0037 Calcium Gluconate Monohydrate 25g 500g >98.0%(T) C 12 H 22 Ca 14 H 2 = (Anh) [ ] MFCD Beil. 3,544 MI RTECS EW H H H H C H H H H CH 2 H 2 Ca 2. H 2 New C2548 Capsaicin -D-Glucopyranoside >90.0%(LC) C 24 H 37 N 8 = [ ] H H H H CH 3 H N 200mg CH 3 CH 3 C0543 Carmine 5g 25g [ ] MFCD MI RTECS FH H H H H Aluminum Calcium Lake H CH 3 CH H H H C0782 Carminic Acid (Natural dye) 5g 25g C 22 H = [ ] MFCD Beil. 10(2)776 MI H H H H H CH 3 CH H H H The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 23

26 Glucose- C0074 -Chloralose (contains -isomer) >85.0%(GC) C 8 H 11 Cl 3 6 = [ ] MFCD mp 181 MI RTECS FM H H 25g H CCl 3 G0275 Copper(II) Gluconate 25g >97.0%(T) C 12 H 22 Cu 14 = [ ] MFCD Beil. 3(4)1256 MI RTECS LZ H H H H C H H H H Cu 2 CH 2 H 2 New D3920 Daidzin >98.0%(LC) C 21 H 20 9 = [ ] MFCD Beil. 18(4)1808 RTECS DJ H H H H 25mg H New D Deoxy-2-fluoro-D-glucopyranose >98.0%(GC) C 6 H 11 F 5 = [ ] MFCD H H 100mg H F H D Deoxy-D-glucose 1g 5g >97.0%(GC) C 6 H 12 5 = [ ] MFCD mp 150 MI RTECS MQ H H H H D2752 3,4-Di--acetyl-6-deoxy-L-glucal 1g 5g >95.0%(GC) C 10 H 14 5 = [ ] MFCD d 1.14 Beil. 17(5)5,94 CH 3 Ac Ac D1949 1,2:5,6-Di--isopropylidene- -D-glucofuranose >97.0%(GC) C 12 H 20 6 = [ ] MFCD mp 110 Beil. 19(5)12,318 MI RTECS LZ CH 3 CH 3 10g 25g H CH 3 CH 3 24

27 Glucose- E0024 Esculin Sesquihydrate >98.0%(LC)(T) C 15 H / 2 H 2 = (Anh) [ ] MFCD Beil. 18(3/4)1326 MI RTECS DJ H H H H. 1 1 / 2 H 2 H 5g 25g E0402 4,6--Ethylidene- -D-glucopyranose >96.0%(GC) C 8 H 14 6 = [ ] MFCD mp 173 CH 3 H 1g 5g H H E0675 Etoposide 100mg >98.0%(LC) C 29 H = [ ] mp 251 MI RTECS KC CH 3 H H CH 3 H CH 3 New G0385 Geniposide >95.0%(LC) C 17 H = [ ] MFCD mp 162 H H 100mg 1g H H H CH 2 H CH 3 H G0274 D-Glucal >95.0%(GC) C 6 H 10 4 = [ ] MFCD mp 62 Beil. 17(5)5,697 1g 5g H H H G0036 Gluconic Acid (contains Gluconolactone) (45-50% in Water) C 6 H 12 7 = [ ] MFCD Beil. 3,542 MI RTECS LZ G0039 D-(+)-Glucono-1,5-lactone >98.0%(T) C 6 H 10 6 = [ ] MFCD mp 153 Beil. 3(4)1255 MI RTECS LZ g 500g H H CH H H H H H H H H CH 2 H 25g 500g H H The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 25

28 Glucose- G0339 -D-Glucopyranose 1-Phosphate Disodium Salt >98.0%(LC) C 6 H 11 Na 2 9 P = [ ] NMR P.172 H H 20mg 100mg H H Na P Na G0048 D-(+)-Glucose >98.0%(GC) C 6 H 12 6 = [ ] MFCD Beil. 31,83 MI RTECS LZ H H 25g 500g H H H G0226 L-(-)-Glucose >98.0%(GC) C 6 H 12 6 = [ ] MFCD MI RTECS LZ H H 1g 5g H H H G0047 -D-Glucose (contains -D-Glucose) >80.0%(GC) C 6 H 12 6 = [ ] MFCD mp 155 Beil. 1(4)4306 MI H H 25g 500g H H H G0259 D-Glucose Diethyl Mercaptal C 10 H 22 5 S 2 = [ ] MFCD mp 128 Beil. 31,475 CH 3 CH 2 S H H H H SCH 2 CH 3 H H H H CH 2 H 1g G0052 D-Glucose 6-Phosphate Barium Salt Heptahydrate >98.0%(W) C 6 H 11 Ba 9 P 7H 2 = (Anh) [ ] MFCD H H 100mg 1g P H H Ba 2. 7H2 G0053 Glucose 1-Phosphate Dipotassium Salt Dihydrate >98.0%(T) C 6 H 11 K 2 9 P 2H 2 = (Anh) [ ] MFCD H H H H 1g K P K. 2H2 26

29 Glucose- G0211 D-Glucose 6-Phosphate Dipotassium Salt Hydrate >98.0%(T) C 6 H 11 K 2 9 P xh 2 = (Anh) [ ] MFCD Price on request H H K P K H H. xh 2 New G0397 Glucotropaeolin Potassium Salt >98.0%(LC) C 14 H 18 KN 9 S 2 = [ ] MFCD H H H H S 10mg NS 3 K G0223 D-Glucuronamide 25g >98.0%(N) C 6 H 11 N 6 = [ ] MFCD mp 167 Beil. 3(4)2009 RTECS LZ H H CNH 2 H H G0302 D-Glucuronic Acid >96.0%(T) C 6 H 10 7 = [ ] MFCD Beil. 3(4)1996 MI RTECS LZ H H 5g 25g CH H H G0055 D-Glucurono-6,3-lactone >99.0%(T) C 6 H 8 6 = [ ] MFCD Beil. 18(3/4)3055 MI RTECS LZ g 500g H H H H0908 Helicin >98.0%(LC) C 13 H 16 7 = [ ] MFCD Beil. 31,223 MI H H H H 1g 5g CH I0017 Indican Hydrate >90.0%(LC) C 14 H 17 N 6 xh 2 = (Anh) [ ] MFCD Beil. 21(3/4)748 MI H H 100mg 500mg H H. xh2 N H The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 27

30 Glucose- G0038 Iron(II) Gluconate Hydrate 25g 500g >95.0%(T) C 12 H 22 Fe 14 xh 2 = (Anh) [ ] MFCD Beil. 3(4)1256 MI RTECS LZ H H H H C H H H H Fe 2. xh 2 CH 2 H 2 I0400 1,2--Isopropylidene- -D-glucofuranose >97.0%(GC) C 9 H 16 6 = [ ] MFCD mp 156 Beil. 19(3/4)4919 H H H 25g CH 3 CH 3 I0688 1,2--Isopropylidene- -D-glucurono-6,3-lactone 1g >98.0%(GC) C 9 H 12 6 = [ ] MFCD mp 121 Beil. 19(3/4)5942 H CH 3 CH 3 G0276 Magnesium(II) Gluconate Hydrate 25g 500g >98.0%(T) C 12 H 22 Mg 14 xh 2 = (Anh) [ ] MFCD Beil. 3(2)350 RTECS M H H H H C H H H H Mg 2. xh 2 CH 2 H 2 M Methoxyphenyl 2--Acetyl- 3--allyl-4,6--benzylidene- -D-glucopyranoside >98.0%(LC) C 25 H 28 8 = Ph Ac 1g 5g CH 3 New M Methoxyphenyl 2--Benzoyl- 3,6-di--benzyl- -D-glucopyranoside C 34 H 34 8 = [ ] NMR P.173 H Bn Price on request Bn CH 3 Bz M Methoxyphenyl 3--Benzyl- 4,6--benzylidene- -D-glucopyranoside >98.0%(LC) C 27 H 28 7 = [ ] mp 207 NMR P.174 Ph Bn H 1g 5g CH 3 28

31 Glucose- M Methoxyphenyl 3--Benzyl- -D-glucopyranoside >98.0%(LC) C 20 H 24 7 = [ ] NMR P.175 H Bn H H 1g CH 3 M Methoxyphenyl -D-Glucopyranoside >97.0%(LC) C 13 H 18 7 = [ ] MFCD mp 176 NMR P.176 H H H H 5g 25g CH 3 M Methoxyphenyl 2,3,4,6-Tetra--acetyl- -D-glucopyanoside >98.0%(LC) C 21 H = [ ] MFCD NMR P.177 Ac Ac Ac Ac 5g CH 3 M Methoxyphenyl 2,4,6-Tri--acetyl- 3--benzyl- -D-glucopyranoside >96.0%(LC) C 26 H = [ ] mp 160 NMR P.178 Ac Bn Ac Ac 1g 5g CH 3 M1125 Methyl 4,6--Benzylidene- -D-glucopyranoside >98.0%(GC) C 14 H 18 6 = [ ] MFCD mp 164 Beil. 19(3/4)4956 Ph H 5g 25g H CH3 M2013 Methyl 2,3-Di--benzoyl-4,6--benzylidene- -D-glucopyranoside >98.0%(LC) C 28 H 26 8 = [ ] MFCD mp 154 Beil. 19(4)4974 Ph Bz 1g Bz CH 3 M0228 Methyl -D-Glucopyranoside >98.0%(GC) C 7 H 14 6 = [ ] MFCD mp 170 Beil. 31,179 MI g 500g H H H H CH3 The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 29

32 Glucose- M0709 Methyl -D-Glucopyranoside Hemihydrate >98.0%(GC) C 7 H / 2 H 2 = (Anh) [ ] MFCD mp 111 Beil. 17(3/4)2911 H H H H 5g 25g CH 3. 1 / 2 H 2 M1759 Methyl (Phenyl 2,3,4-Tri--acetyl-1-thio- -D-glucopyranosid)uronate >98.0%(LC) C 19 H 22 9 S = [ ] mp 119 Beil. 18(3/4)5222 NMR P.179 Ac Ac CCH 3 Ac 1g SPh M1868 Methyl 1,2,3,4-Tetra--acetyl- -D-glucuronate >96.0%(GC) C 15 H = [ ] MFCD mp 179 Beil. 18(3/4)5187 NMR P.180 M1682 Methyl 2,3,4,6-Tetra--acetyl-1-thio- -D-glucopyranoside >98.0%(GC) C 15 H 22 9 S = [ ] mp 91 Beil. 17(3/4)3729 NMR P.181 Ac Ac Ac Ac 1g 5g CCH 3 Ac Ac Ac Ac 1g 5g SCH 3 M1487 Methyl 2,3,4-Tri--benzoyl- -D-glucopyranoside >98.0%(LC) C 28 H 26 9 = [ ] MFCD mp 146 Beil. 17(3/4)3309 NMR P.182 M1488 Methyl 2,3,4-Tri--benzyl- -D-glucopyranoside >98.0%(LC) C 28 H 32 6 = [ ] MFCD mp 67 NMR P.183 Bz Bz Bn Bn 1g 5g H Bz CH3 H 1g Bn CH3 N Nitrophenyl -D-Glucopyranoside [Substrate for -D-Glucosidase] C 12 H 15 N 8 = [ ] MFCD mp 212 H H H H 1g 5g N 2 30

33 Glucose- N Nitrophenyl -D-Glucopyranoside Monohydrate [Substrate for -D-Glucosidase] >98.0%(LC) C 12 H 15 N 8 H 2 = (Anh) [ ] MFCD mp 167 H H H H 1g 5g. H 2 N 2 N Nitrophenyl -D-Glucuronide 25mg >98.0%(LC) C 12 H 13 N 9 = [ ] NMR P.184 H H CH H N 2 N Nitrophenyl -D-Glucuronide [Substrate for -Glucuronidase] >96.0%(LC) C 12 H 13 N 9 = [ ] MFCD mp 93 H H CH H 100mg N 2 New N0909 Nonyl -D-Glucopyranoside >97.0%(GC) C 15 H 30 6 = [ ] MFCD mp 70 H H H H 1g (CH 2 ) 8 CH 3 New A Ac PtdGlc(di-acyl Chain) C 49 H 92 Na 14 P = [ ] NMR P.185 H H Ac H Price on request P (CH 2 ) 16 CH 3 Na (CH 2 ) 18 CH n-ctyl -D-Glucopyranoside 1g 5g >96.0%(GC) C 14 H 28 6 = [ ] MFCD Beil. 17(5)7,38 MI H H H H (CH 2 ) 7 CH n-ctyl -D-Glucopyranoside [for Biochemical Research] >96.0%(GC) C 14 H 28 6 = [ ] MFCD Beil. 17(5)7,38 MI H H H H 1g (CH 2 ) 7 CH 3 The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 31

34 Glucose- G0225 Penta--acetyl- -D-glucopyranose >97.0%(GC) C 16 H = [ ] MFCD mp 113 Beil. 31,119 10g 25g 250g Ac Ac Ac Ac Ac P0028 Penta--acetyl- -D-glucopyranose >99.0%(GC) C 16 H = [ ] MFCD mp 132 Beil. 17(3/4) g 500g Ac Ac Ac Ac Ac P1475 Phenyl 4,6--Benzylidene-1-thio- -D-glucopyranoside >98.0%(LC) C 19 H 20 5 S = [ ] MFCD mp 185 NMR P.186 Ph H H 5g SPh P1346 Phenyl -D-Glucopyranoside >97.0%(GC) C 12 H 16 6 = [ ] MFCD mp 172 Beil. 17(5)7,45 RTECS LZ H H H 1g H Ph P0178 Phenyl -D-Glucopyranoside Hydrate 1g 10g >99.0%(GC) C 12 H 16 6 xh 2 = (Anh) [ ] MFCD mp 173 RTECS LZ H H H H Ph. xh 2 P1476 Phenyl 2,3,4,6-Tetra--acetyl-1-thio- -D-glucopyranoside >98.0%(LC) C 20 H 24 9 S = [ ] MFCD mp 118 NMR P.187 Ac Ac 5g 25g Ac Ac SPh P1736 Phenyl 2,4,6-Tri--acetyl-3--allyl- 1-thio- -D-glucopyranoside >98.0%(LC) C 21 H 26 8 S = [ ] mp 115 NMR P.188 Ac Ac Ac 1g SPh 32

35 Glucose- P0248 Phlorizin Hydrate 1g 5g >97.0%(T) C 21 H xh 2 = (Anh) [ ] MFCD Beil. 17(3/4)3042 MI RTECS UC H H H H H H. xh 2 H G0040 Potassium Gluconate 25g 500g >99.0%(T) C 6 H 11 K 7 = [ ] MFCD MI RTECS LZ H H H H CK H H H H CH 2 H New P1886 Puerarin >98.0%(LC)(T) C 21 H 20 9 = [ ] MFCD Beil. 19(4)3200 RTECS U H H 200mg 1g H H H H S0003 Salicin >98.0%(LC) C 13 H 18 7 = [ ] MFCD mp 200 Beil. 31,214 MI RTECS LZ H H H H 5g 25g CH 2 H New S0903 Sinigrin >98.0%(LC) C 10 H 16 KN 9 S 2 = [ ] MFCD MI RTECS LZ H H H H 100mg S NS 3 K S0156 Sinigrin Hydrate 100mg >98.0%(LC) C 10 H 16 KN 9 S 2 xh 2 = (Anh) [ ] MFCD mp 127 MI RTECS LZ H H H H S NS 3 K. xh 2 G0041 Sodium Gluconate >99.0%(T) C 6 H 11 Na 7 = [ ] MFCD Beil. 3(1)188 MI RTECS LZ g 500g CNa H H H H H H H H CH 2 H The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 33

36 Glucose- S0065 D-Sorbitol >97.0%(GC) C 6 H 14 6 = [ ] MFCD Beil. 1(4)2839 MI RTECS LZ g 500g CH 2 H H H H H H H H H CH 2 H New S0897 Swertiamarin >98.0%(LC) C 16 H = [ ] MFCD mp 114 MI RTECS UQ H H H H CH 2 25mg H T2449 1,2,4,6-Tetra--acetyl-3--allyl- -D-glucopyranose >98.0%(LC) C 17 H = [ ] mp 119 NMR P.189 Ac Ac Ac 1g Ac T1961 2,3,4,6-Tetra--acetyl- -D-glucopyranosyl Bromide (stabilized with CaC 3 ) >98.0%(T) C 14 H 19 Br 9 = [ ] MFCD mp 89 Beil. 17(5)6,368 MI14-60 T1995 2,3,4,6-Tetra--acetyl- -D-glucopyranosyl Fluoride >98.0%(GC) C 14 H 19 F 9 = [ ] MFCD Beil. 17(5)6,357 NMR P.190 Ac Ac Ac Ac Ac 5g Ac Br 1g Ac Ac F A5514 2,3,4,6-Tetra--acetyl- -D-glucopyranosyl Isothiocyanate [for HPLC Labeling] >98.0%(LC)(N) C 15 H 19 N 9 S = [ ] MFCD bp 116 Beil. 31,161 T2491 2,3,4,6-Tetra--acetyl- -D-glucopyranosyl 2,2,2-Trichloroacetimidate >98.0%(LC) C 16 H 20 Cl 3 N 10 = [ ] mp 158 NMR P.191 Ac Ac Ac Ac 100mg 1g Ac Ac Ac Ac NCS 1g 5g NH C CCl 3 34

37 Glucose- New P2079 2,3,4,6-Tetra--acetyl-PtdGlc (di-acyl Chain) C 61 H 114 N 17 P = [ ] NMR P.192 Ac Ac Ac Ac (CH 3 CH 2 ) 3 NH Price on request P (CH 2 ) 16 CH 3 (CH 2 ) 18 CH 3 New P2080 C 41 H 76 N 16 P = NMR P.193 2,3,4,6-Tetra--acetyl-PtdGlc (mono-acyl Chain) Ac Ac Ac Ac P (CH 2 ) 16 CH 3 H (CH 3 CH 2 ) 3 NH Price on request T2020 2,3,4,6-Tetra--benzoyl-D-glucopyranose >90.0%(LC) C 34 H = [ ] MFCD mp mg 1g Bz Bz Bz Bz H A5515 2,3,4,6-Tetra--benzoyl- -D-glucopyranosyl Isothiocyanate [for HPLC Labeling] >98.0%(LC) C 35 H 27 N 9 S = [ ] MFCD Bz Bz 100mg 1g Bz Bz NCS T1991 2,3,4,6-Tetra--benzoyl- -D-glucopyranosyl p-trifluoromethylbenzylthio- N-(p-trifluoromethylphenyl)formimidate >96.0%(LC) C 50 H 37 F 6 N 10 S = [ ] MFCD NMR P.194 Bz Bz Bz Bz 200mg 1g N CF 3 S CH 2 CF 3 T1914 2,3,4,6-Tetra--benzyl-D-glucopyranose >95.0%(LC) C 34 H 36 6 = [ ] MFCD Bn Bn 1g 5g Bn Bn H T1971 2,3,4,6-Tetra--benzyl- D-glucopyranosyl Fluoride >96.0%(LC) C 34 H 35 F 5 = [ ] MFCD mp 45 Bn Bn 500mg Bn Bn F The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 35

38 Glucose- T1922 2,3,4,6-Tetra--benzyl- -D-glucopyranosyl Fluoride >95.0%(GC) C 34 H 35 F 5 = [ ] MFCD mp 69 NMR P.195 Bn Bn 500mg Bn Bn F T1923 2,3,4,6-Tetra--benzyl- -D-glucopyranosyl Fluoride >96.0%(LC) C 34 H 35 F 5 = [ ] MFCD mp 47 NMR P.196 Bn Bn 500mg Bn Bn F T2197 2,3,4,6-Tetra--benzyl- -D-glucopyranosyl N,N,N',N'-Tetramethylphosphorodiamidate (ca. 20% in Benzene) C 38 H 47 N 2 7 P = [ ] MFCD NMR P.197 Bn Bn Bn Bn 5g P N(CH 3 ) 2 N(CH 3 ) 2 T1999 2,3,4,6-Tetra--benzyl- -D-glucopyranosyl p-trifluoromethylbenzylthio- N-(p-trifluoromethylphenyl)formimidate C 50 H 45 F 6 N 6 S = [ ] MFCD mp 123 NMR P.198 Bn Bn Bn Bn 200mg 1g N CF 3 S CH 2 CF 3 T1931 3,4,6-Tri--acetyl-2-deoxy- D-glucopyranose >98.0%(GC) C 12 H 18 8 = [ ] MFCD Ac Ac 100mg 1g Ac H T1596 Tri--acetyl-D-glucal >96.0%(GC) C 12 H 16 7 = [ ] MFCD mp 55 Beil. 17(5)5,699 5g 25g Ac Ac Ac T1933 3,4,6-Tri--benzyl-2-deoxy- D-glucopyranose >98.0%(LC) C 27 H 30 5 = [ ] MFCD Bn Bn 100mg Bn H 36

39 Glucose- T1859 Tri--benzyl-D-glucal >95.0%(LC) C 27 H 28 4 = [ ] MFCD mp 57 Beil. 17(5)5,698 1g 5g Bn Bn Bn G0277 Zinc(II) Gluconate Hydrate 25g 500g >98.0%(T) C 12 H Zn xh 2 = (Anh) [ ] MFCD Beil. 3(3)1059 RTECS ZH H H H H C H H H H Zn 2. xh 2 CH 2 H 2 The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 37

40 Glucosamine- A Acetamido-3--allyl- 4,6--benzylidene-2-deoxy- -D-glucopyranosyl Azide >98.0%(LC) C 18 H 22 N 4 5 = MFCD NMR P.199 Ph 1g N 3 NHAc A Acetamido-3--benzyl- 4,6--benzylidene-2-deoxy- -D-glucopyranosyl Azide >98.0%(LC) C 22 H 24 N 4 5 = [ ] MFCD NMR P.200 Ph Bn 1g N 3 NHAc A Acetamido-4,6--benzylidene- 2-deoxy- -D-glucopyranosyl Azide >98.0%(LC) C 15 H 18 N 4 5 = [ ] NMR P.201 Ph H 1g 5g N 3 NHAc A1614 N -(2-Acetamido-2-deoxy- -D-glucopyranosyl)- N -(tert-butoxycarbonyl)-l-asparagine >96.0%(LC) C 17 H 29 N 3 10 = [ ] MFCD mp 213 NMR P mg H H H H N CH NHBoc A Acetamido-1,3,4,6-tetra--acetyl- 2-deoxy- -D-glucopyranose >98.0%(LC) C 16 H 23 N 10 = [ ] MFCD mp 188 Beil. 18(5)11,132 Ac Ac 1g 5g Ac Ac A Acetamido-3,4,6-tri--acetyl- 2-deoxy- -D-glucopyranosyl Azide >98.0%(LC) C 14 H 20 N 4 8 = [ ] MFCD Beil. 18(5)10,575 NMR P.203 Ac Ac 1g 5g Ac N 3 A Acetamido-3,4,6-tri--acetyl- 2-deoxy- -D-glucopyranosyl Chloride >93.0%(T) C 14 H 20 ClN 8 = [ ] MFCD Beil. 18(5)10,570 Ac Ac 1g 5g Ac Cl 38

41 Glucosamine- A Acetamido-3,4,6-tri--benzyl- 2-deoxy- -D-glucopyranosyl Azide >98.0%(LC) C 29 H 32 N 4 5 = [ ] MFCD NMR P.204 Bn Bn 1g 5g Bn N 3 A1685 N -(2-Acetamido-3,4,6-tri--benzyl-2-deoxy- -D-glucopyranosyl)-N -(tert-butoxycarbonyl)- L-asparagine Benzyl Ester >97.0%(LC) C 45 H 53 N 3 10 = [ ] MFCD NMR P.205 Bn Bn H N CBn Bn 100mg NHBoc A0092 N-Acetyl-D-glucosamine >98.0%(N) C 8 H 15 N 6 = [ ] MFCD Beil. 31,170 H H 25g 500g H H A Azidoethyl 2-Acetamido-2-deoxy- -D-glucopyranoside >98.0%(LC) C 10 H 18 N 4 6 = [ ] NMR P.206 H H H 500mg N 3 B0200 N-Benzoyl-D-glucosamine 25g >98.0%(T) C 13 H 17 N 6 = [ ] MFCD H H H BzHN H G0297 N-GlcNAc-Biotin 50mg C 18 H 30 N 4 7 S = [ ] NMR P.207 H H H H N HN H S NH H G0042 D-Glucosamic Acid >98.0%(T) C 6 H 13 N 6 = [ ] MFCD H H H H 1g CH NH 2 H H H CH 2 H Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 39

42 Glucosamine- G0044 D-(+)-Glucosamine Hydrochloride >98.0%(T) C 6 H 13 N 5 HCl = [ ] MFCD Beil. 1,902 RTECS LZ H H 25g 500g H H 2 N H. HCl G0045 D-Glucosamine xime Hydrochloride >98.0%(LC)(N) C 6 H 14 N 2 5 HCl = [ ] MFCD H NH 2 H H H NH H H H CH 2 H 1g. HCl H0118 N-Hexanoyl-D-glucosamine 1g >98.0%(N) C 12 H 23 N 6 = [ ] MFCD H H H HN H C (CH 2 ) 4 CH 3 M Methoxyphenyl 4--Acetyl- 3,6-di--benzyl-2-deoxy-2-phthalimido- -D-glucopyranoside >98.0%(LC) C 37 H 35 N 9 = [ ] Ac Bn Bn N 1g 5g CH 3 M Methoxyphenyl 3--Allyl-2-azido- 4,6--benzylidene-2-deoxy- -D-glucopyranoside >98.0%(LC) C 23 H 25 N 3 6 = [ ] MFCD mp 121 NMR P.208 Ph 1g N 3 CH 3 M Methoxyphenyl 3--Allyl- 6--benzyl-2-deoxy-2-phthalimido- -D-glucopyranoside >98.0%(LC) C 31 H 31 N 8 = H Bn N 1g 5g CH 3 M Methoxyphenyl 3--Allyl- 4,6--benzylidene-2-deoxy- 2-phthalimido- -D-glucopyranoside >97.0%(LC) C 31 H 29 N 8 = [ ] mp 130 NMR P.209 Ph N 1g 5g CH 3 40

43 Glucosamine- M Methoxyphenyl 2-Amino- 3,6-di--benzyl-2-deoxy- -D-glucopyranoside H Bn Bn 1g 5g CH 3 C 27 H 31 N 6 = [ ] mp 105 NMR P.210 NH 2 M Methoxyphenyl 2-Azido- 4,6--benzylidene-2-deoxy- -D-glucopyranoside >98.0%(LC) C 20 H 21 N 3 6 = MFCD mp 165 NMR P.211 Ph H 1g 5g N 3 CH 3 M Methoxyphenyl 2-Azido- 3,6-di--benzyl-2-deoxy- -D-glucopyranoside H Bn Bn 1g CH 3 C 27 H 29 N 3 6 = [ ] NMR P.212 N 3 M Methoxyphenyl 3--Benzyl- 4,6--benzylidene-2-deoxy- 2-phthalimido- -D-glucopyranoside >98.0%(LC) C 35 H 31 N 8 = [ ] MFCD mp 133 NMR P.213 Ph Bn N 1g CH 3 M Methoxyphenyl 3--Benzyl-2-deoxy- 2-phthalimido- -D-glucopyranoside C 28 H 27 N 8 = [ ] H Bn Price on request H N CH 3 M Methoxyphenyl 4,6--Benzylidene- 2-deoxy-2-phthalimido- -D-glucopyranoside >98.0%(LC) C 28 H 25 N 8 = [ ] MFCD mp 142 NMR P.214 Ph H N 5g CH 3 M Methoxyphenyl 3,6-Di--benzyl- 2-deoxy-2-phthalimido- -D-glucopyranoside C 35 H 33 N 8 = [ ] NMR P.215 H Bn Bn N 1g CH 3 Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 41

44 Glucosamine- M Methoxyphenyl 3,4,6-Tri--acetyl- 2-deoxy-2-phthalimido- -D-glucopyranoside >98.0%(LC) C 27 H 27 N 11 = [ ] MFCD mp 149 NMR P.216 Ac Ac Ac N 5g CH 3 M1649 Methyl 3,4,6-Tri--acetyl- 2-deoxy-2-phthalimido-1-thio- -D-glucopyranoside >98.0%(LC)(N) C 21 H 23 N 9 S = [ ] mp 150 NMR P.217 Ac Ac 1g 5g Ac N SCH 3 N Nitrophenyl 2-Acetamido-2-deoxy- -D-glucopyranoside >98.0%(LC)(N) C 14 H 18 N 2 8 = [ ] MFCD mp 205 Beil. 18(5)11,102 H H H 200mg 1g N 2 P0130 Phenyl N-Acetyl- -D-glucosaminide C 14 H 19 N 6 = [ ] MFCD mp 241 H H 100mg H Ph P1762 Phenyl N-Benzyl-2-amino- 4,6--benzylidene-2-N,3--carbonyl- 2-deoxy-1-thio- -D-glucopyranoside >97.0%(LC) C 27 H 25 N 5 S = [ ] NMR P.218 Ph N 1g SPh Bn P1866 Phenyl 3,4,6-Tri--acetyl-2-deoxy-1-thio- 2-(2,2,2-trichloroethoxyformamido)- -D-glucopyranoside >98.0%(LC) C 21 H 24 Cl 3 N 9 S = [ ] MFCD mp 143 Ac Ac Ac NH 5g SPh C CH 2 CCl 3 T1732 1,3,4,6-Tetra--acetyl-2-azido- 2-deoxy- -D-glucopyranose C 14 H 19 N 3 9 = [ ] MFCD Beil. 17(5)6,400 NMR P.219 Ac Ac 100mg Ac N 3Ac 42

45 Glucosamine- T2196 1,3,4,6-Tetra--acetyl-2-azido- 2-deoxy- -D-glucopyranose >97.0%(LC) C 14 H 19 N 3 9 = [ ] mp 97 NMR P.220 Ac Ac 200mg 1g Ac N 3 Ac T2047 1,3,4,6-Tetra--acetyl-2-deoxy- 2-phthalimido- -D-glucopyranose >97.0%(LC) C 22 H 23 N 11 = [ ] mp 200 NMR P.221 Ac Ac 5g 25g Ac N Ac New T2615 3,4,6-Tri--acetyl-2-deoxy- 2-phthalimido- -D-glucopyranosyl 2,2,2-Trichloroacetimidate C 22 H 21 Cl 3 N 2 10 = [ ] MFCD mp 146 Price on request Ac Ac Ac N NH C CCl 3 T0973 N-Trifluoroacetyl-D-glucosamine >96.0%(N) C 8 H 12 F 3 N 6 = [ ] MFCD H H 1g 5g H HN H C CF 3 V0011 N-Valeryl-D-glucosamine >98.0%(N) C 11 H 21 N 6 = [ ] MFCD H H H 1g H NH C (CH 2 ) 3 CH 3 Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 43

46 Gulose D2191 G0235 (-)-2,3:4,6-Di--isopropylidene-2-keto- L-gulonic Acid Monohydrate >97.0%(T) C 12 H 18 7 H 2 = (Anh) [ ] MFCD Beil. 19(5)12,520 MI L-(+)-Gulonic Acid -Lactone >98.0%(GC) C 6 H 10 6 = [ ] MFCD mp 188 CH 3 CH 3 5g 25g H H H 25g CH CH 3 CH 3. H H 2 G0239 L-Gulose >98.0%(LC) C 6 H 12 6 = [ ] MFCD mp 132 Beil. 1(4)4334 MI g 5g 25g H H H H H 44

47 Idose I0724 I0725 D-Iditol >98.0%(LC) C 6 H 14 6 = [ ] mp 76 bp 230 Beil. 1,544 L-Iditol >98.0%(LC) C 6 H 14 6 = [ ] mp 77 Beil. 1(4) mg CH 2 H H H H H H H H H CH 2 H 200mg CH 2 H H H H H H H H H CH 2 H Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 45

48 Inositol- I0629 allo-inositol >98.0%(LC) C 6 H 12 6 = [ ] MFCD Beil. 6(4)7919 NMR P mg H H H H H H I0632 1D-chiro-Inositol >98.0%(LC) C 6 H 12 6 = [ ] MFCD Beil. 6(4)7920 NMR P mg H H H H H H I0633 1L-chiro-Inositol >98.0%(LC) C 6 H 12 6 = [ ] MFCD mp 240 Beil. 6(4)7920 NMR P mg H H H H H H I0628 epi-inositol >98.0%(LC) C 6 H 12 6 = [ ] MFCD Beil. 6(4)7919 NMR P.225 H 200mg H H H H H I0630 muco-inositol >98.0%(LC) C 6 H 12 6 = [ ] MFCD mp 286 Beil. 6(4)7920 NMR P mg H H H H H H I0040 myo-inositol >99.0%(GC) C 6 H 12 6 = [ ] MFCD mp 226 Beil. 6(2)1157 MI RTECS NM g 500g H H H H H H I0631 scyllo-inositol >98.0%(LC) C 6 H 12 6 = [ ] MFCD Beil. 6(4)7920 NMR P mg 1g H H H H H H 46

49 Inositol- I0634 1L-epi-2-Inosose >98.0%(LC) C 6 H 10 6 = [ ] MFCD NMR P.228 H 200mg H H H H P0409 Phytic Acid (ca. 50% in Water, ca. 1.1mol/L) C 6 H P 6 = [ ] MFCD MI RTECS NM g 500g P 3 H 2 H 2 3 P P 3 H 2 H 2 3 P P 3 H 2 P 3 H 2 P0410 Phytin 25g 500g [ ] MFCD MI RTECS NM Q0070 (+)-epi-quercitol >97.0%(LC) C 6 H 12 5 = [ ] MFCD NMR P.229 H 200mg H H H H Q0071 (+)-proto-quercitol >97.0%(LC) C 6 H 12 5 = [ ] MFCD mp 237 MI NMR P mg H H H H H Q0069 (-)-vibo-quercitol >98.0%(LC) C 6 H 12 5 = [ ] MFCD mp 183 NMR P mg H H H H H Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 47

50 Lyxose L0073 D-(-)-Lyxose >98.0%(LC) C 5 H 10 5 = [ ] MFCD Beil. 31,56 MI g 5g 25g H H H H L0153 L-(+)-Lyxose >98.0%(LC) C 5 H 10 5 = [ ] MFCD Beil. 1(4)4232 H 1g 5g H H H 48

51 D2024 1,2:5,6-Di--isopropylidene- D-mannitol Mannose- 5g 25g H CH 3 >95.0%(GC) C 12 H 22 6 = [ ] MFCD mp 120 Beil. 19(1)826 CH 3 CH 3 H CH 3 D2447 2,3:5,6-Di--isopropylidene- D-mannofuranose CH 3 5g >98.0%(GC) C 12 H 20 6 = [ ] MFCD mp 125 Beil. 19(5)12,5 CH 3 H I0489 3,4--Isopropylidene-D-mannitol 1g 5g >96.0%(GC) C 9 H 18 6 = [ ] MFCD mp 86 Beil. 19(5)3,653 HH 2 C H H CH 2 H CH 3 CH 3 M0044 D-Mannitol 25g 500g >99.0%(T) C 6 H 14 6 = [ ] MFCD mp 168 Beil. 1,534 MI RTECS P H H H H CH 2 H H H H H CH 2 H M1084 L-Mannitol 100mg >96.0%(GC) C 6 H 14 6 = [ ] MFCD mp 165 H H H H CH 2 H H H H H CH 2 H M0958 D-Mannono-1,4-lactone 1g 5g >95.0%(GC) C 6 H 10 6 = [ ] MFCD mp 153 Beil. 18(3/4)3018 H H H H New M2435 N -( -D-Mannopyranosyl)-L-asparagine C 10 H 18 N 2 8 = [ ] NMR P.232 H H H Price on request H H N NH 2 H Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 49

52 Mannose- M0045 D-(+)-Mannose >98.0%(GC) C 6 H 12 6 = [ ] MFCD Beil. 31,284 MI g 500g H H H H H M1308 L-(-)-Mannose 1g >98.0%(LC) C 6 H 12 6 = [ ] MFCD mp 131 Beil. 1(4)4333 H H H H H M0046 Mannose-6-phosphate Barium Salt Hydrate >85.0%(W) C 6 H 11 Ba 9 P xh 2 = (Anh) MFCD Ba 2 P H H. H xh 2 100mg H M Methoxyphenyl -D-Mannopyranoside 5g >98.0%(LC) C 13 H 18 7 = [ ] NMR P.233 H H H H CH 3 M Methoxyphenyl 2,3,4,6-Tetra--acetyl- -D-mannopyranoside >98.0%(LC) C 21 H = [ ] mp 102 NMR P.234 Ac Ac Ac Ac 5g CH 3 M2061 Methyl 2,3:4,6-Di--benzylidene- -D-mannopyranoside >98.0%(LC) C 21 H 22 6 = [ ] MFCD mp 185 Beil. 19(4)6150 Ph 5g 25g Ph CH 3 M0368 Methyl -D-Mannopyranoside >98.0%(GC) C 7 H 14 6 = [ ] MFCD mp g 250g H H H H CH 3 50

53 Mannose- M1501 Methyl 2,3,4,6-Tetra--acetyl-1-thio- -D-mannopyranoside (contains ca. 5% -isomer) >95.0%(LC) C 15 H 22 9 S = [ ] MFCD NMR P.235 Ac Ac Ac 5g Ac SCH 3 M2102 Methyl 2,3,4,6-Tetra--pivaloyl- D-mannopyranoside >97.0%(LC) C 27 H = mp 102 R R R R 1g CH 3 R= C C(CH 3 ) 3 N Nitrophenyl -D-Mannopyranoside [Substrate for -Mannosidase] >98.0%(LC) C 12 H 15 N 8 = [ ] MFCD mp 180 Beil. 17(3/4)2951 H H H H 1g N 2 P1514 1,2,3,4,6-Penta--acetyl- D-mannopyranose >97.0%(GC) C 16 H = [ ] MFCD mp 68 NMR P.236 Ac Ac Ac Ac 5g Ac P1803 1,2,3,4,6-Penta--pivaloyl- D-mannopyranose >98.0%(GC) C 31 H = [ ] mp 169 NMR P.237 R R R R 1g R R= C C(CH 3 ) 3 T1459 1,3,4,6-Tetra--acetyl- -D-mannopyranose >97.0%(GC) C 14 H = [ ] MFCD mp 162 Beil. 17(5)7,247 Ac Ac Ac 1g 5g H Ac T2567 2,3,4,6-Tetra--acetyl- D-mannopyranosyl Fluoride >95.0%(GC) C 14 H 19 F 9 = [ ] NMR P.238 Ac Ac Ac 1g 5g Ac F Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 51

54 Mannose- T2307 T2056 1,3,4,6-Tetra--acetyl- 2--(trifluoromethanesulfonyl)- -D-mannopyranose >98.0%(GC) C 15 H 19 F 3 12 S = [ ] mp 122 NMR P.239 2,3,4,6-Tetra--benzoyl- D-mannopyranose >93.0%(LC) C 34 H = [ ] MFCD mp 182 Ac Ac Ac Bz Bz Bz 100mg S 2 CF 3 Ac 1g 5g Bz H T2568 2,3,4,6-Tetra--pivaloyl- D-mannopyranosyl Fluoride >95.0%(GC) C 26 H 43 F 9 = NMR P.240 R R R R= C R 1g F C(CH 3 ) 3 52

55 Mannosamine A2160 N-Acetyl-D-mannosamine Monohydrate >98.0%(LC) C 8 H 15 N 6 H 2 = (Anh) [ ] MFCD mp 125 H H H 1g 5g NHAc. H 2 H T1733 1,3,4,6-Tetra--acetyl-2-azido- 2-deoxy- -D-mannopyranose >98.0%(LC) C 14 H 19 N 3 9 = [ ] MFCD mp 132 Beil. 17(5)6,400 NMR P mg Ac N 3 Ac Ac Ac Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 53

56 Psicose P1699 P1778 D-Psicose >98.0%(LC) C 6 H 12 6 = [ ] MFCD mp 109 Beil. 1(4)4400 MI L-Psicose >98.0%(LC) C 6 H 12 6 = [ ] mp 113 Beil. 1(4) mg 1g CH 2 H C H H H H H H CH 2 H 100mg C H H H CH 2 H H H H CH 2 H 54

57 Rhamnose R0013 L-(+)-Rhamnose Monohydrate >98.0%(LC) C 6 H 12 5 H 2 = (Anh) [ ] MFCD mp 93 Beil. 31,65 MI CH 3 H H 5g 25g H H. H 2 S0091 g-strophanthin ctahydrate 1g 5g >98.0%(E) C 29 H H 2 = (Anh) [ ] MFCD Beil. 18(3/4)3554 MI RTECS RN CH3 H H H CH H H 3 H H H H. 8H 2 H The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 55

58 Ribose- New D Deoxy-2,2-difluoro- D-erythro-pentonic Acid -Lactone 3,5-Dibenzoate Bz 1g 5g F >98.0%(LC) C 19 H 14 F 2 6 = [ ] MFCD mp 123 Bz F D Deoxy-D-ribose >98.0%(LC) C 5 H 10 4 = [ ] MFCD mp 90 MI RTECS SB g 25g CH H H H H H H CH 2 H M1965 Methyl -D-Ribofuranoside >97.0%(GC) C 6 H 12 5 = [ ] MFCD mp 78 Beil. 17(4)2491 H 1g 5g CH 3 H H A0171 Ribitol >97.0%(GC) C 5 H 12 5 = [ ] MFCD mp 102 Beil. 1,530 MI RTECS VJ H 1g 25g H H H H R0067 -D-Ribofuranose 1-Acetate 2,3,5-Tribenzoate >98.0%(LC) C 28 H 24 9 = [ ] MFCD mp 129 Beil. 17(5)6,213 Bz 5g 25g Ac Bz Bz R0080 -L-Ribofuranose 1-Acetate 2,3,5-Tribenzoate >98.0%(LC) C 28 H 24 9 = [ ] MFCD mp 130 Bz 1g Bz Bz Ac R0063 D-(+)-Ribono-1,4-lactone >95.0%(GC) C 5 H 8 5 = [ ] MFCD mp 86 Beil. 18(5)4,224 H 1g 5g H H 56

59 Ribose- R0025 D-(-)-Ribose >98.0%(GC) C 5 H 10 5 = [ ] MFCD Beil. 1(4)4214 MI RTECS VJ g 250g H H H H R0068 L-Ribose >98.0%(LC) C 5 H 10 5 = [ ] MFCD mp 90 Beil. 1(4)4214 1g 5g 25g H H H H R0082 -D-Ribose 1,5-Bis(phosphate) Tetrasodium Salt C 5 H 8 Na 4 11 P 2 = [ ] NMR P.242 Na P Na H H 5mg P Na Na R0083 C 5 H 8 Na 4 11 P 2 = NMR P.243 -D-Ribose 1,5-Bis(phosphate) Tetrasodium Salt Price on request Na P P Na Na Na H H R0026 Ribose-5-phosphate Barium Salt Hydrate >95.0%(T) C 5 H 9 Ba 8 P xh 2 = (Anh) [ ] MFCD MI mg 1g P Ba 2 H xh 2 H H R0066 Tetra--acetyl- -D-ribofuranose >98.0%(GC) C 13 H 18 9 = [ ] MFCD mp 83 Beil. 17(5)6,205 Ac 5g 25g Ac Ac Ac R0065 Tetra--acetyl- -D-ribopyranose 1g >98.0%(GC) C 13 H 18 9 = [ ] MFCD mp 110 Beil. 17(3/4)2459 Ac Ac Ac Ac The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 57

60 Ribose- T2607 1,2,3-Tri--acetyl-5-deoxy- -D-ribofuranose >97.0%(GC) C 11 H 16 7 = [ ] MFCD mp 67 Beil. 17(4)2287 5g 25g CH 3 Ac Ac Ac T2641 1,3,5-Tri--benzoyl- -D-ribofuranose >97.0%(LC) C 26 H 22 8 = [ ] MFCD mp 140 Beil. 17(4)2505 Bz 5g 25g Bz Bz H 58

61 Sialic Acids- New A2511 N-Acetyl-9-deoxy- 9-aminoneuraminic Acid Price on request H 2 N H H C 11 H 20 N 2 8 = [ ] MFCD NMR P.244 H H CH New A2492 N-Acetyl-9-deoxy- 9-fluoroneuraminic Acid F Price on request H H C 11 H 18 FN 8 = [ ] mp 167 NMR P.245 H H CH A2205 N-Acetyl-2,3-didehydro- 2-deoxyneuraminic Acid >98.0%(LC) C 11 H 17 N 8 = [ ] MFCD mp 134 H H H H 5mg CH A0639 N-Acetylneuraminic Acid Hydrate >96.0%(T) C 11 H 19 N 9 xh 2 = (Anh) [ ] MFCD MI mg 1g 5g H H H H CH H. xh 2 A1821 N-Acetylneuraminic Acid Methyl Ester 1g >95.0%(LC) C 12 H 21 N 9 = [ ] NMR P.246 H H H H H CCH 3 G0336 N-Glycolylneuraminic Acid 10mg >98.0%(LC) C 11 H 19 N 10 = [ ] MFCD HCH 2 H H H C NH H H CH M1706 Methyl 5-Acetamido-4,7,8,9-tetra--acetyl- 3,5-dideoxy-2-S-phenyl-2-thio- D-glycero-D-galacto-2-nonulopyranosylonate >96.0%(LC) C 26 H 33 N 12 S = [ ] mp 183 NMR P.247 Ac Ac Ac Ac SPh 1g CCH 3 The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 59

62 Sialic Acids- New M2319 Methyl 5-Acetamido-7,8,9-tri--acetyl-5-N, 4--carbonyl-3,5-dideoxy-2-S-phenyl-2-thio- D-glycero- -D-galacto-2-nonulopyranosylonate >96.0%(LC) C 25 H 29 N 12 S = [ ] mp 152 Ac Ac Ac N Ac 200mg 1g SPh CCH 3 New M2329 Methyl 5-N,4--Carbonyl- 3,5-dideoxy-2-S-phenyl-2-thio-D-glycero- -D-galacto-2-nonulopyranosylonate >98.0%(LC) C 17 H 21 N 8 S = [ ] NMR P.248 H Price on request H SPh H HN CCH 3 New M2330 C 23 H 27 N 11 S = NMR P.249 Methyl 7,8,9-Tri--acetyl-5-N,4--carbonyl- 3,5-dideoxy-2-S-phenyl-2-thio-D-glycero- -D-galacto-2-nonulopyranosylonate Ac Price on request Ac Ac HN SPh CCH 3 M1707 2,4,7,8,9-Penta--acetyl- N-acetylneuraminic Acid Methyl Ester Ac Price on request Ac Ac C 22 H 31 N 14 = [ ] mp 157 Ac Ac CCH 3 A1822 4,7,8,9-Tetra--acetyl- N-acetylneuraminic Acid Methyl Ester Ac Ac H 1g >90.0%(LC) C 20 H 29 N 13 = [ ] NMR P.250 Ac Ac CCH 3 60

63 Sorbose S0390 D-Sorbose >98.0%(GC) C 6 H 12 6 = [ ] MFCD Beil. 1(4)4411 H H 100mg H H CH 2 H S0066 L-(-)-Sorbose 25g >98.0%(LC) C 6 H 12 6 = [ ] MFCD mp 165 Beil. 1(4)4412 MI RTECS WG H H CH 2 H H H The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 61

64 Tagatose T1501 D-Tagatose >98.0%(GC) C 6 H 12 6 = [ ] MFCD Beil. 1(4)4414 MI RTECS WW H H 1g H H H T2535 L-Tagatose >98.0%(LC) C 6 H 12 6 = [ ] mp 131 Beil. 1(4)4415 MI mg CH 2 H C H H H H H H CH 2 H 62

65 Talose T1398 T2536 L-Talitol >98.0%(LC) C 6 H 14 6 = [ ] T0869 D-Talitol >98.0%(GC) C 6 H 14 6 = [ ] MFCD mp 88 D-(+)-Talose >98.0%(LC) C 6 H 12 6 = [ ] MFCD mp 134 Beil. 31, mg CH 2 H H H H H H 100mg CH 2 H H H H H H H H H CH 2 H H H H CH 2 H 100mg 500mg H H H H H T1767 L-(-)-Talose >98.0%(LC) C 6 H 12 6 = [ ] MFCD mp mg H H H H H The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 63

66 Xylose- D2616 1,2:3,5-Di--isopropylidene- -D-xylofuranose C 11 H 18 5 = [ ] MFCD mp 45 bp 125 /1mmHg Beil. 19(3/4)6076 CH 3 CH 3 5g CH 3 CH 3 I0721 1,2--Isopropylidene- -D-xylofuranose >98.0%(GC) C 8 H 14 5 = [ ] MFCD mp 70 Beil. 19(5)9,435 H 5g 25g H CH 3 CH 3 M1253 Methyl- -D-xylopyranoside >96.0%(GC) C 6 H 12 5 = [ ] MFCD mp 155 Beil. 17(5)6,92 H H 5g 25g CH 3 H N Nitrophenyl -D-Xylopyranoside >98.0%(LC) C 11 H 13 N 7 = [ ] MFCD mp 173 H H 100mg 2 N H N Nitrophenyl -D-Xylopyranoside [Substrate for -Xylosidase] >98.0%(LC) C 11 H 13 N 7 = [ ] MFCD mp 160 Beil. 17(3/4)2438 H H H 100mg N 2 X0018 Xylitol >98.0%(T) C 5 H 12 5 = [ ] MFCD mp 92 Beil. 1,531 MI RTECS ZF g 500g H H H CH 2 H H H H CH 2 H X0019 D-(+)-Xylose >98.0%(LC) C 5 H 10 5 = [ ] MFCD mp 151 Beil. 31,47 MI RTECS ZF g 500g H H H H 64

67 Xylose- X0021 L-(-)-Xylose >97.0%(T) C 5 H 10 5 = [ ] MFCD mp 150 Beil. 31,55 H 5g 25g H H H The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 65

68 New Disaccharides- A2630 Allolactose C 12 H = [ ] mp 168 NMR P.251 H H Price on request H H H H H H A0443 Amygdalin 1g 10g >97.0%(LC) C 20 H 27 N 11 = [ ] MFCD mp 213 Beil. 17(3/4)3614 RTECS H H H H H H H CN CH L0006 Calcium Lactobionate Hydrate 25g C 24 H 42 Ca 24 xh 2 = (Anh) [ ] MFCD H H H H H H H C H Ca 2 2. xh 2 C0056 D-(+)-Cellobiose 5g 25g >98.0%(GC) C 12 H = [ ] MFCD Beil. 31,380 MI H H H H H H H H C0861 -D-Cellobiose ctaacetate 25g >98.0%(GC) C 28 H = [ ] MFCD mp 232 Beil. 17(3/4)3589 Ac Ac Ac Ac Ac Ac Ac Ac New D4215 N,N'-Diacetylchitobiose C 16 H 28 N 2 11 = [ ] MFCD mp 247 NMR P.252 H H Price on request H H H H D3908 Diosmin 5g 25g >85.0%(LC) C 28 H = [ ] MFCD Beil. 18(4)3270 MI CH 3 H H H H H H H H CH 3 66

69 Disaccharides- G0270 Dipotassium Glycyrrhizinate Hydrate 25g >75.0%(LC) C 42 H 60 K 2 16 xh 2 = (Anh) [ ] MFCD KC H H KC H H H H H H. xh 2 CH New F0897 Fuc (1-6)GlcNAc C 14 H 25 N 10 = [ ] MFCD NMR P.253 Price on request H H H CH 3 H H H G0374 C 57 H 55 N 14 = Gal[2Ac,346Bn] (1-3)- GlcNPhth[46Bzd]- -MP Bn Bn Bn Ph Ac Price on request CH 3 N G0330 Gal[2346Ac] (1-3)GalN 3 [46Bzd]- -MP >95.0%(LC) C 34 H 39 N 3 15 = mp 193 NMR P.254 Ac Ac Ac Ac Ph N 3 1g 5g CH 3 M1694 Gal[2346Ac] (1-4)Glc[236Ac]- -MP C 33 H = [ ] Ac Ac Ac Ac Ac Price on request Ac Ac CH 3 G0309 Gal[2346Ac] (1-3)GlcN 3 [46Bzd]- -MP >98.0%(LC) C 34 H 39 N 3 15 = mp 172 NMR P.255 Ac Ac Ac Ph Ac N 3 1g 5g CH 3 G0311 Gal[2346Ac] (1-3)GlcNPhth[46Bzd]- -MP >97.0%(LC) C 42 H 43 N 17 = NMR P.256 Ac Ac Ac Ph Ac N 1g 5g CH 3 The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 67

70 Disaccharides- G0298 Galactinol Hydrate 100mg 1g >99.0%(LC) C 12 H xh 2 = (Anh) [ ] mp 221 Beil. 17(3/4)3008 H H H H H H H. xh2 H H G0379 C 58 H 59 N 13 = Gal[3All,246Bn] (1-3)GlcNPhth[6Bn]- -MP Bn Bn H Bn Price on request Bn N CH 3 M1686 Gal[26Bn] (1-4)Glc[236Bn]- -MP 1g 5g >98.0%(LC) C 54 H = [ ] mp 130 NMR P.257 H H Bn Bn Bn Bn Bn CH 3 M1726 Gal[236Bn] (1-4)Glc[236Bn]- -MP 1g 5g >92.0%(LC) C 61 H = [ ] H Bn Bn Bn Bn Bn Bn CH 3 M1727 Gal[246Bn] (1-4)Glc[236Bn]- -MP 1g >95.0%(LC) C 61 H = [ ] NMR P.258 Bn H Bn Bn Bn Bn Bn CH 3 G0375 Gal (1-3)GalNAc- -pnp 5mg >97.0%(LC) C 20 H 28 N 2 13 = [ ] MFCD mp 228 NMR P.259 H H H H H H N2 G0344 Gal (1-3)GalNAc- -pnp 5mg >98.0%(LC) C 20 H 28 N 2 13 = [ ] NMR P.260 H H H H H H N 2 68

71 Disaccharides- G0340 Gal (1-3)GalNAc- -Thr 5mg >97.0%(LC) C 18 H 32 N 2 13 = [ ] MFCD NMR P.261 H H H H H H CH 3 NH 2 H M1805 Gal (1-4)Glc- -MP 1g >96.0%(LC) C 19 H = [ ] Beil. 17(3/4)3528 H H H H H H H CH 3 New G0420 Gal (1-3)GlcNAc- -pnp C 20 H 28 N 2 13 = [ ] MFCD mp 186 NMR P.262 H H Price on request H H H N 2 H G0373 C 18 H 31 N 5 11 = NMR P.263 GalNAc (1-3)GlcNAc -Ethylazide H H H H Price on request H N 3 G0352 GalNAc (1-3)GlcNAc- -pnp >98.0%(LC) C 22 H 31 N 3 13 = NMR P.264 H H H H H 2mg N 2 G0356 GalNAc (1-4)GlcNAc- -pnp 2mg >98.0%(LC) C 22 H 31 N 3 13 = [ ] NMR P.265 H H H H H N 2 G0026 Gentiobiose 100mg >96.0%(LC) C 12 H = [ ] MFCD Beil. 31,397 MI H H H H H H H H The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 69

72 Disaccharides- G0376 GlcNAc (1-3)GalNAc- -pnp 5mg >98.0%(LC) C 22 H 31 N 3 13 = [ ] NMR P.266 H H H H H N2 G0341 GlcNAc (1-3)GalNAc- -Thr 2mg >97.0%(LC) C 20 H 35 N 3 13 = [ ] NMR P.267 H H H H H CH 3 H NH 2 G0337 GlcNAc (1-2)Man -1-Ethylazide 100mg >98.0%(LC) C 16 H 28 N 4 11 = NMR P.268 H H H H H H N 3 G0299 GlcNPhth[346Ac] (1-3)Gal[246Bn]- -MP >98.0%(LC) C 54 H 55 N 16 = mp 175 NMR P.269 Ac Ac Ac N Bn Bn 200mg 1g Bn CH 3 New G D-Glucopyranosyl- L-ascorbic Acid >98.0%(LC)(T) C 12 H = [ ] MFCD mp 160 H H H H 1g 5g H H H G0150 Glycyrrhizin 1g 25g >93.0%(T) C 42 H = [ ] MFCD Beil. 18(3/4)5156 MI RTECS MD HC H H HC H H H H H H CH H0049 Hesperidin 25g 500g >90.0%(LC)(T) C 28 H = [ ] MFCD Beil. 18(3/4)3219 MI RTECS MK CH 3 H H H H H H H H CH 3 70

73 Disaccharides- I0231 Isomaltose >97.0%(GC) C 12 H = [ ] MFCD H H H 100mg 1g H H H H H M1733 C 23 H 34 N 2 12 = NMR P.270 LacDiNAc MP Glycoside H H H H NHAc 5mg H CH 3 NHAc M1776 C 23 H 34 N 2 12 = NMR P.271 LacDiNAc(I) MP Glycoside H H H H NHAc 5mg H CH 3 NHAc L0005 Lactobionic Acid (mixture of Acid form and Lactone form) >96.0%(T) C 12 H = [ ] MFCD Beil. 31,415 MI H H H H 25g 500g H H H CH H L0008 D-(+)-Lactose Monohydrate 25g 500g >98.0%(LC) C 12 H H 2 = (Anh) [ ] MFCD Beil. 31,408 MI H H H H H H H H. H 2 L0140 Lactulose 25g >98.0%(LC) C 12 H = [ ] MFCD mp 169 MI RTECS LS H H H H H H H CH 2 H M0601 Maltitol 25g 500g >93.0%(GC) C 12 H = [ ] MFCD mp 146 Beil. 17(5)7,145 RTECS LZ H H H H H H H H H Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 71

74 Disaccharides- M0797 Maltitol 25g 500g >98.0%(GC) C 12 H = [ ] MFCD mp 151 Beil. 17(5)7,145 RTECS LZ H H H H H H H H H M0037 D-(+)-Maltose Monohydrate 25g 500g >98.0%(LC) C 12 H H 2 = (Anh) [ ] MFCD Beil. 17(3/4)3057 MI RTECS H H H H H H H H. H 2 M1138 Maltulose Monohydrate 1g >98.0%(GC) C 12 H H 2 = (Anh) [ ] MFCD mp 113 H H H H H H H. H2 H New M2442 C 58 H 55 N 14 = Man[2Bz,3All,46Bzd]- (1-4)GlcNPhth[36Bn]- -MP Ph Bz Bn Price on request Bn N CH 3 M0050 D-(+)-Melibiose Monohydrate 1g 10g C 12 H H 2 = (Anh) [ ] MFCD Beil. 31,421 MI H H H H. H2 H H H H G0151 Monoammonium Glycyrrhizinate Hydrate 1g 25g CH >75.0%(LC) C 42 H 65 N 16 xh 2 = (Anh) [ ] MFCD mp 217 RTECS LZ H H H HC H H CH H H H. NH3. xh2 N0073 Naringin Hydrate 25g >90.0%(T) C 27 H xh 2 = (Anh) [ ] MFCD Beil. 18,528 MI RTECS QN H H H H CH 3 H H H H. xh 2 72

75 Disaccharides- N0675 Neohesperidin Dihydrochalcone Hydrate >98.0%(T) C 28 H xh 2 = (Anh) [ ] MFCD MI RTECS LZ H H CH 3 H H H H H H 5g 25g CH 3 H. xh 2 New N0947 Neu5Ac (2-3)Gal- -ethylamine C 19 H 33 N 2 Na 14 = H H H H NaC Price on request H H H NH 2 New N0948 C 19 H 33 N 2 Na 14 = Neu5Ac (2-6)Gal- -ethylamine H H H H Price on request CNa H H H NH 2 N0791 Neu5Ac (2-3)Gal MP Glycoside 10mg 50mg >90.0%(LC) C 24 H 35 N 15 = [ ] NMR P.272 H H H H CH H H H CH 3 N0792 Neu5Ac (2-6)Gal MP Glycoside 10mg 50mg >98.0%(LC) C 24 H 35 N 15 = NMR P.273 H H H H CH H H CH 3 H N0890 Neu5Ac (2-6)GalNAc- -pnp 5mg >98.0%(LC) C 25 H 35 N 3 16 = NMR P.274 H H H H CH H H N 2 M1761 Neu5Ac[1Me,4789Ac]- (2-6)Gal[24Bz,3Bn]- -MP Ac Ac CCH 3 200mg >95.0%(LC) C 54 H 59 N 21 = NMR P.275 Ac Ac Bz Bn Bz CH 3 Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 73

76 Disaccharides- N0846 Neu5Ac[1Me,4789Ac]- (2-3)Gal[246Bz]- -MP >95.0%(LC) C 54 H 57 N 22 = NMR P.276 Ac Ac Ac CH 3 C Ac Bz Bz 200mg 1g Bz CH 3 M1763 Neu5GcAc[1Me,4789Ac]- (2-6)Gal[24Bz,3Bn]- -MP Ac Ac CCH 3 200mg >97.0%(LC) C 56 H 61 N 23 = NMR P.277 Ac Ac HN Ac Bz Bn Bz CH 3 N0816 C 56 H 59 N 24 = NMR P.278 Neu5GcAc[1Me,4789Ac]- (2-3)Gal[246Bz]- -MP Ac Ac Ac HN Ac Ac Bz CH 3 C Price on request Bz CH 3 Bz N0793 Neu5Gc (2-3)Gal MP Glycoside 5mg >95.0%(LC) C 24 H 35 N 16 = H H H H HN H CH H H H CH 3 N0794 Neu5Gc (2-6)Gal MP Glycoside 5mg >97.0%(LC) C 24 H 35 N 16 = [ ] H H H H HN H CH H H CH 3 H New M1729 Neu5Troc[1Me,4789Ac]- (2-3)Gal[26Bn]- -MP >98.0%(LC) C 48 H 56 Cl 3 N 20 = [ ] Cl 3 C HN Ac Ac H Ac Ac CCH 3 Bn Bn 1g CH 3 N Nitrophenyl -D-Cellobioside 100mg >98.0%(LC) C 18 H 25 N 13 = [ ] MFCD Beil. 17(4)3523 H H H H H H H N 2 74

77 Disaccharides- S0052 cta--acetyl D-(+)-Sucrose >98.0%(T) C 28 H = [ ] MFCD mp 86 MI RTECS WN g 500g Ac Ac Ac Ac Ac Ac Ac Ac P1879 Paeonolide 10mg >97.0%(LC) C 20 H = [ ] Beil. 17(4)3462 H H H H H H Ac CH 3 P1234 Palatinose Hydrate >98.0%(LC) C 12 H xh 2 = (Anh) [ ] MFCD mp 123 Beil. 17(5)7,215 MI H H H H 25g 500g H H. xh 2 H CH 2 H R0035 Rutin Trihydrate 25g >98.0%(T) C 27 H H 2 = (Anh) [ ] MFCD MI RTECS VM CH 3 H H H H H H H H. H 3H 2 H R0062 Rutinose 100mg >98.0%(LC) C 12 H = [ ] MFCD MI CH 3 H H H H H H H H0628 Rutinose Heptaacetate 1g >98.0%(GC) C 26 H = [ ] MFCD mp 168 MI CH 3 Ac Ac Ac Ac Ac Ac Ac New S0839 Sucralose >98.0%(LC) C 12 H 19 Cl 3 8 = [ ] MFCD MI RTECS LW H Cl 5g 25g H Cl H H H Cl Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 75

78 Disaccharides- S0111 T0331 D-(+)-Sucrose >98.0%(LC) C 12 H = [ ] MFCD Beil. 31,424 MI RTECS WN D-(+)-Trehalose Dihydrate >98.0%(GC) C 12 H H 2 = (Anh) [ ] MFCD Beil. 17(3/4)3505 MI RTECS LZ H H 25g 500g H H H 25g 500g H H H H H H H. 2H2 H H H H T0832 D-(+)-Trehalose Anhydrous >98.0%(GC) C 12 H = [ ] MFCD mp 205 Beil. 17(3/4)3505 MI H H H H H 1g 25g H H H G0217 Trisodium Glycyrrhizinate Hydrate 25g >75.0%(LC) C 42 H 59 Na 3 16 xh 2 = (Anh) [ ] MFCD RTECS LZ NaC H H NaC H H H H H H. xh 2 CNa T0542 D-(+)-Turanose C 12 H = [ ] MFCD Beil. 17(3/4)3092 MI H H H H H H 1g 5g H H New X0067 Xylobiose >98.0%(LC) C 10 H 18 9 = [ ] MFCD H H H 100mg 1g H H H X0065 Xylosucrose 100mg 1g >98.0%(LC) C 11 H = [ ] mp 114 Beil. 17(4)3786 H H H H H H H 76

79 Trisaccharides- New A2631 C 30 H 51 F 3 N 2 19 = NMR P.279 A Antigen PEG-trifluoroacetamide H H H CH 3 H H H H H Price on request H N CF 3 New A2485 Acarbose Hydrate >98.0%(LC)(N) C 25 H 43 N 18 xh 2 = (Anh) [ ] MFCD MI14-18 RTECS LZ H H H CH 3 N H H H H H. xh2 H H H 1g 5g H H H New B4172 C 28 H 48 F 3 N 19 = NMR P.280 B Antigen PEG-trifluoroacetamide H H H H H CH 3 H H H H Price on request H N CF 3 New C2795 Cellotriose C 18 H = [ ] MFCD mp 209 H H H H H Price on request H H H H H H New C2642 Chitotriose Trihydrochloride Hydrate >93.0%(LC) C 18 H 35 N HCl xh 2 = (Anh) [ ] mp 255 H H H H 2 N.. H 3HCl xh 2 H H 2 N H 25mg H H 2 N H D1828 Digoxin >96.0%(LC) C 41 H = [ ] MFCD Beil. 18(3/4)2453 MI RTECS IH H CH 3 H 3 100mg 1g H 3 C H H CH 3 H H H New F0895 Fuc (1-2)Gal (1-3)GalNAc- -pnp (=H type 3 -pnp Glycoside) C 26 H 38 N 2 17 = [ ] NMR P.281 CH 3 H H H H Price on request H H H H N 2 Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 77

80 Trisaccharides- New F0896 C 26 H 38 N 2 17 = Fuc (1-2)Gal (1-3)GalNAc- -pnp (=H type 3 -pnp Glycoside) H H H Price on request H H N 2 CH 3 H H H New F0894 Fuc (1-2)Gal (1-3)GlcNAc- -pnp (=H type 1 -pnp Glycoside) C 26 H 38 N 2 17 = [ ] MFCD NMR P.282 G0343 Gal (1-3)[GlcNAc (1-6)]GalNAc- -Thr C 26 H 45 N 3 18 = [ ] NMR P.283 CH 3 H H H H H H Price on request H H N 2 Price on request H H H H H H H H CH3 NH 2 H G0377 Gal (1-3)[Neu5Ac (2-6)]GalNAc- -pnp H H CH 2mg >95.0%(LC) C 31 H 45 N 3 21 = [ ] NMR P.284 H H H H H H H N 2 G0345 Gal (1-3)[Neu5Ac (2-6)]GalNAc- -pnp H H CH 5mg C 31 H 45 N 3 21 = NMR P.285 H H H H H H H N 2 G0347 Gal (1-3)[Neu5Ac (2-6)]GlcNAc- -pnp H H CH 2mg >92.0%(LC) C 31 H 45 N 3 21 = [ ] NMR P.286 H H H H H H H N 2 G0353 Gal (1-4)[Neu5Ac (2-6)]GlcNAc- -pnp H H CH 2mg >90.0%(LC) C 31 H 45 N 3 21 = NMR P.287 H H H H H H H N 2 78

81 Trisaccharides- New G0422 Ganglioside GM 3 (phyto-type) C 59 H 110 N 2 22 = [ ] NMR P.288 H H H H HC H H H Price on request H HN C 17 H 35 H H C 13 H 27 H H New G0419 Ganglioside GM 3 [d18:1, (Carbon-13)C16:0] 13 C 16 C 41 H 104 N 2 21 = NMR P.289 H H H H HC H H H Price on request H H H HN13 C 13 C 15 H 31 C 13 H 27 H New G0402 Gb 3 - -ethylamine C 20 H 37 N 16 = [ ] H H H H H Price on request H H H H H NH 2 New G0403 C 20 H 35 N 3 16 = Gb 3 - -ethylazide H H H H H Price on request H H H H H N 3 M1767 Gb 3 - -MP 100mg >95.0%(LC) C 25 H = [ ] NMR P.290 H H H H H H H H H H CH 3 New G0423 GlcNAc (1-4)[Fuc (1-6)]GlcNAc C 22 H 38 N 2 15 = [ ] NMR P.291 H H Price on request CH 3 H H H H H H G0342 GlcNAc (1-3)[GlcNAc (1-6)]- GalNAc- -Thr >94.0%(LC) C 28 H 48 N 4 18 = [ ] NMR P.292 H H H H H H H 2mg CH 3 H NH2 Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 79

82 Trisaccharides- G0378 GlcNAc (1-3)[Neu5Ac (2-6)]- GalNAc- -pnp H H CH 2mg >97.0%(LC) C 33 H 48 N 4 21 = NMR P.293 H H H H H H N 2 I0329 Isomaltotriose 100mg 1g >97.0%(LC) C 18 H = [ ] MFCD H H H H H H H H H H H K Kestose 1g >98.0%(GC) C 18 H = [ ] MFCD Beil. 17(5)8,416 H H H H H H H H H H M0677 D-(+)-Maltotriose Hydrate >98.0%(LC) C 18 H xh 2 = (Anh) [ ] MFCD H H 1g 5g H H H H H H. xh H 2 H H M0049 D-(+)-Melezitose Hydrate >99.0%(GC) C 18 H xh 2 = (Anh) [ ] MFCD mp 153 Beil. 31,466 MI H H H H H H H H H 5g 25g H. xh 2 H New N0949 C 27 H 46 N 3 Na 19 = Neu5Ac (2-3)Gal (1-4)GlcNAc- -ethylamine H H H NaC H H H H Price on request H H NH 2 New N0950 Neu5Ac (2-6)Gal (1-4)GlcNAc- -ethylamine H H CNa Price on request C 27 H 46 N 3 Na 19 = H H H H H H H NH 2 80

83 Trisaccharides- N0853 C 31 H 45 N 3 21 = NMR P.294 Neu5Ac (2-3)Gal (1-3)GlcNAc- -pnp H H H H H CH H H H Price on request H N 2 N0854 Neu5Ac (2-3)Gal (1-4)GlcNAc- -pnp >95.0%(LC) C 31 H 45 N 3 21 = [ ] NMR P.295 H H H H H CH H H H H 2mg N 2 N0855 Neu5Ac (2-6)Gal (1-3)GlcNAc- -pnp H H CH 1mg >97.0%(LC) C 31 H 45 N 3 21 = NMR P.296 H H H H H H H N 2 N0856 Neu5Ac (2-6)Gal (1-4)GlcNAc- -pnp H H CH 2mg >97.0%(LC) C 31 H 45 N 3 21 = [ ] NMR P.297 H H H H H H H N 2 N0860 Neu5Ac (2-3)Gal (1-4)Glc- -pnp 5mg >97.0%(LC) C 29 H 42 N 2 21 = NMR P.298 H H H H H CH H H H H H N 2 P0927 Panose 100mg >98.0%(LC) C 18 H = [ ] MFCD mp 223 H H H H H H H H H H H R0002 D-(+)-Raffinose Pentahydrate 25g >98.0%(LC) C 18 H H 2 = (Anh) [ ] MFCD mp 80 Beil. 31,462 MI H H H H. 5H2 H H H H H H H Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 81

84 Trisaccharides- New T2912 N,N',N''-Triacetylchitotriose C 24 H 41 N 3 16 = [ ] MFCD NMR P.299 H H H H Price on request H H H H 82

85 Tetrasaccharides- New C2796 Cellotetraose C 24 H = [ ] MFCD mp 253 H H H H H Price on request H H H 2 H H H New C2641 Chitotetraose Tetrahydrochloride Hydrate >95.0%(LC) C 24 H 46 N HCl xh 2 = (Anh) [ ] H H H H2N H H H 2N.. H 4HCl xh 2 H H 2N H 25mg H H2N H G0348 Gal (1-3)GlcNAc (1-3)Gal- (1-4)Glc- -pnp >97.0%(LC) C 32 H 48 N 2 23 = [ ] NMR P.300 H H H H H H H H H H H H 5mg N 2 G0351 Gal (1-4)GlcNAc (1-3)Gal- (1-4)Glc- -pnp C 32 H 48 N 2 23 = [ ] NMR P.301 H H H H H H H H H Price on request H H N 2 H G0380 C 32 H 48 N 2 23 = NMR P.302 GalNAc (1-3)Gal (1-3)Gal (1-4)Glc- -pnp H H H H H H H H H Price on request H H H N 2 G0354 GalNAc (1-3)Gal (1-4)Gal (1-4)Glc- -pnp >88.0%(LC) C 32 H 48 N 2 23 = [ ] NMR P.303 H H H H H H H H H H H H 5mg N 2 G0372 C 28 H 44 N 4 Na 2 25 S = NMR P.304 GlcA[3S] (1-3)Gal (1-4)GlcNAc- (1-2)Man -Ethylazide H Na 3S CNa H H Price on request H H H H H H H N 3 Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 83

86 Tetrasaccharides- H1284 Hyaluronate Tetrasaccharide C 28 H 44 N 2 23 = [ ] Beil. 18(4)7588 HC H H H H H HC H NHAc 1mg 5mg H H H H NHAc New L0237 C 34 H 57 N 7 21 = NMR P.305 LacDiNAc Dimer Ethylazide H H H H H H H Price on request H H N 3 L0229 Lac (1-4)Lac- -C 10 10mg 100mg >98.0%(LC) C 34 H = H H H H H H H H H H H H H (CH 2 ) 9 CH 3 M1022 Maltotetraose 100mg 500mg >95.0%(LC) C 24 H = [ ] MFCD H H H H 3 H H H H N0571 Nistose Trihydrate 1g >98.0%(LC) C 24 H H 2 = (Anh) [ ] MFCD Beil. 17(5)8,417 H H H H H H H H H H H. 3H 2 H H H S0397 Stachyose Hydrate 1g 5g >98.0%(LC) C 24 H xh 2 = (Anh) [ ] MFCD H H H H H H. xh2 H H H H H H H H New T2910 N,N',N'',N'''-Tetraacetylchitotetraose C 32 H 54 N 4 21 = [ ] MFCD mp 300 NMR P.306 H H H H Price on request H H 2 H H 84

87 A2122 3A-Amino-3A-deoxy-(2AS,3AS)- -cyclodextrin Hydrate ligosaccharides- 1g >90.0%(LC) C 36 H 61 N 29 xh 2 = (Anh) [ ] α-cd NH 2. xh 2 (2AS, 3AS)-α-CD A1916 3A-Amino-3A-deoxy-(2AS,3AS)- -cyclodextrin Hydrate 1g >97.0%(T) C 42 H 71 N 34 xh 2 = (Anh) [ ] β-cd NH 2. xh 2 (2AS, 3AS)-β-CD A2123 3A-Amino-3A-deoxy-(2AS,3AS)- -cyclodextrin Hydrate 1g >95.0%(LC) C 48 H 81 N 39 xh 2 = (Anh) [ ] γ-cd NH 2. xh 2 (2AS, 3AS)-γ-CD New C2644 Cellopentaose >95.0%(LC) C 30 H = [ ] MFCD H H H H H H H H 3 25mg H H H New C2762 Chitin ligosaccharides (contains N-Acetylglucosamine) 25g C0776 -Cyclodextrin 10g 25g >98.0%(LC) C 36 H = [ ] MFCD MI F&F 9,129 RTECS GU α-cd C0777 -Cyclodextrin 25g >99.0%(LC) C 42 H = [ ] MFCD MI F&F 9,129 RTECS GU β-cd Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 85

88 ligosaccharides- C0900 -Cyclodextrin 25g 500g >95.0%(LC) C 42 H = [ ] MFCD MI F&F 9,129 RTECS GU β-cd C0869 -Cyclodextrin 5g 25g >98.0%(LC) C 48 H = [ ] MFCD MI F&F 9,129 RTECS GU γ-cd New D4217 C 86 H 141 N 9 62 = NMR P.307 Disialylnonasaccharide -Ethylazide H H H H H H H H CH H H CH H H H H Price on request H H H H H H H H H H H H H NHAc H H H N3 New N0913 C 90 H 141 N 7 64 = Disialylnonasaccharide- -pnp H H CH H H H H H Price on request H H H H CH H H H H H H H H H H H H H H H H NHAc H H H N 2 D4065 Disialyloctasaccharide Price on request C 76 H 125 N 5 57 = NMR P.308 H H CH H H H H H H CH H H H H H H H H H H H H H H H H H H H H NHAc H D3690 DNS-SGN 1mg C 100 H 155 N 9 66 S = H H CH H H H H H H CH H H H H H H H H H H H H H H H H H H H NHAc H H H R R= H N NH S Me CH N Me F0584 Forssman Pentaose MP Glycoside Price on request C 41 H 64 N 2 27 = NMR P.309 H H H H H H H H H H H H H H CH 3 86

89 ligosaccharides- G0355 Gal (1-3)GalNAc (1-3)Gal- (1-4)Gal (1-4)Glc- -pnp >95.0%(LC) C 38 H 58 N 2 28 = NMR P.310 H H H H H H H H H H H H H H H 5mg N2 New G0421 Ganglioside GM 1 [d18:1, (Carbon-13)C16:0] 13 C 16 C 55 H 127 N 3 31 = NMR P.311 H H H H H H H H HC H H H H Price on request H H H 13 C HN H 13 C15H31 C 13H 27 H1041 Heptasaccharide Glc 4 Xyl 3 >95.0%(LC) C 39 H = [ ] MFCD mg Xyl Xyl Xyl α α α β β β Glc Glc Glc Glc H1044 Heptasaccharide Glc 4 Xyl 3 >90.0%(LC) C 39 H = [ ] MFCD mg Xyl Xyl Xyl α α α β β β Glc Glc Glc Glc H1333 HNK-1 Ethylazide Price on request C 34 H 54 N 4 Na 2 30 S = NMR P.312 H Na 3 S CNa H H H H H H H H H H H H N 3 H1285 Hyaluronate Hexasaccharide 1mg 5mg C 42 H 65 N 3 34 = [ ] H HC H H H H HC H NHAc 2 H H H H NHAc H0979 Hydroxypropyl- -cyclodextrin R [ ] MFCD R R 25g 100g R = 7 CH 3 CH 2 CH H n n = 0,1,2... The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 87

90 ligosaccharides- M1025 Maltoheptaose 100mg >90.0%(LC) C 42 H = MFCD H H H H H 6 H H H M1024 Maltohexaose 100mg >95.0%(LC) C 36 H = [ ] MFCD H H H H H 5 H H H M1023 Maltopentaose 100mg 1g >95.0%(LC) C 30 H = [ ] MFCD H H H H 4 H H H H M D-Maltosyl- -cyclodextrin 1g 5g >98.0%(LC) C 54 H = [ ] MFCD H H H H H H H β-cd New M2439 C 38 H 65 N 31 = NMR P.313 Man (1-2)Man (1-3)[Man (1-6)Man- (1-6)]Man (1-4)GlcNAc Price on request H H H H H H H H H H H H H H H H H H H M1356 Methyl- -cyclodextrin (mixture of several Methylated) [ ] MFCD R R R 25g 250g 7 R = H, CH 3 D1732 Methyl- -cyclodextrin (2,6-Di--methyl- and partially 2,3,6-Tri--methyl- mixture) >90.0%(LC) C 56 H = [ ] MFCD H CH 3 CH 3 1g 7 88

91 ligosaccharides- M1212 Mono-6--mesitylenesulfonyl- -cyclodextrin CH 3 1g C 57 H S = MFCD S 2 CH 3 γ-cd CH 3 M1741 Mono-2--(p-toluenesulfonyl)- -cyclodextrin 1g >97.0%(LC) C 49 H S = [ ] β-cd Ts N0693 Nonasaccharide Glc 4 Xyl 3 Gal 2 >75.0%(LC) C 51 H = [ ] MFCD mg Gal Gal β 1 β Xyl Xyl Xyl 1 α α 1 α β β Glc Glc Glc β Glc New P2027 N,N',N'',N''',N''''- Pentaacetylchitopentaose C 40 H 67 N 5 26 = [ ] MFCD mp 295 NMR P.314 H H H H Price on request H H 3 H H P0977 MFCD Poly- -cyclodextrin (Cross-linked by Epichlorohydrin) 1g 5g H H H 7 cross-linked by Epichlorohydrin S0523 Sialylglycopeptide 10mg >95.0%(LC) C 112 H 187 N 15 Na 2 70 = [ ] NMR P.315 H H H H H H H H CNa H H CNa H H H H H H H H H H H H H H H H H NHAc H H H NH 2 Lys Val Ala Asn Lys Thr CH S0849 Sialyl Lewis X-Lactose 1mg 5mg >97.0%(LC) C 43 H 72 N 2 33 = [ ] NMR P.316 H H H H H HC CH3 H H H H H H H H H H H H H The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 89

92 ligosaccharides- New S0910 Sialyl Neolactotetraosylceramide (=Sialyl nlc 4 Cer) C 73 H 131 N 3 31 = [ ] NMR P.317 H H HC H H H H H H H H H H Price on request H HN C 17 H 35 H C 13 H 27 H H T1844 Triacetyl- -cyclodextrin 25g >97.0%(LC) C 84 H = [ ] MFCD Ac Ac Ac 7 90

93 A0733 Alginic Acid Polysaccharides- 25g 500g [ ] MFCD MI RTECS AZ A0456 Amylopectin Hydrate (Amylose free), from Waxy Corn 25g 500g (C 6 H 10 5 )n xh 2 [ ] MFCD MI A0846 Amylose (Mw.=ca. 2,800) 1g [ ] MFCD MI A0847 Amylose (Mw.=ca. 15,000) 1g [ ] MFCD MI A1328 (+)-Arabinogalactan from Larch Wood 25g [(C 5 H 8 4 )(C 6 H 10 5 ) 6 ]x [ ] MFCD A0738 Calcium Alginate 25g 500g [ ] MFCD MI RTECS AZ C1805 -Carrageenan 25g 500g [ ] MFCD MI S H H S 3 n The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 91

94 Polysaccharides- C1804 -Carrageenan 25g 500g [ ] MFCD MI RTECS FI S H H H n C0072 Chitin 25g 250g (C 8 H 13 N 5 )n [ ] MFCD MI RTECS FM C2395 Chitosan (5-20mPa s, 0.5% in 0.5% Acetic Acid at 20 ) 25g 500g [ ] MFCD RTECS FM C2396 Chitosan (50-100mPa s, 0.5% in 0.5% Acetic Acid at 20 ) 25g 100g [ ] MFCD RTECS FM C0831 Chitosan ( mPa s, 0.5% in 0.5% Acetic Acid at 20 ) 25g 500g [ ] MFCD C0335 Chondroitin Sulfate Sodium Salt 25g [ ] MFCD RTECS GA D3672 Dermatan Sulfate Sodium Salt 20mg 100mg [ ] MFCD

95 Polysaccharides- D1448 Dextran 40 (Mw.=ca. 40,000) 25g 500g [ ] MFCD MI RTECS HH D1449 Dextran 70 (Mw.=ca. 70,000) 25g 500g [ ] MFCD MI RTECS HH D1776 Dextran Sulfate Sodium (from Dextran of Mw. Approx. 25,000) 25g [ ] MFCD MI RTECS HH G0331 Glucan from Black Yeast 1g 5g [ ] MFCD RTECS LZ H0393 Heparin Sodium Salt from Hog intestine 100mg 1g [ ] MFCD RTECS MI H0595 Hyaluronic Acid from Cockscomb 1g [ ] MFCD MI H CH 2 H CH H NHCCH 3 H n H0165 Hyaluronic Acid from Bovine Vitreous Humor [Substrate for Hyaluronidase] >75.0%(E) [ ] MFCD MI H Price on request CH 2 H CH H NHCCH 3 H n The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 93

96 Polysaccharides- I0041 Inulin 5g 25g (C 6 H 10 5 )n [ ] MFCD MI P0024 Pectin from Citrus 25g 500g [ ] MFCD MI H0652 Potassium Hyaluronate from Cockscomb 1g [ ] MFCD H CH 2 H CK H NHCCH 3 H n H0603 Sodium Hyaluronate from Cockscomb 100mg 1g [ ] MFCD MI RTECS MT H CH 2 H CNa H NHCCH 3 H n X0048 Xanthan Gum 25g 500g [ ] MFCD MI Z0008 Zymosan [Immunological Reagent] 100mg 1g [ ] MFCD MI RTECS ZI

97 thers- A0520 D-Araboascorbic Acid >98.0%(T) C 6 H 8 6 = [ ] MFCD MI RTECS KF g 500g H H H H A0537 L-Ascorbic Acid >99.0%(T) C 6 H 8 6 = [ ] MFCD mp 192 Beil. 18(3/4)3038 MI RTECS CI g 500g H H H H A1205 L-Ascorbyl 2,6-Dibutyrate 1g >98.0%(T) C 14 H 20 8 = [ ] MFCD mp 125 C H CH 2 CH 2 CH 3 H C CH 2 CH 2 CH 3 B1614 (-)-4,5-Bis[hydroxy(diphenyl)methyl]- 2,2-dimethyl-1,3-dioxolane 5g >97.0%(LC) C 31 H 30 4 = [ ] MFCD mp 196 H H H 3 C CH 3 C1527 Crocin (Gardenia Fruits Extract) 25g C 44 H = [ ] MFCD MI RTECS HL D2239 (+)-1,4-Di--benzyl-D-threitol 1g >98.0%(GC) C 18 H 22 4 = [ ] MFCD mp 56 H H D2240 (-)-1,4-Di--benzyl-L-threitol 1g >98.0%(GC) C 18 H 22 4 = [ ] MFCD mp 56 H H The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 95

98 thers- D0540 Digitonin C 56 H = [ ] MFCD Beil. 19(3/4)1243 MI RTECS IH CH 3 CH 3 CH H 3 H H H H H Gal Glc Xyl Gal Glc 100mg H CH 3 H H D0542 Digitoxin >98.0%(LC) C 41 H = [ ] MFCD mp 257 Beil. 18(3/4)1478 MI RTECS IH H 100mg H 3 C CH 3 H 3 C H H H H H 3 A0757 2,6-Di--palmitoyl-L-ascorbic Acid >97.0%(T) C 38 H 68 8 = [ ] MFCD mp 113 C H (CH 2 ) 14 CH 3 25g H C (CH 2 ) 14 CH 3 D1071 DL-Dithiothreitol >98.0%(T) C 4 H 10 2 S 2 = [ ] MFCD mp 43 bp 130 /2mmHg Beil. 1(3)2360 MI RTECS X g 5g 25g H HS SH H relative D1589 L-Dithiothreitol >95.0%(T) C 4 H 10 2 S 2 = [ ] MFCD mp 51 RTECS EK HS 1g 5g H SH H D1622 >95.0%(LC) C 21 H 26 8 S 2 = [ ] MFCD mp 90 CH 3 S 3 CH 2 CH 2 3 S CH 3 CH 3 CH 3 1g D1623 (+)-1,4-Di--tosyl-2,3--isopropylidene- D-threitol (-)-1,4-Di--tosyl-2,3--isopropylidene- L-threitol >95.0%(LC) C 21 H 26 8 S 2 = [ ] MFCD mp 93 CH 3 S 3 CH 2 CH 2 3 S CH 3 CH 3 CH 3 1g 5g 96

99 New E Ethyl-L-ascorbic Acid >98.0%(T) C 8 H 12 6 = [ ] MFCD mp 114 thers- 5g 25g H H CH 3 CH 2 H New New E0923 N-Ethyl-D-glucamine >98.0%(T) C 8 H 19 N 5 = [ ] MFCD mp 139 G0383 Gentamicin Sulfate [ ] MFCD RTECS LY g 250g H H H H CH 2 NHCH 2 CH 3 H H H H CH 2 H 1g 5g NHCH 3 R R H. 1 2 xh 2 S 4 CH 3 H R 1 =CH 3, R 2 =NHCH 3 H 2 N H NH 2 R 1 =CH 3, R 2 =NH 2 R 1 =H, R 2 =NH 2 H 2 N G0252 D-Glucamine 5g 25g >95.0%(T) C 6 H 15 N 5 = [ ] MFCD Beil. 4(4)1913 MI H H H H CH 2 NH 2 H H H H CH 2 H G0216 DL-Glyceraldehyde Diethyl Acetal 5g 25g >95.0%(GC) C 7 H 16 4 = [ ] MFCD bp 136 /27mmHg d 1.06 H H CH 3 CH 3 H1144 -Homonojirimycin >98.0%(LC) C 7 H 15 N 5 = [ ] MFCD mp 207 NMR P.318 H H 10mg H NH H H I0043 Invertose 25g [ ] MFCD MI The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 97

100 thers- I0406 Isomannide >97.0%(GC) C 6 H 10 4 = [ ] MFCD mp 86 bp 150 /12mmHg Beil. 19(3/4)990 H 25g H H H I0507 (+)-5,6--Isopropylidene-L-ascorbic Acid >98.0%(LC)(T) C 9 H 12 6 = [ ] MFCD Beil. 19(5)10,501 5g 25g CH 3 CH 3 H H I0376 (+)-2,3--Isopropylidene-L-threitol >97.0%(GC) C 7 H 14 4 = [ ] MFCD mp 46 Beil. 19(5)3,157 HCH 2 1g 5g CH 2 H CH 3 CH 3 I0375 (-)-2,3--Isopropylidene-D-threitol >97.0%(GC) C 7 H 14 4 = [ ] MFCD mp 50 bp 96 /0.7mmHg Beil. 19(3/4)971 HCH 2 1g 5g CH 2 H CH 3 CH 3 I0407 Isosorbide >98.0%(GC) C 6 H 10 4 = [ ] MFCD mp 61 MI RTECS LZ g 500g H H H H I0403 Isosorbide 5-Nitrate 10g >98.0%(N) C 6 H 9 N 6 = [ ] MFCD mp 92 MI RTECS LZ H H H N 2 M0227 N-Methyl-D-glucamine 25g 500g >99.0%(T) C 7 H 17 N 5 = [ ] MFCD mp 131 MI H H H H CH 2 NHCH 3 H H H H CH 2 H 98

101 thers- M0713 N-Methyl-D-glucamine Hydrochloride [for Buffer] >98.0%(T) C 7 H 17 N 5 HCl = [ ] MFCD mp 150 H H H H 5g 25g CH 2 NHCH 3 H H H H CH 2 H. HCl A Palmitoyl-L-ascorbic Acid >95.0%(T) C 22 H 38 7 = [ ] MFCD mp 114 RTECS CI C H (CH 2 ) 14 CH 3 25g H H New R0095 Rebaudioside A >98.0%(LC) C 44 H = [ ] MFCD mp 235 RTECS NZ H H H H H H H H H3C H H H H H H H 5g 25g H CH 3 CH2 S0019 Saponin 25g 250g [ ] MFCD RTECS VQ A0539 Sodium L-Ascorbate >98.0%(T) C 6 H 7 Na 6 = [ ] MFCD RTECS CI g 500g H H Na H G0214 Sodium Glucoheptonate Dihydrate >98.0%(T) C 7 H 13 Na 8 2H 2 = (Anh) [ ] MFCD g 500g CNa H H H H H H. 2H2 H H H H CH 2 H A Stearoyl-L-ascorbic Acid >95.0%(T) C 24 H 42 7 = [ ] MFCD mp 117 RTECS CI C H 5g (CH 2 ) 16 CH 3 H H The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 99

102 thers- S0585 Streptomycin Sulfate 25g 500g >95.0%(N) C 21 H 39 N / 2 H 2 S 4 = [ ] MFCD Beil. 18(5)11,82 MI RTECS WK H H NH 2 H H H NH NH H C NH NH H3C H H NH 2. NHCH 11/2 H2S4 3 S0112 Sucrose Fatty Acid Ester 25g 500g MFCD T1647 L-Threitol >98.0%(GC) C 4 H 10 4 = [ ] MFCD mp 90 Beil. 1(4)2808 H H 1g CH 2 H H H CH 2 H 100

103 Reagents for ligosaccharide Synthesis- A1668 Acetic Anhydride (ca. 1mol/L in Dichloromethane) 500ml C 4 H 6 3 = [ ] MFCD Beil. 2(4)386 MI14-56 F&F 15,1 CH 3 CH 3 A1500 Acetoxyacetyl Chloride 25g 100g >95.0%(GC)(T) C 4 H 5 Cl 3 = [ ] MFCD bp 160 d 1.27 flp 71 Beil. 3,240 CH 3 Cl B0643 Allyl Bromide 25g 500g >98.0%(GC) C 3 H 5 Br = [ ] MFCD bp 71 d 1.43 flp 12 Beil. 1,201 MI RTECS UC CH 2 Br A1247 p-anisaldehyde Dimethyl Acetal 25ml 500ml >95.0%(GC) C 10 H 14 3 = [ ] MFCD d 1.07 flp 98 Beil. 8,74 CH 3 CH CH 3 CH 3 New A Azido-3,6,9-trioxaundecanol C 8 H 17 N 3 4 = [ ] N 3 Price on request H B1197 Benzaldehyde Dimethyl Acetal 25ml 500ml >98.0%(GC) C 9 H 12 2 = [ ] MFCD bp 196 d 1.02 flp 71 Beil. 7,209 RTECS CU CH CH 3 CH 3 B0041 Benzenethiol 25ml 500ml >98.0%(GC) C 6 H 6 S = [ ] MFCD d 1.08 flp 76 Beil. 6,294 MI F&F 10,399 RTECS DC SH The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 101

104 Reagents for ligosaccharide Synthesis- B0078 Benzoic Anhydride >97.0%(GC)(T) C 14 H 10 3 = [ ] MFCD mp 42 bp 158 /1mmHg Beil. 9,164 MI F&F 5,23 25g 100g 500g C C B0105 Benzoyl Chloride >98.0%(GC)(T) C 7 H 5 Cl = [ ] MFCD bp 198 d 1.22 flp 72 Beil. 9,182 MI F&F 5,24 RTECS DM ml 500ml C Cl B0411 Benzyl Bromide (stabilized with Propylene xide) 25g 100g 500g CH 2 Br >98.0%(GC) C 7 H 7 Br = [ ] MFCD d 1.44 flp 79 Beil. 5,306 MI F&F 5,25 RTECS XS B0412 Benzyl Chloride (stabilized with -Caprolactam) >99.0%(GC) C 7 H 7 Cl = [ ] MFCD bp 179 d 1.10 flp 67 Beil. 5,292 MI RTECS XS g 500g CH 2 Cl D1356 Bis(4-hydroxyphenyl) Sulfide 25g 500g >98.0%(GC) C 12 H 10 2 S = [ ] MFCD mp 152 Beil. 6,860 RTECS SN H S H B0527 Boron Trifluoride - Ethyl Ether Complex >98.0%(W) BF 3 C 4 H 10 = [ ] MFCD bp 124 d 1.13 MI F&F 9,64 25ml 100ml 500ml BF 3. CH 3 CH 3 B0656 N-Bromosuccinimide 25g 100g 500g >98.0%(T) C 4 H 4 BrN 2 = [ ] MFCD Beil. 21(5)9,543 MI F&F 9,70 N Br 102

105 Reagents for ligosaccharide Synthesis- A5603 B0995 BSTFA [=N,-Bis(trimethylsilyl)trifluoroacetamide] [for Gas Chromatography] >95.0%(GC) C 8 H 18 F 3 NSi 2 = [ ] MFCD bp 142 flp 24 tert-butyldimethylchlorosilane [tert-butyldimethylsilylating Agent] >98.0%(GC) C 6 H 15 ClSi = [ ] MFCD mp 88 bp 125 F&F 10,62 RTECS VV CH 3 CH 3 Si CH 3 CF 3 N 5g 25g 100g CH 3 CH 3 C CH 3 5ml CH 3 Si CH 3 CH 3 CH 3 Si Cl CH 3 T1525 tert-butyldimethylsilyl Trifluoromethanesulfonate >98.0%(T) C 7 H 15 F 3 3 SSi = [ ] MFCD d 1.15 flp 36 F&F 15,54 5g 25g CH 3 CH 3 CH 3 C Si S CF 3 CH 3 CH 3 B1223 tert-butyldiphenylchlorosilane 5ml 25ml 100ml >95.0%(GC) C 16 H 19 ClSi = [ ] MFCD bp 125 /0.06mmHg d 1.07 flp 112 H 3 C F&F 6,81 H 3 C C Si Cl H 3 C C0016 ( )-10-Camphorsulfonic Acid >98.0%(T) C 10 H 16 4 S = [ ] MFCD Beil. 11,316 25g 500g CH 2 S 3 H C0015 (+)-10-Camphorsulfonic Acid 25g 500g >98.0%(T) C 10 H 16 4 S = [ ] MFCD Beil. 11,314 MI F&F 4,68 RTECS ED CH 3 CH 3 CH 2 S 3 H C0972 (-)-10-Camphorsulfonic Acid 25g 500g >98.0%(T) C 10 H 16 4 S = [ ] MFCD Beil. 11(3)585 CH 3 H 3 SCH 2 CH 3 Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 103

106 Reagents for ligosaccharide Synthesis- C0098 Chloroacetyl Chloride 25g 100g 500g >98.0%(GC)(T) C 2 H 2 Cl 2 = [ ] MFCD bp 105 d 1.42 Beil. 2,199 MI F&F 3,46 RTECS A Cl Cl C (Chloromethoxy)ethyltrimethylsilane (stabilized with Diisopropylethylamine) >95.0%(GC) C 6 H 15 ClSi = [ ] MFCD bp 59 /8mmHg d 0.95 flp 46 F&F 10,431 CH 3 5ml 25ml CH 3 Si CH 2 CH 2 CH 2 Cl CH 3 C Chloro-1-methylpyridinium Iodide 25g 500g >98.0%(T) C 6 H 7 ClIN = [ ] MFCD MI F&F 8,95 N Cl I CH 3 C0306 Chlorotrimethylsilane 25ml 100ml 500ml >98.0%(GC) C 3 H 9 ClSi = [ ] MFCD bp 57 d 0.86 flp -28 Beil. 4(3)1857 F&F 10,96 RTECS VV CH 3 CH 3 Si Cl CH 3 T1292 Copper(II) Trifluoromethanesulfonate 5g 25g >98.0%(T) C 2 CuF 6 6 S 2 = [ ] MFCD CF 3 S 2 Cu 2 B0682 Diacetyl 25ml 500ml >98.0%(GC) C 4 H 6 2 = [ ] MFCD bp 88 d 0.98 flp 11 Beil. 1,769 MI F&F 7,21 RTECS EK CH 3 CH 3 D0134 1,4-Diazabicyclo[2.2.2]octane 25g 500g >98.0%(GC)(T) C 6 H 12 N 2 = [ ] MFCD mp 155 MI F&F 7,86 RTECS HM N N 104

107 Reagents for ligosaccharide Synthesis- D1270 1,8-Diazabicyclo[5.4.0]-7-undecene >98.0%(GC)(T) C 9 H 16 N 2 = [ ] MFCD bp 128 /14mmHg d 1.02 flp 116 F&F 7,87 25g 100g 500g N N A0776 Dibenzyl Azodicarboxylate (40% in Dichloromethane, ca. 1.7mol/L) C 16 H 14 N 2 4 = [ ] MFCD CH 2 C N N C CH 2 25g D1547 Di-tert-butyl Dicarbonate [Boc-reagent for Amino Acid] >95.0%(T) C 10 H 18 5 = [ ] MFCD fp 23 flp 47 F&F 10,122 RTECS HT g 100g 500g CH 3 CH 3 CH 3 C C C C CH 3 CH 3 CH 3 D3878 Di-tert-butyl Dicarbonate (ca. 30% in Dioxane) C 10 H 18 5 = [ ] MFCD CH 3 CH 3 C CH 3 100g 500g CH 3 C C C CH 3 CH 3 D3879 Di-tert-butyl Dicarbonate (ca. 30% in Tetrahydrofuran) C 10 H 18 5 = [ ] MFCD CH 3 CH 3 C CH 3 100g 500g CH 3 C C C CH 3 CH 3 D3880 Di-tert-butyl Dicarbonate (ca. 30% in Toluene) C 10 H 18 5 = [ ] MFCD CH 3 CH 3 C CH 3 100g 500g CH 3 C C C CH 3 CH 3 D0223 Dibutyltin Dichloride >97.0%(T) C 8 H 18 Cl 2 Sn = [ ] MFCD mp 42 F&F 1,213 RTECS WH g 500g Cl CH 3 (CH 2 ) 3 Sn (CH 2 ) 3 CH 3 Cl Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 105

108 Reagents for ligosaccharide Synthesis- D0305 Dibutyltin xide 25g 500g >95.0%(W) C 8 H 18 Sn = [ ] MFCD Beil. 4(1)588 F&F 9,141 RTECS WH CH 3 (CH 2 ) 3 Sn (CH 2 ) 3 CH 3 D1070 2,3-Dichloro-5,6-dicyano- 1,4-benzoquinone >97.0%(T) C 8 Cl 2 N 2 2 = [ ] MFCD mp 214 Beil. 10,902 MI F&F 10,135 RTECS GU g 250g NC Cl NC Cl D0436 N,N'-Dicyclohexylcarbodiimide 25g 400g >98.0%(GC) C 13 H 22 N 2 = [ ] MFCD fp 34 MI F&F 10,142 RTECS FF N C N D1868 (Diethylamino)sulfur Trifluoride [Fluorinating Reagent] >90.0%(T) C 4 H 10 F 3 NS = [ ] MFCD bp 32 /10mmHg d 1.23 flp 23 MI F&F 10,142 5g 25g 100g F CH 3 CH 2 N S F CH 3 CH 2 F A0705 Diethyl Azodicarboxylate (40% in Toluene, ca. 2.2mol/L) C 6 H 10 N 2 4 = [ ] MFCD d 0.96 flp 41 Beil. 3,123 F&F 9,160 25g 100g 250g CH 2 CH 3 N N CH 3 CH 2 D2971 Diisobutylaluminum Hydride (19% in Hexane, ca. 1.0mol/L) 100ml 500ml [(CH 3 ) 2 CHCH 2 ] 2 AlH C 8 H 19 Al = [ ] MFCD flp -23 Beil. 4(4)4400 F&F 17,123 A0057 2,2-Dimethoxypropane 25ml 500ml >98.0%(GC) C 5 H 12 2 = [ ] MFCD bp 80 d 0.85 flp -9 Beil. 1,648 F&F 5,226 CH 3 CH 3 CH 3 CH 3 106

109 Reagents for ligosaccharide Synthesis- D (3-Dimethylaminopropyl)- 3-ethylcarbodiimide >98.0%(GC)(T) C 8 H 17 N 3 = [ ] MFCD bp 45 /0.3mmHg d g 25g CH 3 CH 3 CH 2 N C N (CH 2 ) 3 N CH 3 D (3-Dimethylaminopropyl)- 3-ethylcarbodiimide Hydrochloride [Coupling Agent for Peptides Synthesis] 5g 25g 250g CH 3 CH 3 CH 2 N C N (CH 2 ) 3 N CH 3. HCl >98.0%(T) C 8 H 17 N 3 HCl = [ ] MFCD mp 115 RTECS FF D Dimethylaminopyridine 25g 100g 500g >99.0%(T) C 7 H 10 N 2 = [ ] MFCD mp 110 bp 190 /150mmHg Beil. 22(2)341 MI F&F 10,155 RTECS US N CH 3 CH 3 N D2159 Dimethylthiophosphinoyl Chloride 1g 5g >97.0%(GC) C 2 H 6 ClPS = [ ] MFCD bp 78 /15mmHg d 1.22 CH 3 CH 3 S P Cl P0801 Diphenyl Phosphate 1g 25g >99.0%(LC)(T) C 12 H 11 4 P = [ ] MFCD mp 69 Beil. 6,178 RTECS TC P H C1415 Diphenylphosphinic Chloride 10g 25g >98.0%(GC)(T) C 12 H 10 ClP = [ ] MFCD bp 222 /16mmHg d 1.27 flp 26 Beil. 16(4)1038 F&F 15,150 P Cl P0231 Diphenyl Sulfone 25g 500g >99.0%(GC) C 12 H 10 2 S = [ ] MFCD mp 127 Beil. 6,300 MI RTECS SX S Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 107

110 Reagents for ligosaccharide Synthesis- D1002 Diphenyl Sulfoxide >99.0%(GC) C 12 H 10 S = [ ] MFCD mp 71 bp 198 /10mmHg Beil. 6,300 F&F 1,348 RTECS DA g 25g 100g S D2358 Diphenyltin Sulfide [Activator for -Glycoside Synthesis] 1g >97.0%(W) C 12 H 10 SSn = [ ] MFCD mp 185 Sn S E0077 Ethylenediamine Anhydrous >98.0%(GC)(T) C 2 H 8 N 2 = [ ] MFCD fp 10 bp 116 d 0.90 flp 34 Beil. 4,230 MI F&F 4,231 RTECS KH ml 500ml H 2 N NH 2 E0081 Ethylenediamine Monohydrate >98.0%(T) C 2 H 8 N 2 H 2 = 60.10(Anh) [ ] MFCD bp 118 d 0.96 Beil. 4,230 MI F&F 4,231 25ml 500ml H 2 N NH 2. H 2 F0516 N -[(9H-Fluoren-9-ylmethoxy)carbonyl]- L-serine tert-butyl Ester 1g 5g >98.0%(LC)(N) C 22 H 25 N 5 = [ ] mp 127 H HN Fmoc C(CH 3 ) 3 F0517 N -[(9H-Fluoren-9-ylmethoxy)carbonyl]- L-threonine tert-butyl Ester H 1g 5g >98.0%(LC)(N) C 23 H 27 N 5 = [ ] mp 100 CH 3 HN Fmoc C(CH 3 ) 3 F0341 Fluoromethyl Phenyl Sulfone 1g 5g >97.0%(GC) C 7 H 7 F 2 S = [ ] MFCD mp 53 S 2 CH 2 F 108

111 Reagents for ligosaccharide Synthesis- H0914 Hafnocene Dichloride 1g 5g 25g >98.0%(T) C 10 H 10 Cl 2 Hf = [ ] MFCD F&F 16,120 RTECS MG Cl Hf Cl H0989 Hexyldimethyloctylammonium Bromide 5g 25g >97.0%(T) C 16 H 36 BrN = [ ] MFCD CH 3 (CH 2 ) 7 N CH 3 CH 3 (CH 2 ) 5 CH 3 Br H0172 Hydrazine Monohydrate >98.0%(T) H 4 N 2 H 2 = 32.05(Anh) [ ] MFCD d 1.03 flp 75 MI F&F 9,236 RTECS MV ml 500ml H 2 NNH 2. H 2 H0204 Hydrazine Monohydrate (79%) H 4 N 2 H 2 = 32.05(Anh) [ ] MFCD d 1.03 flp 75 MI F&F 9,236 RTECS MV g 500g H 2 NNH 2. H 2 H1112 Hydrazine Acetate >98.0%(T) H 4 N 2 C 2 H 4 2 = [ ] mp 101 Beil. 2,107 F&F 1,445 5g 25g H 2 NNH 2. CH 3 C H H0182 Hydrogen Bromide (30% in Acetic Acid, ca. 5.1mol/L) [for Peptide research] 25g 500g HBr HBr = [ ] MFCD d 1.40 MI H Hydroxybenzotriazole Monohydrate 25g 200g 500g >97.0%(T) C 6 H 5 N 3 H 2 = (Anh) [ ] MFCD mp 160 Beil. 26,41 F&F 6,288 RTECS DM N N N H. H2 Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 109

112 Reagents for ligosaccharide Synthesis- I0001 Imidazole >98.0%(T) C 3 H 4 N 2 = [ ] MFCD mp 90 Beil. 23(3/4)564 MI F&F 2,220 RTECS NI g 100g 500g N H N I0060 Iodomethane (stabilized with Copper chip) >99.5%(GC) CH 3 I = [ ] MFCD bp 43 d 2.28 Beil. 1,69 MI F&F 9,308 RTECS PA ml 100ml 300ml CH 3 I I0074 N-Iodosuccinimide 5g 25g 100g >98.0%(T) C 4 H 4 IN 2 = [ ] MFCD Beil. 21(3/4)4576 MI RTECS WN N I L0042 Levulinic Acid >97.0%(GC)(T) C 5 H 8 3 = [ ] MFCD fp 29 Beil. 3,671 MI F&F 10,230 RTECS I g 500g CH 3 H L0063 2,3-Lutidine 25ml 500ml >98.0%(GC)(T) C 7 H 9 N = [ ] MFCD bp 161 d 0.95 flp 50 Beil. 20(3/4)2765 N CH 3 CH 3 L0085 2,4-Lutidine 25ml 500ml >95.0%(GC) C 7 H 9 N = [ ] MFCD bp 157 d 0.93 flp 37 Beil. 20(3/4)2768 F&F 6,224 RTECS K CH 3 N CH 3 L0065 2,5-Lutidine 5ml 25ml 500ml >98.0%(GC) C 7 H 9 N = [ ] MFCD bp 157 d 0.93 flp 48 Beil. 20(3/4)2774 RTECS K CH 3 N CH 3 110

113 Reagents for ligosaccharide Synthesis- L0067 2,6-Lutidine 25ml 500ml >98.0%(GC) C 7 H 9 N = [ ] MFCD bp 144 d 0.92 flp 33 Beil. 20(3/4)2776 MI F&F 1,626 RTECS K CH 3 N CH 3 L0066 3,4-Lutidine 25ml 500ml >98.0%(GC) C 7 H 9 N = [ ] MFCD bp 179 d 0.96 flp 61 Beil. 20(3/4)2787 RTECS K CH 3 CH 3 N L0068 3,5-Lutidine 25ml 500ml >98.0%(GC) C 7 H 9 N = [ ] MFCD bp 172 d 0.94 flp 47 Beil. 20(3/4)2788 CH 3 CH 3 N M Methoxybenzyl Chloride (stabilized with Amylene) 25ml CH 2 Cl >98.0%(GC)(T) C 8 H 9 Cl = [ ] MFCD bp 127 /24mmHg d 1.15 flp 109 Beil. 6(4)2137 F&F 1,668 CH 3 M1264 Methoxymethyltrimethylsilane 5ml >95.0%(GC) C 5 H 14 Si = [ ] MFCD bp 85 d 0.76 flp -5 Beil. 4(3)1844 CH 3 CH 3 Si CH 2 CH 3 CH 3 M Methoxyphenol >99.0%(GC) C 7 H 8 2 = [ ] MFCD mp 57 bp 243 Beil. 6,843 RTECS SL g 500g H CH 3 M0137 Methylamine (ca. 40% in Water, ca. 12mol/L) 25ml 500ml CH 5 N = [ ] MFCD d 0.90 flp -10 RTECS PF CH 3 NH 2 Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 111

114 Reagents for ligosaccharide Synthesis- M0558 Methylhydrazine 25ml 100ml >98.0%(GC) CH 6 N 2 = [ ] MFCD bp 87 d 0.87 Beil. 4(2)957 MI F&F 4,340 RTECS MV H 2 NNHCH 3 M1494 Methyl Tributylstannyl Sulfide 25g 100g >98.0%(W) C 13 H 30 SSn = [ ] d 1.16 CH 3 (CH 2 ) 3 (CH 2 ) 3 CH 3 Sn SCH 3 (CH 2 ) 3 CH 3 T0680 Methyl Trifluoroacetate 25g 500g >98.0%(GC) C 3 H 3 F 3 2 = [ ] MFCD bp 43 d 1.29 flp -20 Beil. 2(4)463 CF 3 CH 3 M1573 Morpholinosulfur Trifluoride 1g 5g >93.0%(T) C 4 H 8 F 3 NS = [ ] MFCD bp 42 /0.5mmHg flp 76 SF 3 N N Nitrobenzoic Acid 25g 500g >90.0%(GC) C 7 H 5 N 4 = [ ] MFCD mp 144 Beil. 9,370 MI RTECS DH C H N 2 T2669 Tetrabutylammonium p-nitrophenoxide 5g 25g >98.0%(LC)(T) C 22 H 40 N 2 3 = [ ] mp 145 RTECS CH 3 (CH 2 ) 3 (CH 2 ) 3 CH 3 N (CH 2 ) 3 CH 3 (CH 2 ) 3 CH 3 N 2 M0450 Trichloro(methyl)silane 25g 500g >98.0%(GC)(T) CH 3 Cl 3 Si = [ ] MFCD bp 65 d 1.28 flp -8 Beil. 4(3)1896 RTECS VV CH 3 Cl Si Cl Cl 112

115 Applications for Sugar-conjugates New Through the research in carbohydrate field, various biological functions of oligosaccharides have been elucidated in life phenomena such as infection, cell-cell recognition, information transmission, fertilization and cell division. The materials containing sugar chains are expected as new functional bioengineering materials which can be applied to medical materials, for example biosensors which specifically bind to toxins or pathogens, composite materials used for surface plasmon resonance (SPR) or crystal oscillator (QCM), or affinity chromatography for the purification of various biopolymers. Sugar chains having a thiol group, carboxyl group, amino group or azido group at the reducing terminal can be applied to immobilization onto resin beads and gold substrates, introduction of fluorescent groups or biotin, or the use of click chemistry as shown below. Sugar-conjugates are expected as important tools for new bioengineering building materials. Surface Plasmon Resonance (SPR) Biotin H H H H H H H H H R H R= NH2 (G0402) / N3 (G0403) H H H H H R H H H R= NHTFAc (A2631) / NH2 Beads / Resins H H HC H H H H H R H H R= NH2 (N0949) / SH HN / HN C CH Click Chemistry Fluorecent Groups H H HC H H H H CH H H H H H H H H H H H H H H H H H CH H H H H H H H H H H D4217 H H H H H G0422 H H N 3 HN C 17H 35 H C 13H 27 H Sugar derivatives applied to sugar-conjugates. Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 113

116 Glycosynthase (Endo-M-N175Q)- New G0365 Glycosynthase (Endo-M-N175Q) is an enzyme developed by Yamamoto, Umekawa, et al. through site-directed mutation of areas around the active center of A1651 Endo-M 1) which is already marketed. Since the feature of Glycosynthase is efficient transglycosylation activity by using oxazoline derivatives as glycosyl donors while suppressing sugar hydrolysis activity, the resulting glycosylated products are obtained in high yield with less digestion of the products by the enzyme. Due to this feature Glycosynthase is expected to be applied as useful tool in glycotechnology. Umekawa and her colleagues caused transglycosylation reactions at the GlcNAc site of sperm antigen CD52 using oxazoline derivatives of the high-mannose type sugar chains or the complex type sugar chains as glycosyl donors 2). They succeeded in obtaining glycosylated products in high yield of 84% and 76%, respectively. Moreover, they also achieved transglycosylation reactions using two biologically active blood-pressure-lowing peptides, PAMP12 and Substance P, as glycosyl acceptors and the oxazoline derivative of a complex type sugar chain containing sialic acids as a glycosyl donor in 95% and 98% yield, respectively 3). The articles in 2009 describe the advantages of this glycosylation method using sugar-oxazoline derivatives 4-5). Practical realization of efficient transglycosylation reactions would also be useful for expansion into glycoprotein synthesis, such as the area of biosimilars, and creation of new functional sugar complexes can be expected. References 1) K. Yamamoto, S. Kadowaki, J. Watanabe, H. Kumagai, Biochem. Biophys. Res. Commun. 1994, 203, ) M. Umekawa, C. Li, T. Higashiyama, W. Huang, H. Ashida, K. Yamamoto, L-X. Wang, J. Biol. Chem. 2010, 285, ) M. Umekawa, T. Higashiyama, T. Tanaka, M. Noguchi, A. Kobayashi, S. Shoda, W. Huang, L-X. Wang, H. Ashida, K. Yamamoto, Biochimica et Biophysica Acta 2010, 1800, ) P. Bojarova, V. Kren, Trends in Biotechnology 2001, 92, ) J. R. Rich, S. G. Withers, Nature Chemical Biology 2009, 5,

117 Glycosynthase (Endo-M-N175Q)- A set of the transglycosylation data u sing a glycosynthase (Endo-M-N175Q) is shown below (Fig. 3). The oxazoline derivative of a complex type sugar as a glycosyl donor was transglycosylated with GlcNAc-β-pNP as a glycosyl acceptor, and the glycosylated product was afforded in a high yield of 95% after 24 hours. The sustained and effective production of the glycosylated compound was identifi ed from HPLC profi les and MALDI-TF MS as shown below (Fig. 4 and 5). H H CNa H H H H H H H H H H H H H H CNa H H H H H H H H H H H oxazoline derivative of a complex type sugar H N H H H N 2 GlcNAc-β-pNP (N0866) Endo-M-N175Q (G0365) H H CNa H H H H H H H H H H H H H H CNa H H H H H H H H H H Fig. 3 Transglycosylation of oxazoline derivative and GlcNAc-β-pNP H H glycosylated product H H N2 Fig. 4 HPLC profi les of transglycosylation reaction. HPLC: DS, CH 3 CN / H 2, UV 260nm : GlcNAc-β-pNP : glycosylated product Mass/Charge Fig. 5 MALDI-TF MS spectrum of transglycosyled product. Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 115

118 Endo-M Man GlcNAc glycoprotein Endo-M A1651 GlcNAc Protein Hydrolysis Man Man GlcNAc + GlcNAc GlcNAc -R + GlcNAc Protein Protein H R transglycosylation product acceptor Transglycosylation A1651 Endo-M is one of the enzymes called endo-β- N-acetylglucosaminidases (endo-β-glcnac-ases). This enzyme was found by Yamamoto et al., in the culture fluid of Mucor hiemalis isolated from soil 1). Endo-M hydrolyzes N,N'-diacetylchitobiose moiety in oligosaccharides bound to the asparaginyl residue of various glycoproteins through N-glycosidic linkage. The efficacy of this enzyme comes from the fact that one N-acetylglucosamine residue remains bound to the protein while cleaving the N,N'-diacetylchitobiose moiety. The enzyme is thus able to transfer the intact oligosaccharide to suitable acceptors (Fig.1). Haneda et al. have transferred oligosaccharides to 9-flu orenylmethoxycarbonyl-asparaginyl-n - acetylglucosaminide [Fmoc-Asn(GlcNAc)] by incubating sialotransferrin glycopeptide, asialotransferrin glycopeptide and Man 6 GlcNAc 2 -Asn-peptide with Endo-M 2). Furthermore, synthetic hcg (β12-16)- GlcNAc-peptide has been subjected to transglycosylate of sialo complex type oligosaccharide. An alternative synthetic method of peptide containing GlcNAc has been developed by Inazu et al 3). This method uses Fmoc-Asn(GlcNAc), which is synthesized from N- Fmoc aspartic acid (Fmoc-Asp-H) and azide of GlcNAc, instead of Fmoc-Asn-H, and it is applied to a mixed acid anhydride method using dimethylphosphothioic acid (Mpt-MA) which generally shows poor responses toward hydroxyl group. By combining this method with Endo-M, many glycopeptides can be designed and easily prepared. Yamamoto has compiled the outline of this methodology as the Chemo-Enzymatic Synthesis in his review 4). Endo-M can also be used to create new functions, by introducing oligosaccharides, to the substances that originally do not have the oligosaccharide 5). Unlike the conventional endo-β-glcnac-ase, it has been found that Endo-M is an enzyme with a broad substrate specificity, cleaving not only the high mannose type and hybrid type of asparagine-linked oligosaccharides but also the complex type oligosaccharides in glycoproteins. Especially, the transglycosylation reaction of sialo complex type oligosaccharides was possible only by using Endo-M. Therefore, Endo-M is expected to be applied to various fields. Mucor hiemalis β N N N β N β This Endo-M was merchandised as the fruition of NED project under licenses from patent-holding companies of Takara Bio Inc. and Kirin Brewery Co., LTD. References 1) S. Kadowaki, K. Yamamoto, M. Fujisaki, K. Izumi, T. Tochikura, T. Yokoyama, Agric. Biol. Chem. 1988, 54, 97; K. Yamamoto, S. Kadowaki, J. Watanabe, H. Kumagai, Biochem. Biophys. Res. Commun. 1994, 203, ) K. Haneda, T. Inazu, K. Yamamoto, H. Kumagai, Y. Nakahara, A. Kobata, Carbohydr. Res. 1996, 292, 61. 3) M. Mizuno, I. Muramoto, T. Kawakami, M. Seike, S. Aimoto, K. Haneda, T. Inazu, Tetrahedron Lett. 1998, 39, 55. 4) K. Yamamoto, J. Biosci. Bioeng. 2001, 92, ) S. Kojima, T. Hasegawa, T. Yonemura, K. Sasaki, K. Yamamoto, Y. Makimura, T. Takahashi, T. Suzuki, Y. Suzuki, K. Kobayashi, Chem. Commun. 2003, ) T. nozawa, J. Kumada, Trends in Glycoscience and Glycotechnology, 2003, 15,

119 Endo- α H H H H H H Endo- A1844 H H H H H H H + H Donor Acceptor Acceptor : compounds possessing hydroxyl groups e.g. monosaccharides, peptides, proteins, etc. Yamamoto et al. have purified and isolated A1844 endoα-n-acetylgalactosaminidase (Endo-α) found in the culture fluid of Bifidobacterium longum 1). Endo-α can recognize the structure of the Galβ1-3GalNAc disaccharide α-linked with a hydroxyl group. It releases Galβ1-3GalNAc by hydrolysis. When a compound possessing a hydroxyl group coexists as an acceptor, the released Galβ1-3GalNAc is transferred to the acceptor 2). Discovered by Yamamoto et al., Endo-α can transfer Galβ1-3GalNAc to various compounds such as monosaccharides, peptides, and proteins, using core 1 contained in mucin-type oligosaccharide chains as a donor. As a tool for the enzymatic synthesis of glycoconjugates, it is expected that many applications for Endo-α will be found in a wide range of fields. (Bifidobacterium longum) α N α α β α β β α β This Endo-α was merchandised as the fruition of NED project. References 1) K. Fujita, F. ura, N. Nagamine, T. Katayama, J. Hiratake, K. Sakata, H. Kumagai, K. Yamamoto, J. Biol. Chem. 2005, 280, ) H. Ashida, K. Yamamoto, T. Murata, T. Usui, H. Kumagai, Arch. Biochem.Biophys. 2000, 373, 394; T. Katayama, K. Fujita, K. Yamamoto, J. Biosci. Bioeng. 2005, 99, 457. This product is not available for purchase in the U.S. Chemicals itemized in our catalog are for testing or research purpose only. Therefore, please note those chemicals are not guaranteed in the user's favor relating to various problems under the Patent Law that might occur through their use. 117

120 Glycohydrolase- A1844 endo- -N-Acetylgalactosaminidase(=Endo- ) Recombinant: from Bifidobacterium longum expressed in Escherichia coli 100munits [ ] MFCD EC A1651 endo- -N-Acetylglucosaminidase(=Endo-M) Recombinant: from Mucor hiemalis expressed in Candida boidinii [Purity: single band by SDS-PAGE(85KDa)] 100munits [ ] MFCD EC A0447 -Amylase diluted with Starch, from Bacillus subtilis 25g 500g [ ] MFCD EC MI RTECS BU A0448 -Amylase from Soybean 25g [ ] MFCD EC MI RTECS BU C0057 Cellulase from Aspergillus niger 1g 5g 25g [ ] MFCD EC RTECS FJ M0035 Glucoamylase from Rhizopus (contains 50% Diatomaceous earth) 25g [ ] MFCD EC G0050 Glucose xidase from Aspergillus niger 1g [ ] MFCD EC MI RTECS RQ

121 G0035 -Glucosidase from Almonds Glycohydrolase- 100mg [ ] MFCD EC G0365 Glycosynthase (Endo-M-N175Q) Recombinant: from Mucor hiemalis expressed in Escherichia coli 100munits [ ] MFCD EC P0026 Pectinase from Aspergillus niger 25g [ ] MFCD EC The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 119

122 Lectin, Fucose Specific Lectins recognize oligosaccharides and specifically well reversibly binded ones. Thus, lectins are widely utilized in cell biology related fields such as blood-type studies and binding studies of oligosaccharides to cancer cell surfaces, and many other important studies 1). Lectins are widely distributed in nature and found from almost all types of living beings organisms like plants, microorganisms, fungus, invertebrates, vertebrates and viruses. The product introduced today is a new-type of lectin isolated from Aspergillus oryzae in Japanese sake fermentation. This lectin has proven to have a strong affinity toward L-fucose according to the results of hemagglutination inhibition assay 2). The fucose bonding position shows the highest binding for oligosaccharides are the ones containing L-Fucα1,6 and α1,2. Fucosyl residues α1,3 and α1,4 also possess the specificity. The molecular weight of L-fucose specific lectin subunit, a dimeric substance, showed 35,000 (Fig. 1). This lectin shows 26% similarity to lectine isolated from Aleuria aurantia 2), and its substrate specificity is also thought to be relatively similar. Generally, lectins have been applied for the detection and the analysis of complex-type oligosaccharides as they can specifically recognize oligosaccharides. Especially, the ones with fucose typically possess physiological properties. Therefore, these lectins are often used for such purposes. For example, fucosylated oligosaccharides are known to participate in the life processes such as embryonic growth, differentiation, cell recognition, canceration, and inflammation. When in-vivo transformations of the fucose to oligosaccharides take place, such reactions are recognized as important indications of the antigen epitopes for the Lewis blood-type and cancer related carbohydrate antigens 3). The Aspergillus oryzae fucose specific lectin is not only utilized as an analyzing tool for the sugarbinding specificity of complex-type oligosaccharides, but it is highly applicable for a wide spectrum of studies on oligosaccharides 4). Aspergillus oryzae α α α α Fig.1. SDS-PAGE L : 0.25mg/ml 5 l CBB Staining pure grade : single band Gel : Gradient subunit Mr : This lectin was merchandised under the technical tie-up with GEKKEIKAN SAKE CMPANY, LTD. L0169 Lectin, Fucose specific from Aspergillus oryzae (5mg/mL, PBS ph6.5) 1ml MFCD References 1) N. Sharon, H. Lis, Lectins (Japanese translation), Japan Scientific Societies Press: Tokyo, ) Molecular cloning and overexpression of flea gene encoding a fucose-specific lectin of Aspergillus oryzae H. Ishida, T. Moritani, Y. Hata, A. Kawato, K. Suginami, Y. Abe, S. Imayasu, Biosci. Biotechnol. Biochem. 2002, 66(5), ) H. Narimatsu, Tanpakushitsu Kakusan Koso 1998, 43(16), ) A. Kuno, Y. Kato, A. Matsuda, M. K. Kaneko, H. Ito, K. Amano, Y. Chiba, H. Narimatsu, J. Hirabayashi, Mol. Cell. Proteomics 2009, 8,

123 Anti-Glyco Antibodies New Carbohydrate chains are called the third life chain following the protein and the nucleic acid and are one of the most important issues in the post genome research. Tokyo Chemical Industry Co. LTD. (TCI) supports glycoscience research by providing useful anti-carbohydrate chain antibodies. Most carbohydrate chains attach to lipids or proteins and occur in the form of glycoproteins or glycolipids (N-glycan, -glycan, proteoglycans and others). Carbohydrate chains are known to be expressed on brain, nerve, cancer, and endothelial cells. Some carbohydrate chains are known to relate to diseases (e.g., cancer, Alzheimer's disease, Guillain-Barré syndrome, Lysosome syndrome such as Fabry disease, gangliosidosis), differentiation and development (ips/es cells). Antibodies are proteins which are one of the components of the immune system. The specificity of antibodies is likened to the interaction between a key and a keyhole. Antibodies are useful reagents for research in many scientific disciplines including life science and diagnostic reagents. Anti-carbohydrate antibodies can recognize glycolipids or glycoproteins. TCI mainly produces antibodies against glycolipids; ganglio series, globo series, lacto series, and neo-lacto series. These antibodies can be used for immunohistochemistry, cell-staining, inhibition assay for cell adhesion, flow cytometry, ELISA, TLC-immunostaining and other methods. TCI antibodies are very useful tools for analyzing the expression of carbohydrate chains and their functions. Labeled anti-carbohydrate chain antibodies will also be available soon. ELISA, Cell ELISA Western blotting TLC-immunostaining The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 121

124 Anti-Glyco Antibodies- New A2506 Anti-Gb 3 Monoclonal Antibody Price on request New A2586 Anti-Gb 3 Monoclonal Antibody (Culture Supernatant) Price on request New A2507 Anti-GD 1a Monoclonal Antibody 1vial New A2508 Anti-GD 1b Monoclonal Antibody 1vial New A2580 Anti-GD 3 Monoclonal Antibody Price on request New A2579 Anti-GD 3 Monoclonal Antibody (Culture Supernatant) Price on request New A2505 Anti-GM 1 Monoclonal Antibody 1vial 122

125 Anti-Glyco Antibodies- New A2576 Anti-GM 2 Monoclonal Antibody Price on request New A2575 Anti-GM 2 Monoclonal Antibody (Culture Supernatant) Price on request New A2582 Anti-GM 3 Monoclonal Antibody Price on request New A2581 Anti-GM 3 Monoclonal Antibody (Culture Supernatant) Price on request New A2578 Anti-Lewis X Monoclonal Antibody Price on request New A2577 Anti-Lewis X Monoclonal Antibody (Culture Supernatant) Price on request New A2510 Anti-Lewis Y Monoclonal Antibody Price on request The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 123

126 Anti-Glyco Antibodies- New A2587 Anti-Lewis Y Monoclonal Antibody (Culture Supernatant) Price on request New A2509 Anti-Sialyl Lewis A Monoclonal Antibody (2D3) 1vial New A2584 Anti-Sialyl Lewis A Monoclonal Antibody (1H4) Price on request New A2583 Anti-Sialyl Lewis A Monoclonal Antibody (1H4) (Culture Supernatant) Price on request 124

127 Secondary Antibodies New G0406 Goat Anti-Mouse IgG FITC Conjugate Price on request New G0407 Goat Anti-Mouse IgG HRP Conjugate Price on request New G0408 Goat Anti-Mouse IgM Price on request New G0417 Goat Anti-Mouse IgM HRP Conjugate Price on request New G0418 Goat Anti-Rabbit IgG HRP Conjugate Price on request The chemical, physical and toxicological properties of the new chemicals have not been thoroughly investigated. Please handle with care. 125

128 126

129 NMR Data 183 main Glyco products among our glycochemistry-related products show 1 H NMR spectrum. 127

130 NMR Data Index Ph H Layout of the Index 211 M1637 N 3 CH 3 Page Product Number Structural Formula 136 T M M1628 Arabinose Ac Ac Ac NH C CCl 3 Fucose CH 3 Ac Ac SCH 3 Ac CH 3 Bn Bn SCH 3 Bn 139 M M M M1482 Galactose & Galactosamine Ph Bn CH 3 Ph H CH 3 Ph CH3 CH3 H H H CH3 143 M M M M M1633 H Bn H H CH 3 Ph H H CH 3 H H CH3 CH 3 CH3 H H Bn Bn CH3 CH 3 CH3 Bn Bn CH3 148 M M M M M1477 H H H H CH3 CH 3 CH 3 CH3 CH 3 CH3 CH3 CH 3 H H CH3 CH 3 CH 3 H CH3 CH3 Ac Ac Ac Ac CH3 153 M M M P P1477 Bn Bn Bn Bn CH3 Bn H Bn Bn CH3 H Bz Bz Bz CH3 Bn Bn Bn Ac SPh Ac Ac Ac Ac SPh 158 P P T A A1832 Ph Ph Bn Bn Bn Bn SPh Ac Ac Ac SPh Ac Ac Ac Ac NH C CCl 3 H N 3 HN Fmoc C(CH3) 3 H N 3 CH 3 C(CH 3) 3 HN Fmoc 163 A M P P T1731 H H H N 3 Ph N 3 CH 3 H H H NH SPh C CH 2 CCl 3 Ac Ac Ac NH SPh C CH 2 CCl 3 Ac Ac Ac N 3Ac 128

131 168 A A B B4171 Glucose & Glucosamine H H H H Ac CH 3 Ac Ac Ac Ac N 3 Ph Bn Bn Bn Bn Bn H Bn Bn 172 G M M M M1631 H H H H Na P Na H Bn Bn CH 3 Bz Ph Bn H CH 3 H Bn H H CH 3 H H H H CH3 177 M M M M M1682 Ac Ac Ac Ac CH 3 Ac Bn Ac Ac CH 3 Ac Ac CCH 3 Ac SPh Ac Ac CCH 3 Ac Ac Ac Ac Ac Ac SCH M M N A P1475 Bz Bz H Bz CH3 Bn Bn H Bn CH3 H H CH H N 2 H H Ac H P (CH2)16CH3 Na (CH 2) 18CH 3 Ph H H SPh 187 P P T T T2491 Ac Ac Ac Ac SPh Ac Ac Ac SPh Ac Ac Ac Ac Ac Ac Ac Ac F Ac Ac Ac Ac NH C CCl P P T T T1923 Ac Ac Ac P (CH2)16CH3 Ac (CH 2) 18CH 3 (CH3CH2)3NH Ac Ac Ac P (CH2)16CH3 Ac H (CH 3CH 2) 3NH Bz Bz Bz Bz N S CH2 CF 3 CF 3 Bn Bn Bn Bn F Bn Bn Bn Bn F 197 T T A A A1811 Bn Bn Bn Bn P N(CH 3 ) 2 N(CH 3 ) 2 Bn Bn Bn Bn N S CH2 CF 3 CF 3 Ph N 3 NHAc Ph Bn N 3 NHAc Ph H N 3 NHAc 202 A A A A A2172 H H H H N CH NHBoc Ac Ac Ac N 3 Bn Bn Bn N 3 Bn Bn Bn H N CBn NHBoc H H H N 3 129

132 207 G M M M M1637 H H H H N HN NH H H S Ph N 3 CH3 Ph N CH 3 H Bn Bn NH2 CH 3 Ph H N 3 CH M M M M M1480 H Bn Bn CH 3 Ph Bn N CH 3 Ph H N CH 3 H Bn Bn N CH 3 Ac Ac Ac N CH3 N3 217 M P T T T2047 Ac Ac Ac N SCH 3 Ph N SPh Bn Ac Ac Ac N 3Ac Ac Ac Ac N 3 Ac Ac Ac Ac N Ac 222 I I I I0628 Inositol H H H H H H H H H H H H H H H H H H H H H H H H 226 I I I Q Q0071 H H H H H H H H H H H H H H H H H H H H H H H H H H H 231 Q M M M1647 H H H H H Mannose & Mannosamine H H H H H N NH 2 H H H H H CH 3 Ac Ac Ac Ac CH3 235 M P P T T2307 Ac Ac Ac Ac SCH 3 Ac Ac Ac Ac Ac R R R R= C R R C(CH 3 ) 3 Ac Ac Ac Ac F Ac Ac Ac S 2 CF 3 Ac 240 T T R R0083 R R R R= C R F C(CH 3 ) 3 Ac N 3 Ac Ac Ac Ribose Na P Na H H P Na Na Na P Na H H P Na Na 130

133 244 A A A M1706 Sialic Acids H 2 N H H H H CH F H H H H CH H H H H H CCH 3 Ac Ac Ac Ac SPh CCH M M A A2630 H H H HN SPh CCH3 Ac Ac Ac HN SPh CCH3 Ac Ac Ac Ac H CCH 3 Disaccharides H H H H H H H H 252 D F G G G0311 H H H H H H H H H CH3 H H H Ac Ac Ph Ac Ac N3 CH 3 Ac Ac Ac Ph Ac N3 CH3 Ac Ac Ac Ph Ac N CH M M G G G0340 H H Bn Bn Bn Bn CH 3 Bn Bn H Bn Bn Bn Bn Bn CH3 H H H H H H N2 H H H H H H N2 H H H H H H CH3 H NH2 262 G G G G G0376 H H H H H N2 H H H H H H N 3 H H H H H N2 H H H H H N 2 H H H H H N2 267 G G G M M1776 H H H H H CH 3 H H H H H H H Ac Ac Ac N Bn Bn Bn H H CH3 H H NHAc H NHAc CH3 H H H H NHAc H NHAc CH3 NH 2 N N N N M N0846 H H CH H H H H H CH 3 H H H H CH H H CH3 H H H H H CH H H N2 Ac Ac CCH 3 Ac Bz Ac Bn Bz CH 3 Bz Ac Ac Bz CH3C Ac Bz Ac CH3 277 M N A B4172 Ac Ac CCH 3 Ac HN Ac Bz Ac Bn Bz CH 3 Bz Ac Ac Bz CH 3C Ac CH3 HN Ac Bz Ac Trisaccharides H H H H H CH 3 H H H H N CF 3 H H H H H H CH 3 H H H H N CF3 131

134 281 F F G G G0345 H H H H CH 3 H H H H N 2 H H H H CH 3 H H H H N2 H H H H H H H H H H CH H H H H H H H N2 H H CH H H H H H H H N 2 CH 3 NH2 H 286 G G G G M1767 H H CH H H H H H H H N 2 H H CH H H H H H H H N2 H H H HC H H H H H H H HN C 17H 35 H C 13H 27 H H H H HC H H H H H H H HN13 C 13 C15H31 C 13H 27 H H H H H H H H H H H CH G G G N N0854 H H CH3 H H H H H H H H H H H H H CH 3 H H H CH H H H H H H N2 H H H CH H H H H H H N 2 H H H CH H H H H H H N 2 NH N N N T2912 H H CH H H H H H H H N 2 H H CH H H H H H H H N 2 H H H CH H H H H H H H N 2 H H H H H H H H 300 G G0351 Tetrasaccharides H H H H H H H H H H H H N2 H H H H H H H H H H H H N G G G0372 H H H H H H H H H H H H N 2 H H H H H H H H H H H H N 2 H Na 3S CNa H H H H H H H H H N3 305 L T2910 H H H H H H H H H N3 H H H H H H 2 H H 307 D D4065 H H CH H H CH ligosaccharides H H H H H H CH H H H H H H H H H H H H H H H H H H H NHAc H H H N3 H H H H H H H H CH H H H H H H H H H H H H H H H H H H NHAc H 132

135 309 F G G0421 H H H H H H H H H H H H H H CH 3 H H H H H H H H H H H H H H H N2 H H H H H H H H HC H H H H H H H 13 C HN 13 C 15H 31 C 13H 27 H 312 H1333 H Na3S CNa H H H H H H 315 S0523 H H H H H H N3 313 M2439 H H H H H H H H H H H H H H H H H H H 316 S P2027 H H H H H H 3 H H 317 S0910 H H CNa H H H H H H H H CNa H H H H H H H H H H H H H H H H H NHAc H H H NH 2 Lys Val Ala Asn Lys Thr CH H H H H HC H H H H CH 3 H H H H H H H H H H H H HC H H H H H H H H H H H H H HN C 17H 35 C 13H 27 H 318 H1144 thers H H H NH H H 133

136 134

137 Layout of the Sheet M1628 Methyl 2,3,4-Tri--benzyl-1-thio- -L-fucopyranoside C28H324S = [ ] CH3 Solvent : CDCl3 Internal Standard : Bn Si(CH3)4 Bn Measured Temperature : 22.4 SCH3 Bn Chemical Name Molecular Formula Molecular Weight CAS Registry Number Product Number Structural Formula CAS 1H NMR Spectra were recorded on a JEL JNM ECX 400 spectrometer. 135

138 T2695 2,3,4-Tri--acetyl- -L-arabinopyranosyl 2,2,2-Trichloroacetimidate C 13 H 16 Cl 3 N 8 = [ ] Ac Ac NH C CCl 3 Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 23.1 Ac

139 M1626 Methyl 2,3,4-Tri--acetyl-1-thio- -L-fucopyranoside C 13 H 20 7 S = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.2 CH 3 Ac Ac SCH 3 Ac Please refrain from the conversion of these data without permission. These data have been released on our homepage. 137

140 M1628 Methyl 2,3,4-Tri--benzyl-1-thio- -L-fucopyranoside C 28 H 32 4 S = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.4 CH 3 Bn Bn SCH 3 Bn

141 M Methoxyphenyl 3--Allyl-2--benzyl-4,6--benzylidene- -D-galactopyranoside Ph C 30 H 32 7 = Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.7 Bn CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 139

142 M Methoxyphenyl 3--Allyl-4,6--benzylidene- -D-galactopyranoside C 23 H 26 7 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 40.0 Ph H CH

143 M Methoxyphenyl 3--Allyl-4,6--benzylidene-2--(4-methylbenzoyl)- -D-galactopyranoside Ph C 31 H 32 8 = Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.8 CH 3 CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 141

144 M Methoxyphenyl 3--Allyl- -D-galactopyranoside C 16 H 22 7 = [ ] Solvent : CD 3 D Internal Standard : Si(CH 3 ) 4 Measured Temperature : 19.9 H H H CH

145 M Methoxyphenyl 3--Benzyl- -D-galactopyranoside C 20 H 24 7 = [ ] Solvent : CD 3 D Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.0 H Bn H H CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 143

146 M Methoxyphenyl 4,6--Benzylidene- -D-galactopyranoside C 20 H 22 7 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.0 Ph H H CH

147 M Methoxyphenyl 2,6-Bis--(4-methylbenzoyl)- -D-galactopyranoside C 29 H 30 9 = Solvent : CD 3 D/CDCl 3 = 1/1 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.8 H H CH 3 CH 3 CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 145

148 M Methoxyphenyl 2,6-Di--benzyl- -D-galactopyranoside C 27 H 30 7 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.3 H H Bn Bn CH

149 M Methoxyphenyl 2,6-Di--benzyl-3,4--isopropylidene- -D-galactopyranoside C 30 H 34 7 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.1 CH 3 CH 3 Bn Bn CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 147

150 M Methoxyphenyl -D-galactopyranoside C 13 H 18 7 = [ ] Solvent : CD 3 D Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.2 H H H H CH

151 M Methoxyphenyl 3,4--Isopropylidene-2,6-bis- -(4-methylbenzoyl)- -D-galactopyranoside C 32 H 34 9 = Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.2 CH 3 CH 3 CH 3 CH 3 CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 149

152 M Methoxyphenyl 3,4--Isopropylidene- -D-galactopyranoside C 16 H 22 7 = [ ] Solvent : CD 3 D Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.0 CH 3 CH 3 H CH H

153 M Methoxyphenyl 3,4--Isopropylidene-6--(4-methylbenzoyl)- -D-galactopyranoside C 24 H 28 8 = Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.5 CH 3 CH 3 H CH 3 CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 151

154 M Methoxyphenyl 2,3,4,6-Tetra--acetyl- -D-galactopyranoside C 21 H = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.4 Ac Ac Ac Ac CH

155 M Methoxyphenyl 2,3,4,6-Tetra--benzyl- -D-galactopyranoside C 41 H 42 7 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.9 Bn Bn Bn Bn CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 153

156 M Methoxyphenyl 2,4,6-Tri--benzyl- -D-galactopyranoside C 34 H 36 7 = [ ] Bn Bn Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.0 H Bn CH

157 M1933 Methyl 2,3,6-Tri--benzoyl- -D-galactopyranoside C 28 H 26 9 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 25.9 H Bz Bz Bz CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 155

158 P2078 Phenyl 2--Acetyl-3,4,6-tri--benzyl- 1-thio- -D-galactopyranoside C 35 H 36 6 S = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 27.6 Bn Bn Bn Ac SPh

159 P1477 Phenyl 2,3,4,6-Tetra--acetyl-1-thio- -D-galactopyranoside C 20 H 24 9 S = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.4 Ac Ac Ac Ac SPh Please refrain from the conversion of these data without permission. These data have been released on our homepage. 157

160 P1679 Phenyl 2,3,4,6-Tetra--benzyl-1-thio- -D-galactopyranoside C 40 H 40 5 S = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.0 Bn Bn Bn Bn SPh

161 P1680 Phenyl 2,4,6-Tri--acetyl-3--allyl-1-thio- -D-galactopyranoside C 21 H 26 8 S = Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.6 Ac Ac Ac SPh Please refrain from the conversion of these data without permission. These data have been released on our homepage. 159

162 T2295 2,3,4,6-Tetra--acetyl- -D-galactopyranosyl 2,2,2-Trichloroacetimidate C 16 H 20 Cl 3 N 10 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.4 Ac Ac Ac Ac C NH CCl

163 A1833 -(2-Azido-4,6--benzylidene-2-deoxy- -D-galactopyranosyl)- N-[(9H-fluoren-9-ylmethoxy)carbonyl]-L-serine tert-butyl Ester C 35 H 38 N 4 9 = [ ] Ph Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.0 H N 3 C(CH 3 ) 3 HN Fmoc Please refrain from the conversion of these data without permission. These data have been released on our homepage. 161

164 A1832 -(2-Azido-4,6--benzylidene-2-deoxy- -D-galactopyranosyl)- N-[(9H-fluoren-9-ylmethoxy)carbonyl]-L-threonine tert-butyl Ester C 36 H 40 N 4 9 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.0 Ph H N 3 CH 3 C(CH 3) 3 HN Fmoc

165 A Azidoethyl 2-Acetamido-2-deoxy- -D-galactopyranoside C 10 H 18 N 4 6 = [ ] Solvent : D 2 H H H N 3 Measured Temperature : Please refrain from the conversion of these data without permission. These data have been released on our homepage. 163

166 M Methoxyphenyl 3--Allyl-2-azido-4,6--benzylidene-2-deoxy- -D-galactopyranoside Ph C 23 H 25 N 3 6 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.4 N 3 CH

167 P1643 Phenyl 2-Deoxy-1-thio-2-(2,2,2-trichloroethoxyformamido)- -D-galactopyranoside C 15 H 18 Cl 3 N 6 S = [ ] Solvent : CD 3 D Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.2 H H H NH SPh C CH 2 CCl Please refrain from the conversion of these data without permission. These data have been released on our homepage. 165

168 P1642 Phenyl 3,4,6-Tri--acetyl-2-deoxy-1-thio- 2-(2,2,2-trichloroethoxyformamido)- -D-galactopyranoside C 21 H 24 Cl 3 N 9 S = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.0 Ac Ac Ac NH SPh C CH 2 CCl

169 T1731 1,3,4,6-Tetra--acetyl-2-azido-2-deoxy- -D-galactopyranose C 14 H 19 N 3 9 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.9 Ac Ac Ac N 3Ac Please refrain from the conversion of these data without permission. These data have been released on our homepage. 167

170 A Acetyl-5-methoxyphenyl -D-Glucopyranoside C 15 H 20 8 = [ ] Solvent : CD 3 D Measured Temperature : 24.1 H H H H Ac CH

171 A Azidoethyl 2,3,4,6-Tetra--acetyl- -D-glucopyranoside C 16 H 23 N 3 10 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.5 Ac Ac Ac Ac N Please refrain from the conversion of these data without permission. These data have been released on our homepage. 169

172 B4170 Benzyl 2,3-Di--benzyl-4,6--benzylidene- -D-glucopyranoside C 34 H 34 6 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 25.1 Ph Bn Bn Bn

173 B4171 Benzyl 2,3,4-Tri--benzyl- -D-glucopyranoside C 34 H 36 6 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 23.8 Bn Bn H Bn Bn Please refrain from the conversion of these data without permission. These data have been released on our homepage. 171

174 G0339 -D-Glucopyranose 1-Phosphate Disodium Salt C 6 H 11 Na 2 9 P = [ ] Solvent : D 2 H H H H Na P Na Measured Temperature :

175 M Methoxyphenyl 2--Benzoyl- 3,6-di--benzyl- -D-glucopyranoside C 34 H 34 8 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 27.7 H Bn Bn Bz CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 173

176 M Methoxyphenyl 3--Benzyl-4,6--benzylidene- -D-glucopyranoside C 27 H 28 7 = [ ] Solvent : DMS-d 6 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.1 Ph Bn H CH

177 M Methoxyphenyl 3--Benzyl- -D-glucopyranoside C 20 H 24 7 = [ ] Solvent : DMS-d 6 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.7 H Bn H H CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 175

178 M Methoxyphenyl -D-Glucopyranoside C 13 H 18 7 = [ ] Solvent : CD 3 D Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.9 H H H H CH

179 M Methoxyphenyl 2,3,4,6-Tetra--acetyl- -D-glucopyranoside C 21 H = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.2 Ac Ac Ac Ac CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 177

180 M Methoxyphenyl 2,4,6-Tri--acetyl-3--benzyl- -D-glucopyranoside C 26 H = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 25.0 Ac Bn Ac Ac CH

181 M1759 Methyl (Phenyl 2,3,4-Tri--acetyl-1-thio- -D-glucopyranosid)uronate C 19 H 22 9 S = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.0 Ac Ac CCH 3 Ac SPh Please refrain from the conversion of these data without permission. These data have been released on our homepage. 179

182 M1868 Methyl 1,2,3,4-Tetra--acetyl- -D-glucuronate C 15 H = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.0 Ac Ac CCH 3 Ac Ac

183 M1682 Methyl 2,3,4,6-Tetra--acetyl-1-thio- -D-glucopyranoside C 15 H 22 9 S = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.0 Ac Ac Ac Ac SCH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 181

184 M1487 Methyl 2,3,4-Tri--benzoyl- -D-glucopyranoside C 28 H 26 9 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.9 Bz Bz H Bz CH

185 M1488 Methyl 2,3,4-Tri--benzyl- -D-glucopyranoside C 28 H 32 6 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.7 Bn Bn H Bn CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 183

186 N Nitrophenyl -D-Glucuronide C 12 H 13 N 9 = [ ] Solvent : D 2 External Standard : t-buh ( 1.23) Measured Temperature : 22.9 H H CH H N

187 A Ac PtdGlc(di-acyl Chain) C 49 H 92 Na 14 P = [ ] Solvent : CDCl 3 /CD 3 D = 1/1 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 26.6 H H Ac H P (CH 2 ) 16 CH 3 Na (CH 2 ) 18 CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 185

188 P1475 Phenyl 4,6--Benzylidene-1-thio- -D-glucopyranoside C 19 H 20 5 S = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.5 Ph H H SPh

189 P1476 Phenyl 2,3,4,6-Tetra--acetyl-1-thio- -D-glucopyranoside C 20 H 24 9 S = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 19.8 Ac Ac Ac Ac SPh Please refrain from the conversion of these data without permission. These data have been released on our homepage. 187

190 P1736 Phenyl 2,4,6-Tri--acetyl-3--allyl-1-thio- -D-glucopyranoside C 21 H 26 8 S = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.5 Ac Ac Ac SPh

191 T2449 1,2,4,6-Tetra--acetyl-3--allyl- -D-glucopyranose C 17 H = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.3 Ac Ac Ac Ac Please refrain from the conversion of these data without permission. These data have been released on our homepage. 189

192 T1995 2,3,4,6-Tetra--acetyl- -D-glucopyranosyl Fluoride C 14 H 19 F 9 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.8 Ac Ac Ac Ac F

193 T2491 2,3,4,6-Tetra--acetyl- -D-glucopyranosyl 2,2,2-Trichloroacetimidate C 16 H 20 Cl 3 N 10 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.8 Ac Ac Ac Ac NH C CCl Please refrain from the conversion of these data without permission. These data have been released on our homepage. 191

194 P2079 2,3,4,6-Tetra--acetyl-PtdGlc(di-acyl Chain) C 61 H 114 N 17 P = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 25.2 Ac Ac Ac Ac P (CH 2 ) 16 CH 3 (CH 2 ) 18 CH 3 (CH 3 CH 2 ) 3 NH

195 P2080 2,3,4,6-Tetra--acetyl-PtdGlc(mono-acyl Chain) C 41 H 76 N 16 P = Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 25.5 Ac Ac Ac Ac P (CH 2 ) 16 CH 3 H (CH 3 CH 2 ) 3 NH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 193

196 T1991 2,3,4,6-Tetra--benzoyl- -D-glucopyranosyl p-trifluoromethylbenzylthio-n-(p-trifluoromethylphenyl)formimidate C 50 H 37 F 6 N 10 S = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.4 Bz Bz Bz Bz N S CH 2 CF 3 CF

197 T1922 2,3,4,6-Tetra--benzyl- -D-glucopyranosyl Fluoride C 34 H 35 F 5 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.6 Bn Bn Bn Bn F Please refrain from the conversion of these data without permission. These data have been released on our homepage. 195

198 T1923 2,3,4,6-Tetra--benzyl- -D-glucopyranosyl Fluoride C 34 H 35 F 5 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.8 Bn Bn Bn Bn F

199 T2197 2,3,4,6-Tetra--benzyl- -D-glucopyranosyl N,N,N',N'-Tetramethylphosphorodiamidate (ca. 20% in Benzene) C 38 H 47 N 2 7 P = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 25.0 Bn Bn Bn Bn P N(CH 3 ) 2 N(CH 3 ) Please refrain from the conversion of these data without permission. These data have been released on our homepage. 197

200 T1999 2,3,4,6-Tetra--benzyl- -D-glucopyranosyl p-trifluoromethylbenzylthio-n-(p-trifluoromethylphenyl)formimidate C 50 H 45 F 6 N 6 S = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.0 Bn Bn Bn Bn N S CH 2 CF 3 CF

201 A Acetamido-3--allyl-4,6--benzylidene- 2-deoxy- -D-glucopyranosyl Azide C 18 H 22 N 4 5 = Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 45.0 Ph NHAc N Please refrain from the conversion of these data without permission. These data have been released on our homepage. 199

202 A Acetamido-3--benzyl-4,6--benzylidene-2-deoxy- -D-glucopyranosyl Azide C 22 H 24 N 4 5 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 45.0 Ph Bn NHAc N

203 A Acetamido-4,6--benzylidene-2-deoxy- -D-glucopyranosyl Azide C 15 H 18 N 4 5 = [ ] Solvent : CD 3 D Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.0 Ph H NHAc N Please refrain from the conversion of these data without permission. These data have been released on our homepage. 201

204 A1614 N -(2-Acetamido-2-deoxy- -D-glucopyranosyl)-N -(tert-butoxycarbonyl)-l-asparagine C 17 H 29 N 3 10 = [ ] Solvent : CD 3 D Internal Standard : Si(CH 3 ) 4 Measured Temperature : 45.0 H H H H N CH NHBoc

205 A Acetamido-3,4,6-tri--acetyl-2-deoxy- -D-glucopyranosyl Azide C 14 H 20 N 4 8 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.2 Ac Ac Ac N Please refrain from the conversion of these data without permission. These data have been released on our homepage. 203

206 A Acetamido-3,4,6-tri--benzyl-2-deoxy- -D-glucopyranosyl Azide C 29 H 32 N 4 5 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 19.8 Bn Bn Bn N

207 A1685 N -(2-Acetamido-3,4,6-tri--benzyl-2-deoxy- -D-glucopyranosyl)- N -(tert-butoxycarbonyl)-l-asparagine Benzyl Ester C 45 H 53 N 3 10 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.3 Bn Bn Bn H N CBn NHBoc Please refrain from the conversion of these data without permission. These data have been released on our homepage. 205

208 A Azidoethyl 2-Acetamido-2-deoxy- -D-glucopyranoside C 10 H 18 N 4 6 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 23.2 H H H N

209 G0297 N-GlcNAc-Biotin C 18 H 30 N 4 7 S = [ ] Solvent : DMS-d 6 Measured Temperature : 22.1 H H H H N H HN S NH H Please refrain from the conversion of these data without permission. These data have been released on our homepage. 207

210 M Methoxyphenyl 3--Allyl-2-azido-4,6--benzylidene-2-deoxy- -D-glucopyranoside C 23 H 25 N 3 6 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.0 Ph N 3 CH

211 M Methoxyphenyl 3--Allyl-4,6--benzylidene-2-deoxy-2-phthalimido- -D-glucopyranoside C 31 H 29 N 8 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.3 Ph N CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 209

212 M Methoxyphenyl 2-Amino-3,6-di--benzyl-2-deoxy- -D-glucopyranoside C 27 H 31 N 6 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 23.6 H Bn Bn NH 2 CH

213 M Methoxyphenyl 2-Azido-4,6--benzylidene-2-deoxy- -D-glucopyranoside C 20 H 21 N 3 6 = Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.7 Ph H N 3 CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 211

214 M Methoxyphenyl 2-Azido-3,6-di--benzyl-2-deoxy- -D-glucopyranoside C 27 H 29 N 3 6 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 23.8 H Bn Bn N 3 CH

215 M Methoxyphenyl 3--Benzyl-4,6--benzylidene-2-deoxy- 2-phthalimido- -D-glucopyranoside C 35 H 31 N 8 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.2 Ph Bn N CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 213

216 M Methoxyphenyl 4,6--Benzylidene-2-deoxy-2-phthalimido- -D-glucopyranoside C 28 H 25 N 8 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.0 Ph H N CH

217 M Methoxyphenyl 3,6-Di--benzyl-2-deoxy-2-phthalimido- -D-glucopyranoside C 35 H 33 N 8 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.4 H Bn Bn N CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 215

218 M Methoxyphenyl 3,4,6-Tri--acetyl-2-deoxy-2-phthalimido- -D-glucopyranoside C 27 H 27 N 11 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.0 Ac Ac Ac N CH

219 M1649 Methyl 3,4,6-Tri--acetyl-2-deoxy-2-phthalimido-1-thio- -D-glucopyranoside C 21 H 23 N 9 S = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.2 Ac Ac Ac N SCH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 217

220 P1762 Phenyl N-Benzyl-2-amino-4,6--benzylidene-2-N,3--carbonyl- 2-deoxy-1-thio- -D-glucopyranoside C 27 H 25 N 5 S = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 23.2 Ph N SPh Bn

221 T1732 1,3,4,6-Tetra--acetyl-2-azido-2-deoxy- -D-glucopyranose C 14 H 19 N 3 9 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.0 Ac Ac Ac N 3Ac Please refrain from the conversion of these data without permission. These data have been released on our homepage. 219

222 T2196 1,3,4,6-Tetra--acetyl-2-azido-2-deoxy- -D-glucopyranose C 14 H 19 N 3 9 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 18.9 Ac Ac Ac N 3 Ac

223 T2047 1,3,4,6-Tetra--acetyl-2-deoxy-2-phthalimido- -D-glucopyranose C 22 H 23 N 11 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.0 Ac Ac Ac N Ac Please refrain from the conversion of these data without permission. These data have been released on our homepage. 221

224 I0629 allo-inositol C 6 H 12 6 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 22.7 H H H H H H

225 I0632 1D-chiro-Inositol C 6 H 12 6 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 21.8 H H H H H H Please refrain from the conversion of these data without permission. These data have been released on our homepage. 223

226 I0633 1L-chiro-Inositol C 6 H 12 6 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 22.1 H H H H H H

227 I0628 epi-inositol C 6 H 12 6 = [ ] H H H Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 23.0 H H H Please refrain from the conversion of these data without permission. These data have been released on our homepage. 225

228 I0630 muco-inositol C 6 H 12 6 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 21.9 H H H H H H

229 I0631 scyllo-inositol C 6 H 12 6 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 23.0 H H H H H H Please refrain from the conversion of these data without permission. These data have been released on our homepage. 227

230 I0634 1L-epi-2-Inosose C 6 H 10 6 = [ ] H H Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 22.2 H H H

231 Q0070 (+)-epi-quercitol C 6 H 12 5 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 22.0 H H H H H Please refrain from the conversion of these data without permission. These data have been released on our homepage. 229

232 Q0071 (+)-proto-quercitol C 6 H 12 5 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 22.5 H H H H H

233 Q0069 (-)-vibo-quercitol C 6 H 12 5 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 22.2 H H H H H Please refrain from the conversion of these data without permission. These data have been released on our homepage. 231

234 M2435 N -( -D-Mannopyranosyl)-L-asparagine C 10 H 18 N 2 8 = [ ] Solvent : D 2 Internal Standard : Acetone ( 2.22) Measured Temperature : 19.6 H H H H H N NH 2 H

235 M Methoxyphenyl -D-Mannopyranoside C 13 H 18 7 = [ ] Solvent : CD 3 D Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.2 H H H H CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 233

236 M Methoxyphenyl 2,3,4,6-Tetra--acetyl- -D-mannopyranoside C 21 H = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.3 Ac Ac Ac Ac CH

237 M1501 Methyl 2,3,4,6-Tetra--acetyl-1-thio- -D-mannopyranoside (contains ca.5% -isomer) C 15 H 22 9 S = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.9 Ac Ac Ac Ac SCH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 235

238 P1514 1,2,3,4,6-Penta--acetyl-D-mannopyranose C 16 H = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.6 Ac Ac Ac Ac Ac

239 P1803 1,2,3,4,6-Penta--pivaloyl-D-mannopyranose C 31 H = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.1 R R R R R= C R C(CH 3 ) Please refrain from the conversion of these data without permission. These data have been released on our homepage. 237

240 T2567 2,3,4,6-Tetra--acetyl-D-mannopyranosyl Fluoride C 14 H 19 F 9 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.9 Ac Ac Ac Ac F

241 T2307 1,3,4,6-Tetra--acetyl-2--(trifluoromethanesulfonyl)- -D-mannopyranose C 15 H 19 F 3 12 S = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.7 Ac Ac Ac S 2 CF 3 Ac Please refrain from the conversion of these data without permission. These data have been released on our homepage. 239

242 T2568 2,3,4,6-Tetra--pivaloyl-D-mannopyranosyl Fluoride C 26 H 43 F 9 = Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.7 R R R R R= C F C(CH 3 )

243 T1733 1,3,4,6-Tetra--acetyl-2-azido-2-deoxy- -D-mannopyranose C 14 H 19 N 3 9 = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.8 Ac N 3 Ac Ac Ac Please refrain from the conversion of these data without permission. These data have been released on our homepage. 241

244 R0082 -D-Ribose 1,5-Bis(phosphate) Tetrasodium Salt C 5 H 8 Na 4 11 P 2 = [ ] Solvent : D 2 Measured Temperature : 19.3 Na P Na H H P Na Na

245 R0083 -D-Ribose 1,5-Bis(phosphate) Tetrasodium Salt C 5 H 8 Na 4 11 P 2 = Solvent : D 2 Na P Na P Na Na Measured Temperature : 19.3 H H Please refrain from the conversion of these data without permission. These data have been released on our homepage. 243

246 A2511 N-Acetyl-9-deoxy-9-aminoneuraminic Acid C 11 H 20 N 2 8 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 20.7 H 2 N H H H H CH

247 A2492 N-Acetyl-9-deoxy-9-fluoroneuraminic Acid C 11 H 18 FN 8 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 22.2 F H H H H CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 245

248 A1821 N-Acetylneuraminic Acid Methyl Ester C 12 H 21 N 9 = [ ] H H H Solvent : CD 3 D Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.8 H H CCH

249 M1706 Methyl 5-Acetamido-4,7,8,9-tetra--acetyl-3,5-dideoxy-2-S-phenyl- 2-thio-D-glycero-D-galacto-2-nonulopyranosylonate C 26 H 33 N 12 S = [ ] Ac Ac SPh Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.4 Ac Ac CCH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 247

250 M2329 Methyl 5-N,4--Carbonyl-3,5-dideoxy-2-S-phenyl-2-thio- D-glycero- -D-galacto-2-nonulopyranosylonate C 17 H 21 N 8 S = [ ] H H SPh Solvent : CD 3 D Internal Standard : Si(CH 3 ) 4 Measured Temperature : 23.7 H HN CCH

251 M2330 Methyl 7,8,9-Tri--acetyl-5-N,4--carbonyl-3,5-dideoxy-2-S-phenyl-2-thio- D-glycero- -D-galacto-2-nonulopyranosylonate C 23 H 27 N 11 S = Ac Ac SPh Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 27.7 Ac HN CCH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 249

252 A1822 4,7,8,9-Tetra--acetyl-N-acetylneuraminic Acid Methyl Ester C 20 H 29 N 13 = [ ] Ac Ac H Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.5 Ac Ac CCH

253 A2630 Allolactose C 12 H = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 21.3 H H H H H H H H Please refrain from the conversion of these data without permission. These data have been released on our homepage. 251

254 D4215 N,N'-Diacetylchitobiose C 16 H 28 N 2 11 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 24.6 H H H H H H

255 F0897 Fuc (1-6)GlcNAc C 14 H 25 N 10 = [ ] Solvent : D 2 Internal Standard : Acetone ( 2.22) Measured Temperature : 22.0 H H CH 3 H H H H Please refrain from the conversion of these data without permission. These data have been released on our homepage. 253

256 G0330 Gal[2346Ac] (1-3)GalN 3 [46Bzd]- -MP Ph C 34 H 39 N 3 15 = Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.9 Ac Ac Ac Ac N 3 CH

257 G0309 Gal[2346Ac] (1-3)GlcN 3 [46Bzd]- -MP C 34 H 39 N 3 15 = Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 22.5 Ac Ac Ac Ph Ac N 3 CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 255

258 G0311 Gal[2346Ac] (1-3)GlcNPhth[46Bzd]- -MP C 42 H 43 N 17 = Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.0 Ac Ac Ac Ph Ac N CH

259 M1686 Gal[26Bn] (1-4)Glc[236Bn]- -MP C 54 H = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 23.1 H H Bn Bn Bn Bn Bn CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 257

260 M1727 Gal[246Bn] (1-4)Glc[236Bn]- -MP C 61 H = [ ] Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 23.4 Bn H Bn Bn Bn Bn Bn CH

261 G0375 Gal (1-3)GalNAc- -pnp C 20 H 28 N 2 13 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 22.7 H H H H H H N Please refrain from the conversion of these data without permission. These data have been released on our homepage. 259

262 G0344 Gal (1-3)GalNAc- -pnp C 20 H 28 N 2 13 = [ ] Solvent : D 2 Measured Temperature : 21.5 H H H H H H N

263 G0340 Gal (1-3)GalNAc- -Thr C 18 H 32 N 2 13 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 22.0 H H H H H H CH 3 NH 2 H Please refrain from the conversion of these data without permission. These data have been released on our homepage. 261

264 G0420 Gal (1-3)GlcNAc- -pnp C 20 H 28 N 2 13 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 24.8 H H H H H H N

265 G0373 GalNAc (1-3)GlcNAc -Ethylazide C 18 H 31 N 5 11 = Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 21.5 H H H H H N Please refrain from the conversion of these data without permission. These data have been released on our homepage. 263

266 G0352 GalNAc (1-3)GlcNAc- -pnp C 22 H 31 N 3 13 = Solvent : DMS-d 6 Measured Temperature : 21.8 H H H H H N

267 G0356 GalNAc (1-4)GlcNAc- -pnp C 22 H 31 N 3 13 = [ ] Solvent : DMS-d 6 /D 2 =8/2 Internal Standard : DMS Measured Temperature : 23.8 H H H H H N Please refrain from the conversion of these data without permission. These data have been released on our homepage. 265

268 G0376 GlcNAc (1-3)GalNAc- -pnp C 22 H 31 N 3 13 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 21.8 H H H H H N

269 G0341 GlcNAc (1-3)GalNAc- -Thr C 20 H 35 N 3 13 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 20.6 H H H H H CH 3 NH 2 H Please refrain from the conversion of these data without permission. These data have been released on our homepage. 267

270 G0337 GlcNAc (1-2)Man -1-Ethylazide C 16 H 28 N 4 11 = Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 21.1 H H H H H H N

271 G0299 GlcNPhth[346Ac] (1-3)Gal[246Bn]- -MP C 54 H 55 N 16 = Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.5 Ac Ac Ac N Bn Bn Bn CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 269

272 M1733 LacDiNAc MP Glycoside C 23 H 34 N 2 12 = Solvent : DMS-d 6 /D 2 =49/1 Internal Standard : t-buh ( 1.23) Measured Temperature : 22.3 H H H H NHAc H CH 3 NHAc

273 M1776 LacDiNAc(I) MP Glycoside C 23 H 34 N 2 12 = Solvent : DMS-d 6 /D 2 =49/1 Internal Standard : t-buh ( 1.23) Measured Temperature : 50.0 H H H H NHAc H CH 3 NHAc Please refrain from the conversion of these data without permission. These data have been released on our homepage. 271

274 N0791 Neu5Ac (2-3)Gal MP Glycoside C 24 H 35 N 15 = [ ] Solvent : CD 3 D Internal Standard : Si(CH 3 ) 4 Measured Temperature : 23.2 H H H H CH H H H CH

275 N0792 Neu5Ac (2-6)Gal MP Glycoside C 24 H 35 N 15 = Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 23.0 H H H H CH H H CH 3 H Please refrain from the conversion of these data without permission. These data have been released on our homepage. 273

276 N0890 Neu5Ac (2-6)GalNAc- -pnp H H CH C 25 H 35 N 3 16 = Solvent : D 2 H H H H Measured Temperature : 16.8 N

277 M1761 Neu5Ac[1Me,4789Ac] (2-6)Gal[24Bz,3Bn]- -MP C 54 H 59 N 21 = Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.2 Ac Ac Ac Ac CCH 3 Bz Bn Bz CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 275

278 N0846 Neu5Ac[1Me,4789Ac] (2-3)Gal[246Bz]- -MP C 54 H 57 N 22 = Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 21.0 Ac Ac Ac CH 3 C Ac Bz Bz Bz CH

279 M1763 Neu5GcAc[1Me,4789Ac] (2-6)Gal[24Bz,3Bn]- -MP C 56 H 61 N 23 = Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.9 Ac Ac Ac HN Ac Ac CCH 3 Bz Bn Bz CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 277

280 N0816 Neu5GcAc[1Me,4789Ac] (2-3)Gal[246Bz]- -MP C 56 H 59 N 24 = Solvent : CDCl 3 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 20.5 Ac Ac Ac HN Ac Ac Bz CH 3 C Bz CH 3 Bz

281 A2631 A Antigen PEG-trifluoroacetamide C 30 H 51 F 3 N 2 19 = Solvent : CD 3 D Internal Standard : Si(CH 3 ) 4 Measured Temperature : 24.1 H H H H CH 3 H H H H H N CF Please refrain from the conversion of these data without permission. These data have been released on our homepage. 279

282 B4172 B Antigen PEG-trifluoroacetamide C 28 H 48 F 3 N 19 = Solvent : CD 3 D Internal Standard : Si(CH 3 ) 4 Measured Temperature : 23.2 H H H H H CH 3 H H H H H N CF

283 F0895 Fuc (1-2)Gal (1-3)GalNAc- -pnp (=H type 3 -pnp Glycoside) C 26 H 38 N 2 17 = [ ] Solvent : D 2 Internal Standard : Acetone ( 2.22) Measured Temperature : 21.6 CH 3 H H H H H H H H N Please refrain from the conversion of these data without permission. These data have been released on our homepage. 281

284 F0894 Fuc (1-2)Gal (1-3)GlcNAc- -pnp (=H type 1 -pnp Glycoside) C 26 H 38 N 2 17 = [ ] Solvent : D 2 Internal Standard : Acetone ( 2.22) Measured Temperature : 20.9 CH 3 H H H H H H H H N

285 G0343 Gal (1-3)[GlcNAc (1-6)]GalNAc- -Thr C 26 H 45 N 3 18 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 22.0 H H H H H H H H CH 3 H NH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 283

286 G0377 Gal (1-3)[Neu5Ac (2-6)]GalNAc- -pnp C 31 H 45 N 3 21 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 22.1 H H H H H H H H CH H N

287 G0345 Gal (1-3)[Neu5Ac (2-6)]GalNAc- -pnp C 31 H 45 N 3 21 = Solvent : D 2 Measured Temperature : 21.8 H H H H H H H H CH H N Please refrain from the conversion of these data without permission. These data have been released on our homepage. 285

288 G0347 Gal (1-3)[Neu5Ac (2-6)]GlcNAc- -pnp C 31 H 45 N 3 21 = [ ] Solvent : D 2 Measured Temperature : 20.1 H H CH H H H H H H H N

289 G0353 Gal (1-4)[Neu5Ac (2-6)]GlcNAc- -pnp H H CH C 31 H 45 N 3 21 = Solvent : D 2 Measured Temperature : 20.7 H H H H H H H N Please refrain from the conversion of these data without permission. These data have been released on our homepage. 287

290 G0422 Ganglioside GM 3 (phyto-type) C 59 H 110 N 2 22 = [ ] Solvent : CD 3 D Internal Standard : Si(CH 3 ) 4 Measured Temperature : 27.2 H H H H HC H H H H H H HN C 17 H 35 H C 13 H 27 H

291 G0419 Ganglioside GM 3 [d18:1, (Carbon-13)C16:0] 13 C 16 C 41 H 104 N 2 21 = Solvent : CDCl 3 /CD 3 D/D 2 = 5/5/1 Internal Standard : Si(CH 3 ) 4 Measured Temperature : 23.9 H H H H HC H H H H H H HN13 C 13 C 15 H 31 C 13 H 27 H Please refrain from the conversion of these data without permission. These data have been released on our homepage. 289

292 M1767 Gb 3 - -MP C 25 H = [ ] Solvent : D 2 Measured Temperature : 20.6 H H H H H H H H H H CH

293 G0423 GlcNAc (1-4)[Fuc (1-6)]GlcNAc C 22 H 38 N 2 15 = [ ] Solvent : D 2 Internal Standard : Acetone ( 2.22) Measured Temperature : 22.6 H H H H H CH 3 H H H Please refrain from the conversion of these data without permission. These data have been released on our homepage. 291

294 G0342 GlcNAc (1-3)[GlcNAc (1-6)]GalNAc- -Thr C 28 H 48 N 4 18 = [ ] Solvent : D 2 Measured Temperature : 70.0 H H H H H H H CH 3 NH 2 H

295 G0378 GlcNAc (1-3)[Neu5Ac (2-6)]GalNAc- -pnp C 33 H 48 N 4 21 = Solvent : D 2 Measured Temperature : 16.8 H H H H H H H CH H N Please refrain from the conversion of these data without permission. These data have been released on our homepage. 293

296 N0853 Neu5Ac (2-3)Gal (1-3)GlcNAc- -pnp C 31 H 45 N 3 21 = Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 21.0 H H H H H CH H H H H N

297 N0854 Neu5Ac (2-3)Gal (1-4)GlcNAc- -pnp C 31 H 45 N 3 21 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 20.3 H H H H H CH H H H H N Please refrain from the conversion of these data without permission. These data have been released on our homepage. 295

298 N0855 Neu5Ac (2-6)Gal (1-3)GlcNAc- -pnp C 31 H 45 N 3 21 = Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 19.9 H H H H CH H H H H H N

299 N0856 Neu5Ac (2-6)Gal (1-4)GlcNAc- -pnp C 31 H 45 N 3 21 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 23.2 H H H H CH H H H H H N Please refrain from the conversion of these data without permission. These data have been released on our homepage. 297

300 N0860 Neu5Ac (2-3)Gal (1-4)Glc- -pnp C 29 H 42 N 2 21 = Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 21.9 H H H H H CH H H H H H N

301 T2912 N,N',N''-Triacetylchitotriose C 24 H 41 N 3 16 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 22.4 H H H H H H H H Please refrain from the conversion of these data without permission. These data have been released on our homepage. 299

302 G0348 Gal (1-3)GlcNAc (1-3)Gal (1-4)Glc- -pnp C 32 H 48 N 2 23 = [ ] Solvent : D 2 H H H H H H H H H H H H N 2 Measured Temperature :

303 G0351 Gal (1-4)GlcNAc (1-3)Gal (1-4)Glc- -pnp C 32 H 48 N 2 23 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 21.6 H H H H H H H H H H H H N Please refrain from the conversion of these data without permission. These data have been released on our homepage. 301

304 G0380 GalNAc (1-3)Gal (1-3)Gal (1-4)Glc- -pnp C 32 H 48 N 2 23 = Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 21.2 H H H H H H H H H H H H N

305 G0354 GalNAc (1-3)Gal (1-4)Gal (1-4)Glc- -pnp C 32 H 48 N 2 23 = [ ] Solvent : D 2 Measured Temperature : 22.1 H H H H H H H H H H H H N Please refrain from the conversion of these data without permission. These data have been released on our homepage. 303

306 G0372 GlcA[3S] (1-3)Gal (1-4)GlcNAc (1-2)Man -Ethylazide C 28 H 44 N 4 Na 2 25 S = Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 22.1 H Na3S CNa H H H H H H H H H N

307 L0237 LacDiNAc Dimer Ethylazide C 34 H 57 N 7 21 = Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 24.4 H H H H H H H H H N Please refrain from the conversion of these data without permission. These data have been released on our homepage. 305

308 T2910 N,N',N'',N'''-Tetraacetylchitotetraose C 32 H 54 N 4 21 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 22.1 H H H H H H 2 H H

309 D4217 Disialylnonasaccharide -Ethylazide H H CH C 86 H 141 N 9 62 = Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 27.9 H H H H H H CH H H H H H H H H H H H H H H H H H H H NHAc H H H N Please refrain from the conversion of these data without permission. These data have been released on our homepage. 307

310 D4065 Disialyloctasaccharide C 76 H 125 N 5 57 = Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 23.0 H H H H H H H H CH H H CH H H H H H H H H H H H H H H H H H NHAc H H

311 F0584 Forssman Pentaose MP Glycoside C 41 N 64 N 2 27 = Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 20.1 H H H H H H H H H H H H H H CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 309

312 G0355 Gal (1-3)GalNAc (1-3)Gal (1-4)Gal (1-4)Glc- -pnp C 38 H 58 N 2 28 = Solvent : D 2 Measured Temperature : 21.0 H H H H H H H H H H H H H H H N

313 G0421 Ganglioside GM 1 [d18:1, (Carbon-13)C16:0] 13 C 16 C 55 H 127 N 3 31 = Solvent : DMS-d 6 /D 2 = 49/1 Internal Standard : DMS Measured Temperature : 60.0 H H H H H H H H H HC H H H H H H 13 C HN 13 C 15 H 31 C 13 H 27 H Please refrain from the conversion of these data without permission. These data have been released on our homepage. 311

314 H1333 HNK-1 Ethylazide C 34 H 54 N 4 Na 2 30 S = Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 22.2 H Na 3 S CNa H H H H H H H H H H H H N

315 M2439 Man (1-2)Man (1-3)[Man (1-6)Man- (1-6)]Man (1-4)GlcNAc C 38 H 65 N 31 = Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 60.0 H H H H H H H H H H H H H H H H H H H Please refrain from the conversion of these data without permission. These data have been released on our homepage. 313

316 P2027 N,N',N'',N''',N''''-Pentaacetylchitopentaose C 40 H 67 N 5 26 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 22.1 H H H H H H 3 H H

317 S0523 Sialylglycopeptide C 112 H 187 N 15 Na 2 70 = [ ] Solvent : D 2 Measured Temperature : 20.7 H H CNa H H H H H H CNa H H H H H H H H H H H H H H H H H H H NHAc H H H NH 2 Lys Val Ala Asn Lys Thr CH Please refrain from the conversion of these data without permission. These data have been released on our homepage. 315

318 S0849 Sialyl Lewis X-Lactose C 43 H 72 N 2 33 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 21.3 H H H H HC H CH 3 H H H H H H H H H H H H H

319 S0910 Sialyl Neolactotetraosylceramide (=Sialyl nlc 4 Cer) C 73 H 131 N 3 31 = [ ] Solvent : DMS-d 6 /D 2 = 49/1 Internal Standard : DMS Measured Temperature : 50.0 H H HC H H H H H H H H H H H H H HN C 17 H 35 C 13 H 27 H Please refrain from the conversion of these data without permission. These data have been released on our homepage. 317

320 H1144 -Homonojirimycin C 7 H 15 N 5 = [ ] Solvent : D 2 Internal Standard : t-buh ( 1.23) Measured Temperature : 23.0 H H H NH H H

321 Product Name Index- A AA-2G... G A Antigen PEG-trifluoroacetamide... A Acarbose Hydrate... A Acetamido-3--allyl-4,6--benzylidene-2-deoxy- -D-glucopyranosyl Azide... A Acetamido-9-amino-3,5,9-trideoxy-D-glycero-D-galactononulopyranosonic Acid... A Acetamido-3--benzyl-4,6--benzylidene-2-deoxy- -D-glucopyranosyl Azide... A Acetamido-4,6--benzylidene-2-deoxy- -D-glucopyranosyl Azide... A Acetamido-N-biotinyl-2-deoxy- -D-glucopyranosylamine... G [2-Acetamido-2-deoxy-3--(2-acetamido-2-deoxy- -D-glucopyranosyl)- -D-galactopyranosyl]-L-threonine.. G Acetamido-2-deoxy-4--(2-acetamido-2-deoxy- -D-glucopyranosyl)-D-glucopyranose... D Acetamido-2-deoxy-D-galactopyranose Hydrate... A [2-Acetamido-2-deoxy-3--( -D-galactopyranosyl)- -D-galactopyranosyl]-L-threonine... G Acetamido-2-deoxy-D-glucopyranose... A Acetamido-2-deoxy- -D-glucopyranose 1,3,4,6-Tetraacetate... A Acetamido-2-deoxy- -D-glucopyranosylaminobiotin... G N -(2-Acetamido-2-deoxy- -D-glucopyranosyl)- N -Boc-L-asparagine... A N -(2-Acetamido-2-deoxy- -D-glucopyranosyl)- N -(tert-butoxycarbonyl)-l-asparagine... A Acetamido-2-deoxy- -D-glucopyranosyl Chloride 3,4,6-Triacetate... A Acetamido-2-deoxy-D-mannopyranose Monohydrate... A Acetamido-3,5-dideoxy-D-glycero-D-galactononulopyranosonic Acid Hydrate... A Acetamido-1,3,4,6-tetra--acetyl-2-deoxy- -D-glucopyranose... A Acetamido-3,4,6-tri--acetyl-2-deoxy- -D-glucopyranosyl Azide... A Acetamido-3,4,6-tri--acetyl-2-deoxy- -D-glucopyranosyl Chloride... A Acetamido-3,4,6-tri--benzyl-2-deoxy- -D-glucopyranosyl Azide... A N -(2-Acetamido-3,4,6-tri--benzyl-2-deoxy- -D-glucopyranosyl)-N -Boc-L-asparagine Benzyl Ester... A N -(2-Acetamido-3,4,6-tri--benzyl-2-deoxy- -D-glucopyranosyl)-N -(tert-butoxycarbonyl)- L-asparagine Benzyl Ester... A Acetamido-3,5,9-trideoxy-9-fluoro-D-glycero-D-galactononulopyranosonic Acid... A Acetic Anhydride (ca. 1mol/L in Dichloromethane)... A Acetone Dimethyl Acetal... A Acetoxyacetyl Chloride... A N-Acetyl-Chitooligosaccharides (contains N-Acetylglucosamine)... C N-Acetyl-D-chondrosamine Hydrate... A N-Acetyl-9-deoxy-9-aminoneuraminic Acid... A N-Acetyl-9-deoxy-9-fluoroneuraminic Acid... A N-Acetyl-2,3-didehydro-2-deoxyneuraminic Acid... A N-Acetyl-D-galactosamine Hydrate... A endo- -N-Acetylgalactosaminidase (=Endo- ) Recombinant: from Bifidobacterium longum expressed in Escherichia coli... A N-Acetyl-D-glucosamine... A endo- -N-Acetylglucosaminidase (=Endo-M) Recombinant: from Mucor hiemalis expressed in Candida boidinii [Purity: single band by SDS-PAGE(85KDa)]... A N-Acetyl-D-mannosamine Monohydrate... A Acetyl-5-methoxyphenyl 6--( -L-Arabinopyranosyl)- -D-glucopyranoside... P Acetyl-5-methoxyphenyl -D-Glucopyranoside... A N-Acetylneuraminic Acid Hydrate... A N-Acetylneuraminic Acid Methyl Ester... A N-Acetylneuraminic Acid Methyl Ester 2,4,7,8,9-Pentaacetate... M N-Acetylneuraminic Acid Methyl Ester 4,7,8,9-Tetraacetate... A Acetylpropionic Acid...L Acetyl-2,3,5-tri--benzoyl- -D-ribofuranose... R Acetyl-2,3,5-tri--benzoyl- -L-ribofuranose... R Acetyl-2,3,4-tri--benzyl-D-glucopyranose... A Acid Maltase from Rhizopus (contains 50% Diatomaceous earth)...m Adonitol... A Alginic Acid... A Alginic Acid Calcium Salt... A Allitol... A Allolactose... A ( -D-Allopyranosyloxy)benzaldehyde... F D-(+)-Allose... A Allyl Bromide... B A-Amino-3A-deoxy-(2AS,3AS)- -cyclodextrin Hydrate... A A-Amino-3A-deoxy-(2AS,3AS)- -cyclodextrin Hydrate... A A-Amino-3A-deoxy-(2AS,3AS)- -cyclodextrin Hydrate... A Amino-1-deoxy-D-glucitol... G Amino-2-deoxy-D-glucopyranose Hydrochloride... G Amino-1-deoxy-D-sorbitol... G Aminomethane (ca. 40% in Water, ca. 12mol/L)...M Aminophenyl -D-Galactopyranoside... A Amygdalase from Almonds... G Amygdalin... A Amylase diluted with Starch, from Bacillus subtilis... A Amylase from Soybean... A Amyloheptaose...M Amylohexaose...M Amylopectin Hydrate (Amylose free), from Waxy Corn... A Amylopentaose...M Amylose (Mw.=ca. 15,000)... A Amylose (Mw.=ca. 2,800)... A Amylotetraose...M ,5-Anhydro-2-deoxy-D-arabino-hex-1-enitol... G ,5-Anhydro-2-deoxy-D-lyxo-hex-1-enitol... G ,5-Anhydro-2-deoxy-D-arabino-hex-1-enitol 3,4,6-Tri--acetyl Ether... T ,5-Anhydro-2-deoxy-D-lyxo-hex-1-enitol 3,4,6-Tri--acetyl Ether... T ,5-Anhydro-2-deoxy-D-arabino-hex-1-enitol 3,4,6-Tribenzyl Ether... T ,5-Anhydro-2-deoxy-D-lyxo-hex-1-enitol 3,4,6-Tribenzyl Ether... T ,5-Anhydro-2-deoxy-6--(triisopropylsilyl)- D-lyxo-hex-1-enitol... T ,6-Anhydro- -D-glucose... A ,6-Anhydro-2,3,4-tri--benzyl- -D-glucopyranose... A p-anisaldehyde Dimethyl Acetal... A Anisyl Chloride (stabilized with Amylene)...M Anti-Gb 3 Monoclonal Antibody... A Anti-Gb 3 Monoclonal Antibody (Culture Supernatant)... A Anti-GD 1a Monoclonal Antibody... A Anti-GD 1b Monoclonal Antibody... A Anti-GD 3 Monoclonal Antibody... A Anti-GD 3 Monoclonal Antibody (Culture Supernatant)... A Anti-GM 1 Monoclonal Antibody... A Anti-GM 2 Monoclonal Antibody... A Anti-GM 2 Monoclonal Antibody (Culture Supernatant)... A Anti-GM 3 Monoclonal Antibody... A Anti-GM 3 Monoclonal Antibody (Culture Supernatant)... A Anti-Lewis X Monoclonal Antibody... A Anti-Lewis X Monoclonal Antibody (Culture Supernatant).. A Anti-Lewis Y Monoclonal Antibody... A Anti-Lewis Y Monoclonal Antibody (Culture Supernatant).. A Anti-Sialyl Lewis A Monoclonal Antibody (2D3)... A Anti-Sialyl Lewis A Monoclonal Antibody (1H4)... A Anti-Sialyl Lewis A Monoclonal Antibody (1H4) (Culture Supernatant)... A DL-Arabinitol... A D-(+)-Arabinitol... A L-(-)-Arabinitol... A (+)-Arabinogalactan from Larch Wood... A D-(-)-Arabinose... A L-(+)-Arabinose... A DL-Arabitol... A D-(+)-Arabitol... A L-(-)-Arabitol... A D-Araboascorbic Acid... A Arbutin... A L-Ascorbic Acid... A L-Ascorbic Acid Sodium Salt... A L-Ascorbyl 2,6-Dibutyrate... A

322 Product Name Index- L-Ascorbyl 2,6-Dipalmitate... A L-Ascorbyl 6-Palmitate... A L-Ascorbyl 6-Stearate... A (2-Azido-4,6--benzylidene-2-deoxy- -D-galactopyranosyl)-N-[(9H-fluoren- 9-ylmethoxy)carbonyl]-L-serine tert-butyl Ester... A (2-Azido-4,6--benzylidene-2-deoxy- -D-galactopyranosyl)-N-[(9H-fluoren- 9-ylmethoxy)carbonyl]-L-threonine tert-butyl Ester... A (2-Azido-4,6--benzylidene-2-deoxy- -D-galactopyranosyl)-N-Fmoc-L-serine tert-butyl Ester.. A (2-Azido-4,6--benzylidene-2-deoxy- -D-galactopyranosyl)-N-Fmoc-L-threonine tert-butyl Ester..A [2-(2-Azidoethoxy)ethoxy]ethyl 2,3,4,6-Tetra--acetyl-D-galactopyranoside... G Azidoethyl 2-Acetamido-2-deoxy- -D-galactopyranoside.. A Azidoethyl 2-Acetamido-2-deoxy- -D-glucopyranoside.. A Azidoethyl -D-Glucopyranoside... A Azidoethyl 2,3,4,6-Tetra--acetyl- -D-glucopyranoside.. A Azido-3,6,9-trioxaundecanol... A Azodicarboxylic Acid Dibenzyl Ester (40% in Dichloromethane, ca. 1.7mol/L)... A Azodicarboxylic Acid Diethyl Ester (40% in Toluene, ca. 2.2mol/L)... A B Baicalin... B B Antigen PEG-trifluoroacetamide... B Barosmin... D Benzaldehyde Dimethyl Acetal... B Benzamido-2-deoxy-D-glucopyranose... B Benzenethiol... B Benzoic Anhydride... B ,2,3-Benzotriazol-1-ol Monohydrate... H Benzoyl Chloride... B N-Benzoyl-D-glucosamine... B Benzyl Bromide (stabilized with Propylene xide)... B Benzyl Chloride (stabilized with -Caprolactam)... B Benzyl 2,3-Di--benzyl-4,6--benzylidene- -D-glucopyranoside... B Benzyl 2,3,4-Tri--benzyl- -D-glucopyranoside... B BGIT... A (+)-(2R,3R)-1,4-Bis(benzyloxy)-2,3-butanediol... D (-)-(2S,3S)-1,4-Bis(benzyloxy)-2,3-butanediol... D Bis(cyclopentadienyl)hafnium Dichloride... H (-)-4,5-Bis[hydroxy(diphenyl)methyl]- 2,2-dimethyl-1,3-dioxolane... B (4R,5R)-(-)-4,5-Bis(hydroxymethyl)- 2,2-dimethyl-1,3-dioxolane...I (4S,5S)-(+)-4,5-Bis(hydroxymethyl)- 2,2-dimethyl-1,3-dioxolane...I Bis(4-hydroxyphenyl) Sulfide... D (4R,5R)-(+)-4,5-Bis(tosyloxymethyl)- 2,2-dimethyl-1,3-dioxolane... D (4S,5S)-(-)-4,5-Bis(tosyloxymethyl)- 2,2-dimethyl-1,3-dioxolane... D N,-Bis(trimethylsilyl)trifluoroacetamide... A Bluo-Gal... B Boc Anhydride... D Boc 2... D Boc 2 (ca. 30% in Dioxane)... D Boc 2 (ca. 30% in Tetrahydrofuran)... D Boc 2 (ca. 30% in Toluene)... D Boron Trifluoride - Ethyl Ether Complex... B Bromo-4-chloro-3-( -D-galactopyranosyloxy)indole... B Bromo-4-chloro-3-indolyl -D-Galactopyranoside [for Biochemical Research]... B Bromo-6-chloro-3-indolyl -D-Galactopyranoside (contains ca. 10% Ethyl Acetate) [for Biochemical Research].. B Bromo-3-indolyl -D-Galactopyranoside [for Biochemical Research]... B Bromo-1-propene... B Bromopropylene... B N-Bromosuccinimide... B Bromotoluene (stabilized with Propylene xide)... B BSTFA [=N,-Bis(trimethylsilyl)trifluoroacetamide] [for Gas Chromatography]... A ,3-Butanedione... B L-1,2,3,4-Butanetetrol... T tert-butylchlorodimethylsilane... B tert-butylchlorodiphenylsilane... B tert-butyldimethylchlorosilane [tert-butyldimethylsilylating Agent]... B tert-butyldimethylsilyl Chloride... B tert-butyldimethylsilyl Triflate... T tert-butyldimethylsilyl Trifluoromethanesulfonate... T tert-butyldiphenylchlorosilane... B C Calcium Alginate... A Calcium Gluconate Monohydrate... G Calcium Lactobionate Hydrate...L Calcium Phytate... P ( )-10-Camphorsulfonic Acid... C (+)-10-Camphorsulfonic Acid... C (-)-10-Camphorsulfonic Acid... C Capsaicin -D-Glucopyranoside... C Carmine... C Carmine Red... C Carminic Acid (Natural dye)... C Carrageenan... C Carrageenan... C D-(+)-Cellobiose... C D-Cellobiose ctaacetate... C Cellopentaose... C D-(+)-Cellose... C Cellotetraose... C Cellotriose... C Cellulase from Aspergillus niger... C Chitin... C Chitin ligosaccharides (contains N-Acetylglucosamine)... C Chitosan (5-20mPa s, 0.5% in 0.5% Acetic Acid at 20 )... C Chitosan (50-100mPa s, 0.5% in 0.5% Acetic Acid at 20 ).. C Chitosan ( mPa s, 0.5% in 0.5% Acetic Acid at 20 ).. C Chitosan Tetramer Hydrate... C Chitosan Trimer Hydrate... C Chitotetraose Tetrahydrochloride Hydrate... C Chitotriose Trihydrochloride Hydrate... C Chloralose (contains -isomer)... C Chloro-2-acetamido-2-deoxy-3,4,6-tri--acetyl- -D-glucose... A Chloroacetyl Chloride... C Chlorodimethylphosphine Sulfide... D Chlorodiphenylphosphine xide... C Chloro-3-indolyl -D-Galactopyranoside [for Biochemical Research]... C (Chloromethoxy)ethyltrimethylsilane (stabilized with Diisopropylethylamine)... C (Chloromethyl)anisole (stabilized with Amylene)... M Chloro-1-methylpyridinium Iodide... C Chlorotoluene (stabilized with -Caprolactam)... B Chlorotrimethylsilane... C Chondroitin Sulfate B Sodium Salt... D Chondroitin Sulfate Sodium Salt... C Chondrosamine Hydrochloride... G Cleland's Reagent... D L-Cleland's Reagent... D Copper(II) Gluconate... G Copper(II) Triflate... T Copper(II) Trifluoromethanesulfonate... T Crocetin Digentiobiosyl Ester (Gardenia Fruits Extract)... C Crocin (Gardenia Fruits Extract)... C Cyclodextrin... C Cyclodextrin... C Cyclodextrin... C Cyclodextrin... C Cyclodextrin Henicosaacetate... T Cycloheptaamylose... C Cyclohexaamylose... C D-1,2,3,5/4-Cyclohexanepentol... Q L-1,2,4/3,5-Cyclohexanepentol... Q L-1,3,4/2,5-Cyclohexanepentol... Q Cyclooctaamylose... C D DABC... D Daidzin... D DANA... A

323 Product Name Index- DAST... D DBU... D DCC... D DDQ... D DEAD (40% in Toluene, ca. 2.2mol/L)... A Decyl 4-- -D-Lactopyranosyl- -D-lactopyranoside...L ,3-Dehydro-2-deoxy-N-acetylneuraminic Acid... A '-Demethylepipodophyllotoxin 9-(4,6--Ethylidene- -D-glucopyranoside)...E Deoxy-2,2-difluoro-D-erythro-pentonic Acid -Lactone 3,5-Dibenzoate... D Deoxy-2-fluoro-D-glucopyranose... D Deoxy-2-fluoro-D-glucose... D Deoxy-D-galactopyranose 3,4,6-Tribenzyl Ether... T Deoxy-D-galactose... D Deoxy-D-galactose... D Deoxy-L-galactose... F Deoxy-D-glucopyranose 3,4,6-Triacetate... T Deoxy-D-glucose... D Deoxy-2-hexanamido-D-glucopyranose... H Deoxy-L-mannose Monohydrate... R Deoxy-2-pentanamido-D-glucopyranose... V Deoxy-D-ribose... D Deoxy-2-trifluoroacetamido-D-glucopyranose... T Deoxy-2-valeramido-D-glucopyranose... V Dermatan Sulfate Sodium Salt... D Dextran 40 (Mw.=ca. 40,000)... D Dextran 70 (Mw.=ca. 70,000)... D Dextran Sulfate Sodium (from Dextran of Mw. Approx. 25,000)... D D-(+)-Dextrose... G Diacetone-D-glucose... D Diacetyl... B ,4-Di--acetyl-1,5-anhydro-2,6-dideoxy-L-arabinohex-1-enitol... D N,N'-Diacetylchitobiose... D ,4-Di--acetyl-6-deoxy-L-glucal... D ,4-Di--acetyl-L-rhamnal... D ,4:3,6-Dianhydroglucitol...I ,4:3,6-Dianhydromannitol...I ,4:3,6-Dianhydrosorbitol...I ,4-Diazabicyclo[2.2.2]octane... D ,8-Diazabicyclo[5.4.0]-7-undecene... D DIBAL-H (19% in Hexane, ca. 1.0mol/L)... D Dibenzyl Azodicarboxylate (40% in Dichloromethane, ca. 1.7mol/L)... A (+)-1,4-Di--benzyl-D-threitol... D (-)-1,4-Di--benzyl-L-threitol... D DiBoc... D Di-tert-butyl Dicarbonate [Boc-reagent for Amino Acid]... D Di-tert-butyl Dicarbonate (ca. 30% in Dioxane)... D Di-tert-butyl Dicarbonate (ca. 30% in Tetrahydrofuran)... D Di-tert-butyl Dicarbonate (ca. 30% in Toluene)... D Dibutyldichlorotin... D Di-tert-butyl Pyrocarbonate... D Di-tert-butyl Pyrocarbonate (ca. 30% in Dioxane)... D Di-tert-butyl Pyrocarbonate (ca. 30% in Tetrahydrofuran).. D Di-tert-butyl Pyrocarbonate (ca. 30% in Toluene)... D Dibutyltin Dichloride... D Dibutyltin xide... D ,6-Di--butyryl-L-ascorbic Acid... A ,3-Dichloro-5,6-dicyano-1,4-benzoquinone... D (1,6-Dichloro-1,6-dideoxy- -D-fructofuranosyl)- 4-chloro-4-deoxy- -D-galactopyranoside...S N,N'-Dicyclohexylcarbodiimide... D (Diethylamino)sulfur Trifluoride [Fluorinating Reagent]... D Diethyl Azodicarboxylate (40% in Toluene, ca. 2.2mol/L).. A Digitonin... D Digitoxin... D Digoxin... D ,3-Dihydroxy-1,4-butanedithiol... D DL-2,3-Dihydroxy-1,4-butanedithiol... D (2R,3R)-(-)-2,3-Dihydroxy-1,4-butanedithiol... D (3R,4R)-Dihydroxydihydro-2(3H)-furanone...E ,4'-Dihydroxydiphenyl Sulfide... D ,6-Dihydroxy-4-oxo-2-phenyl-4H-1-benzopyran-7-yl -D-Glucopyranosiduronic Acid... B Diisobutylaluminum Hydride (19% in Hexane, ca. 1.0mol/L)..D ,2:5,6-Di--isopropylidene- -D-allofuranose... D ,3:4,5-Di--isopropylidene- -D-fructopyranose... D ,2:3,4-Di--isopropylidene- -D-galactopyranose... D ,2:5,6-Di--isopropylidene- -D-glucofuranose... D (-)-2,3:4,6-Di--isopropylidene-2-keto- L-gulonic Acid Monohydrate... D ,2:5,6-Di--isopropylidene-D-mannitol... D ,3:5,6-Di--isopropylidene-D-mannofuranose... D ,3:4,5-Di--isopropylidene-1--sulfamoyl- -D-fructopyranose... T ,2:3,5-Di--isopropylidene- -D-xylofuranose... D (-)-2,3:4,6-Di--isopropylidene- -L-xylo-2-hexulofuranosonic Acid Monohydrate... D ,3-Diketobutane... B ,4-Dimercapto-2,3-butanediol... D DL-1,4-Dimercapto-2,3-butanediol... D (2R,3R)-(-)-1,4-Dimercapto-2,3-butanediol... D ,2-Dimethoxypropane... A , -Dimethoxytoluene... B (3-Dimethylaminopropyl)-3-ethylcarbodiimide... D (3-Dimethylaminopropyl)-3-ethylcarbodiimide Hydrochloride [Coupling Agent for Peptides Synthesis]... D Dimethylaminopyridine... D (4R,5R)-(+)-2,2-Dimethyl-4,5-bis(tosyloxymethyl)- 1,3-dioxide... D (4S,5S)-(-)-2,2-Dimethyl-4,5-bis(tosyloxymethyl)- 1,3-dioxide... D ,6-Di--methyl- -cyclodextrin... D (4R,5R)-(-)-2,2-Dimethyl-1,3-dioxolane-4,5-dimethanol...I (4S,5S)-(+)-2,2-Dimethyl-1,3-dioxolane-4,5-dimethanol...I (-)-trans-, '-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)- bis(diphenylmethanol)... B Dimethylglyoxal... B Dimethylphosphinothioyl Chloride... D ,3-Dimethylpyridine...L ,4-Dimethylpyridine...L ,5-Dimethylpyridine...L ,6-Dimethylpyridine...L ,4-Dimethylpyridine...L ,5-Dimethylpyridine...L Dimethylthiophosphinoyl Chloride... D Diosmin... D ,6-Di--palmitoyl-L-ascorbic Acid... A Diphenyl Phosphate... P Diphenylphosphinic Chloride... C Diphenyl Sulfone... P Diphenyl Sulfoxide... D Diphenyltin Sulfide [Activator for -Glycoside Synthesis].. D Dipotassium D-Glucose-6-phosphate Hydrate... G Dipotassium Glycyrrhizinate Hydrate... G Disialylnonasaccharide -Ethylazide... D Disialylnonasaccharide- -pnp... N Disialyloctasaccharide... D Dithioerythritol... D DL-Dithiothreitol... D L-Dithiothreitol... D (+)-1,4-Di--tosyl-2,3--isopropylidene-D-threitol... D (-)-1,4-Di--tosyl-2,3--isopropylidene-L-threitol... D DMAP... D DNS-SGN... D DTE... D DL-DTT... D L-DTT... D Dulcitol... G E EDAC... D EDAC... D EDC... D EDC... D EDCI... D Emulsin from Almonds... G Endo- Recombinant: from Bifidobacterium longum expressed in Escherichia coli... A Endo-M Recombinant: from Mucor hiemalis expressed in Candida boidinii [Purity: single band by SDS-PAGE(85KDa)].. A D-Erythorbic Acid... A meso-erythritol...e D-Erythronic -Lactone...E D-Erythronolactone...E

324 Product Name Index- Esculin Sesquihydrate...E Ethyl-L-ascorbic Acid...E Ethyl-3-(3-dimethylaminopropyl)carbodiimide... D Ethyl-3-(3-dimethylaminopropyl)carbodiimide Hydrochloride... D Ethylenediamine Anhydrous...E Ethylenediamine Monohydrate...E N-Ethyl-D-glucamine...E ,6--Ethylidene- -D-glucopyranose...E ,6--Ethylidene- -D-glucose...E Etoposide...E F Fatty Acid Sucrose Ester...S N -[(9H-Fluoren-9-ylmethoxy)carbonyl]- L-serine tert-butyl Ester... F N -[(9H-Fluoren-9-ylmethoxy)carbonyl]- L-threonine tert-butyl Ester... F Fluoromethyl Phenyl Sulfone... F Fluoromethylsulfonylbenzene... F Fmoc-Ser[GalN 3 [46Bzd]- ]-tbu... A N -Fmoc-L-serine tert-butyl Ester... F Fmoc-Ser-tBu... F N -Fmoc-L-threonine tert-butyl Ester... F Fmoc-Thr[GalN 3 [46Bzd]- ]-tbu... A Fmoc-Thr-tBu... F Formylphenyl -D-Allopyranoside... F Formylphenyl -D-Glucopyranoside... H Forssman Pentaose MP Glycoside... F D-Fructofuranosyl - -D-Galactopyranosyl-(1-6)-- - D-galactopyranosyl-(1-6)- -D-glucopyranoside Hydrate...S D-Fructofuranosyl -D-Xylopyranoside... X D-(-)-Fructose... F L-(+)-Fructose... F Fuc (1-2)Gal (1-3)GalNAc- -pnp (=H type 3 -pnp Glycoside)... F Fuc (1-2)Gal (1-3)GalNAc- -pnp (=H type 3 -pnp Glycoside)... F Fuc (1-2)Gal (1-3)GlcNAc- -pnp (=H type 1 -pnp Glycoside)... F Fuc (1-6)GlcNAc... F L-Fucopyranose 1,2,3,4-Tetraacetate... T D-(+)-Fucose... D L-(-)-Fucose... F Fungitetraose Trihydrate... N G Gal[246Ac,3All]- -SPh... P Gal[2Ac,346Bn] (1-3)GlcNPhth[46Bzd]- -MP... G Gal[2Ac,346Bn]- -SPh... P Gal[2346Ac] (1-3)GalN 3 [46Bzd]- -MP... G Gal[2346Ac] (1-4)Glc[236Ac]- -MP... M Gal[2346Ac] (1-3)GlcN 3 [46Bzd]- -MP... G Gal[2346Ac] (1-3)GlcNPhth[46Bzd]- -MP... G D-Galactal... G Galactinol Hydrate... G Galactitol... G D-Galactopyranosyl-D-fructose...L D-Galactopyranosyl-D-glucopyranose Monohydrate..M D-Galactopyranosyl-D-glucopyranose... A D-Galactopyranosyl-L-myo-inositol Hydrate... G D-(+)-Galactosamine Hydrochloride... G D-(+)-Galactose Anhydrous... G L-(-)-Galactose... G D-Galactose Pentaacetate... G D-Galacturonic Acid Hydrate... G Gal[3All,246Bn] (1-3)GlcNPhth[6Bn]- -MP... G Gal[246Bn,3All]- -SPh... P Gal[26Bn] (1-4)Glc[236Bn]- -MP... M Gal[246Bn] (1-4)Glc[236Bn]- -MP... M Gal[236Bn] (1-4)Glc[236Bn]- -MP... M Gal[2346Bn]- -SPh... P Gal (1-3)[Fuc (1-2)]Gal- -PEG-trifluoroacetamide... B Gal (1-4)Gal (1-4)Glc- -ethylamine... G Gal (1-4)Gal (1-4)Glc- -ethylazide... G Gal (1-3)GalNAc (1-3)Gal (1-4)Gal (1-4)Glc- -pnp... G Gal (1-3)GalNAc- -pnp... G Gal (1-3)GalNAc- -pnp... G Gal (1-3)GalNAc- -Thr... G Gal (1-4)Glc- -MP...M Gal (1-3)GlcNAc (1-3)Gal (1-4)Glc- -pnp... G Gal (1-4)GlcNAc (1-3)Gal (1-4)Glc- -pnp... G Gal (1-3)[GlcNAc (1-6)]GalNAc- -Thr... G Gal (1-3)GlcNAc- -pnp... G GalNAc (1-3)[Fuc (1-2)]Gal- -PEG-trifluoroacetamide.. A GalNAc (1-3)Gal (1-3)Gal (1-4)Glc- -pnp... G GalNAc (1-3)Gal (1-4)Gal (1-4)Glc- -pnp... G GalNAc (1-3)GalNAc (1-3)Gal (1-4)Gal- (1-4)Glc MP Glycoside... F GalNAc (1-3)GlcNAc -Ethylazide... G GalNAc (1-4)GlcNAc (1-3)GalNAc (1-4)GlcNAc- -ethylazide...l GalNAc (1-3)GlcNAc- -pnp... G GalNAc (1-4)GlcNAc- -pnp... G Gal (1-3)[Neu5Ac (2-6)]GalNAc- -pnp... G Gal (1-3)[Neu5Ac (2-6)]GalNAc- -pnp... G Gal (1-3)[Neu5Ac (2-6)]GlcNAc- -pnp... G Gal (1-4)[Neu5Ac (2-6)]GlcNAc- -pnp... G Ganglioside GM 3 (phyto-type)... G Ganglioside GM 1 [d18:1, (Carbon-13)C16:0]... G Ganglioside GM 3 [d18:1, (Carbon-13)C16:0]... G Gb 3 - -ethylamine... G Gb 3 - -ethylazide... G Gb 3 - -MP...M Geniposide... G Gentamicin Sulfate... G Gentiobiose... G GITC... A GlcA[234Ac,6Me]- -SPh...M GlcA[3S] (1-3)Gal (1-4)GlcNAc (1-3)Gal (1-4)Glc -Ethylazide... H GlcA[3S] (1-3)Gal (1-4)GlcNAc (1-2)Man -Ethylazide... G Glc (1-4)Glc (1-4)Glc... C Glc (1-4)Glc (1-4)Glc (1-4)Glc... C Glc (1-4)Glc (1-4)Glc (1-4)Glc (1-4)Glc... C Glc (1-4)Glc- -pnp... N N-GlcNAc-Biotin... G GlcNAc (1-4)[Fuc (1-6)]GlcNAc... G GlcNAc (1-3)GalNAc- -pnp... G GlcNAc (1-3)GalNAc- -Thr... G GlcNAc (1-4)GlcNAc... D GlcNAc (1-3)[GlcNAc (1-6)]GalNAc- -Thr... G GlcNAc (1-4)GlcNAc (1-4)GlcNAc... T GlcNAc (1-4)GlcNAc (1-4)GlcNAc (1-4)GlcNAc... T GlcNAc (1-4)GlcNAc (1-4)GlcNAc (1-4)GlcNAc- (1-4)GlcNAc... P GlcNAc (1-2)Man -1-Ethylazide... G GlcNAc (1-3)[Neu5Ac (2-6)]GalNAc- -pnp... G GlcNPhth[346Ac] (1-3)Gal[246Bn]- -MP... G GlcNPhth[36Bn,4Ac]- -MP...M D-Glucal... G D-Glucamine... G Glucan from Black Yeast... G Glucoamylase from Rhizopus (contains 50% Diatomaceous earth)...m ,6-Glucobiose...I Glucoheptonic Acid Sodium Salt Dihydrate... G Gluconic Acid (contains Gluconolactone) (45-50% in Water)... G Gluconic Acid Anhydride... G Gluconic Acid Calcium Salt Monohydrate... G Gluconic Acid Copper(II) Salt... G Gluconic Acid Iron(II) Salt Hydrate... G Gluconic Acid -Lactone... G Gluconic Acid Magnesium(II) Salt Hydrate... G Gluconic Acid Potassium Salt... G Gluconic Acid Sodium Salt... G Gluconic Acid Zinc(II) Salt Hydrate... G D-(+)-Glucono-1,5-lactone... G D-Glucopyranose 1-Phosphate Disodium Salt... G D-Glucopyranosyl-L-ascorbic Acid... G ( -D-Glucopyranosyl)-4',7-dihydroxyisoflavone... P D-Glucopyranosyl-D-fructose Monohydrate...M D-Glucopyranosyl-D-fructose Hydrate... P D-Glucopyranosyl-D-glucose...I ( -D-Glucopyranosyloxy)benzaldehyde... H ( -D-Glucopyranosyloxy)-4'-hydroxyisoflavone... D

325 Product Name Index- (1S)-1 -( -D-Glucopyranosyloxy)-7-(hydroxymethyl)- 1,4a,5,7a -tetrahydrocyclopenta[c]pyran- 4-carboxylic Acid Methyl Ester... G D-Glucosamic Acid... G D-(+)-Glucosamine Hydrochloride... G D-Glucosamine xime Hydrochloride... G D-Glucosaminic Acid... G D-(+)-Glucose... G L-(-)-Glucose... G D-Glucose (contains -D-Glucose)... G Glucosecarboxylic Acid Sodium Salt Dihydrate... G D-Glucose Diethyl Dithioacetal... G D-Glucose Diethyl Mercaptal... G Glucose xidase from Aspergillus niger... G D-Glucose Pentaacetate... G D-Glucose Pentaacetate... P D-Glucose 6-Phosphate Barium Salt Heptahydrate... G Glucose 1-Phosphate Dipotassium Salt Dihydrate... G D-Glucose 6-Phosphate Dipotassium Salt Hydrate... G Glucosidase from Almonds... G Glucotropaeolin Potassium Salt... G D-Glucuronamide... G D-Glucuronic Acid... G D-Glucuronic Acid Lactone... G D-Glucurono-6,3-lactone... G DL-Glyceraldehyde Diethyl Acetal... G N-Glycolylneuraminic Acid... G Glycosynthase (Endo-M-N175Q) Recombinant: from Mucor hiemalis expressed in Escherichia coli... G Glycyrrhizic Acid... G Glycyrrhizic Acid Dipotassium Salt Hydrate... G Glycyrrhizic Acid Monoammonium Salt Hydrate... G Glycyrrhizic Acid Trisodium Salt Hydrate... G Glycyrrhizin... G Glycyrrhizin Dipotassium Salt Hydrate... G Glycyrrhizin Monoammonium Salt Hydrate... G Glycyrrhizin Trisodium Salt Hydrate... G Glyoxaline...I Goat Anti-Mouse IgG FITC Conjugate... G Goat Anti-Mouse IgG HRP Conjugate... G Goat Anti-Mouse IgM... G Goat Anti-Mouse IgM HRP Conjugate... G Goat Anti-Rabbit IgG HRP Conjugate... G L-(+)-Gulonic Acid -Lactone... G L-Gulonolactone... G L-Gulose... G H Hafnocene Dichloride... H Helicide... F Helicin... H Heparin Sodium Salt from Hog intestine... H Hepta--acetyl Rutinose... H Heptakis(2,6-di--methyl)- -cyclodextrin... D Heptasaccharide Glc 4 Xyl 3... H Heptasaccharide Glc 4 Xyl 3... H Hesperidin... H N-Hexanoyl-D-glucosamine... H Hexyldimethyloctylammonium Bromide... H HNK-1 Ethylazide... H HBt Monohydrate... H Homonojirimycin... H H type 1 -pnp Glycoside... F H type 3 -pnp Glycoside... F H type 3 -pnp Glycoside... F Hyaluronate Hexasaccharide... H Hyaluronate Tetrasaccharide... H Hyaluronic Acid from Bovine Vitreous Humor [Substrate for Hyaluronidase]... H Hyaluronic Acid from Cockscomb... H Hyaluronic Acid Potassium Salt from Cockscomb... H Hyaluronic Acid Sodium Salt from Cockscomb... H Hydrazine Monohydrate... H Hydrazine Monohydrate (79%)... H Hydrazine Acetate... H Hydrobromic Acid (30% in Acetic Acid, ca. 5.1mol/L)... H Hydrogen Bromide (30% in Acetic Acid, ca. 5.1mol/L) [for Peptide research]... H Hydroquinone- -D-glucoside... A Hydroquinone Monomethyl Ether...M Hydroxyanisole...M Hydroxybenzotriazole Monohydrate... H Hydroxycoumarin-6-yl -D-Glucopyranoside Sesquihydrate...E (Hydroxymethyl)phenyl -D-Glucopyranoside...S Hydroxyphenyl -D-Glucopyranoside... A Hydroxypropyl- -cyclodextrin... H I D-Iditol...I L-Iditol...I Imidazole...I Indican Hydrate...I Indole-D-glucoside Hydrate...I Indoxyl-D-glucoside Hydrate...I allo-inositol...i D-chiro-Inositol...I L-chiro-Inositol...I epi-inositol...i muco-inositol...i myo-inositol...i scyllo-inositol...i L-epi-2-Inosose...I Inulin...I Invertose...I Iodomethane (stabilized with Copper chip)...i N-Iodosuccinimide...I Iron(II) Gluconate Hydrate... G D-Isoascorbic Acid... A Isomaltose...I Isomaltotriose...I Isomaltulose Hydrate... P Isomannide...I (+)-5,6--Isopropylidene-L-ascorbic Acid...I (4R,5R)-(+)-2,3--Isopropylidene-1,4-di--tosyl-D-threitol.. D (4S,5S)-(-)-2,3--Isopropylidene-1,4-di--tosyl-L-threitol.. D ,3--Isopropylidene-D-erythronolactone...I ,2--Isopropylidene- -D-glucofuranose...I ,2--Isopropylidene- -D-glucurono-6,3-lactone...I ,4--Isopropylidene-D-mannitol...I (2R,3R)-2,3--Isopropylidene-1,1,4,4-tetraphenyl- 1,2,3,4-butanetetrol... B (-)-2,3--Isopropylidene-1,1,4,4-tetraphenyl-L-threitol... B (+)-2,3--Isopropylidene-L-threitol...I (-)-2,3--Isopropylidene-D-threitol...I ,2--Isopropylidene- -D-xylofuranose...I Isopropyl- -D-thiogalactopyranoside...I Isopropyl 1-Thio- -D-galactopyranoside...I Isosorbide...I Isosorbide 5-Mononitrate...I Isosorbide 5-Nitrate...I K 1-Kestose... K L LacDiNAc Dimer Ethylazide...L LacDiNAc MP Glycoside...M LacDiNAc(I) MP Glycoside...M Lac (1-4)Lac- -C 10...L LacMP...M LacMP 3'-H, per Bn...M LacMP 4'-H, per Bn...M LacMP 3'4'-H, per Bn...M LacMP per Ac...M Lactobionic Acid (mixture of Acid form and Lactone form)..l Lactobionic Acid Calcium Salt Hydrate...L D-(+)-Lactose Monohydrate...L Lactulose...L Lectin, Fucose specific from Aspergillus oryzae (5mg/mL, PBS ph6.5)...l Levulinic Acid...L D-(-)-Levulose... F Lupeose Hydrate...S ,3-Lutidine...L ,4-Lutidine...L ,5-Lutidine...L ,6-Lutidine...L

326 Product Name Index- 3,4-Lutidine...L ,5-Lutidine...L D-(-)-Lyxose...L L-(+)-Lyxose...L M Magenta-Gal (contains ca. 10% Ethyl Acetate)... B Mag-Gal (contains ca. 10% Ethyl Acetate)... B Magnesium(II) Gluconate Hydrate... G Maltitol... M Maltitol... M Maltoheptaose... M Maltohexaose... M Maltopentaose... M D-(+)-Maltose Monohydrate... M D-Maltosyl- -cyclodextrin... M Maltotetraose... M D-(+)-Maltotriose Hydrate... M Maltulose Monohydrate... M Man[2Bz,3All,46Bzd] (1-4)GlcNPhth[36Bn]- -MP...M Man (1-2)Man (1-3)[Man (1-6)Man (1-6)]- Man (1-4)GlcNAc... M Manneotetrose Hydrate...S D-Mannitol... M L-Mannitol... M D-Mannono-1,4-lactone... M N -( -D-Mannopyranosyl)-L-asparagine... M D-(+)-Mannose... M L-(-)-Mannose... M Mannose-6-phosphate Barium Salt Hydrate... M MEHQ... M D-(+)-Melezitose Hydrate... M D-(+)-Melibiose Monohydrate... M Melitose Pentahydrate... R Methoxybenzaldehyde Dimethyl Acetal... A Methoxybenzyl Chloride (stabilized with Amylene)... M Methoxymethyltrimethylsilane... M Methoxyphenol... M Methoxyphenyl 3--(2-Acetamido-2-deoxy- -D-galactopyranosyl)-2-acetamido-2-deoxy- -D-glucopyranoside... M Methoxyphenyl 4--(2-Acetamido-2-deoxy- -D-galactopyranosyl)-2-acetamido-2-deoxy- -D-glucopyranoside... M Methoxyphenyl -(5-Acetamido-3,5-dideoxy-D-glycero- -D-galacto-2-nonulopyranosonic Acid)-(2-3)- -D-galactopyranoside... N Methoxyphenyl -(5-Acetamido-3,5-dideoxy-D-glycero- -D-galacto-2-nonulopyranosonic Acid)-(2-6)- -D-galactopyranoside... N Methoxyphenyl 2--Acetyl-3--allyl-4,6--benzylidene- -D-glucopyranoside... M Methoxyphenyl 4--Acetyl-3,6-di--benzyl-2-deoxy- 2-phthalimido- -D-glucopyranoside... M Methoxyphenyl 3--(N-Acetyl- -neuraminosyl)- -D-galactopyranoside... N Methoxyphenyl 6--(N-Acetyl- -neuraminosyl)- -D-galactopyranoside... N Methoxyphenyl 3--Allyl-2-azido-4,6--benzylidene- 2-deoxy- -D-galactopyranoside... M Methoxyphenyl 3--Allyl-2-azido-4,6--benzylidene- 2-deoxy- -D-glucopyranoside... M Methoxyphenyl 3--Allyl-2--benzyl-4,6--benzylidene- -D-galactopyranoside... M Methoxyphenyl 3--Allyl-6--benzyl-2-deoxy- 2-phthalimido- -D-glucopyranoside... M Methoxyphenyl 3--Allyl-4,6--benzylidene-2-deoxy- 2-phthalimido- -D-glucopyranoside... M Methoxyphenyl 3--Allyl-4,6--benzylidene- -D-galactopyranoside... M Methoxyphenyl 3--Allyl-4,6--benzylidene- 2--(4-methylbenzoyl)- -D-galactopyranoside... M Methoxyphenyl 3--Allyl- -D-galactopyranoside...M Methoxyphenyl 2-Amino-3,6-di--benzyl-2-deoxy- -D-glucopyranoside... M Methoxyphenyl 2-Azido-4,6--benzylidene-2-deoxy- -D-glucopyranoside... M Methoxyphenyl 2-Azido-3,6-di--benzyl-2-deoxy- -D-glucopyranoside... M Methoxyphenyl 2--Benzoyl-3,6-di--benzyl- -D-glucopyranoside...M Methoxyphenyl 3--Benzyl-4,6--benzylidene-2-deoxy- 2-phthalimido- -D-glucopyranoside...M Methoxyphenyl 3--Benzyl-4,6--benzylidene- -D-glucopyranoside...M Methoxyphenyl 3--Benzyl-2-deoxy-2-phthalimido- -D-glucopyranoside...M Methoxyphenyl 3--Benzyl- -D-galactopyranoside...M Methoxyphenyl 3--Benzyl- -D-glucopyranoside...M Methoxyphenyl 4,6--Benzylidene-2-deoxy- 2-phthalimido- -D-glucopyranoside...M Methoxyphenyl 4,6--Benzylidene- -D-galactopyranoside...M Methoxyphenyl 2,6-Bis--(4-methylbenzoyl)- -D-galactopyranoside...M Methoxyphenyl 2,4-Di--benzoyl-3--benzyl-6-- (methyl 5-Acetamido-4,7,8,9-tetra--acetyl-3,5-dideoxy- D-glycero- -D-galacto-2-nonulopyranosonate)- -D-galactopyranoside...M Methoxyphenyl 2,4-Di--benzoyl-3--benzyl-6-- [methyl 5-(Acetoxyacetamido)-4,7,8,9-tetra--acetyl- 3,5-dideoxy-D-glycero- -D-galacto-2-nonulopyranosonate]- -D-galactopyranoside...M Methoxyphenyl 3,6-Di--benzyl-2-deoxy-2-phthalimido- -D-glucopyranoside...M Methoxyphenyl 2,6-Di--benzyl- -D-galactopyranoside..M Methoxyphenyl 4--(2,6-Di--benzyl- -D-galactopyranosyl)-2,3,6-tri--benzyl- -D-glucopyranoside...M Methoxyphenyl 2,6-Di--benzyl-3,4--isopropylidene- -D-galactopyranoside...M Methoxyphenyl -D-Galactopyranoside...M Methoxyphenyl -( -D-Galactopyranosyl)-(1-4)- -( -D-galactopyranosyl)-(1-4)- -D-glucopyranoside...M Methoxyphenyl 4--( -D-Galactopyranosyl)- -D-glucopyranoside...M Methoxyphenyl -D-Glucopyranoside...M Methoxyphenyl -(5-Hydoxyacetamido-3,5-dideoxy- D-glycero- -D-galacto-2-nonulopyranosonic Acid)-(2-6)- -D-galactopyranoside... N Methoxyphenyl -(5-Hydroxyacetamido-3,5-dideoxy- D-glycero- -D-galacto-2-nonulopyranosonic Acid)-(2-3)- -D-galactopyranoside... N Methoxyphenyl 3--[N-(Hydroxyacetyl)- -neuraminosyl]- -D-galactopyranoside... N Methoxyphenyl 6--[N-(Hydroxyacetyl)- -neuraminosyl]- -D-galactopyranoside... N Methoxyphenyl 3,4--Isopropylidene-2,6-bis- -(4-methylbenzoyl)- -D-galactopyranoside...M Methoxyphenyl 3,4--Isopropylidene- -D-galactopyranoside...M Methoxyphenyl 3,4--Isopropylidene- 6--(4-methylbenzoyl)- -D-galactopyranoside...M Methoxyphenyl -D-Mannopyranoside...M Methoxyphenyl 2,3,4,6-Tetra--acetyl- -D-galactopyranoside...M Methoxyphenyl 3--(2,3,4,6-Tetra--acetyl- -D-galactopyranosyl)-2-azido-4,6--benzylidene- 2-deoxy- -D-galactopyranoside... G Methoxyphenyl 3--(2,3,4,6-Tetra--acetyl- -D-galactopyranosyl)-2-azido-4,6--benzylidene- 2-deoxy- -D-glucopyranoside... G Methoxyphenyl 3--(2,3,4,6-Tetra--acetyl- -D-galactopyranosyl)-4,6--benzylidene-2-deoxy- 2-phthalimido- -D-glucopyranoside... G Methoxyphenyl 4--(2,3,4,6-Tetra--acetyl- -D-galactopyranosyl)-2,3,6-tri--acetyl- -D-glucopyranoside...M Methoxyphenyl 2,3,4,6-Tetra--acetyl- -D-glucopyanoside...M Methoxyphenyl 2,3,4,6-Tetra--acetyl- -D-mannopyranoside...M Methoxyphenyl 2,3,4,6-Tetra--benzyl- -D-galactopyranoside...M Methoxyphenyl 2,4,6-Tri--acetyl-3--benzyl- -D-glucopyranoside...M Methoxyphenyl 3,4,6-Tri--acetyl-2-deoxy- 2-phthalimido- -D-glucopyranoside...M

327 Product Name Index- 4-Methoxyphenyl 3--(3,4,6-Tri--acetyl-2-deoxy- 2-phthalimido- -D-glucopyranosyl)-2,4,6-tri--benzyl- -D-galactopyranoside... G Methoxyphenyl 2,4,6-Tri--benzoyl-3-- (methyl 5-Acetamido-4,7,8,9-tetra--acetyl-3,5-dideoxy- D-glycero- -D-galacto-2-nonulopyranosonate)- -D-galactopyranoside... N Methoxyphenyl 2,4,6-Tri--benzoyl-3-- (methyl 5-Acetoxyacetamido-4,7,8,9-tetra--acetyl-3,5- dideoxy-d-glycero- -D-galacto-2-nonulopyranosonate)- -D-galactopyranoside... N Methoxyphenyl 2,3,6-Tri--benzyl- -D-galactopyranoside... M Methoxyphenyl 2,4,6-Tri--benzyl- -D-galactopyranoside... M Methoxyphenyl 4--(2,3,6-Tri--benzyl- -D-galactopyranosyl)-2,3,6-tri--benzyl- -D-glucopyranoside... M Methoxyphenyl 4--(2,4,6-Tri--benzyl- -D-galactopyranosyl)-2,3,6-tri--benzyl- -D-glucopyranoside... M Methyl 5-Acetamido-3,5-dideoxy- D-glycero-D-galacto-2-nonulopyranosonate... A Methyl 5-Acetamido-2,4,7,8,9-penta--acetyl- 3,5-dideoxy-D-glycero-D-galacto-2-nonulopyranosonate... M Methyl 5-Acetamido-4,7,8,9-tetra--acetyl- 3,5-dideoxy-D-glycero-D-galacto-2-nonulopyranosonate... A Methyl 5-Acetamido-4,7,8,9-tetra--acetyl-3,5-dideoxy- 2-S-phenyl-2-thio-D-glycero-D-galacto-2-nonulopyranosylonate...M Methyl 5-Acetamido-7,8,9-tri--acetyl-5-N,4--carbonyl- 3,5-dideoxy-2-S-phenyl-2-thio-D-glycero- -D-galacto- 2-nonulopyranosylonate... M Methylamine (ca. 40% in Water, ca. 12mol/L)... M Methyl -D-Arabinopyranoside... M Methyl 4,6--Benzylidene- -D-glucopyranoside... M Methyl 5-N,4--Carbonyl-3,5-dideoxy-2-S-phenyl-2-thio- D-glycero- -D-galacto-2-nonulopyranosylonate... M Methyl- -cyclodextrin (mixture of several Methylated)...M Methyl- -cyclodextrin (2,6-Di--methyl- and partially 2,3,6-Tri--methyl- mixture)... D Methyl 2,3-Di--benzoyl-4,6--benzylidene- -D-glucopyranoside... M Methyl 2,3:4,6-Di--benzylidene- -D-mannopyranoside..M Methyl -L-Fucopyranoside... M Methyl -L-Fucopyranoside... M Methyl -D-Galactopyranoside Monohydrate... M Methyl -D-Galactopyranoside... M N-Methyl-D-glucamine... M N-Methyl-D-glucamine Hydrochloride [for Buffer]...M Methyl -D-Glucopyranoside... M Methyl -D-Glucopyranoside Hemihydrate... M Methyl (1S)-1 -( -D-Glucopyranosyloxy)- 7-(hydroxymethyl)-1,4aalpha,5,7aalphatetrahydrocyclopenta[c]pyran-4-carboxylate... G Methyl -D-Glucoside... M Methyl -D-Glucoside Hemihydrate... M Methylhydrazine... M Methyl Iodide (stabilized with Copper chip)...i Methyl -D-Mannopyranoside... M Methyl-D-mannoside... M Methyl -D-Mannoside... M Methyl (Phenyl 5-Acetamido-4,7,8,9-tetra--acetyl-3,5- dideoxy-2-thio-d-glycero-d-galacto-2-nonulopyranosid)onate..m Methyl (Phenyl 5-Acetamido-7,8,9-tri--acetyl- 5-N,4--carbonyl-3,5-dideoxy-2-thio-D-glycero- -D-galacto-2-nonulopyranosid)onate... M Methyl (Phenyl 5-N,4--Carbonyl-3,5-dideoxy-2-thio- D-glycero- -D-galacto-2-nonulopyranosid)onate... M Methyl (Phenyl 7,8,9-Tri--acetyl-5-N,4--carbonyl-3,5- dideoxy-2-thio-d-glycero- -D-galacto-2-nonulopyranosid)onate..M Methyl (Phenyl 2,3,4-Tri--acetyl-1-thio- -D-glucopyranosid)uronate... M Methyl -D-Ribofuranoside... M Methyl 1,2,3,4-Tetra--acetyl- -D-glucopyranuronate...M Methyl 1,2,3,4-Tetra--acetyl- -D-glucuronate... M Methyl 2,3,4,6-Tetra--acetyl-1-thio- -D-glucopyranoside... M Methyl 2,3,4,6-Tetra--acetyl-1-thio- -D-mannopyranoside (contains ca. 5% -isomer)...m Methyl 2,3,4,6-Tetra--pivaloyl-D-mannopyranoside... M Methyl 7,8,9-Tri--acetyl-5-N,4--carbonyl-3,5-dideoxy- 2-S-phenyl-2-thio-D-glycero- -D-galacto- 2-nonulopyranosylonate...M Methyl 3,4,6-Tri--acetyl-2-deoxy-2-phthalimido-1-thio- -D-glucopyranoside...M Methyl 2,3,4-Tri--acetyl-1-thio- -L-fucopyranoside...M Methyl 2,3,6-Tri--benzoyl- -D-galactopyranoside...M Methyl 2,3,4-Tri--benzoyl- -D-glucopyranoside...M Methyl 2,3,4-Tri--benzyl- -D-glucopyranoside...M Methyl 2,3,4-Tri--benzyl-1-thio- -L-fucopyranoside...M Methyl Tributylstannyl Sulfide...M Methyltrichlorosilane...M Methyl Trifluoroacetate... T Methyl- -D-xylopyranoside...M Monoammonium Glycyrrhizinate Hydrate... G Mono-6--mesitylenesulfonyl- -cyclodextrin...m Mono-2--(p-toluenesulfonyl)- -cyclodextrin...m Morph-DAST...M Morpholinosulfur Trifluoride...M N NANA Hydrate... A Naringenin 7-Rhamnoglucoside Hydrate... N Naringin Hydrate... N NBS... B Neohesperidin Dihydrochalcone Hydrate... N Neu5Ac Hydrate... A Neu5Ac (2-3)Gal- -ethylamine... N Neu5Ac (2-6)Gal- -ethylamine... N Neu5Ac (2-3)Gal (1-4)[Fuc (1-3)]GlcNAc (1-3)Gal- (1-4)Glc...S NeuAc (2-3)Gal (1-4)Glc-ceramide (phyto-type)... G Neu5Ac (2-3)Gal (1-4)GlcNAc- -ethylamine... N Neu5Ac (2-6)Gal (1-4)GlcNAc- -ethylamine... N Neu5Ac (2-3)Gal (1-4)GlcNAc (1-3)Gal- (1-4)Glc-ceramide...S Neu5Ac (2-3)Gal (1-3)GlcNAc- -pnp... N Neu5Ac (2-3)Gal (1-4)GlcNAc- -pnp... N Neu5Ac (2-6)Gal (1-3)GlcNAc- -pnp... N Neu5Ac (2-6)Gal (1-4)GlcNAc- -pnp... N Neu5Ac (2-3)Gal (1-4)Glc- -pnp... N Neu5Ac (2-3)Gal MP Glycoside... N Neu5Ac (2-6)Gal MP Glycoside... N Neu5Ac (2-6)GalNAc- -pnp... N Neu5Ac[1Me,4789Ac] (2-6)Gal[24Bz,3Bn]- -MP...M Neu5Ac[1Me,4789Ac] (2-3)Gal[246Bz]- -MP... N Neu5Ac[1Me,4789Ac]-SPh...M Neu5Gc... G Neu5GcAc[1Me,4789Ac] (2-6)Gal[24Bz,3Bn]- -MP...M Neu5GcAc[1Me,4789Ac] (2-3)Gal[246Bz]- -MP... N Neu5Gc (2-3)Gal MP Glycoside... N Neu5Gc (2-6)Gal MP Glycoside... N Neu5Troc[1Me,4789Ac] (2-3)Gal[26Bn]- -MP...M NIS...I Nistose Trihydrate... N Nitrobenzoic Acid... N Nitrophenyl 2-Acetamido-2-deoxy- 3--(2-acetamido-2-deoxy- -D-galactopyranosyl)- -D-glucopyranoside... G Nitrophenyl 2-Acetamido-2-deoxy- 4--(2-acetamido-2-deoxy- -D-galactopyranosyl)- -D-glucopyranoside... G Nitrophenyl 2-Acetamido-2-deoxy- -D-galactopyranoside... N Nitrophenyl 2-Acetamido-2-deoxy- 3--( -D-galactopyranosyl)- -D-galactopyranoside... G Nitrophenyl 2-Acetamido-2-deoxy- 3--( -D-galactopyranosyl)- -D-glucopyranoside... G Nitrophenyl 2-Acetamido-2-deoxy- -D-glucopyranoside... N Nitrophenyl N-Acetyl- -D-galactosaminide... N Nitrophenyl N-Acetyl- -D-glucosaminide... N Nitrophenyl -D-Cellobioside... N Nitrophenyl -L-Fucopyranoside... N Nitrophenyl -D-Fucopyranoside... N Nitrophenyl -D-Galactopyranoside [Substrate for -D-Galactosidase]... N

328 Product Name Index- 4-Nitrophenyl -D-Galactopyranoside [Substrate for -D-Galactosidase]... N Nitrophenyl -D-Galactopyranoside [Substrate for -Galactosidase]... N Nitrophenyl -D-Glucopyranoside [Substrate for -D-Glucosidase]... N Nitrophenyl -D-Glucopyranoside Monohydrate [Substrate for -D-Glucosidase]... N Nitrophenyl -D-Glucopyranosiduronic Acid... N Nitrophenyl -D-Glucopyranosiduronic Acid... N Nitrophenyl -D-Glucuronide... N Nitrophenyl -D-Glucuronide [Substrate for -Glucuronidase]... N Nitrophenyl -D-Mannopyranoside [Substrate for -Mannosidase]... N Nitrophenyl -D-Xylopyranoside... N Nitrophenyl -D-Xylopyranoside [Substrate for -Xylosidase]... N Nonasaccharide Glc 4 Xyl 3 Gal 2... N Nonyl -D-Glucopyranoside... N Nystose Trihydrate... N Ac PtdGlc(di-acyl Chain)... A cta--acetyl -D-Cellobiose... C cta--acetyl D-(+)-Saccharose...S cta--acetyl D-(+)-Sucrose...S ,3,4,6,7,8,9,10-ctahydropyrimido[1,2-a]azepine... D n-ctyl -D-Glucopyranoside [for Biochemical Research] n-ctyl -D-Glucopyranoside NPG... N uabain ctahydrate...s xovaleric Acid...L P Paeonolide... P Paeonoside... A Palatinose Hydrate... P Palmitoyl-L-ascorbic Acid... A Panose... P Pectin from Citrus... P Pectinase from Aspergillus niger... P ,4,7,8,9-Penta--acetyl- N-acetylneuraminic Acid Methyl Ester... M Penta-N-acetylchitopentaose... P N,N',N'',N''',N''''-Pentaacetylchitopentaose... P Penta--acetyl- -D-galactopyranose... G Penta--acetyl- -D-glucopyranose... G Penta--acetyl- -D-glucopyranose... P Pentaacetyl- -D-glucosamine... A Pentaacetyl- -D-glucose... G Pentaacetyl- -D-glucose... P ,2,3,4,6-Penta--acetyl-D-mannopyranose... P L-2,3,4,6/5-Pentahydroxycyclohexanone...I ,2,3,4,6-Penta--pivaloyl-D-mannopyranose... P Phenyl 2-Acetamido-2-deoxy- -D-glucopyranoside... P Phenyl N-Acetyl- -D-glucosaminide... P Phenyl 2--Acetyl-3,4,6-tri--benzyl-1-thio- -D-galactopyranoside... P Phenyl 3--Allyl-2,4,6-tri--benzyl-1-thio- -D-galactopyranoside... P Phenyl N-Benzyl-2-amino-4,6--benzylidene- 2-N,3--carbonyl-2-deoxy-1-thio- -D-glucopyranoside... P Phenyl 4,6--Benzylidene-1-thio- -D-glucopyranoside... P Phenyl 2-Deoxy-1-thio-2-(2,2,2-trichloroethoxyformamido)- -D-galactopyranoside... P Phenyl -D-Galactopyranoside... P Phenyl -D-Glucopyranoside... P Phenyl -D-Glucopyranoside Hydrate... P Phenyl -D-Glucoside... P Phenyl -D-Glucoside Hydrate... P Phenyl Mercaptan... B Phenyl Sulfone... P Phenyl Sulfoxide... D Phenyl 2,3,4,6-Tetra--acetyl-1-thio- -D-galactopyranoside.. P Phenyl 2,3,4,6-Tetra--acetyl-1-thio- -D-glucopyranoside.. P Phenyl 2,3,4,6-Tetra--benzyl-1-thio- -D-galactopyranoside.. P Phenyl 2,4,6-Tri--acetyl-3--allyl-1-thio- -D-galactopyranoside... P Phenyl 2,4,6-Tri--acetyl-3--allyl-1-thio- -D-glucopyranoside... P Phenyl 3,4,6-Tri--acetyl-2-deoxy-1-thio-2- (2,2,2-trichloroethoxyformamido)- -D-galactopyranoside.. P Phenyl 3,4,6-Tri--acetyl-2-deoxy-1-thio-2- (2,2,2-trichloroethoxyformamido)- -D-glucopyranoside.. P Phenyl 2,3,4-Tri--benzyl-1-thio- -L-fucopyranoside... P Phlorizin Hydrate... P Phosphoric Acid Diphenyl Ester... P Phytic Acid (ca. 50% in Water, ca. 1.1mol/L)... P Phytin... P PNPG... N Polyarabinogalactan from Larch Wood... A Poly- -cyclodextrin (Cross-linked by Epichlorohydrin)... P Potassium Gluconate... G Potassium Hyaluronate from Cockscomb... H D-Psicose... P L-Psicose... P Puerarin... P N-(4-Pyridyl)dimethylamine... D Pyrocarbonic Acid Di-tert-butyl Ester... D Pyrocarbonic Acid Di-tert-butyl Ester (ca. 30% in Dioxane).. D Pyrocarbonic Acid Di-tert-butyl Ester (ca. 30% in Tetrahydrofuran)... D Pyrocarbonic Acid Di-tert-butyl Ester (ca. 30% in Toluene).. D Q (+)-epi-quercitol... Q (+)-proto-quercitol... Q (-)-vibo-quercitol... Q R D-(+)-Raffinose Pentahydrate... R Rebaudioside A... R L-(+)-Rhamnose Monohydrate... R D-(+)-Rhodeose... D L-(-)-Rhodeose... F Ribitol... A D-Ribofuranose 1-Acetate 2,3,5-Tribenzoate... R L-Ribofuranose 1-Acetate 2,3,5-Tribenzoate... R D-Ribofuranose 1,2,3,5-Tetraacetate... R D-(+)-Ribonic Acid -Lactone... R D-(+)-Ribono-1,4-lactone... R D-Ribopyranose 1,2,3,4-Tetraacetate... R D-(-)-Ribose... R L-Ribose... R D-Ribose 1,5-Bis(phosphate) Tetrasodium Salt... R D-Ribose 1,5-Bis(phosphate) Tetrasodium Salt... R Ribose-5-phosphate Barium Salt Hydrate... R Rose-Gal... C Rutin Trihydrate... R Rutinose... R Rutinose Heptaacetate... H S D-(+)-Saccharose...S Saccharose Fatty Acid Ester...S D-(+)-Saccharose ctaacetate...s Salicin...S Salicylaldehyde- -D-glucoside... H Salmon-Gal... C Saponin...S Schardinger -Dextrin... C Schardinger -Dextrin... C Schardinger -Dextrin... C Schardinger -Dextrin... C SEM-Chloride (stabilized with Diisopropylethylamine)... C SGP...S SG-pNP... N Sialylglycopeptide...S Sialyl Lewis X-Lactose...S Sialyl Neolactotetraosylceramide (=Sialyl nlc 4 Cer)...S Sialyl nlc 4...S Sinigrin Hydrate...S Sinigrin...S Sodium 6--Acetyl- -D-glucopyranosyl (R)-2-(Icosanoyloxy)-3-(stearoyloxy)propyl Phosphate... A Sodium L-Ascorbate... A Sodium Glucoheptonate Dihydrate... G

329 Product Name Index- Sodium Gluconate... G Sodium Hyaluronate from Cockscomb... H D-Sorbitol...S D-Sorbose...S L-(-)-Sorbose...S Stachyose Hydrate...S Stearoyl-L-ascorbic Acid... A Streptomycin Sulfate...S g-strophanthin ctahydrate...s Sucralose...S D-(+)-Sucrose...S Sucrose Fatty Acid Ester...S D-(+)-Sucrose ctaacetate...s Sulfur Trifluoride Diethylamine Complex... D Swertiamarin...S Synaptase from Almonds... G T D-Tagatose... T L-Tagatose... T D-Talitol... T L-Talitol... T D-(+)-Talose... T L-(-)-Talose... T TATM... T TBDMSCl... B TBDMS Triflate... T TBSCl... B TBS Triflate... T ,7,8,9-Tetra--acetyl-N-acetylneuraminic Acid Methyl Ester.. A ,2,4,6-Tetra--acetyl-3--allyl- -D-glucopyranose... T ,3,4,6-Tetra--acetyl-2-azido-2-deoxy- -D-galactopyranose... T ,3,4,6-Tetra--acetyl-2-azido-2-deoxy- -D-glucopyranose... T ,3,4,6-Tetra--acetyl-2-azido-2-deoxy- -D-glucopyranose... T ,3,4,6-Tetra--acetyl-2-azido-2-deoxy- -D-mannopyranose... T Tetra-N-acetylchitotetraose... T N,N',N'',N'''-Tetraacetylchitotetraose... T ,3,4,6-Tetra--acetyl-2-deoxy-2-phthalimido- -D-glucopyranose... T ,2,3,4-Tetra--acetyl- -L-fucopyranose... T ,3,4,6-Tetra--acetyl- -D-galactopyranosyl 2,2,2-Trichloroacetimidate... T ,3,4,6-Tetra--acetyl- -D-glucopyranosyl Bromide (stabilized with CaC 3 )... T ,3,4,6-Tetra--acetyl- -D-glucopyranosyl Fluoride... T ,3,4,6-Tetra--acetyl- -D-glucopyranosyl Isothiocyanate [for HPLC Labeling].. A ,3,4,6-Tetra--acetyl- -D-glucopyranosyl 2,2,2-Trichloroacetimidate... T ,2,3,4-Tetra--acetyl- -D-glucopyranuronic Acid Methyl Ester... M ,2,3,4-Tetra--acetyl- -D-glucuronic Acid Methyl Ester..M ,3,4,6-Tetra--acetyl- -D-mannopyranose... T ,3,4,6-Tetra--acetyl-D-mannopyranosyl Fluoride... T ,3,4,6-Tetra--acetyl-PtdGlc(di-acyl Chain)... P ,3,4,6-Tetra--acetyl-PtdGlc(mono-acyl Chain)... P Tetra--acetyl- -D-ribofuranose... R Tetra--acetyl- -D-ribopyranose... R ,3,4,6-Tetra--acetyl-2--(trifluoromethanesulfonyl)- -D-mannopyranose... T ,3,4,6-Tetra--benzoyl-D-glucopyranose... T ,3,4,6-Tetra--benzoyl- -D-glucopyranosyl Isothiocyanate [for HPLC Labeling].. A ,3,4,6-Tetra--benzoyl- -D-glucopyranosyl p-trifluoromethylbenzylthio-n-(p-trifluoromethylphenyl) formimidate... T ,3,4,6-Tetra--benzoyl-D-mannopyranose... T ,3,4,6-Tetra--benzyl-D-glucopyranose... T ,3,4,6-Tetra--benzyl-D-glucopyranosyl Fluoride... T ,3,4,6-Tetra--benzyl- -D-glucopyranosyl Fluoride... T ,3,4,6-Tetra--benzyl- -D-glucopyranosyl Fluoride... T ,3,4,6-Tetra--benzyl- -D-glucopyranosyl N,N,N',N'-Tetramethylphosphorodiamidate (ca. 20% in Benzene)... T ,3,4,6-Tetra--benzyl- -D-glucopyranosyl p-trifluoromethylbenzylthio-n-(p-trifluoromethylphenyl) formimidate... T Tetrabutylammonium p-nitrophenoxide... T ,3,4,6-Tetra--pivaloyl-D-mannopyranosyl Fluoride... T ,4'-Thiodiphenol... D Thiophenol... B L-Threitol... T TMCS... C Topiramate... T D-(+)-Trehalose Anhydrous... T D-(+)-Trehalose Dihydrate... T ,3,4-Tri--acetyl- -L-arabinopyranosyl 2,2,2-Trichloroacetimidate... T Tri-N-acetylchitotriose... T N,N',N''-Triacetylchitotriose... T Triacetyl- -cyclodextrin... T ,4,6-Tri--acetyl-2-deoxy-D-glucopyranose... T ,4,6-Tri--acetyl-2-deoxy-2-phthalimido- -D-glucopyranosyl 2,2,2-Trichloroacetimidate... T ,2,3-Tri--acetyl-5-deoxy- -D-ribofuranose... T Tri--acetyl-D-galactal... T Tri--acetyl-D-glucal... T ,3,5-Tri--benzoyl- -D-ribofuranose... T ,4,6-Tri--benzyl-2-deoxy-D-galactopyranose... T ,4,6-Tri--benzyl-2-deoxy-D-glucopyranose... T Tri--benzyl-D-galactal... T Tri--benzyl-D-glucal... T Tributyl(methylthio)tin...M Trichloro(methyl)silane...M Triethylammonium (R)-2-Hydroxy- 3-(stearoyloxy)propyl 2,3,4,6-Tetra--acetyl- -D-glucopyranosyl Phosphate... P Triethylammonium (R)-2-(Icosanoyloxy)- 3-(stearoyloxy)propyl 2,3,4,6-Tetra--acetyl- -D-glucopyranosyl Phosphate... P Triethylenediamine... D Trifluoroacetic Acid Methyl Ester... T N-Trifluoroacetyl-D-glucosamine... T Trifluoromethanesulfonic Acid tert-butyldimethylsilyl Ester.. T Trifluoromethanesulfonic Acid Copper(II) Salt... T ',5,7-Trihydroxy-4'-methoxyflavone 7-Rutinoside... D (Triisopropylsilyl)-D-galactal... T ,,4-Trimethoxytoluene... A Trimethylchlorosilane... C Trimethylsilyl Chloride... C (Trimethylsilyl)ethoxymethyl Chloride (stabilized with Diisopropylethylamine)... C Trimethylsilylmethyl Methyl Ether...M Trisodium Glycyrrhizinate Hydrate... G D-(+)-Turanose... T V N-Valeryl-D-glucosamine... V Vitamin C... A Vitamin C Sodium Salt... A Vitamin P... H X Xanthan Gum... X X-Gal... B XLLG Glc 4 Xyl 3 Gal 2... N XXXG Glc 4 Xyl 3... H XXXG Glc 4 Xyl 3... H Xylitol... X Xylobiose... X Xyloglucan Heptasaccharide Glc 4 Xyl 3... H Xyloglucan Heptasaccharide Glc 4 Xyl 3... H Xyloglucan Nonasaccharide Glc 4 Xyl 3 Gal 2... N D-Xylopyranosyl-D-xylose... X D-(+)-Xylose... X L-(-)-Xylose... X Xylosucrose... X Z Zinc(II) Gluconate Hydrate... G Zymosan [Immunological Reagent]...Z

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331 Appendix Basic Structures of Glycolipids / Basic Structures of Glycoproteins / Basic Structures of Proteoglycans / The Physical Properties of the Typical rganic Solvents Freezing Mixtures / Preparation of Reagents and Solutions / Pressure-Temperature Nomograph /

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335 rganic Solvents bp C mp C d 20/4 C Compatibility with Water C weight of solvents Miscibility with Waterb) Methanol (MeH) a) Ethanol (EtH) (96.0) Propanol (n-prh) (71.7) Isopropyl Alcohol (i-prh) (88.0) Butanol (BuH) (57.5) Isobutyl Alcohol (i-buh) (67) sec-butyl Alcohol (s-buh) (73.2) tert-butyl Alcohol (t-buh) (88.2) Ethylene Glycol a) 1,2-Dimethoxyethane (Glyme) (89.9) Diethyl Ether (Et 2) (98.7) c) Diisopropyl Ether (i-pr 2) (95.5) Acetic Acid (AcH) a) Ethyl Acetate (AcEt) (91.5) c) Acetic Anhydride (Ac 2) Tetrahydrofuran (THF) (93.3) 1,4-Dioxane (82) Acetone a) Ethyl Methyl Ketone (88.7) Carbon Tetrachloride (CCl 4) (95.9) Chloroform (CHCl 3) (97.8) Dichloromethane (CH 2Cl 2) (98.5) 1,2-Dichloroethane (ClCH 2CH 2Cl) (91.8) Benzene (C 6H 6) (91.2) Toluene (79.8) o-xylene (50.1) Cyclohexane (91) Pentane (98.6) Hexane (94.4) Heptane Acetonitrile (CH 3CN) (84.2) Nitromethane (CH 3N 2) (76.4) Dimethylformamide (DMF) a) Hexamethylphosphoric Triamide (HMPA) Triethylamine (Et 3N) Pyridine (Py) (58.7) Dimethyl Slufoxide (DMS) a) Carbon Disulfide (CS 2) (97.2) a) It doesn't form azeotropic mixture b) freely miscible c) highly soluble in water partially miscible practically immiscible (solubility : less than 1%) Example of combination of recrystallization solvents The crystals are obtained from the solution of single or more than one solvent. In the two solvent system, solvent A and B should be miscible : when solubility is A > B, it is desirable that the boiling point is A < B and the density is A > B. Freezing mixtures Temp. C Freezing mixtures Temp. C Ice 0 Ethylene Glycol / C 2-15 Ice(100) / NH 4Cl (25) -15 Ice(100) / NaCl(33) -21 Carbon Tetrachloride / N 2-23 Carbon Tetrachloride / C 2-23 Ice(100) / EtH (100) -30 Acetonitrile / N 2-41 Ice(100) / CaCl 2 (150) -49 Chloroform / N 2-63 Chloroform / C 2-63 Ethanol / C 2-72 Ether / C 2-77 Acetone / C 2-78 Methanol / N 2-98 n-pentane / N N References 1 "Yuki Kagaku Jikken no Tebiki 1", editors : T. Goto, T. Shiba, T. Matsuura, Kagaku Dojin 2 "Shinhan Kiso Yuki Kagaku Jikken", K. Hata, K. Watanabe, Maruzen 333

336 Initial Concentration of Ammonium Sulfate (%) Final Concentration of Ammonium Sulfate (%) Ammonium Sulfate (solid) to be added (g) to 1L

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340 How to calculate the bp under atmospheric pressure from bp under reduced pressure Connect a degree on the line C and its corresponding bp on the line A under reduced pressure using a straight line. An intersection found by step on the line B serves as an approximate bp in atmospheric pressure. *This nomograph applies to nonassociated solvent. Since the bp obtained from this nomograph is an approximate value, it is not an exact bp. Reference Science of Petroleum, Vol.II. p.1281 (1938). 338

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350 Reagents for Glyco Chemistry & Biology 4th Edition Not for Sale Fourth Edition : July 2013 Publisher TKY CHEMICAL INDUSTRY C., LTD , Nihonbashi-Honcho, Chuo-Ku, Tokyo , Japan Editor TKY CHEMICAL INDUSTRY C., LTD. Technical Information Management Department 2013 Tokyo Chemical Industry Co., Ltd. Reproduction forbidden without permission. T Printed in Japan

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