com_avail_chiral.cdx

Transcription

1 Commercially Available Chiral Synthetic Units > Amino Acids C L-Alanine (Ala, A) [ ] / 100g * D-Ala: [ ] / 100g * araninamide-cl: [ ] / 5g * t Bu ester-cl [ ] / 5g * Et ester-cl [ ] / 25g * Me ester-cl [ ] / 25g * D-Ala-Me-ester-Cl [ ] / 25g * -Boc-D-Ala: [ ] / 25g * -Boc-L-Ala: [ ] / 100g * -Cbz: [ ] / 100g * -Fmoc-L-Ala: [ ] 8400 / 25g * -Boc-D-Ala-Me ester: [ ] / 10g * -Boc-L-Ala-Me ester: [ ] / 10g * -Boc--Me: [ ] / 5g * -Boc-Weinreb amide:[ ] / 5g *,-di( n Pr): [ ] 8800 / 1g 2 C L-Arginine (Arg, R) [ ] / 500g * D-Arg: [ ] / 5g * α-bz-et ester-cl: [ ] / 25g * α-boc: [ ] / 5g * α-cbz: [ ] 4600 / 5g * α-boc-δ,ω-dicbz: [ ]15600 / 2.5g * α-fmoc: [ ] / 5g * α-ts-me ester-cl: [ ] / 100g * ω-nitro: [ ] 9000 / 10g * ω-nitro-me ester-cl: [ ] / 25g 2 C L-Asparagine (Asn, ) [ ] * monohydrate [ ] 4800 / 100g * D-Asn-monohydrate: [ ] / 100g * -Ac: [ ] / 5g * -Boc: [ ] / 100g * -Cbz: [ ] 6600 / 10g * -Fmoc: [ ] 5900 / 5g 2 C L-Lysine (Lys, K) [ ] / 100g * L-Lys-2Cl [ ] / 100g * L-Lys-Cl [ ] 7500 /1kg * D-Lys: [ ] / 25g * D-Lys-Cl [ ] / 25g * α-ac: [ ] 9000 / 1g * ε-ac: [ ] / 5g * α-boc: [ ] / 25g * α-boc-ε-fmoc: [ ] / 25g * α-fmoc-ε-boc: [ ] / 25g * ε-boc: [ ] / 5g * α-cbz: [ ] / 5g * (D-)α-Cbz: [ ] / 5g * ε-cbz: [ ] / 50g * α ε-dicbz: [ ] / 25g C update: K.isaki L-Aspartic acid (Asp, D) [ ] 7700 / 500g * D-Asp: [ ] 8300 / 25g * K salt-hydrate: [ ] 5900 / 100g * a salt-monohydrate: [no CAS-o.] / 500g * -Ac: [ ] / 25g * dime ester-cl: [ ] / 25g * dibn ester-ts: [ ] / 25g * -Boc: [ ] / 10g * -Boc-1-Bn ester: [ ] / 25g * -Boc-4-Bn ester: [ ] / 25g * (D-)-Boc-4-Bn ester: [ ] / 25g * -Boc-4-Me ester: [ ] / 5g * -Cbz-1-Me ester: [ ] / 5g * -Cbz-4-Me ester: [ ] / 5g * -Cbz-4- t Bu ester: [ ] / 5g * -Cbz: [ ] 7800 / 25g * -Cbz-anhydride: [ ] / 25g L-Glutamic acid (Glu, E) [ ] 8400 / 1kg * D-Glu: [ ] / 100g * mono a salt-hydrate: [ ] 8100 / 1kg * γ-bn ester: [ ] / 25g * γ-me ester-cl: [ ] / 25g * diet ester-cl: [ ] 9400 / 25g * -Ac: [ ] 8800 / 100g * (D-)-Bz: [ ] / 10g * -(4-aminoBz)-diEt ester: [ ] / 25g * (D-)-Boc-1-Bn ester: [ ] / 25g * -Fmoc-γ- t Bu ester hydrate: [ ] / 5g * -Fmoc-γ- t Bu ester: [ ] / 25g * -(4-nitroBz)-hemihydrate: [ ] / 5g * -phthaloyl: [ ] / 10g * -Cbz: [ ] 7300 / 25g * -Cbz-1-Me ester: [ ] 7600 / 1g * (S)--Cbz-,α-methylidene: [ ] / 5g * -Fmoc-4- t Bu ester: [ ] / 25g * (S)--Cbz-,α-methylidene: [ ] / 5g C S C L-Cysteine (Cys, C) [ ] / 500g * L-Cystine (Cys dimer) [ ] / 500g * Cl salt-hydrate: [ ] / 1kg * Et ester-cl: [ ] / 100g * Me ester-cl: [ ] 4600 / 25g * cystine dime ester-2cl: [ ] / 25g * -Ac: [ ] / 500g * -Ac-Me ester: [ ] / 25g * S-Bz: [ ] / 100g * -Boc-Me ester:[ ] / 25mL * -Cbz-S-: [ ] / 25g *,S-diAc-Me ester: [ ] 9600 / 5g * -Fmoc-S-Tr: [ ] / 5g * S-: [ ] / 5g * S-Tr: [ ] / 5g * S,-carbonyl: [ ] / 5g 2 C L-Glutamine (Gln, Q) [ ] / 500g * α-boc:[ ] / 25g * α-boc-δ-tr: [ ] / 5g * α-fmoc:[ ] 5900 / 5g * α-cbz: [ ] / 25g C L-istidine (is, ) [ ] / 1kg * Cl-hydrate: [ ] / 1kg * D-is-Cl-hydrate: [ ] 7800 / 5g * Me ester-2cl: [ ] / 100g * α-boc: [ ] 9600 / 5g * α-boc- im -Tr: [ ] / 5g * α-fmoc- im -Tr: [ ] / 25g * α, im -diboc-me ester: [ ] / 5g * α-cbz: [ ] 7900 / 5g C L-Leucine (Leu, L) [ ] / 1kg * D-Leu: [ ] / 25g * Me ester-cl: [ ] 8000 / 25g * -Boc: [ ] / 100g * (D-)-Boc:[ ] / 25g * -Boc-Me ester: [ ] / 25mL * -Boc-Weinreb amide: [ ] / 5g * -Cbz: [ ] 8900 / 25mL * -Fmoc: [ ] / 100g * leucinamide-cl: [ ] 7500 / 5g * p-nitroanilide [ ] / 5g L-Proline (Pro, P) [ ] / 1kg C * D-Pro: [ ] 7700 / 5g * Me ester-cl: [ ] / 25g * Bn ester-cl: [ ] / 5g * -Bn-Et ester: [ ] / 5g * -Cbz: [ ] 6300 / 10g * -Cbz-pyrrolidinylamide: [ ] / 5g L-Tryptophan (Trp, W) [ ] / 1kg * D-Trp: [ ] / 100g * Bn ester: [ ] / 5g * Me ester-cl: [ ] / 25g *(D-)Me ester-cl: [ ] / 5g * -Ac-Et-ester: [ ] / 1g * -Boc: [ ] / 100g * (D-)-Boc: [ ] 8100 / 1g * -Boc-Weinreb amide: [ ] / 5g * -Cbz: [ ] / 25g * -Fmoc: [ ] / 25g * -trifluoroacetyl-acylchloride: [ ] / 25g * -Boc: [ ] 9000 / 5g * -Cbz: [ ] 9900 / 25g * -Fmoc: [ ]5900 / 5g * -methoxycarbonyl-me ester: [ ] / 5g C

2 C L-Tyrosine (Tyr, Y) [ ] / 1kg * D-Tyr: [ ] 4600 / 5g * Cl salt: [ ] / 25g * hydrazide: [ ] / 25g * Me ester: [ ] / 100g * Me ester-cl: [ ] 7800 / 25g * α-ac-tyrosinamide: [ ] / 5g * -Ac: [ ] 6100 / 25g * -Ac-Et ester hydrate: [ ] /25g * -Bz-Et ester: [ ] / 25g * -Boc: [ ] / 100g * -Boc--Me: [ ] / 5g * (D-)-Boc--Me: [ ] / 25g * -Boc-Me ester: [ ]19800 / 25g * -Fmoc-- t Bu: [ ] / 5g * -Cbz-hydrate: [ ] / 25g C L-Threonine (Thr, T) [ ] / 1kg * D-Thr: [ ] / 100g * -Bz: [ ] / 5g * -Bz-Me ester [ ] 8200 / 1g * -Boc: [ ] 8700 / 5g * -Boc--Bn: [ ] / 5g * -Boc-Me ester: [ ] / 10g * -Boc-- t Bu: [ ] / 5g * -Cbz: [ ] / 25g * -Cbz-Me ester: [ ] / 5g C L-enylalanine (e, F) [ ] / 1kg * D-e: [ ] / 100g * -Ac: [ ] 6500 / 5g * -Ts: [ ] / 50g * -Ts-acylchloride: [ ] / 25g * -Boc: [ ] / 100g * -ethoxycarbonyl: [ ] / 25g * (D-) -Boc: [ ] / 25g * -Boc-Me ester: [ ] / 25g *,-dime: [ ] / 5g * -Fmoc: [ ] / 25g * Et ester-cl: [ ] / 50g * (D-) Me ester-cl: [ ] / 10g * Me ester-cl: [ ] 7100 / 10g * -Cbz: [ ] / 5g MeS C L-Methionine (Met, M) [ ] / 1kg * D-Met: [ ] / 25g * -Boc: [ ] / 25g * -Boc-Cy 2 salt: [ ] / 25g * (D-)-Boc: [ ] / 25g * -Cbz: [ ] / 25g * Et-ester-Cl: [ ] / 50g * Me-ester-Cl: [ ] / 25g C L-Isoleucine (Ile, I) [ ] / 1kg * -Boc: [ ] / 25g * -Cbz: [ ] / 25g C L-Serine (Ser, S) [ ] / 1kg * D-Ser: [ ] / 25g * Et ester-cl: [ ] 8000 / 5g * Me ester-cl: [ ] 9700 / 25g *(D-)Me ester-cl: [ ] / 25g * -Bn-D-Ser:[ ] / 5g * -Boc--Me: [ ] / 5g * -Boc: [ ] / 100g * (D-) -Boc: [ ] / 5g * -Boc--Bn: [ ] / 25g * (D-) -Boc--Bn: [ ] / 25g * -Boc-Me ester: [ ] / 10g * (D-) -Boc-Me ester: [ ] / 10g * -Cbz: [ ] / 25g * -Cbz-Me ester: [ ] / 10g * (D-) -Cbz-Me ester: [ ] / 10g *,-dibn--tbs-bn ester:[ ] / 10 ml *,-dibn--tbs-me ester:[ ] / 5g *,-dibn-bn ester:[ ] 9500 / 10mL * (D-),-diBn-Me ester:[ ] / 5g *,-dibn-me ester:[ ] / 5g * -Fmoc-- t Bu: [ ] / 5g * -Tr-Me ester: [ ] / 25g * (R)--Cbz-,α-methylidene: [ ] / 5g * (S)--Cbz-,α-methylidene: [ ] / 5g C L-Valine (Val,V) [ ] / 1kg * D-Val: [ ] / 25g * Me ester-cl: [ ] / 50g * (D-)Me ester-cl: [ ] / 5g * Et ester-cl: [ ] / 25g * -Boc--Me: [ ] / 5g * -Boc: [ ] / 100g * (D-) -Boc: [ ] / 25g * -Boc-Weinreb amide: [ ] / 5g * -Boc-Me ester: [ ] / 25mL * -Cbz: [ ] 4000 / 5g * -Fmoc: [ ] 5900 / 5g * (D-)-Fmoc: [ ] / 5g * valinamide-cl: [ ] / 5g C L-enylglycine [ ] / 100g * D-: [ ] 6200 / 100g * (D-)acylchloride-Cl: [ ] / 100g * Me ester-cl: [ ] / 50g * (D-)Me ester-cl: [ ] / 100g * D-phenylglycinamide-Cl: [ ] / 5g * -Boc: [ ] / 5g * (D-) -Boc: [ ] / 5g * -3,5-dinitrobenzoyl: [ ] / 5g * (D-) -3,5-dinitrobenzoyl: [ ] / 5g C L-orvaline [ ] / 10g * D-: [ ] 9800 / 5g * -Boc: [ ] / 25g * (D-)-Boc: [ ] / 5g C L-orleucine [ ] / 10g * D-: [ ] 5900 / 1g * -Cbz: [ ] / 5g * -Fmoc: [ ] / 5g C L-tert-Leucine [ ] / 25g * -Boc: [ ] / 25g * -Cbz-Cy 2 salt: [ ] / 25g C 2 trans-4-ydroxy-l-proline [ ] / 100g * -Ac: [ ] / 10g * -Boc: [ ] / 25g * -Boc-Me ester: [ ] / 5g * -Boc-Bn ether: [ ] / 25g * -Cbz: [ ] / 25g C 2 cis-4-ydroxy-d-proline [ ] / 10g S C D-Penicillamine [ ] / 100g * L-: [ ] / 5g 2 C L-rnithine * Cl salt: [ ] 7800 / 100g * (D-)Cl salt: [ ] / 10g C L-omophenylalanine *Cl-salt: [ ] / 5g 2 L-omoarginine * 2Cl salt:[ ] / 5g C L-omoserine [ ] / 5g C

3 C Pipecolinic acid * (S)--Boc: [ ] / 5g * (R)--Boc: [ ] / 5g * (S)--Cbz: [ ] 16900/ 5g * (R)--Cbz: [ ] / 5g C 2 ipecotic acid * Et ester-l-tartrate salt: [ ] / 10g * -Fmoc: [ ] / 5g I I I Thyroxine [ ] / 5g *a salt-hydrate: [ ] / 5g S C 2 I L-Thioproline [ ] / 100g C C * =, L-DPA [ ] / 500g * =, 2Cl-hydrate: [ ] / 25g * =I, [ ] / 25g * = 2, [ ] / 25g C * hemihydrate: [ ] / 5g 2 C 2 * hydrate: [ ] / 5g [ ] / 5g C 2 [ ] 9000 / 5g * -Cbz: [ ] / 10g * Bn ester-ts: [ ] / 10g * t Bu amide:[ ] / 5g *,-carbamate: [ ] / 5g Me Me * Cl salt: [ ] / 5g * Ts salt: [ ] / 5g 2 C * -Cbz-Me ester: [ ] / 5g * -Tr-Me ester: [ ] 9300 / 5g * (2R,1R): [no CAS o.] / 5g * (2S,1R): [no CAS o.] / 5g C L-Cyclohexyl-Ala [ ] / 5g C L-Me-Ala [ ] / 5g * D-: [ ] / 5g * -Cbz: [ ] / 5g * -Cbz--Me: [ ] / 5g C Cyclohexylglycine * -Boc: [ ] / 5g * (D-)-Cbz: [ ] / 5g C * =, L-: [ ] / 50g * =, D-: [ ] 7100 / 100g * =, L-Me ester-cl: [ ] / 5g * =, D-Me ester-cl: [ ] / 5g * =F, D-: [ ] / 5g [ ] 7000 / 5g C 2 [ ] / 5g 2 C [ ] / 25g * -Cbz: [ ] / 25g 2 C * 2Cl salt: [ ] / 5g * α,γ-carbonyl-γ-cbz: [ ] / 5g C 2 Bz * (1S, 2R)-: [ ] / 5g * (1R, 2S)-: [ ] / 5g C C 2 * (S)-Me ester: [ ] / 5g C C 2 Me * (R): [ ] / 5mL * (S): [ ] / 5g C 2 [ ] / 10g * (S)- n Bu ester: [ ] / 25mL * (R)-Et ester: [ ] / 5g * (S)-Et ester: [ ] / 5g * (S)-Me ester: [ ] / 5g * (S): [ ] / 5g * (R): [ ] / 5g * (S)--Tr: [ ] / 5g

4 * -Cbz: [ ] / 5g -Br [ ] / 5g 2 D-Cycloserine [ ] / 5g C [ ] / 25g -Cl [ ] / 5g -Cl * (R): [ ] / 5g * (S): [ ] / 5g [ ] / 5g

5 > Amino Alcohols Alaninol * (S)-: [ ] / 10g * (R)-: [ ] / 5g * (R)--Boc: [ ] / 5g * (S)--Boc: [ ] / 5g * (S)-,-diBn: [ ] / 5g * (S)--Cbz: [ ] / 5g L-Tryptophanol [ ] / 1g Valinol * (R)-: [ ] / 5g * (S)-: [ ] / 25g * (D-)-Boc: [ ] 7800 / 1g * -Boc: [ ] / 5g * -Fmoc: [ ] / 5g * (R)-,-carbamate: [ ] / 2.5g * (S)-,-carbamate: [ ] / 5g L-enylglycinol [ ] / 5g * D-: [ ] / 25g * L--Bn: [ ] / 5g * L--Boc: [ ] 6800 / 1g * D--Boc: [ ] / 1g * (R)-,-carbamate: [ ] / 5g * (S)-,-carbamate: [ ] / 5g L-Prolinol [ ] / 25g * D-: [ ] / 5g * -Bn: [ ] / 25g * -Boc: [ ] / 5g * (D-)-Boc: [ ] / 1g * -(2-Me-Bz)--Me: [ ] 9700 / 1g * (R)--(2-methoxybenzoyl); [ ] 6700 / 1g * (S)--(2-methoxybenzoyl); [ ] / 5g * (S)--formyl--Me: [ ] / 5g * (S)--Me: [ ] / 25g enylalaninol * (R)-: [ ] / 5g * (S)-: [ ] / 10g * (R)--Boc: [ ] / 5g * (S)--Boc: [ ] / 10g * (R)--Cbz: [ ] / 5g * (S)--Cbz: [ ] / 5g * (S)-,-diBn: [ ] / 5g * (S)--Ts: [ ] / 5g * (R)-,-carbamate: [ ] / 25g * (S)-,-carbamate: [ ] / 25g * (S)-,-carbamate-Ac: [ ] / 5g * (R)-,-carbamate-propionyl: [ ] / 5g * (S)-,-carbamate-propionyl: [ ] / 5g L-Leucinol [ ] / 25g * D-: [ ] / 5g * (D-)-Boc: [ ] 9000 / 1g * -Boc: [ ] / 5g * -Cbz: [ ] / 5g L-Tyrosinol * Cl salt: [ ] 6000 / 1g L-istidinol * 2Cl salt: [ ] / 5g L-tert-Leucinol [ ] / 5g * -Boc: [ ] / 5g orephedrine *(1S,2R)- -dime, -Methylephedrine [ ] 5200 / 1g *(1R,2S)- -dime [ ] 4200 / 1g * -Me--(2-amnoacetyl)-: [ ] / 5g * -dime--bn bromide: [ ] 9800 / 5g * (1R,2S)-.-di n Bu: [ ] / 5g * (1S,2R)-.-di n Bu: [ ] / 5g * (1R,2S)-.-diEt-Cl: [no CAS o.] / 5g * (1S,2R)-.-diEt-Cl: [no CAS o.] / 5g Me Pseudoephedrine *(1R, 2R): [ ] / 25g *(1S, 2S): [ ] / 100g *(1S, 2S)-α-fluoroacetamide: [ ] / 25g *(1R, 2R)-propionamide: [no CAS o.] / 5g *(1S, 2S)-propionamide: [ ] / 5g Me enylephrine * Cl salt: [ ] / 100g * (1R, 2S)-: [ ] / 5g * (1S, 2R)-: [ ] / 5g L-Isoleucinol [ ] / 5g Epinephrine [ ] / 100g * (R)-: [ ] 8600 / 5g * (S)-: [ ] / 5g Bn [ ] / 1g * -Boc: [ ] / 5g [ ] / 5g *-Boc: [ ] / 5g * (D-)-Boc: [ ] / 5g * (L-)-Boc: [ ] / 5g * =, (R,R)-: [ ] / 5g * =, (S,S)-: [ ] / 5g * = 2, (R,R)-: [ ] 8900 / 25g * = 2, (S,S)-: [ ] / 50g * = 2, dichloroacetamide, Chloramphenicol [ ] 9500 / 25g * =SMe, (S,S)-, Thiomicamine: [ ] / 500g

6 S L-Cysteinol * S-Bz: [ ] / 5g * (S)--Boc: [ ] / 5g * (S)--Boc: [ ] / 5g * (1R,1'R): [no CAS o.] / 5g * (1S,1'R): [no CAS o.] / 5g Me 2 Chirald [ ] / 50g Bn [ ] / 5g * (R): [ ] / 5g * (R)-Cl: [ ] / 10g * (R)--Bn: [ ] / 5g * (S)--Bn: [ ] 9600 / 5g * (R)--Boc: [ ] / 5g [ ] / 5g * (R)-Cl salt [ ] / 5g 2 * (R)-: [ ] / 5g * (S)-: [ ] / 5g 2 [ ] / 5g * - t Bu: [ ]18000 / 5g

7 > Acids, Esters C 2 Mandelic acid * (R): [ ] 5500 / 25g * (S): [ ] / 100g * (R)-Ac: [ ] 9500 / 5g * (S)-Ac: [ ] 9000 / 5g * (R)-Bn ester: [ ] / 25g * (S)-Bn ester: [ ] / 25g * (R)-Et ester: [ ] / 25g * (S)-Et ester: [ ] / 25g * (R)-3-Cl: [ ] / 25g * (R)--formyl-acylchloride: [ ] / 5g * (R)-Me ester: [ ] / 5g * (S)-Me ester: [ ] / 5g 2 C C 2 L-Tartaric acid [ ] 3000 / 500g * D-: [ ] / 100g *,'-diallyltartaramide: [ ] / 100g * D-,,','-tetraMe tartaramide: [ ] / 5g *,,','-tetrame tartaramide: [ ] / 25g *,'-dibenzyltartramide: [ ] / 5g *,'-dibenzyl D-tartramide: [ ] 6400 / 1g * dibz-d-tartaric acid:[ ] / 250g * dibz-l-tartaric acid:[ ] / 100g * dipiv-d-tartaric acid:[ ] / 5g * dipiv-l-tartaric acid:[ ] 9700 / 5g * ditoluoyl-d-tartaric acid:[ ] / 100g * ditoluoyl-l-tartaric acid:[ ] 9300 / 25g * dibz-l-tartaric acid monohydrate:[ ] / 500g * D-DMT:[ ] / 25g * L-DMT:[ ] 9100 / 100g * D-DET:[ ] / 500g * L-DET:[ ] / 500g * D-DIPT:[ ] / 50g * L-DIPT:[ ] / 100g * diac-l-tartaric acid anhydride:[ ] / 50g * benzilydene acetal-dime ester: [ ] / 25g * (+)-isopropylidene acetal-dime ester: [ ] 8400 / 5g * (-)-isopropylidene acetal-dime ester: [ ] / 25mL * mono-a salt-hydrate: [ ] / 1kg L-Ascorbic acid [ ] 6400 / 500g * 6-palmitate: [ ] / 100g * 2',3'-isoproplidene acetal: [ ] / 25g * a salt: [ ] 6800 / 1kg Dehydroascorbic acid [ ] / 5g D-Isoascorbic acid [ ] 6700 / 500g *a salt-hydrate: [ ] 4800 / 250g C 2 * (R): [ ] 7300 / 1g * (S): [ ] 8000 / 1g C 2 L-Lactic acid [ ] / 1kg * -Ac: [ ] / 10g * -Ac-lactyl chloride: [ ] / 5g * Bn ester: [ ] / 25mL * Et ester: [ ] 4400 / 500g * I Pr ester: [ ] 4400 / 100g * D-isobutyl ester: [ ] / 25mL * D--Bn: [ ] / 25g * n Bu ester:[ ] / 100mL * dimer lactone: [ ] / 100g * -TBS-Et ester:[ ] / 25mL * (R)-lactamide: [ ] / 50g * (S)-lactamide: [ ] / 50g * (R)-Me ester: [ ] 5900 / 5g * (S)-Me ester: [ ] / 100g * (S)--(phenylcarbamoyl): [ ] / 5g * a salt: [ ] / 50g * (D-)a salt: [ ] / 5g C 2 * =Br (R):[ ] / 50mL * =Br (S):[ ] 8200 / 5g * =Cl (S):[ ] / 5g * =Cl (R)-Me ester:[ ] / 5g C 2 * =Br, (R)-Me ester: [ ] / 5g * =Br, (S)-Me ester: [ ] / 5g * =, (R)-Me ester: [ ] / 5g * =, (S)-Me ester: [ ] / 25g C 2 * =, (S): [ ] / 5g * =Br, (R): [ ] / 25g * =Br, (S): [ ] / 25g C 2 [ ] 4900 / 1g C 2 [ ] / 100g * Me ester: [ ] / 50g C 2 * =Br, (R)-Et ester: [ ] / 5g * =Cl, (R)-Et ester: [ ] / 5g * =Cl, (S)-Et ester: ] / 5g * =C, (R)-Et ester: [ ] / * =, (R)-Et ester: [ ] / 5g * =, (S)-Et ester: [ ] / 5g * =, (R)-a salt: [ ] 8900 / 1g * =, (R)-Me ester: [ ] / 25g C 2 [ ] / 5g C 2 * (R)-Me ester: [ ] / 5g * (S)-Me ester: [ ] / 5g C 2 * (R): [ ] / 1g * (S): [ ] / 1g C 2 * D-: [ ] / 5g * L-: [ ] / 5g * (R)-Bn ester: [ ] / 5g * (S)-Bn ester: [ ] / 5g * (S)-Me ester: [ ] / 100g C 2 * (R)-Et ester: [ ] / 1kg C 2 [ ] / 5g C 2 * (R): [ ] / 5g * (S): [ ] / 5g C 2 * (R): [ ] / 5mL * (S): [ ] / 5mL

8 2 C C 2 Malic acid * (R): [ ] 6400 / 5g * (S): [ ] 6700 / 100g * (S)-dia salt hydrate: [ ] / 25g * (R)-diiMe ester:[ ] / 5mL * (S)-diMe ester:[ ] / 25g * (R)-diisopropyl ester:[ ] / 25mL * (S)-diisopropyl ester:[ ] / 25mL * (R)-acetonide:[ ] / 25g * (S)-acetonide:[ ] / 25g 2 C C 2 Citramalic acid * (R):[ ] / 5g * (S):[] / 5g 2 C C 2 * (R): [ ] 9000 / 5g * (S): [ ] / 5g * (R)-diMe ester:[ ] 8000 / 5g 2 C [ ] / 10g C 2 Me C 2 * (R): [ ] / 25g * (S), aproxen: [ ] 9000 / 25g C 2 C 2 * (R): [ ] / 5g *(S): [ ] / 5g * (S): [ ] / 25g *(R)-Et ester: [ ] / 1g 2 C C 2 * (1R,3S): [ ] / 500g * (1S,3R): [ ] / 1g Cl 3 C Cl 3 C [ ] 6800 / 5g [ ] / 25g 2 C [ ] 9100 / 1g 2 C Ac C 2 Me C 2 Et [ ] / 25mL [ ] / 5g C 2 (S)-Ibuprofen [ ] / 10g C 2 2 [no CAS o.] / 100g C 2 * (R): [ ] / 5g * (S): [ ] / 5g Pantolactone * (R): [ ] 4400 / 25g * (S): [ ] / 5g * (R)-acrylate: [ ] / 5g Me 2 C [ ] / 10g Ac [ ] / 25g [ ] / 5g * -cis: [ ] / 1g * -trans: [ ] / 5g Me * (R): [ ] / 25g * (S): [ ] / 25g Me Me C 2 Me C 2 Me * (S,S,S,S): [ ] / 5g * (R,R,R,R): [ ] / 25g Me C 2 Me C 2 Me Me [no CAS o.] / 5g

9 > Sugers D-Galactose [ ] / 1kg * pentaacetate: [ ]30200 / 100g * pentapivaloate: [ ] / 5g *(1,2)-(3,4)-diisopropylidene: [ ] / 5g D-Glucose: [ ] / 5kg * L-: [ ] / 25g * =α-me, [ ] / 25g * =β-, [ ] / 5g Bz Bz Bz Bz * =α-bz, [ ] / 5g * =α-br, [ ] / 5g D-Glucosamine * hydrate: [ ] / 1kg * -Ac: [ ] / 500g * -Boc: [ ] / 25g * pentaacetate: [ ] / 5g Ac Ac Et [ ] / 5g Ac Ac R * R=Me: [ ] / 25g * R=Allyl: [ ] / 5g * R=: [ ] / 5g * R=2-nitrophenyl: [ ] / 25g * R=4-nitrophenyl, hydrate: [ ] / 5g Ac Ac * =α-ac, [ ] 6500 / 100g * =β-ac, [ ] / 500g * =α-br, [ ] / 5g * =β-allyl, [ ] / 1g * =β-s, [ ] / 5g * =β- n C 8 17, [ ] / 5g Bn Bn Bn Bn * =β- i Pr, [ ] / 5g * =α-trichloroacetimidate, [ ] / 5g Ac Ac Ac Cl Ac [ ] / 5g Allyl [ ] / 5g Ac Ac [ ] / 5g CCF 3 D-Galactal * triacetate: [ ] / 5g * tribenzoate:[ ] / 5g [ ] / 25g Me [ ] / 5g a D-Galacturonic acid-a [ ] / 25g [ ] / 10g * =, [ ] / 100g * =α-me, [ ] / 1kg [ ] 5400 / 1kg * =β-, [ ] / 25g * =α--(4-nitrophenyl), [ ] / 25g * =β- n C 8 17,[ ] / 100g D-Gluclonic acid [ ] / 100g [ ] 7800 / 1g S S [ ] / 5g D-Glucal [ ] / 10g * tribn: [ ] / 5g * triac: [ ] / 100g * tritbs: [ ] / 5g 2 D-Gluclonamide [ ] / 25g

10 L-Mannose [ ] / 5g L-Arabinose [ ] / 100g * D-: [ ] / 100g * L-Arabitol: [ ] / 100g * D-Arabitol: [ ] / 250g D-Mannnosamine *Cl salt: [ ] / 5g Lyxose * D-: [ ] 6300 / 5g * L-: [ ] / 25g Ac Ac Ac [ ] / 5g Et D-Fructose [ ] 5200 / 1kg * =, D-ylose [ ] / 1kg * L-ylose: [ ] / 25g * =β-me, [ ] 7400 / 25g Cl [ ] / 5g Br D-Fucose [ ] / 5g * L-: [ ] / 100g Ac Ac Ac * D-: [ ] / 5g * L-: [ ] / 5g CCl 3 α-chloralose [ ] / 1kg CCl 3 β-chloralose [ ] 6600 / 100g [ ] / 5g [ ] 6600 / 25g Me [ ] / 5g [ ] / 5g [ ] / 50g Bz Ms Ac [ ] 7100 / 5g C 2 * hydrate: [ ] / 100g * D-: [ ] / 25g * L-: [ ] / 25g *monohydrate: [ ] / 25g [ ] / 1kg [ ] / 25g [ ] 9800 / 25g C 2 D-Saccharic acid * K salt: [ ] / 500g

11 D-Mannitol [ ] 4300 / 1kg * hexaac: [ }13700 / 100g * 1,2-5,6-diisopropylidene: [ ] / 25g * 1,2-isopropylidene: [ ] / 1g * 3,4-isopropylidene: [ ] / 5g * 1,2-3,4-dicyclohexylidene: [ ] / 25g Ac Ac Ac Ac Ac D-Ribose [ ] / 100g * tetraac: [ ] / 25g * 1-Ac-2,3,5-triBz: [ ] / 10g Ac * hydrate: [ ] / 10g * R=Me, [ ] / 1kg * R=Et, [ ] 5800 / 100g (p- 2 -Bz) Ac [ ] / 5g R [ ] 8500 / 1g * =, 2-Deoxyribose * =Me, [ ] / 5g * a salt: [ ] 2800 / 1kg ct [ ] / 50g Me D-Sorbitol [ ] 4200 / 1kg * hexaacetate: [ ] / 100g * D-: [no CAS o.] / 5g [ ] / 5g [ ] / 100g * L-: [no CAS o.] / 5g D-Threitol * D-2,3--benzylidene: [ ] 7100 / 1g * L-2,3--benzylidene: [ ] / 5g * D-2,3--benzylidene-1,4-diTs: [ ] / 5g * L-2,3--benzylidene-1,4-diTs: [ ] / 5g * D-2,3--isopropylidene: [ ] 9300 / 1g D-Isosorbide [ ] / 500g Isomannide [ ] / 100g [ ] / 1kg [ ] / 25g C C 2 Me [ ] / 5g

12 > Alcohols Glycidol * (R): [ ] / 5g * (S): [ ] / 5g * (R)-butyrate: [ ] / 5g * (S)-butyrate: [ ] / 5g * (R)-Me ether: [ ] / 5g * (S)-Me ether: [ ] / 5g * (R)-m-nitrobenzenesulfonate: [ ] / 25g * (S)-m-nitrobenzenesulfonate: [ ] / 25g * (R)-p-nitrobenzoate: [ ] 9600 / 1g * (S)-p-nitrobenzoate: [ ] 9700 / 1g * (R)-tosylate: [ ] / 25g * (S)-tosylate: [ ] / 25g * (R)-Tr ether: [ ] / 5g * (S)-Tr ether: [ ] / 5g * (S)-TBS ether: [ ] / 5g * (R)-p-nitrobenzoate: [ ] / 1g * (S)-p-nitrobenzoate: [ ] / 5g [ ] / 5g Br * (R):[ ] / 5g * (S):[ ] / 5g Cl * (R):[ ] / 5g * (S):[ ] / 5g * (R): [ ] / 5g * (S): [ ] / 5g * (S): [ ] / 5g * (R): [ ] / 5g * (R): [ ] / 5g * (S): [ ] / 5g F [ ] / 25g Br * (R): [ ] 7100 /1g * (S): [ ] 5700 / 1g [ ] 3900 / 10g * Ms ester: [ ] / 5g n-c 6 13 * (R): [ ] / 10g * (S): [ ] / 10g n-c 7 15 * (R): [ ] / 5g * (S): [ ] / 5g n-c 8 17 [ ] / 5g n-c 9 19 [ ] / 5g Cl * (R): [ ] / 5g * (S): [ ] / 5g * (R): [ ] / 25g * (S): [ ] / 25g * (R)-1-(4-F-)ether:[ ] / 5g * (S)-1-(4-F-)ether: [ ] / 5g * (R)-carbonate: [ ] / 25g * (S)-carbonate: [ ] / 25g Bn [ ] / 5g * (R)-BIL: [ ] / 10g * (S)-BIL: [ ] / 10g * (R)-diAc: [ ] / 25g * (R)-diTs: [ ] / 25g * (S)-diTs: [ ] / 25g Cl n-c 6 13 * (R):[ ] / 25g * (S):[ ] / 25g [ ] / 5g * (R)- 8 -BIL [ ] / 5g * (S)- 8 -BIL [ ] / 1g Ts ydrobenzoin * (R,R): [ ] / 25g * (S,S): [ ] / 25g * (R): [ ] 7100 / 1g * (S): [ ] 9100 / 1g * (S)-2-tosylate: [ ] / 1g Bn [ ] / 5g * (R):[ ] 8700 / 1g * (S): [ ] / 1g Me * (R):[ ] / 5g * (S):[ ] / 5g Bn [ ] / 25g [ ] / 5g Ac [ ] / 5g [ ] / 1g * (R):[ ] / 5g * (S):[ ] / 5g * (R,R):[ ] / 5g * =Br [ ] / 5g * =Cl [ ] / 5g * (R): [ ] / 5g * (S): [ ] / 25g

13 > Amines enethylamine * (R):[ ] / 100mL * (S): [ ] / 100mL * (S)--Bn: [ ] / 50mL * (R)--Bn: [ ] / 50mL * (S)--Allyl: [ ] / 10mL * (R)-4-Cl: [ ] / 5g * (S)-4-Cl: [ ] / 5g * (R)--Me: [ ] / 5g * (S)--Me: [ ] / 5g * (R)-,-diMe: [ ] / 5g * (S)-,-diMe: [ ] / 5g * (R)--3,5-dinitrobenzoyl: [ ] /1g * (S)--3,5-dinitrobenzoyl: [ ] / 5g * (R)-phenylglyoxylamide: [ ] / 5g * (R)-monophthalamide: [ ] / 1g * (S)-monophthalamide: [ ] 4300 / 1g * (R)-monosuccinamide: [ ] / 5g * (S)-monosuccinamide: [ ] / 5g * (R)-trifluoroacetyl: [ ]18100 / 50g * (S)-trifluoroacetyl: [ ]17400 / 50g 2 2Cl * (R)-: [ ] / 1g * (S)-: [ ] / 1g * (R): [ ] / 5g * (S): [ ] / 5g * =Br, (R): [ ] / 5g * =Me, (R): [ ] / 1g * =Me, (S):[ ] / 1g * =Me, (S): [ ] / 25g * = 2, (R)-Cl: [ ] 6600 / 1g * = 2, (S)-Cl:[ ] 5700 / 1g 2Cl [ ] / 10g 2Cl [ ] / 10g * (R): [ ] 6800 / 5g * (S): [ ] 9000 / 5g [ ] / 5g * (S)--Bn-Cl: [ ] / 5g 2 [ ] 8500 / 500g * acetate: [ ] / 25g * (R,R): [ ] / 10g * (S,S): [ ] / 10g * (R,R)-Cl: [ ] / 5g * (S,S)-Cl: [ ] / 5g * (R): [ ] / 25g * (S): [ ] / 5g * -Boc:[ ] 9800 / 1g * (R)-BIAMIE: [ ] / 1g * (S)-BIAMIE: [ ] / 1g 2 * (R,R):[ ] / 5g * (S,S):[ ] / 1g * (R,R)-L-tartrate salt:[ ] / 10g * (S,S)-D-tartrate salt:[ ] / 10g * (R,R)-,'-diTs:[ ] / 5g * (S,S)-,'-diTs:[ ] / 5g * (R,R)-,'-diTf:[ ] / 5g 2 * (R,R): [ ] / 1g [no CAS o.] / 5g * (R)-2Cl: [ ] 6400 / 1g * (S)-2Cl: [ ] 9800 / 1g [ ] 9600 / 1g (-)-Sparteine [ ] / 100mL *sulfate-hydrate: [ ] / 100g Cl S (-)-Tetramisole [ ] 6700 / 10g

14 > itrile, Isonitrile, Isocyanate, Sulfur 2 S Bn Ts S S * (R,R): [ ] / 5g * (S,S): [ ] / 5g [ ] / 5g [ ] / 5g [ ] / 5g C * =, (R)-Mandelonitrile [ ] / 5g * =Cl, (R): [ ] / 5g * =Me, (R): [ ] / 5g C Cl [ ] / 5g C * (R): [ ] / 5g * (S): [ ] / 1g C * (R): [ ] / 5g * (S): [ ] / 5g C [ ] / 10g S [ ] / 5g > Ketones, alides, Epoxides, etc... [ ] / 5g [ ] / 5g * (R):[ ] / 25g * (S):[ ] / 25g * (R):[ ] / 5g * (S):[ ] / 5g * (R):[ ] / 25g * (S):[ ] / 25g Ac Cl [ ] / 25g [ ] / 5g I Cl Epichlorohydrin * (R):[ ] / 25g * (S):[ ] / 25g * (R,R): [ ] / 5g * (S,S): [ ] / 5g Cl * (S): [ ] / 5g * (R): [ ] / 5g

15 > atural Products C (+)-Pulegone [ ] / 100mL (85%) Dihydrocarveol [ ] / 25mL Perillaldehyde * (R): [ ] / 5mL * (S): [ ] / 25g C 2 Isopulegol * (+): [ ] / 1mL * (-): [ ] / 5mL * (R)-Carvone [ ] / 500mL * (S)-Carvone [ ] 7800 / 25mL Carvone hydrate [ ] 7300 / 1g Perillic acid * (S): [ ] / 5g Isomenthol [ ] / 1kg * chloromethyl ther: [ ] / 5g Carveol (mix) [ ] / 50g * acetate: [ ] / 10g * propionate: [ ] / 25g Limonene * (R): [ ] 5100 / 500mL * (S): [ ] / 250g [ ] / 50g Limonene oxide * (+)-mixture: [ ] / 250 g * (-)-mixture: [no CAS o.] / 250g Perillyl alcohol * (R): [ ] 9500 / 1g * (S): [ ] / 50g Menthol * (-)-: [ ] / 500g * (+)-: [ ] / 50g * (-)-menthoxyacetyl chloride: [ ] / 5g * (+)-menthoxyacetic acid: [ ] / 5mL * (-)-menthoxyacetic acid: [ ] / 10g * (-)-acetate: [ ] 8800 / 100mL * (+)-acetate: [ ] / 5mL * (-)-chloride: [ ] / 10g * (-)-chloroformate: [ ] / 100g * (+)-chloroformate: [ ] / 25mL] * (-)-chloromethyl ether: [ ] / 10g * (+)-chloromethyl ether: [ ] / 5g S Tol Menthone [ ] / 100g eomenthol [ ] / 25g * (1S)-acetate: [ ] 9500 / 1g * (1R)-acetate: [ ] / 1g * (R,S,R,S S )-: [ ] / 10g * (S,R,S,R S )-: [ ] / 10g 2-Carene [ ] / 25mL 3-Carene [ ] / 5mL (+)-ootkatone [ ] / 5g (>85%) * (1R)-: [ ] / 10g * (1S)-: [ ] / 5g

16 * (+)-Camphene [ ] / 1kg * (-)-Camphene [ ] / 1kg * (+)-Camphor [ ] / 500g * (-)-Camphor [ ] / 10g * (S)-Camphorquinone [ ] / 5g * (R)-Camphorquinone [ ] 9600 / 5g * (R)-Fenchone [ ] / 250g * (S)-Fenchone [ ] / 100mL (R)-Fenchol [ ] / 500g Isopinocampheylamine * (-): [ ] / 5g * (+): [ ] / 5g Isopinocampheol * (-): [ ] / 100g * (+): [ ] / 100g (-)-trans-myrtanol [ ] / 10g C (+)-cis-myrtanylamine [ ] / 10g (1R)-opol [ ] / 1L * Bn ether: [ ] / 100g (1R)-Myrtenal [ ] / 50g (1R)-Myrtenol [ ] / 100g (1R)-opinone [ ] / 5g (+)-Longifolene [ ] / 25mL * (+)-α-pinene: [ ] / 500mL * (-)-α-pinene: [ ] / 500mL Verbenone [ ] / 50g (-)-β-pinene [ ] / 1L Verbenol [ ] / 25g 3 S * (S)-CSA [ ] / 500g * (R)-CSA [ ] / 100g * (S)-CSAamide [ ] / 5g * (R)-CSAamide [ ] / 5g * (R)-CSA- 3 salt [ ] / 50g * (S)-CSAchloride [ ] / 100g * (R)-CSAchloride [ ] / 100g C 2 3 S Br [ ] / 1g Br [ ] 5300 / 5g CF 3 * (+)-: [ ] / 5g * (-)-: [ ] / 1g * (R,R,R): [ ] / 5g * (S,S,S): [ ] / 5g CF 2 CF 2 CF 3 * (+)-: [ ] / 5g * (-)-: [ ] / 5g * (R)-: [ ] / 1g * (S)-: [ ] / 500g * (S)-Ac: [ ] / 500g * (1R): [ ] / 5g * (1S): [ ] / 5g * (S):[ ] / 5g * (S)-acyl chloride:[ ] / 5g 3 S Br * 3 salt: [ ] 9800 / 25g C 2 [ ] / 5g Br Br [ ] 7100 / 5g

17 Citronellal * (R):[ ] / 5g * (S):[ ] / 5g C Citronellene [ ] / 100mL Citronellic acid * (R):[ ] / 5g * (S):[ ] 9700 / 1g C 2 Citronellol * (R):[ ] / 1g * (S):[ ] / 5g (-)-Thujone [ ] / 25g Cl Pilocarpine [ ] / 50g S C 2 Me Me Strychnine [ ] / 100g Brucine [ ] 7800 / 25g * hydrate: [ ] / 100g * sulfate hydrate: [ ] 6000 / 25g Biotin [ ] / 25g Br * (R):[ ] / 5g * (S):[ ] / 25g Linalool [ ] / 100mL C 2 Chinchonidine [ ] / 100g Chinchonine [ ] / 250g D-Quinic acid [ ] / 100g Me Me Quinine [ ] / 50g Quinidine [ ] / 50g

18 > Comment 実用性のある価格帯を考慮し 1g あたり 円程度までの試薬を集めました 合成素子としての有用性に欠ける不斉触媒 不斉配位子 キラルアンモニウム塩 オリゴペプチド オリゴ糖などの縮合系化合物 複雑な天然物は除いてあります 価格はアルドリッチカタログ 記載の価格です ( 単位 : 円 ) 他社のほうが安い場合も少なからずあるので 注文前に Ald 以外のカタログもチェックしてみて下さい 高めのキラル試薬 市販スケールが小さいもの (1~5g) が大量に欲しくなったときは Scifinder などで調べてみて 自分で合成するというのも一つの策です CAS o. の若いものなどは 効率的合成法が確立されている場合も少なくありません 構造式はすべて手入力なので誤りが相当量あると思われます 自己責任で使用して下さい 誤りを見つけた場合は制作者 ([email protected]) までご一報頂けると幸いです Aldrich Advanced Search も便利です ご活用下さい