12
1) 1
2) 3) 2
4) 5) 6) 5) 6) 1-1 1-1 (1) 6) 3
(2) (3) ) ) ) ) ) 4
) s. (4) 5
6
(1) 7) 7) 8) 1-2 1-2 1-3 1-4 1-5 7
1-2 1-2 1-3 1-4 1-5 a. b. c. 8
(2) 1-6 1-6 (3) 9
(4) 1-7 1-7 10
(1) 6) 1-8 6) 1-8 (2) 9) ( 1-9 ) 11
( 1-10) 1-9 () 1-10 12
2-1-1 (1) 2-1 Single Spring TypeT Type Box Multiple Type 1) 2-1 13
(2) (3) 14
(4) (5) 15
2-1-2 (1) 2-2() 2-2() 2-3() 2-3() 1-1 2-2 16
2-3 2-4 2-4 (2) 17
(3) (4) (5) 1) F.K.Savage: Racks:Design,Construction,Insulation and Maintenance Electroplating Engineering Handbook Edited by A.K.Graham 1955. 18
40 40 2-2-1 (1) () a. () b. c. d. () (2) (3) (1) b.c.d. (2-2-2 ) (4) (throwing throwing power) ( ) 2-5 19
2-5 (J.B.Mohler J.B.Mohler) (5) (covering power) a. b. 2-2-2 (1) 2-6 ()() 2-7 1 2 1 2 2-6 ()() ph 2-7 20
i 1 (1) d2 i 2 d 1 1,2 2-6 1,2 (2) d de 2+K di i 1, i, 2 d de 1+K di k de/di 1 2 ( )( ) ( ) M 1 i1' CEff 1 (3) M 2 i 2 ' CEff 2 (2) (3)(CEff1CEff2) (2) 2-1 2-8 ()( ) 2-8 2 1. 2. 2-1 2-8 21
a. b. c. d. e. f. g. 2-9 2-10 2-9 2-10 ()() 2-2-3 (1) ( ) 2-11 () 22
2-11 (2) () 2-12 () () 2-12 (3) () () 33 ( 2-3 ) (4) 23
()() () ()()() (5) ( 60 ) ()( ) () ()() ()() (6) () ( 600 ) () 2-13 () WI 2 L S p ( ) () () () 2-13 (D.R.Turner,Plating & SurfFin NII.1976) 24
(7) ()() (8) 2-14 () () () () 1 n 2 2-14 (9) () () 2-15 2-15 25
2-2-4 (1) () 2-1 2-1 () ( ) (2) 2-2 2-2 2-3 2-2 () () 1.0 1.2A 0.2A 0.7A 0.3A 0.3A 1.2 1.6 0.3 1 0.4 0.4 1.6 3 0.5 1.9 0.6 0.8 2.0 5 0.8 3 1 1.4 2.6 9 1.5 4.8 1.6 2 3.2 20 3.3 7.5 2.5 3.1 4.0 27 4.5 11 3.6 5 36 31 4 19 6 8 312.5 62 8 38 12 16 325 125 15 76 25 31 350 250 31 153 50 62 650 500 62 305 100 125 675 750 93 457 150 187 6100 1000 124 610 200 250 6150 1500 186 915 300 375 26
2-3 ( 100) ( ) (99.96) 25.2 2017-T4 2024-T3 6061-T4 6063-T6 7075-T6 (2) 70-30 65-35 60-40 30 30 40 50 30 20 27 28 18 13 100 (99.73) 8.3 3.58 2.6 2.5 12 11 302 2.3 316 2.2 410 3.4 430 3.55 B265-52T grade2 B265-52T grade3 3.1 3.1 Metal Finishing Guide Book(1959) () 2-2-5 2-16 2-16 2-2-6 (1) () 2-17 2-18 27
2-17 2-18 (2) ( ) 2-19 2-19 (3) (W0) 0 n 1 2-20 2-21 n 2 1 3 2 1 n (1953) 28
() I 2 I 2 (a) 2-20 (b) 2-21 2-2-7 ( ) () 2-22 (a) (b)(c)(d)(f) (e)(f) 2-22 2-23 2-24 29
2-23 2-24 2-2-8 (1) a. 2-25 b. c. 2-26 (a) 2-26(c) d. 2-26(e) e. 2-25 2-26 30
(2) 2-27 (10 ) 2-27 (3) ()() (de/di)(d d ) 2-28 2-28 2-2-2 (2)()(dE/di) 3.31 2.41 2.21 1.47 1.24 1.19 0.634 0.522 0.356 0.178 0.157 0.085 (4) (150200 ) 31
( 1015) 2-29 2-29 (5) (6) 2-30 2-30 32
(7) 2-31 2-31 2-2-9 2-32 2-33 2-34 2-32 2-33 2-34 2-2-10 2-35 33
2-36 2-35 2-36 2-2-11 2-37 2-38 2-39 2-37 () 2-38 2-39 () 34
2-2-12 () 2-40 2-40 () 2-41 M1 M2 2-41 35
2-3-1 2-42 () 2-43 2-42 2-43 2-44 4-45 2-44 4-45 2-2 36
2-2 2-3-2 2-46 2-47 2-46 2-47 2-3-3 (1) 2-2-6 2-17 2-48 () 2-49 37
9000 2-48 2-49 (2) ( ) 2-2-6 2-19 (3) () 2-2-6 2-19 2-3 2-3 2-3-4 (1) 38
(2) () () 2-4 2-4 2-50(A)(B)( ) 2-51 2-50 2-51 (3) 2-52 2-53 2-54 39
2-52 2-53 2-54 2-3-5 0.10.3m () 2-55 2-55 40
() () a. b. c. 2-3-6 () (1) 2-56 2-57 2-58 2-59 2-60 2-61 2-56 () 41
2-57 2-58 2-59 2-60 2-61 42
(2) 2-62 2-62 (3) 2-63 2-64 2-65 2-66 2-63 () 2-64 () 2-65 43
2-66 (4) 2-67 2-67 (5) 2-68 2-68 44
2-4-1 2-69 2-69 45
2-4-2 2-70 2-70 2-4-3 2-4-4 2-4 46
2-4 93 0.125 0.005 2-4-5 (1) (2) a. b. 2040 c. 160 1015 (3) 170200 1520 47
2-71 2-71 2-4-6 2-5 2-6 2-72 2-5 () 2-6 2-72 2-7 48
2-7 49
2-5-1 () 2-5 2-5 CuNiCr 50
2-5-2 2-73 2-73 2-74 () () 2-74 2-5-3 51
(1) 2-8 2-8 (2) (3) 2-5-4 2-9 2-75 52
2-9 2-75 53
2-76 2-76 () 2-6-1 10 13 54
() (VA ) 2-6-2 ( ) 2-2-6(1) 2-10 a. 2-77 55
b. c. d. e. f. g. 2-78 2-10 () 2-77 () () 2-78 2-11 2-79 56
2-11 2-79 2-6-3 (2-2-6 (3)) () n n ( ) 2-80 (2-2-3 (5)) 2-81 2-82 2-80 () 57
2-81 2-82 2-6-4 2-83 2-12 ( ) 2-12 2-83 2-12 CuNiCr 58
2-6-5 2-2-9 2-3-6 a. b. c. ph d. e. 2-13 2-14 CuNiCr 2-13 2-14 CuNiCr 2-84 2-85 59
2-84 () 2-85 () 2-6-6 2-86 2-87 () 2-86 2-87 2-15 2-16 2-88 2-15 60
2-16 2-88 2-88 a. b. c. d. 2-6-7 2-89 61
2-89 2-6-8 2-90 2-91 2-90 B1B2 S P R C 2-91 62
2-92 2-92 2-6-9 () 2-17 2-17 63
2-6-10 2-93 () 2-18 2-93 2-18 2-6-11 () 2-94 (A)(B) (A) (B) 2-94 (A)(B) 64
(A)(B) 20 2-6-12 2-6-10 2-6-11 2-95 2-96 2-95 2-96 () 65
2-6-13 33 2-19 2-20 2-19 2-20 2-21 NO.22 NO.23 66
NO.24 2-22 NO.25 NO.26 2-21 2-22 2-4-5 2-97 2-23 2-23 () 67
2-97 2-6-14 2-98 2-24 2-98 2-24 68
2-6-15 2-99 2-99 2-6-16 2-100 2-100 69
3-1-1 3-1 3-1 3-1-2 () ()()() () () () 100150 3-2 3-3 () 70
3-2 3-3 3-1-3 3-4 3-5 () 3-5() 3-4 71
() () 3-5 3-1-4 2-2-8 3-6 3-7 3-6 3-7 72
3-7 3-6 3-8 m/m 3-8 3-1-5 3-9 3-10 3-9 3-10 73
3-11 100200mm ( 3-12 ) 3-11 3-12 3-1-6 2-2-8 ( ) () 74
3-1-7 3-1-8 3-13 3-13 3-1-9 3-14 3-14 75
3-2-1 3-15 3-15 3-16 3-16 76
3-2-2 3-17 Cu NiCr (m) 32 40 30 35 38 44 31 38 38 14 52 22 27 24 27 26 33 38 22 60 10 35 11 46 3-17 3-2-3 3-18 3-18 77
3-2-4 3-19 () 3040 m 3-19 () 3-20 3-20 (ab) 78
3-21 79
3-1 80
3-22 81
82
83
84
85
86
87
88
89
90
91
92
ppm ( 100 10 ) (CpCpk) 3-4-1 9000 () ()100 1030 ppm ppm ppm()parts par million 100 ( ) () 93
100ppm ppm 3-4 3-4 3-4-2 (Cp) (Cp) 3-30 3-31 94
3-30 () 3-31 95
3-4-3 ( ) 3-32 3-32 10 3-1-1 3-1 process capability 96
3-33 3-34 3-33 3-34 3-5 3-5 335 97
3-35 3-35 3-35 0.69 1.00 3-5 3-4-4 (1) 3-36 (2) 3-37 98
(3) 3-38 3-4-5 3-4 3-4 3-40 3-41 3-40 3-41 99
3-39 100
3-40 3-41 3-4-6 3-59 101
3-5 3-6 3-7 3-8 3-9 102
5 () 3-5-1 ()( ) 3-42 103
3-42 3-5-2 3-42 () 104
3-43 3-43 () () () () () 3-5-3 105
3-43 3-18 ()2-6-2 (2-2-4 ) 2-2-6 ) (2-5-2 ) () ( 3-44 ) 3-44 3-5-4 106
3-45 3-10 3-11 3-45 3-10 3-11 107
3-5-5 (2-6-13 ) ( 3-10 ) 3-5-6 (a) 3-46 b 3-12 ) 3-46 a (b) 3-46 108
3-12 3-13 (A) (B) (C) 3-13 3-47 3-47 3-48 3-49 3-48 3-49 109
3-49 3-5-7 3-50 3-50 3-50 110
111
112
4-2-1 4-1 4-1 4-2 4-2 113
4-2 () 4-2-2 4-3 (a) 4-3(a) (b) 4-3(b) 4-3 4-2-3 2 (a) 4-4 114
4-4 (b) 4-5 4-5 () 115
4-4-6 1 4-7 4-7 4-7 116
4-8 4-9 4-8 4-9 117
4-10 4-10 4-11 a a b ab a ba ab N N N 4-11 2 4-12 118
4-12 4-13() 4-13() 4-13 119
2-14 ph 2-14 4-15 4-15 () 120
0.8 4-16 19.63 4-16 212 4-16 121
14 2022 4-17 4-17 (1) 122
(2) (3) (4) (5) (6) 4-4-1 1985 10 (PVC)MMAPP 3 PVC PP 123
PP PP 4-18 4-18 4-19 4-20 4-19 () 4-20 124
Q&A 1 Q A Q2 A 1.3 1.5 4-21 4-22 4-21 125
4-22 () Q3 A (N 4-23 4-23 () 126
Q4 40 10 A Q4 4-24 4-24 () 127
2A 4-25 4-28 4-25 4-26 4-27 4-28 mmmmmmmm 2A 1.5 3A 2.5 5A 4 8A 128
PVC PP Q5 A 2 4-29 4-29 4-30 4-30 129
4-30 4-31 4-31 1.3 1.5 4-32 130
4-32 (Whyco Chromium Co.Inc.) 4-33 4-33 4-4-2 (a) (b) 131
90 (c) rpm 4-11 ab 4-34 4-34 132
cm 4-4-3 Q6 A (a) 133
(b) (c) 4-4-1 4-35 4-35 () 134
4-4-4 Q7 A 1 4-36 2 2 2 4-36 135
I I IA/ I I A/ 4-37 A/ 4-37 136
Q8 A 4-38 4-38 4-39 3 4-40 137
4-39 4-40 138
4-41 4-41 Q9 A (-) (-) () (-) 139
4-4-5 140
H ph ph311 ph H ph H ph 2 Q10 A 141
5-1-1 (1) Q1 A 5-1 142
5-1 (a) 5-2 5-2 5070 1020 1020 143
1315 15110 110120 120 630rpm Enyedy (1) () 1 14rpm 50cm 20rpm (b) 5-3 144
5-3 100200rpm 20cm 190rpm 25cm 28rpm 50 3590 7090 (c) 7080 1/41/5 145
5-4 5-4 () (d) 5-5 5-6 5-5 5-6 () 146
(2) Q2 A 1996 5-7 5-1 5-7 147
5-1 5-8 5-9 7080 5-8 5-9 100 (H10) 148
60 PRTR Q3 A (a) UF (b) 149
O/W W/O CaCI (3) Q4 (1)(2) A (a) Q5 A 5-2 150
5-2 () ()() () () (a) HLB (b) () (c) (d) n- (b) Q6 A 151
H H H (c) Q7 A 152
(d) Q8 A PRPeriodic reverse PR 510A/ 0.5A/ 5-3 153
5-3 ( ) PR PR 5-1-2 (1) Q9 A 1950 (a) 5-4 154
g/l g/l g/l M (A/) 5-4 50 105 120 1.82.2 0 3249 0.14.0 34 94 79 2.52.8 00.5 2236 0.14.0 18 45 90 2.22.3 00.25 2332 0.11.5 16.7 48.3 65 2.62.9 00.25 2030 0.13.0 Zn² ² Zn² OH ² Hull Wernlund 7590 Na ZnCN NaOH NaOH ZnCN ² 20ZnOH ² NaOH Na ZnOH Na ZnOH NaCN Na ZnCN M M NaCNg/LZng/L 4-4-5 3 155
g/ L NaCN g/ L L - - - 190mm250mm mmmm rpm 5.2L 4.86 2 1000 19.3 Zn M 5-6 (4) 156
- (b) Q10 A NaOHZn1113 15L PVA 8090L Zn1013LZaOH120150gLNaOH Zn1113 5-10 157
5-10 120L 911L 90110gL NaOHZn1011 - - - 158
- Q11 A 5-8 g/l g/l g/l g/l g/l H 5-8 4050 200220 5.06.0 159 6080 180220 2030 5.06.0 7080 120 140 2030 5.06.0
50mgL H H 5.55.8 5-9 5-9 3ppm 2ppm 10ppm 50ppm 250ppm - - - (2) 160
- - (2) 161
(a) Q12 A 5-12 g/l g/l g/l g/l g/l V 5-12 45 70 1820 4575 815 5065 610 162 60 85 1820 4575 815 5065 610 90100 120140 2030 4575 815 5065 612 CuCN NaCN NaCuCN2 (1) NaCuCN2 NaCN Na CuCN (2) Na CuCN3 NaCN Na CuCN4 ² (3) -
40gLCu 28g/L 618 163
- - g/l Cu 2030 () g/l 3050 ()g/l 1015 H 12.012.5 g/l Cu 4050 5570 11.512.5 11.512.5 2040 (b) H 164
S. E. Craig Jr. H (3) Q13 A 5-15 5-16 5-15 () 5-16 165
5-16 (Cl Ni² + ² + ² + ² + Q14 - A - 166
(a)throwing Power 267ml 0.5A 15 5-12 4 X 5-18 1 2 Field 5-12 5-18 5-19 (a) 5-19 167
(b)covering Power 5-13 50mm 200 40 20 3 5-13 5 3 0.12A 20mm100mm 120cm² 0.1Adm² 5-13 5-17 5 5-20 ² + 168
190mm250mm 1mm 2mm 8rpm 5.2L 15mm2mm 4.86 1000 19.3 505 30A 0.6Adm 45 m 5-14 5-16 5-14 (a) 5-16 f fa bf 169
5-14 (a) 5-15 (b) 5-16 (f) 170
gl 68gL gl 12gL ² + () NiSO46H2O 150gL NiCl26H2O 100gL NiSO46H2O 250gL NaCl 30gL gl H 4.24.8 H Na (4) (a) 171
5-21 5-21 () () 30 g/l 3 g/l 120 g/l 70 g/l 80 g/l 0.51.0A/dm 2 2025 Q15 A 5-22 5-22 172
5-23 5-23 () () ()g/l 14g/l) 80120 g/l 2060 g/l 0.050.3Adm 0.53Adm 0.050.15Adm 1 20gL 173
25 5-22 30L 20L 5-24 () 5-24 20 30 g/l 80120 g/l 60100 g/l 20 50 g/l 1525 0.050.1 A/dm 2 0.1 0.3 A/dm 2 0.5 A/dm 2 A/dm 2 (b) 19 JIS 16 99.7 16 JIS-H-86221993 JIS-H-86201993 99.9 58.5 99.9 174
Q16 A 5-25 5-25 F. I. Nobel 1966 5-26 5-27 5-26 10cm6.5cm 10rpm 0.71mm1.3cm 2300 23.9K Ni 23.9K Co 175
5-27 5-17 5 14 5-27 5-17 H 5-18 5-27 H H H 1011 176
5-18 ph 0.05 Q17 () A 5-19 6rpm 8rpm11rpm 6 250mm 400mm 16000 177
03 6rpm8rpm11rpm 5-19 5-28 5-20 5-28 95 2 () 2 () 95 (0.05)V(0.05) 95 (0.05) () 178
(a) T() T (b) () (c) T et (d) F2/27(0.01)5.49 o 0.019 0.0095 21.59 0.0119 27 0.00044 0.0309 29 F2/27(0.01)5.49 5-20 o 0.0125 0.0063 27.0 0.0063 27 0.00023 0.0188 29 6rpm 11rpm F (5) 2 5-29 (a) (b) 179
(c) 5-29 5-30 5-31 5-30 180
5-31 abnormal codeposition(induced codeposition) H 5-21 5-23 181
5-21 5-22 5-23 2 5-24 / 182
5-24 / nb n/n² 0.14b/b² 0.13n-u n/n 0.005 u/u 0.52V nb nb 5-32 5-25 5-26 5-32 SnPb () 5-25 183
5-26 Pb n-u u n ⁴ u /n u Na SnO 3H O100g/LCuCN25g/L NaCN50g/L NaCN22g/L NaCN NaOH Sn-Cu 5-27 Sn Cu Sn-Cu 5-28 5-27 NaCN NaOH 5-28 Cu Sn SnCu 5-29 Sn-Cu 5-33 Cu /Sn Cu 184
5-29 CuSn 5-33 CuSn 5-1-3 (1) 185
5-30 5-30 () (2) Q18 A 5-34 5-34 186
5-31 5-31(a)r-OH-r 5-31(b) Cr-O-r 5-31 5-32 5-32 5-34 4 187
5-33 5-34 5-33 () 5-34 () 188
Q19 A ph r (a) r r /L r 35g/L g/l r 10/L n 1g/L r 30/L 15g/L H (b) 2025 1030 80 4060 189
5-2-1 5-35 5-35 190
5-36 5-36 5-37 (1) (n) 5-37 (1) 191
5-38 5-38 5-39(a) 1/2 5-39(b) 3 5-39(c) 5-39(d) 192
190250 1mmmm rpm 5.2 15mmmm 4.86 2040 5-39 5-40 5-40 5 100 5.2L 5-40 30 23 1/2 4 4 30 1 8 4 8 4 8 193
5-40 5-40 30 20 5-2-2 194
200mm 340mm 3mm 50L 1163/L 96/L 405/L 325 /L PVC PP 6 200mm 250mm3 PVC 1mm 2mm 1mm 2mm PP 0.5mmmm 8rpm 15mm2mm Ni 60/l 1/2 20 20L 5-41 10 5-41 20% 40% 1mm PVC 5-42 195
5-42 () 5-43 5-43 5-42 7 40% 40% 90120 5-44 196
5-44 ( d 100) 20L 5-45 1 ( 10 ) 10 1 ( 10 ) 5-45 40% 5-46 5-46 () 197
PP 40 5-47 5-46 1mm PVC 5-47 PP / / /0.51.5 / 2.53.5 198
5-2-3 5-48 5-48 199
5-3-1 1 5-49 5-49 1 5-50 200
5-50 1 1 1 5-3-2 ph 201
(1) (a) 5-35 5-36 1/10 5-35 5-36 5-36 5-51 202
5-51 (b) 5-52 2675176 02A/ 5-53 5-54 5-52 203
5-53 5-54 (c) Throwing Power H Haring (d) Covering Power (2) (a) 204
(b) (IC) HPLCCVS (c) (3) H (a)ph ph ph ph11 ph11 H 1 ph311 H 1 1 H H ph ph H H (b) (c) X X 205
ISO-90002000 2mm 1) (1995) 2) (1980) 3)(1988) 4)21 (1986) 5)(1979) 6).11(1988) 7).537(1983) 8).44(1988) 9) 59 (1979) 10) 8 (1979) 11).362(1960) 12) (1959) 13) R.F. Enyedy Handbook of Barrel FinishingReinhold(1955) 206
14).245(1979) 15).169(1987) 16) 912 (1992) 17) Vol.45.875(1994) 18).17(1980) 19) R.O. Hull & C.J. WernlundTrans. Electrochem. Soc.Vol.80.407(1941) 20) G.J. Casey Jr.CEF and R.K. AsherCEFPating and Surface Finishing Vol.8.51(1979) 21)1(1978) 22) Vol.17.93(1966) 23) Lugi, V. BrougnatellAnn. Chem.Vol.18.152(1800) 24) F. FraryTrans. Amer. Electrochem. Soc. Vol.23.25(1913) 25) E. C. RinkerU.S. Pat2905601(1950) 26) E. A. ParkerPlatingVol.40.621(1953) 27) F. I. NobelB. D. OstrowPlatingSep..1099(1966) 28) Vol.35.156(1988) 29) Ch. J. Raub Plating and Surface FinishingVol.63.35(1976) 30) F. B. Koch Plating and Surface FinishingVol.67.52(1980) 31),Vol.31.512(1980) 32) A. BrennerElectrodepsition of Alloys Academic Press 33) 34) 35) Vol.32.539(1985) 36) 37)(1979) 38) A. K. Graham Electroplating Engineering Handbook Van Nostrand Reinhold(1971) 39) Vol.13.200(1962) 40) Eugene G. ChapdelainePlatingVol.53.471(1966) 207
(1) (2) (3) 6-2 6-3 6-2 6-4 6-1 208
(4) 6-1 6-2 6-1 6-2 6-3 () 209
6-4 () 6-1 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 6-2 210
105-8453 3-5-1 37 TEL:03-5470-1523 FAX:03-5470-1526 Copyright C 2001 All right reserved.