13 01.04.01 -
13... 6... 7 1. ｨC... 15 1.1.... 16 1.1.1.. 16 1.1.2.... 18 1.1.3.... 24 1.1.4.... 26 1.1.5.... 29 1.1.6.... 30 1.1.7.... 31 1.1.8.... 32 1.1.9. -... 34 1.1.10.... 35 1.2.... 37 1.2.1.... 37 2
131.2.2.... 43 1.3.... 44 2.... 48 2.1.... 48 2.2.... 50 2.3.... 54 2.4.... 58 2.4.1. 58 2.4.2.... 61 2.4.3.... 64 2.5.... 67 2.5.1.... 67 2.5.2.... 69 2.6.... 71 2.7.... 75 2.8.... 79 3
133.... 80 3.1.... 80 3.1.1.... 80 3.1.2.... 87 3.1.3.... 104 3.1.4.... 112 3.1.5.... 115 3.2.... 116 3.2.1.... 117 3.2.2. -... 120 3.2.3.... 125 3.2.4.... 129 3.3.... 130 4
134.... 131 4.1.... 131 4.2. -... 134... 136... 139... 152... 153... 154... 155 5
13 ｨC ｨC - ｨC ｨC ｨC - - ｨC ｨC ｨC ｨC ｨC AOP ｨC Advanced Oxidation Processes CFD - Computational Fluid Dynamics DNS - Direct Numerical Simulation EDC - Endocrine Disrupting Compounds ESI - ElectroSpray Ionization IDA - LES - Large Eddy Simulation NP1EC - NTA - PhACs - Pharmaceutically Active Compounds PCP - Personal Care Products RANS - Reynolds-Averaged Navier-Stokes equations SST - Shear Stress Transport TT - 6
13 254 7
13 ｨC 8
13 1. 2. 3. 4. 1. - 2. 9
133. 2 2 4. 5. 1. 2. - 3. 1. 10
13-2. - 3. - - 2 O 2 - - -4 - -3 11
13-3 - -30%, -- - 137 60 4. - 12
13 Microsoft Office Excel 2010. - - - -SME 00InPULSe - Integrated Pulsed ULtraviolet - 2014-202003. 13
13 - (2013), 00 03`(2014), XLII. 14
131. ｨC, AOP - Advanced Oxidation Processes) ｨC, 15
131.1. 1.1.1. - [1] - [2]. [3]. [1,2,4,5], 16
13 [6]. 00 03..,,, (). ｨC - [7] 17
13 60 (-1) [8,9]. 1.1.2. [10] [11] [10], H 2 O 2 [12], Na 2 S 2 O 8, NaClO, NaBrO [13] [14] [15]. 18
13 [16]., 60 Co ( 50%) [3]., 137 Cs 90 Sr [11]. - ph = 1. [8] - ｨC 238, 239, 240 74ｨC87 %, 241 ｨC95 %, 244 ｨC95 %. [17]. [13] [12, 18, 19] KMnO 4 [3]., [20]. - [21], [22]. [23, 24]. 19
13. [24, 25]: 6ｦ1 ), - ph 12-13, - 60-80 [12] 20
13 60 Co 54 Mn [12, 26, 27] ( -2 50 [22]. [3] - ｨC [28] 21
13 6ｦ1 6ｦ1 6ｦ1 2 2 [29],, -3). - ; [30]. [31] 2 2 [32]., -- ｨC [33] [34]. [35, 36, 37]. 22
13 [3] - - [38] NｨCH C=N) [39] 23
13 15. [40] (V-UV UV- UV- 315 UV- [41] [3] [7]. 1.1.3. AOP-AOP ｨC - [42] [38] ( -1 [41] 10 9 ｨC 10 11 6ｦ1 ( - 3 6ｦ1[43]). [44] 24
13 - [14] [45]. 3.06 2.25 2.80 2.05 2.42 1.78 2.07 1.52 1.77 1.30 1.49 1.10 1.36 1.00 1.07 0.74 0.95 0.69 0.5 0.37 95 2 O 2 2 2 O 2 2 [46] [44] 2 2 O 2 2 O 2 2 O 2 ; 2 2 -, 2 2-25
13 2 O 2 AOP (-4). 1.1.4. [47], [48]. [49]. AOP 26
13 [50]: Endocrine Disrupting Compounds (EDC) ｨC Pharmaceutically Active Compounds (PhACs) ｨC Personal Care Products (PCP) ｨC [51], : NP1EC (TT) -,, [43]. 27
13 ; ; EDC, -70% [49] -95% [52] [53]. ), [54]. ｪ ｪ ｨC - [49] 28
13 - ｨC [55] [56]. AOP ph [57]. 1.1.5., 29
13 [58]. 1.1.6. -. ; 4 ｨC - - 0,3 2. [59]Light Sources, Inc 16 30
13[60]. - -5). 1-61-6.,,,, 10 ｨC 1 000. 2.. [62] 1.1.7. -. - 31
13 0 2 [63][64], ｨC 900 1-7. 1.1.8. )., [65] - [66]. - 32
13, [67]. 0-15 [68] [69], ( -8). 33
13 1-9. 1.1.9. - ), - 000 ) - [70] [71] [72, 73].,,, 34
13 [74]. -10. 1.1.10. ) ｨC -300 000 2 ). [15].. (-11). 35
13-2 ) ｨC.. ｨC - 36
13 ｨC [53,75-82]. 1.2.,, ｨC 1.2.1. [84] [85], 37
13 DNS) - 1 [86]: u i ｨC t ｨC x i ｨC ｨC 3 ; p ｨC ｨC g ｨC 2. [87] Tflops/s. [88] DNS [89] RANS). LES) 1 38
13 - [89]: ｨC - [89]: u i ｨC t ｨC x i ｨC ｨC 3 ; p ｨC ｨC g ｨC 2. LES LES-DNS [90] DNS[88]. (RANS) 39
13 [91]: ｨC - u i ｨC t ｨC x i ｨC ｨC 3 ; p ｨC ｨC g ｨC 2., [92], 40
13 ｨC ｨC. k [91]: ; ; ; ; [91]. [91]. 41
13 ; ; ; ;,,,, CFD) [91]. (SST) k- k- [93, 94]. k- k-k. k- k- F 1 k- k- (1-F 1 ) F 1 [94]: 42
13 (RANS). DNS LES 1.2.2. 1.2.2.1. [95] i- [96]: i ｨC i ｨC D i ｨC 43
13 D t [97]: [96]: d 1 ｨC ｨC r ｨC - F j ｨC 1.3. 44
13-2. - % % 2 85-90 0,5 ｨC 1 000 15 ｨC 20 1 ｨC 10 10 ｨC 15 0.2 ｨC 0,4 0,1 ｨC 0,01-50...70 15ｨC 50 100-10 000 4 000 ｨC 16 000 1 000 ｨC 2 000 1 000-10 000 000 2 2 2 2 ｨC 45
13 ｨC 3, 190-300.. 1., ; 46
13 2. :, ; 3.. 47
132.,,.. 2.1. 2 ) ( 2 ) [98]. - - 48
13 [98] 278 t - S - L - Q- 3 [49] Technologies, Inc, [99].,, 49
13-1. : (DO, k- ｨC 2.2., DNS 50
13 [90].,, RANS ｨC [100] LES ｨC [101]. [101] LES ｨC (-2). RANS.,, RANS. RANS 51
13-4 k-k-, k- k-, k- 50- [91], k-., -3 ( [102]). 52
13 53
13, k-. 2.3. - ｨC 3 ｨC ｨC ｨC ANSYS v 54
13 [101] [100], k- CFX-Mesh No Slip, [103] ANSYS CFX ｨC Streamline ｨC ), Time on Streamline [103]) -5-2-8. - -9 2-1), -9-55
13 -. - - 2-1). 56
13-10 -7,, 57
13. 2.4..,, [104] [105] U 0 C, L, R 0 d l p 0 ) 2.4.1. 2-11 U 0. R p U p., L. R 0. U l U r 58
13 : : ; ; [106] [107]: - 59
13 [108] ): ｨC ) [108]. [104] 60
13 ｨC [104] : 2.4.2. ｨC ｨC - ｨC ｨC [105] ｨC 20 (2-15) 61
13 2 0,, 15 2 0 4,9 10 3/ exp ｨC 3 ; ｨC - 0 0 ｨC 1 Xe 0 12, 6 (11594) 23 1,38 10 ｨC 1 (1 ) ｨC ｨC 16 3,3 10 0 3 2 2 2 (1 ) 1 exp ｨC j- ｨC j- 0 ). 0 62
13 -: 1/2 8 0 2,110 2 1 2 0 3 / 2 15 0 0 4,9 10 exp 2 2 4 10 50 10 18 20 ｨC 1 0 3 1 3 0 ｨC ( ) (1 ) [109]: 63
137,55 10 (1 ) 4 0 0 ｨC 2.4.3. [110] -[111]: ｨC Z ｨC ｨC ; ｨC ｨC ｨC - ｨC [105] - -- [112]: (2-28) 64
13 ｨC [104]; ｨC [112]). 12600 20000 50 600 [109]: 0 7 9 1,4410 2 6, 4810 121 exp 1000 0 1 ｨC 0ｨC 300.,, 65
13 190220, 0.57, 2201500, 0.9. 190 ( 190) 0 1500 ( ) [104]: 15 2 11,9 10 ' 0,9 1 exp( ) 5 7 1,44 10 exp 1 : 15 11,9 10 ' 0,9 1 exp( ) 2 5 7 1,44 10 exp 1 15 11,9 10 1 ' 0,9 1 exp( ) 2 5 7 1,44 10 exp 1 ｨC 66
134 1.4410 11.9 ln 1000 ( ) 1000 5 1,, 5%.. 2.5. 2.5.1. [100] 67
13. -12). ｨC ｨC,, 68
13 (2-34) -,, ; -,, : 2.5.2. [113]: 69
13 ｨC, ｨC ｨC ｨC ｨC. : ｨC, [113].,. [114],,,, [113]: 70
13 -,, ｨC ｨC, [113] [115]:, 2.6.,, 71
13., ｨC, ｨC,, (. 2.4, 5) -,, [101] [100], - 72
13. c ( ). c. 2-13., 73
13,, [49] [100]. [114]., 74
13, 2.7. -14,, -14,,,, 75
13. ). -15-16: -1 ), 2 2 ), -17-18 - -- 76
13 77
13-35%. -22 78
13 ( -23). 35% 2.8.,... 79
133. 3.1. 3.1.1. - PURITEC - -1 80
13-2 ; 81
13 3 ; V8 G1);, ｨC ｨC,, 3 82
13,, ｨC ｨC, - - 83
13 - - - - - 72- ( -, 8,6-10,0. 84
13 Fe(III) Ti(IV). -202003.. 60 4,, -4. 4 85
13 -ｨC 0,5 (0,4 - - - ｨC - ｨC ｨC ｨC - 2 2 ;, -50 60 86
133.1.2.,,, - Osram PURITEC HNS 15W - 25. 2 - -300 2. -l 2 2-002-25665344-2008 - NaOH. [116] [117], 87
13, - - - - [76] - [117] - Bi(NO 3 ) 3 *5H 2 O. 3-5-3.17 88
13 0 ｨC ｨC t ｨC k ｨC ln(c 0 /C) ｨCt. 89
13 90
13-1. 2 2 0,0281-0,0497 - - 0,0026-0,0302 2 2 0,0071 0,0211 0,0144 0,0524 - - 0,0002-0,0045-2 2 0,0019 0,0274 0,0041 0,0445 - -1 91
13 ｨC -2. -1. t 10 30 50 0,72 (7,1) 0,66 (6,5) 0,82 (8,1) 0,92 (9,1) 0,88 1,11 (8,7) (11,0) - -3. t, 10 30 50 0,16 (1,55) 0,20 (1,96) 0,24 (2,4) 0,22 (2,2) 0,31 (3,1) 0,42 (4,1) 92
13 -. 2 2 2 2-2 2 2 2 ) - 5 [118, 119] 93
13 17.. - - ｨC ESI). LabSolutions LCMS Ver NIST MS Search 2.0f, MassBank service METLIN Metabolite Search ), (1 ｨC 2-3 - 4 - ) -ｨC -8). -7 94
13, ｨC -, - - NaNO 3 4-3 NaNO 3 2 2 2,2`,2``- - - [31]. 95
13 3 - [120] NaNO 3 ｨC 300 96
13 1 NaNO 3 502 - : - 2 ), N- S- 3-10. - - NaNO 3 97
13-4. 10 20 30 40 50 60 70 80 90 10 0 3 NaNO 3 ( 0,6 0,9 1,2 1,5 1,7 1,8 1,9 2 2,1 2,2 NaNO 3 ( 1,5 2,6 3,5 4,3 4,9 5,5 6,1 6,9 7,5 7,9 98
13 7 ｨC -2, 0,4; 0,08-7) ｨC 2 2 - -10) ｨC 2 2-13) ｨC 2 2 - - - - - -- -14. 99
13 100
13 - -17 101
13 60 5 60 - ｨC 3 ). 60-60, ｨC 60 60-60 5 102
13-60 60%. 2 2-2 2-60 0 60 240 480 960 26,9 29,2 28,4 24,7 35,4 26,9 28,6 39,7 35,6 60,0, IDA,, 103
133.1.3. 1.1.2,, - 2 2-3 - 3 6 - - - [121]. - -193-19: 6 104
13 3-20 4. -19, 105
13-21. - (-22-3-24). -6.. 106
13 107
13-6 - -6 - - - 40,6). m/z 173,5 [EDTA- 4H+Co(II)]2, / m/z 346,9 [EDTA- 4H+Co(III)], / m/z 347,9 [EDTA- 3H+Co(II)], / O 3 2,63 7,09 2,98 O 3 1,46 7,13 1,84 O 3 0,76 5,50 1,24 O 3 0,45 4,10 0,8 O 3 0,24 2,10 0,4 O 3 0,07 1,00 0,1 UV/ O 3 0,63 8,24 1,01 UV/ O 3 0,27 4,10 0,23 UV/ O 3 0,08 0,87 0,05 UV/ O 3 0,02 0,03 0,003 108
13, - -26- - 2 2-109
13 - -, 9,5- Na + ｨC 6,4; K + ｨC 3,9; Mg 2+ ｨC 14,0; Ca 2+ ｨC 50,0; Cl - ｨC 5,7; SO 2-4 ｨC 35,0; HCO - 3 ｨC 192; - 305- ), - Fe(III) Ti(IV). -202003. -200003. -7-27. 110
13. - 2 2, NaNO 3, 1 7,0 100 4000 2 2 119,5 100 4000 3 3 8,2 100-3 1 111
133.1.4. - 2600- ｨC 3,8--0,6--10,2-10,4. -(1,6-2,0) ﾁ104, 134 Cs- (1,0-4,3) ﾁ10 3, 60 Co-(1,4-3,8) ﾁ10 3 --(2,1-3,5) ﾁ10 4. - 137 Cs, 134 ( 10%). 112
13 2-2 2 1 2 3 4 5 6 137 Cs 60 Co I 50 2,2 II >190 1,5 I + II >9450 3,3 I 14 2,6 II >570 1,6 I + II >7900 4,3 I 11 2,6 II >695 1,6 I + II >7900 4,2 I 14 2,6 II >720 1,9 I + II >9900 5,0 I 12 2,0 II 202 1,4 I + II 2329 2,9 I 14 1,7 II >695 1,4 I + II >9900 2,3 113
13 - - -29 137-14 (2-137 - 60-114
133.1.5. 3 2 2-60 ｨC -; - - ; 115
13-3.2.. 116
133.2.1. -30. 1 ｨC ｨC ｨC ｨC ｨC - 8500 ﾀ500-30 (200 ｭ300-3. 117
13 - Fe(IIIAl(III). 2 ｨC ｨC 120 ｨC ｨC - [122]. --40 ｱ. -30 0 1. 2. 3. - 118
134. 5. 6. - em -31. 119
13 em em 3.2.2. - [123] - Al(III) ｨC -Fe(III). Fe(III 120
13-32, ｨC 8,0. - NaOH 121
13[122] -33 ｨC Al 2 (OH) 5 Cl -33 Fe(III). Fe (III 122
13,, ｨC ｨC = 7,0, [HemFe(III)] = 0,5, -33). ｨC ｨC W ｨC ｨC,, 1,17%. 0-0 ｨC - NaOH 123
13-100 ｨC,, -34. -34 Fe(III),, 124
133.2.3. - [53, 106] CO 2 H 2 O - ｨC 125
13(3-10) RH ｨC ｨC, ｨC e 3 ｨC -35 -- ｨC -30 126
13 2 2. 0 0 em 0-3 3-2 2 2, 2 2 2 2 2 127
13 ｨC -36 2 3 - ) 3-128
13 2 3 0 = 2 3 3 3.2.4.,, ｨC 8,0; ｨC ｨC 3 3. 129
133.3.., 60., 5 130
134. 4.1. -1 3 3. V 3 3 3 V 3 V 3 V 3 ), - - Fe (III ｨC FeCl 3 *6H 2 O V 3 - ｨC 200 - -1. ｨC 8,0 - ｨC 20 - -1. 131
13V = 3 - - - 3-10, 11 (V 3 0 ｨC 3 V 3-2 2 (10%). - - - - ｨC 132
1316 1 4 5 6 12 20 9 14 8 7 1 2 11 13 15 18 3 10 16 17 21 22 1- V 3 8 - - 15-2- 9 - - 16 ｨC 3- V 3 10 - ｨC. 3 17-4- Fe (III) V 11- V 3 18-5- V 12-19 ｨC ph 6- V 13 ｨC - 20,21 ｨC 3 7- - 14 - - 22 ｨC 3 133
134.2. -, -, 190-, 5-1. 6 5-134
13 135
13 - -. 136
13-3 2 2 ) - - -30%, - 137
13-8 ｨC 2016-2017. 138
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