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- ぜんぺい ひろき
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8 1-2 1,826t/ y (1.1 %) 91.1% 155,401t/y 85t/y 170,665t/ y 1,377t/ y(0.8% ) 6,992t/ y(4.1 %) 46,560t /y (27.2%) 107,100 t/ y (62.6%) 7,157t/ y(4.2%) 4.3% 1% 2.6%
9 1-3
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11 1-5
12 1-6
13 1-7
14 Technology Time
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17 1-11
18 1-12
19 CH4CO2 CH4 (Methane fermentation) (Biogas) Anaerobic Digestion UASB ) CH RPS ) CH ,400 t-co2 33 kw 67 kl 1-13
20 1-14
21 L/g-VS CH4 L-CH4/g-VS (C6H10O5 )n + nh2o 3nCH4 + 3nCO % C16H24O5N H2O 8.25CH CO2 + 4NH HCO % C50H90O H2O 34.75CH CO % (-CH2-)n+ 0.5nH2O 0.75nCH nCO % C17H29O10N + 6.5H2O 9.25CH CO2 + NH4 + + HCO % C46H73O31N + 14H2O 24CH4 +21CO2 + NH4 + + HCO % C46H73O31N H2O CH CO2 + NH4 + + HCO % C10H19O3N + 5.5H2O 6.25CH CO2 + NH4 + + HCO % C5H7O2N + 4.0H2O 2.5CH4 +1.5CO2 + NH4 + + HCO % C22H39O10N + 9H2O 13CH4 + 8CO2 + NH4 + + HCO % C7H12O4N + 9H2O 13CH4 + 8CO2 + NH4 + + HCO %
22 8-10) UASB 1980 UASB 1015kgCOD/m 3 d UASB 2000 UASB 60% UASB 11-17) EGSB(Expanded Granular Sludg Bed) IC Internal Circulation Reactor= UASB UASB 2030kgCOD/m 3 d CODCr 18) UASB EGSB ,652,000m 3 4,800t A 5,200kL UASB ,860,000m 3 4,800t A 5,200kL 1881 M. Louis Mauras Mouras Automatic Scavenger (Mouras ) Imhoff tank % DS ,600m TS ) TS 51% VS 57% CH4:60%(57-63%)CO2: 1-16
23 36% (32-40%)H2S:1164ppm( ppm) 19) 10 20) 1-17
24
25 t/d %65% 2430 TS TS COD L/g-VS L-CH4/g-VS COD 270kg-COD/t 70 kl COD 10kg-COD/kL Nm 3 /t 200kWh/t kl 1.8Nm 3 /kl 3.2kWh/kL 1-19
26 Golueke Pfeffer US RefCoM (Refuse Conversion to Methane) Waste Management, Inc 22-24) 8% EC (CEC) Dranco, Valorga, BTA, Biocel COMPOGAS( )Waasa BIMA TS10% TS 10% 7080% m
27 28 1t/d t/d t/d t/d t/d t/d t/d t/d t/d t/d t/d t/d t/d t/d t/d BIMA TS m m % H2S ppm kWh/ % 46.6% % 1-21
28 H2S CO2 4050% TS 515 COD 1) 2) 3), 4) 5) 2004 ECO INDUSTRY, 9(9), ) Vol.21, No.10, (1998) 7) (2003) No , ) (1962) 4, ) (1962) 4, ) (1976) 55, ) 21,
29 12) (2003) IHI-IC 39, ) (2003) UASB EGR 39, ) (2003) EGSB Super 39, ) (2003) PANBIC-H 39, ) (2003) 39, ) (2003)UASB TROLL 39, ) (2003) ) ) ) ) (No.94), ) (No.94), ) (No.94), ) (2003) 14, ) (2000) 64, ) 2003 ECO INDUSTRY, 8(6), ) , ) , ) , ) , ) (2004) 89, ) , ) ) :, ) )
30 LCA 150,000 2 CO 2 CH 4 N 2 O CH 4 NO
31 NO H25 H , , , , , , , , , , ,010 84, , H ,670 4,980 m 3 / 71,000 45,000 2,500 BOD (mg/l) S S (mg/l) BOD (mg/l) S S (mg/l) H12 H25 148, ,000 t/ 62,868 71,781 1,157 g/ 1-25
32 3.1.4 (H12 ) 59.0 H g/ 298 H g/ %1157g80%99g 1157g99g kj/kg 5, g/ 99g 199g H25 H kg/ 174, , , ,659 kg/ 44,438 50,738 50,738 50,738 kg/ 8,316 16,633 kg/ 174, , , , KJ/kg 20,945 20,945 20,945 20,945 kj/kg- 5,667 5,667 5,839 6,027 1,157 g/ g/ g/ Hl 25W Hl=, = KJ/Kg,= (), W= () CO 2 200t/ 1-26
33 CO 2 CH 4 N 2 O CO H25 H kg/ 172, , , ,026 kj/kg 5,667 5,667 5,839 6,027 MJ/ 975,226 1,113,481 1,098,774 1,084, (kwh/) 12,854,022 14,676,300 14,482,446 14,288,591 MJ/ kWh/MJ LCA 633, ,
34 m 3 / 71,000 45,000 2,500 BOD (mg/l) S S (mg/l) BOD (mg/l) S S (mg/l) BC L/ BOD S S g/100g g/ =99g/ H
35 , , ,360 56, ,360 71,000 71,039 71,079 kg/ 12,805 12,805 12,805 BOD kg/ 628 1,257 kg/ 12,805 13,433 14,062 mg/l kg/ 10,846 10,846 10,846 kg/ kg/ 10,846 11,308 11,769 mg/l L/ 10 3 g/m 3 m 3 g/ g/100g g/ S-BOD SS t-ds/ H VS H25 H t-ds/ t-ds/ m 3 / 1,107 2,040 2,109 2,179 1 t-ds/ m 3 / 1,103 2,032 2,102 2,171 t-ds/ m 3 / kg/ DS 1 H
36 7 VS TS SRT MLSS AOR SOR CH 4 N 2 O 1-30
37 3.4.1 H , ,010 m 3 / 21,463 42,926 kwh/ 30,662 61,324 LCA
38
39
40
41 ) 2-1
42 ) ) 3
43 2) ) 4) 5), 6) 3 Ca 21 Mg[(Si 0.75 Al 0.25 )O 4 ] 8 O 4 Cl 4 JIS 6) 2-3
44 0.5 t 0.3 t 0.3 t 0.25 t 0.85 t 0.15 t 1.0 t 6) 3 7) EPS mm cm g/cm MPa 8) 1 100% 1) Pneusol 500 9) 1/151/20 40 mm 1) 2-4
45 10) Excavation of new soil (52,000,000 m 3 ) Inland landfill and others (170,000,000 m 3 ) Soil use at construction sites (126,000,000 m 3 ) Reused soil (74,000,000 m 3 ) Surplus soil generation at construction sites (245,000,000 m 3 ) Coastal landfill (2,000,000 m 3 ) Illegal dumping? (Mg) (%) 30,000, ,000, ,000, ,000, ,000, ,000, ,000,
46 ) 12) 12) 11) PRTR Chemical Abstract Service
47 13) 14) ) The Community Bureau of Reference (BCR) Program ), 17) Aggressiveness ph ph 7 15) 3BCR Step 1 Step 2 Step mol/l 0.5 mol/l 1.0 mol/l (1) (2) (3) ph 2-7
48 ph ph 8 46 ph 18) 46 ph 46 ph ph ph ph ph 19), ph 20) 8 18)
49 46 21) 22), 23) 46 14) 9 18) L/S = 100 ph = ) ISO/TC190Soil Quality 24) 2-9
50 13) 17) X 15) 2 1 N Bioavailability ISO/TC190 Bioavailability 24) Kosson 25) Percolation-controlled Mass transfer-controlled ph 26), 27) 2-10
51 1) ) Vol.45, No.6, pp ) Kawasaki, H., Horiuchi, S., Akatsuka, M., and Sano, S. (1992): Fly-ash slurry island II. Construction in Hakucho Ohashi Project, Journal of Material Engineering, ASCE, Vol.4, No.2, ) 1995 Vol.44, No.503, pp ) pp ) ) ) ) Long, N.T. (1996): Utilization of used tyres in civil engineering-the Pneusol Tyresoil, Environmental Geotechnics, M. Kamon (ed.), Balkema, Rotterdam, pp ) Park, J.K., Kim. J.Y., Edil, T.B., and Madsen, C.D. (1996): Use of ground tires for organic compound containment in the soil-bentonite (SB) slurry cutoff wall, Environmental Geotechnics, M. Kamon (ed.), Balkema, Rotterdam, pp ) Vol.45, No.1, pp ) Vol.45, No.3, pp ) 2000 Vol.11, No.6, pp ) 2001 Vol.12, No.3, pp ) 2000 Vol.11, No.6, pp ) 2002BCR 5 pp ) ) pp
52 19) 1996 Vol.7 No.5pp ) 2002 ANC 13 pp ) 2002 Vol.51, No.8, pp ) ) Kamon, M., Shoji, Y., Endo, K., Kida, A., and Sakai, S. (2004): Leaching characteristics of hexavalent chromium from sludge stabilized with Portland cement and waste concrete powder, Proceedings of the Fourth Japan-Korea Joint Seminar on Geoenvironmental Engineering, Kyoto University, pp ) ISO ISO/TC190 Vol.52, No.2, pp ) Kosson, D.S., van der Sloot, H.A., Sanchez, F., and Garrabrants, A.C. (2002): An integrated framework for evaluating leaching in waste management and utilization of secondary materials, Environmental Engineering Science, Vol.19, No.3, pp ) 2000 Vol.49, No.10, pp ) 2003 Vol.51, No.5, pp
53 2-13
54 2-14
55 2-15
56 2-16
57 m m m m m m
58 2-18
59 - 2-19
60 - 2-20
61 - 2-21
62
63 Eco-Industrial Development ; EID EID EID
64 Divisionof Technology, Industryand Economics,
65 (Industrial Ecology) EhrenfeldGertler (steady-state economies) Georgescu-Roegen(1971) Herman Daly(1991) Cloud(1977) (Industrial ecosystem) 1989 FroshR A Robert Ayres 1993 (Industrial metabolism) Lowe Nelson Nemerow (feedstock) Lowe (Environmentally Balanced Industrial Complex)(EBIC) IE Kalundborg The Kalundborg companies (industrial symbiosis) PCSD EIP 3-3
66 EIP EIP Kalundborg Kalundborg Eco-IndustrialParkEIP 1993 President s Council on Sustainable DevelopmentPCSD ZERI EIP Kalungborg Geng2004 WebGIS GIS
67 1 6 GIS 1km 1km 3 Web GIS ( ) ( ) km 1 JMP
68 t t
69 ha
70 CO2 3-8
71 1) Framework of Environmental Evaluation of Industrial Symbiotic Collaboration in Eco Industrial Estates,,Vol.32,pp.75-80,2000 2),,Vol.28,pp ,2000 3),,Vol.31,pp ,2004 4),,Vol.32,pp ,2004 5) WEBGIS 6) 7) -jisc- 3-9
72 3-10
73 3-11
74 3-12
75 738 t 3-13
76 3-14
77 3-15
78 738 t 3-16
79 3-17
80 LCA
81 (1) (2) (3) (4) 3-19
82
83 ,000 kcal/ 3 ()
84 e-co 3-22
85 SMP SMPScrap Melting Process 2 1 SMP SMP SMPScrap Melting Process SMP SMP mm 8,000kcalg 6,600kcal g JATMA
86 SMP SMP SMP SMP A SMP SMP ASR ASR CO2 CO2 CO2 CO2
87 SMP % 6 6% 15% SMP SMP 10% SMP 10%SMP 90% 3-25
88 CO2 / CO2 / CO2 / CO2 / SMP CO ( CO ) SMP 10 CO2 SMP 3-26
89 SMP SMP SMP SMP SMP
90 SMP 1) ) ) ) Nippon Steel Monthly ) 18pp
91 3-29
92 3-30
93 S CT S i S CT js S X is, j S OS ε OS X, i O, jo ε A, i S, js Z X Z Z Z i, j a Z Z = i, j Z CT Z CT X Z Z j = Z i j X Z Z Z i, j S O S O i i, j j CT Z Z i = Z j X Z Z Z i, j S O OS = X + X ε O S S O O O O,,,,, O O i j X S S S O i, j O OS io jo = + a S io jo ε,, A, is, js CT S j a OS w X i j i j X i i OS OS ε +, O, O w X i j A io jo is js j S O S O i, j j ε OS, S, S A i j min z{o,s} Z X Z Z i, j Z a Z Z i, j Z CT j Z CT Z i Z OS ε O ε OS X, i O, S j A, i S, j OS OS wx wa 3-31
94 3-32 ( ) ( ) ( ) ( ) ( ) = i j IND j i j i j i j i COM i j i j i j i j i j i X X Y VAD X X X X X, 5, 3,,, 7, 6, 4, 2, 0, 1 1 ε ε ( ) ( ) { } ( ) ( ) = j i i i COM j i j i j i j i j i i j j IND j i j i j i XP FD X X X X X IM X X Y, 7, 6, 4, 2, 0,, 5, 3,, 1 1 ε ε
95 w COM i ε COM, i + w IND ε IND, j j min d ( X + X + X ) = M 1+ ε ) ( m, i i, j i, j i, j m, i, j m, i, j ( + ) e m, j Em, j 1 ε E, m, j = { d m, i ( X i, j + X i, j + X i, j ) NONBURNi, j } i = j q out 3 5 wst { ( d + d ) ( Y + X + X )} + d wst ( ) m, i m, i, j i, j i, j i, j 1+ ε m, p p, j m, j i wst p, j = WSTp, q w j ε + w ε m, j m, j m, i, j m, i, j i j p + e m, j min out d m, i, j 3-33
96 wst d m, p MCONS m i = dm i CONS,, i AS t t t = d INV m, i m, i i 3-34
97 t t0 STK, = STK, f ( t t0 + T ) + m i m i i i t t0 t1 = 1 AS t t 1 m, i f ( t ) i (t) f i 3-35
98 S 45 t STK m, i = SRVm, i t SRV t S 45 t = d ASS m, i m, i i 3-36
99 1995 (100 ) 1995 (100 ) 3-37
100 Vol.32,
101 3-39
102
103 R 2.1 ( ) A ( )B ( ) ( ) 11/111/14 ( ) ( ) 4-1
104 g 200g 1/ g//day g//day [g//]
105
106
107 A 4-5
108 B 4-6
109 4-7
110 ) 20012) )
111 4-9
112 4-10
113 4-11
114 4-12
115 1) PET PET 2 2) 3) PET
116 83 PET /21/
117 PET PET 90 PET
118 PET PET PET ± m
119 PET PET PET
120 PET [t/] [t/] 265[/] [kwh/t] [kwh/] [t/] 2040kWh/t 4-18
121 /2 [ ] 265 /km /km
122 ) ) ) PET 7) PET PET
123 PET 10.11g/( ) g/( ) 1.1 g/( PET PET
124 11 PET 10PET
125 ] α0.9 5 α0.2 4 α [ /] [] α α0.3 α [ / ] 11PET 4-23
126 1997 1) 15 2) )F.R.McDougall p ) 5) 6) 7)PET
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