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1 アクリット総合カタロ.indd :26:27 PM

2 Korea China Japan Thailand 1 アクリット総合カタロ.indd :26:30 PM

3 アクリペットのグレード Grades of Types Grade 特徴 Features 代表的な用途 Typical Produsts 標準グレード Standard Grades 光学グレード Optical Grades 特殊グレード Special Grades 耐衝撃グレード Impact Resistant Grades 帯電防止グレード Antistatic Grades 持続性帯電防止グレード Continuous Antistatic 特殊カラー Special Colors VH MD MF VH (optical) VH5 TF8, TF9 VH6 VHM VHS SV VH4 IRD series IRH series IRK series IRL series IRS series IRG series VRL series VRS series TBR series TBV series フィルターカラー Filter Colors 高拡散カラー Diffusion Colors 標準メタクリル樹脂中で 最高の耐熱性を有します Standard grade with top grade of heat resistance 成形性 耐熱性のバランスがとれており 広い用途に利用できます Balanced molding and heat resistance characteristics 流動性に優れ 大型あるいは薄肉成形品用途に適しています Good fluidity and suitable for large molding or thin wall molding. 光学レンズ用 VH の性能はそのままに 異物量を低減しています for oprical lens : lower contaminations 耐熱性を重視しながら 流動性を向上させています Top grade of heat resistance and good fluidity. 流動性に優れており 薄肉導光板に適しています Higher fluidity for thin thickness injection molding 厚肉のシート押出成形に適しています Suitable for thick extrusion sheet VH の耐熱性はそのままに 成形性を向上させています Balanced molding and heat resistance characteristics VH の耐熱性はそのままに 成形性を向上させています Balanced molding and heat resistance characteristics 最も流動性に優れ 耐熱性も有しています Higher fluidity and good heat resistance VH の性能を維持し 耐溶剤性を向上させています Heat resistance & Solvent rsistance 外観 流動性に優れています Good looking and good molding property 外観 耐熱性に優れています Good looking and good heat resistance 耐衝撃性 耐熱性 成形性のバランスがとれています Balanced impact proof, molding property, and heat resistance 耐衝撃性 耐熱性 成形性のバランスがとれています Balanced impact proof, molding property, and heat resistance 耐衝撃グレード中 最も高い流動性を有します Top-grade of fluidity among impact proof grades. 耐衝撃性 耐熱性に優れ 押出成形も可能です Good impact proof and good heat resistance, for extrusion 高耐衝撃性の標準タイプです Standard type of top-grade impact proof 高耐衝撃性 流動性に優れています Good impact proof and good molding properties 帯電防止性に優れてます Good Antistatic property 水洗にも耐える持続性帯電防止性能と耐衝撃性を有します Continuous Antistatic 特定波長の光線をカットします Cut the light ray of specific wavelength 高拡散性が優れ 高い全光透過率を有します Good photo diffusion and high transparency of total waves 自動車テールランプ フロントグリル 工業機器カバーレンズ Tail Lamps of Automobile テーブルウェア Table Ware コップ サラダボール Cup, Salad Bowl fθ レンズ, CD ピックアップレンズ fθlens for LBP, Pick up lens of CD 光学レンズ 導光体 Optical Lens タブレット ノートパソコン用導光板 LGP of Notebook PC/Tablet 押出導光板用シート LGP of Monitor (Extrusion) 自動車メーターパネル自転車反射鏡自動車 LED 集光レンズ LED Lens of Automobile 共押出表層 Overlayer of co-extrusion Sheets & Siding 自動車テールランプ Tail Lamps of Automobile ボールペン バス用品 Ball Point Pens, Bath Goods 照明器具 機器液晶窓 自動車外装部品 Lights,Window of LCD,Exterior Parts of Automobile カーバイザー アウターピラー Visor, Outer pillar of Automobile 携帯電話窓 カーバイザー Mobilephone, Visor of Automobile 共押出表層 液晶 TV 枠 Overlayer of co-extrusion, Frame of LCD TV 建材シート, テーブルエッジ Construction Sheet, Edge Belt of Table 自動車内装部品 オーディオ表示部 携帯電話窓 Interior Parts of Automobile,Audio System Indicator Window of Mobile-phone 自動車内装部品 オーディオ表示部 携帯電話窓 Interior Parts of Automobile,Audio System Indicator Window of Mobile-phone 照明器具 機器液晶窓 Lights, Window of LCD 掃除機, 半導体ケース House Cleaner, IC Tray 赤外線リモコン, サングラス Remote Control Device, Sun Glasses LED カバー 拡散導光体 Diffuser of LED Lighting 2 アクリット総合カタロ.indd :26:31 PM

4 物理的性熱的性機械的性電気的性 アクリペットの一般物性値 ( 標準グレード )General Properties of (GP-PMMA) 標準グレー 項目 Item 試験方法 Method 試験条件 Condition 単位 Unit 耐熱 High VH He 3 密度 Density JIS K7112 ISO 1183 g/cm 質Physical properties 全光線透過率 Total luminous transmittance JIS K ISO mm % 93 曇価 Haze JIS K7136 ISO mm % 0.3 屈折率 Refractive index JIS K7142 ISO 489 nd 吸水率 Water absorption JIS K7209 ISO 62 24hr % 比 熱 Specific heat JIS K7123 J/(g K) 1.5 線膨張係数 Coefficient of linear thermal expansion JIS K7197 1/ 熱伝導率 Thermal conductivity JIS A1412 W/(m ) 0.2 荷重たわみ温度 Temperature of deflection under load JIS K7191-1,2 ISO 75-1,2 1.8MPa 100 ビカット軟化温度 Vicat softening temperature JIS K7206 ISO 306 B Thermal properties メルトフローレート Melt flow rate JIS K7210 ISO , 37.3N g/10min 2.0 スパイラル流動長 ( 厚み 2mm) Spiral flow (2mm thickness) MCC 法 MCC Method 230 mm mm 220 成形収縮率 Mold shrinkage MCC 法 MCC Method % 質曲げ弾性率 Flexural modulus JIS K7171 ISO 178 GPa 3.3 引張 ( 降伏 ) 応力 Tensile strength JIS K7162 ISO A/5 MPa 77 引張破壊ひずみ Elongation JIS K7162 ISO A/5 % 6 引張弾性率 Modulus of elasticity JIS K7162 ISO A/ 1 GPa 3.3 曲げ ( 降伏 ) 応力 Flexural strength JIS K7171 ISO 178 MPa 140 Mechanical properties シャルピー衝撃強さ Charpy impact strength JIS K ISO eU unnotched kj/m eA Vnotched kj/m ロックウェル硬さ Rockwell hardness JIS K ISO M scale 質誘電率 Dielectric constant JIS K Hz 表面抵抗率 Surface resistivity JIS K6911 Ω >10 体積抵抗率 Electrical volume resistivity JIS K6911 Ωm >10 13 絶縁破壊強さ Dielectric strength JIS K6911 4kV/sec MV/m 20 Electrical properties 誘電正接 Power factor JIS K Hz 耐アーク性 Arc resistance JIS K 燃焼性燃焼性クラス Flammability classification UL94 1.5mm, 3.0mm - HB * 日本国内向け 着色品 については 菱晃にて承ります 3 アクリット総合カタロ.indd :26:31 PM

5 A) レード Standard Grades 導光板グレード LGP Grades 特殊グレード (Special Grades) h Heat <<<>>> 高流動 HighFlow 射出用高流動 Injection 押出シート用 Extrusion MD MF VH5 TF8 000 TF9 000 VH6 光学用 Optical VH /000 VHM * は紫外線吸収剤入り 000 は紫外線吸収剤なし *= UV absorbed 000= non absorbed 耐熱 良流動 High Heat & Good Flow VHS SV 耐溶剤 Anti-Solvent VH >10 16 >10 16 >10 16 >10 16 >10 16 >10 16 >10 16 >10 16 >10 16 >10 16 >10 16 >10 13 >10 13 >10 13 >10 13 >10 13 >10 13 >10 13 >10 13 >10 13 >10 13 > HB HB HB HB (0.75mm) HB HB HB HB HB HB HB * 数値は代表値であり保証値ではありません *All technical information and data are typical values, and are not standard value. 4 アクリット総合カタロ.indd :26:32 PM

6 物理的性熱的性機械的性電気的性 アクリペットの一般物性値 ( 耐衝撃グレードほか )General Properties of ( 項目 Item 試験方法 Method 試験条件 Condition 単位 Unit VH 3 密度 Density JIS K7112 ISO 1183 g/cm 質Physical properties 全光線透過率 Total luminous transmittance JIS K ISO mm % 93 曇価 Haze JIS K7136 ISO mm % 0.3 屈折率 Refractive index JIS K7142 ISO 489 nd 吸水率 Water absorption JIS K7209 ISO 62 24hr % 比 熱 Specific heat JIS K7123 J/(g K) 1.5 線膨張係数 Coefficient of linear thermal expansion JIS K7197 1/ 熱伝導率 Thermal conductivity JIS A1412 W/(m ) 0.2 荷重たわみ温度 Temperature of deflection under load JIS K7191-1,2 ISO 75-1,2 1.8MPa 100 ビカット軟化温度 Vicat softening temperature JIS K7206 ISO 306 B Thermal properties メルトフローレート Melt flow rate JIS K7210 ISO , 37.3N g/10min 2.0 スパイラル流動長 ( 厚み 2mm) Spiral flow (2mm thickness) MCC 法 MCC Method 230 mm mm 220 成形収縮率 Mold shrinkage MCC 法 MCC Method % 質曲げ弾性率 Flexural modulus JIS K7171 ISO 178 GPa 3.3 引張 ( 降伏 ) 応力 Tensile strength JIS K7162 ISO A/50 MPa 77 引張破壊ひずみ Elongation JIS K7162 ISO A/50 % 6 引張弾性率 Modulus of elasticity JIS K7162 ISO A/ 1 GPa 3.3 曲げ ( 降伏 ) 応力 Flexural strength JIS K7171 ISO 178 MPa 140 Mechanical properties シャルピー衝撃強さ Charpy impact strength JIS K ISO eU unnotched kj/m eA Vnotched kj/m ロックウェル硬さ Rockwell hardness JIS K ISO R scale - - 質誘電率 Dielectric constant JIS K Hz 表面抵抗率 Surface resistivity JIS K6911 Ω >10 体積抵抗率 Electrical volume resistivity JIS K6911 Ωm >10 13 絶縁破壊強さ Dielectric strength JIS K6911 4kV/sec MV/m 20 Electrical properties 誘電正接 Power factor JIS K Hz 耐アーク性 Arc resistance JIS K 燃焼性燃焼性クラス Flammability classification UL94 1.5mm, 3.0mm - HB * IR シリーズ VR シリーズ TB シリーズの日本国内向けについては 菱晃にて承ります 5 アクリット総合カタロ.indd :26:32 PM

7 (HI-PMMA & Special) 汎用 Standard 耐熱 Heat resistance IR D50 IR H50 IR K304 耐衝撃グレード Impact Modified Grades IR L 高流動 High flow IR S204 IR S404 押出 Extrusion IR G304 高衝撃 High impact resistance VRL40 VRS40 *002 はブルーイングナチュラル *002 : Bluish natural color 帯電防止 Antistatic 一般帯防 Standard Antistatic TBR134 持続性 Continuous Antistatic TBV >10 16 >10 16 >10 16 >10 16 >10 16 >10 16 >10 16 >10 16 >10 16 >10 11 >10 11 >10 13 >10 13 >10 13 >10 13 >10 13 >10 13 >10 13 >10 13 > HB HB HB HB HB HB HB HB HB - HB * 数値は代表値であり保証値ではありません * All technical information and data are typical values, and are not standard value. 6 アクリット総合カタロ.indd :26:32 PM

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12 成形加工上の注意 1. 予備乾燥アクリペットを通常の環境条件下で長期間保管していると 約 1% の吸水量になることがあります 吸水したまま成形しますと 発泡や銀条その他の欠陥が成形品に現れますので 成形直前に材料を乾燥することが必須です 2. 貯蔵アクリペットは ポリエチレン袋を用いて密封されていますが 長期在庫中にはポリエチレン袋を透して吸湿することが知られています 従って できるだけ温度や湿度の低い場所に保管し 古い在庫品から使用することが望まれます また 長期在庫品を使用する場合には 十分に予備乾燥を行ってから使用してください 3. 防塵アクリペットは 特別に設計された防塵工場内で製造 梱包されていますので 異物の混入は非常に少なくなっています しかし これが開封され 予備乾燥 ホッパー投入 成形といった工程を経た成形品には 多くの異物混入要因があります 異物混入防止対策としては次の方法が有効です (1) 工場内の整理整頓をし 空気中に浮遊する塵埃を可能なかぎり少なくすること (2) 予備乾燥機内 乾燥皿 空気取り入れ口フィルター等の清掃 (3) 予備乾燥機内の乾燥皿と摺動部の点検 (4) 乾燥皿には 新しいクラフト紙あるいは長繊維布のカバーをつけること (5) 作業衣は 長繊維のものを用い 木綿 毛等の短繊維のものを避けること (6) 機器の清掃を定期的に行うこと (7) 梱包袋を開いたままで放置しないこと 4. 再生材の使用注意深く再生された材料に関しては 物性的には2 3 回使用することが可能ですが 異物混入の恐れが高いため あまりお勧めできません 再生材を使用される場合には 新しい材料に対して 20 30% 程度が限界と思われます ただし 着色材料の場合には 変色の恐れがあるため再生材は使用できません 再生材の混合量が多い場合には 通常よりもシリンダー温度を若干低めに設定する必要があります 5. アニーリング処理成形品には急冷による残留応力が内在しており 塗装工程や溶剤との接触によりクラック発生の原因となります 成形品を変形が生ずるより若干低い温度に加熱することにより 残留応力が除去されクラックを防止できます 特に 羽布がけや その他機械加工を施したものでは アニーリング処理を行った方が安心です 6. 射出成形機の清掃アクリペット以外の樹脂を成形した後にアクリペットを成形する場合や 違う色のアクリペットを引き続き成形するとき 又は 単一色調で長時間成形して炭化物が発生してきた場合には シリンダーを充分清掃することが必要です シリンダーの清掃には 分解掃除する方法とスクラップ又は掃除用樹脂を空うちして清掃する方法が採用できます (1) 分解掃除シリンダーを本体から外し ノズル スクリューを分解して溶剤で充分洗浄します アクリペットを使用した後ならばトルエン等を用いることができます しかし この分解掃除は時間を要するため 予め掃除済みの予備シリンダーと交換するほうが能率的です (2) 空うち掃除シリンダーを分解せずに樹脂を通して掃除するものです 一般にはアクリペットのスクラップを粉砕したものをホッパーから投入し 通常の射出成形を行う温度より5 10 高い温度で 他樹脂の残留が認められなくなるまで空うちします 掃除の終了を判定するためには 時々新しいアクリペットを投入して これがノズルから出始めたら通常の成形を行い 成形品中の異物の有無を確認する方法を採ることができます 11 アクリット総合カタロ.indd :26:34 PM

13 Notice on molding 1. Predrying The water absorption of ACRYPET may rise up to 1% if it is stored in the non-conditioned environment for a long period. Molding with wet resin would result in appearance of cells, silver streaks or other defects on a product. Therefore it is required to pre-dry the material just before molding. 2. Storage Note that ACRYPET is sealed up using polyethylene bag,but it does not provide complete protection against moistening, i.e., the water absorption may rise in a long period storage. It is recommended strongly to store in low moisture and low temperature condition and consume older one first. When using old stock, make sure to pre-dry completely. 3. Dust control ACRYPET is produced and packed in the specially designed full-dust-control plant to eliminate foreign substance. However, once unpacked, there may be many phases where foreign substance may mix into molded product in such process as predrying, hopper charging and molding. The following preventive measures are effective. (1)Organize your plant thoroughly to reduce floating dust in the room. (2)Clean the inside of pre-dryer, drying plates, air filter of inlet and any other components touching material. (3)Inspect drying plates and sliding parts within the pre-dryer. (4)Cover the drying plates with new craft paper or long-fiber fabric. (5)Adopt work cloths made of long-fiber fabric in spite of that of short-fiber fabric such as cotton and wool. (6)Clean machinery periodically. (7)Do not leave material bags open. 4. Use of recycled resin Recycled resin processed in a cautious manner can be used two or three times from the viewpoint of physical characteristics. However, it is not so recommended because there may be high risks of contamination by foreign substance. The mix rate of recycled resin must be maximum 20 to 30% for the total quantity if using it. For colored material, however, recycled resin is not available because there may be risk of unexpected gradation of color. If percentage of recycled resin is near to the maximum mix rate, the cylinder temperature must be set to slightly lower temperature than usual. 5. Annealing of molded products So residual stress just after quick cooling still remains in a molded product that cracks may be formed in the paint process or at the contact with solvent. To prevent such crack forming, heats a molded product at the slightly lower temperature than the formable temperature to remove this residual stress. Especially, it is recommended to add the annealing to products buffed or machined. 6. Cleaning of injection molding machine Full cleaning of the disassembled cylinder is required when you mold ACRYPET products after other kind of resin, or when you use different colored ACRYPET successively after molding previous one, or when carbide is accumulated in the cylinder owing to single color molding for a long time. Cylinder cleaning method includes 2 types. One is disassembly cleaning and another is dummy injection using scrap resin or cleaning resin. (1)Disassembly cleaning Remove the cylinder from the main body and disassemble the nozzle and the screw. Clean them with solvent completely. Toluene and the like can be used after molding ACRYPET. These cleaning methods, however, take a long time, and so, exchange it simply for the spare cylinder that has been cleaned to save time. (2)Dummy injection cleaning This method is used to clean the cylinder without disassembly by shooting resin. Generally, feed the crushed ACRYPET from the hopper and continue the dummy injection with setting the cylinder temperature at 5 to 10 higher than ordinary one till the residue from other resin is extruded completely. To determine completion of cleaning, feed new ACRYPET several times and execute normal molding after new resin is extruded and inspect whether the test products include foreign substance. 12 アクリット総合カタロ.indd :26:34 PM

14 アクリペットの適合規格 1. ISO ISO9 ISO14 三菱ケミカル ( 富山事業所 大竹事業所 ) ダイヤポリアクリレート 三菱化学高分子材料 ( 南通 ) 2. 食品衛生法関連試験方法 : 食品衛生法 食品 添加物等の規格基準 ( 昭和 34 年厚生省告示第 370 号 ) ポリメタクリル酸メチルを主成分とする合成樹脂製の器具又は容器包装 ( 昭和 57 年厚生省告示第 20 号 ) 試験機関 : 財団法人日本プラスチック検査協会アクリペットVH,MD,MF( 自然色に限る ) 3.FDA(Food and Drug Administration) 試験規格 : 連邦食品医薬品化粧品法 (Federal Food, Drug, and Cosmetic Act) 21CFR 半硬質及び硬質のアクリルと変性アクリルプラスチック アメリカ合衆国保険福祉省 (U.S. Department of Health and Human Services) に属する 食品医薬品庁 (Food and Drug Administration) が担当 試験機関 : 財団法人日本食品分析センター試験結果 : アクリペットVH MD MF: アルコール含有率 8% 以上の食品を除いて 150 F 以下での熱充填又は殺菌の条件にて全ての種類の食品に使用可能 4. 電気用品取締法による材料登録 (1) 熱可塑性プラスチックのボールプレッシャー温度限界試験方法 : 電気用品取締法 電気用品部品 材料任意登録制度 ( 平成 2 年 ) 試験機関 : 財団法人日本電気用品試験所 (JET) アクリペットVH,VHM,VHS,MD,MF,IR,VR (2) 水平燃焼試験結果登録品試験方法 : 電気用品取締法 電気用品部品 材料任意登録制度 ( 平成 2 年 ) 試験機関 : 財団法人日本電気用品試験所 (JET) アクリペットVH,VH4,VH12,VHM,VHS,MD,MF,S,SV,V,IR,VR 5. UL 規格 (94HB ファイル番号 :E54695) 試験方法 :UL94(Underwriters Laboratories Inc. 制定による自主規格 ) 試験機関 :Underwriters Laboratories Inc.(UL) アクリペットVH, VH4, VH5, VH6, VHM, VHS, MD, MF, TF8,TF9,V, IR, VR, TBV150 菱晃 (E95683)VH, VH5, VHM, VHS, MD, MF, V, IR, VR, TBV150 ダイヤポリアクリレート (E168067)VH, MD, MF, V, VHS, IR 三菱化学高分子材料 ( 南通 ) (E256044) VH, MD, MF, V, VHS, TF8, IR LOTTE MCC Corporation (E323372) VH, VH5, VH6, TF8, TF9 6. AMECA 登録色 (Automotive Manufacturers Equipment Compliance Agency, Inc.) 試験方法 :SAE J576C(The Engineering Resource for Advancing Mobility) 試験機関 :ETL Testing Laboratories, inc. アクリペット VH,VH3F,VH4,VH4F,VHM,VHS,MD,V,IR Color No. 次ページ参照 13 アクリット総合カタロ.indd :26:34 PM

15 Applicable Standards 1. ISO ISO9, ISO14 Mitsubishi Chemical (Toyama, Otake), Diapolyacrylate, Mitsubishi Chemical Polymer Nantong 2. FDA (Food and Drug Administration in USA) Standard: Federal Food and Drug and Cosmetic Act 21CFR (Acrylic and modified acrylic plastic, semi rigid and rigid) Tested at Japan Food Research Laboratories Results: VH, MD, MF : for use in contact with all types of food except high alcoholic content foods (greater than 8 percent alcohol) at or below 150,, in the condition of heat filling or sterilization. 3. UL standards (94HB.File No.E54695) Standards: UL94 (Self-restrictive standards established by Underwriters Laboratories Inc.) Tested at Underwriters Laboratories, Inc. Grades : VH, VH4, VH5, VH6, VHM, VHS, MD, MF, TF8, TF9, V, IR, VR, TBV150 RYOKO (E95683) VH, VH5, VHM, VHS, MD, MF, V, IR, VR, TBV150 Diapolyacrylate (E168067) VH, MD, MF, V, VHS, IR Mitsubishi Chemical Polymer Nantong (E256044) VH, MD, MF, V, VHS, TF8, IR LOTTE MCC CORPORATION (E323372) VH, VH5, VH6, TF8, TF9 4. AMECA (Automotive Manufacturers Equipment Compliance Agency, Inc.) Standards: SAE J576C (The Engineering Resouce for Advanced Mobility) Tested at ETL Testing Laboratories, INC. Grades : VH, VH3F, VH4, VH4F, VHM, VHS, MD, V, IR AMECA 2015 年時点登録色 AMECA registered colors (2015) Grade:VH, VH3F, VH4, VH4F, VHM, VHS, MD, V, IR Color No. Color Clear 002 White 007 White 101 Red 111 Red 112 Red 113 Red 116 Red 117 Red 120 Red 121 Red 128 Red 129 Red 141 Red 142 Red 143 Red 151 Red 1007 Red 361 Clear 362 Clear 363 Clear 364 White Color No. Color 203 Yellow 209 Yellow 252 Yellow 253 Yellow 254 Yellow 255 Yellow 256 Yellow 257 Yellow 258 Yellow 259 Yellow 262 Yellow 263 Yellow 264 Yellow 265 Yellow 266 Yellow 267 Yellow 270 Yellow 290 Yellow 2 Yellow Color No. Color 5101 Red 5101B Red 5111 Red 5112 Red 5113 Red 5114 Red 5115 Red 5116 Red 5117 Red 5118 Red 5119 Red 5121 Red 5131 Red 5141 Red 5142 Red 5143 Red 5151 Red 5203 Yellow 5204 White 5206 Yellow 5213 Yellow 5223 Yellow 5233 Yellow 5243 Yellow 5253 Yellow 5256 Yellow Color No. Color 5263 Yellow 5266 Yellow 5273 Yellow 5276 Red 5283 Yellow 5293 Yellow 5296 Red 5303 Yellow 5313 Yellow 5323 Yellow 5333 Yellow 5343 Yellow 5353 Yellow 5363 Yellow 5373 Yellow 5383 Yellow 5386 Red 5393 Yellow 5403 Yellow 5413 Yellow 5423 Yellow 5456 Red 5470 White Color No. Color 531 Gray 533 Gray 541 Gray Gray Gray Gray Gray Gray Gray Gray Gray Gray Gray Gray Gray Gray Gray Gray Gray Gray Gray Gray Gray White Color No. Color Gray Gray Gray Gray Gray Gray Gray Gray Gray Gray Gray Gray Gray Gray Gray Gray White White White White White White White White White White PR5556 White PYR5406 Clear 14 アクリット総合カタロ.indd :26:35 PM

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