D nucleation 3 3D nucleation
Glucose isomerase 10 V / nm s -1 5 0 0 5 10 C - C e / mg ml -1
kinetics
µ R K kt
kinetics
kinetics
kinetics r β π µ π r a r s + a s : β: µ πβ µ β s c s c a a r, & exp exp 0, 0 kt a J kt J J S C s µ πβ
r a r N a r N S S δ π δ π kinetics β π µ π r a r s + r a N a N N a N s s s β µ β π µ β π µ + + + 1/ 1/ & µ β µ kt K r r r a kt K N kt K s c s s s 0 0 1 Q r µ kt K s 0
kinetics a τ 1 J s 1A R a τ 1 aj s A τ N n J s Aτ A n? A n N n τ J τ s 1 / 3 A aj a R τ 1/ 3 0 : a J / 3 s 1/ 3 exp πβ as 3 µ kt
kinetics
kinetics
3 c c r r r 19 1 0 λ µ kt K s 0 kinetics λ 0 0 19 19 / µ β λ kt a aks r a a R s c µ β s c a r
kinetics
T T h M L µ µ µ L µ S M S L S L S L M S S M S L M L L T h T P T T P T h h h s s T s T h s T h,, µ µ µ µ 1
R R C C 3 4 3 4 R R S π γ π µ + 3 3 16 µ γ π S S C 3 16 exp exp 3 0 0 kt J kt J J S C µ γ π
3 R K R R R a aν a P Pe S P P πmkt πmkt S exp E aν exp kt µ kt E kt desol C S exp k C 1 exp kt d µ e e
4 a τ 1 J s 1A R a τ 1 aj s A τ N n J s Aτ A n? A n N n τ J τ s 1 / 3 R A aj a τ 1/ 3 0 : a J / 3 s 1/ 3 exp πβ as 3 µ kt
c c r r r 19 1 0 λ µ kt K s 0 λ 0 0 19 19 / µ β λ kt a aks r a a R s c µ β s c a r 5
010 5 6 Hard copies 514 A4 3 5 Intro Experimental Results&Discussion or
H0 energy E E d µ
H0 R C µ S T γ, P l T e S γ T e T
H0
H0
H0
H0 R V V V V V V
H0 Thermal roughening Kinetic roughening
H18 http://www.techplaza.city.higashiosaka.osaka.jp/word/keyword/etching.html
H18 1, d sinθ nλ http://kic.web.infoseek.co.jp/needs_seeds /nano_tech/yamashita/
H18 http://www.nims.go.jp/jpn/news/press/pdf/press65.pdf
H18 Pectin Esterase Google Scholar
H18 Silicon GaN Photonic Crystal, Protein Crystal
H18 X X Integrated Circuit, IC
H18 DNA 3 http://www3.tokai-sc.jaea.go.jp/sangaku/contents/titeki/santa/g/images/g-09-1.jpg
H18 h k l1/x 1/y 1/z 111
H18 DNA Si 1. Photonic. DNA 4. 3.
H18 160 4000-103 5000 http://www.spring8.or.jp/ja/current_result/press_release/006/060404_fig/fig_html
H18 µ Si http://www.nims.go.jp/jpn/news/press/pdf/press65.pdf
H18 DNA DNA
H18 %
H18
H18 Silicon Silicon http://www.silicone.jp/j/products/oil/search/index.html
H18
H18 P 0 Zn-Mg-Ho p-zn-mg-ho 6 6 P 0 Zn-Mg-Ho p-zn-mg-ho http://www.chem.sci.osaka-u.ac.jp/lab/micro/report/005/005res08.html.ja
H18
H18
H18 lnc/c e 0.01 lnc/c e 1~
H18 0 I ln K RT V p Si http://nikon.topica.ne.jp/pec_j/society/story00.htm Si
H18 DNA nm/s mm 10
H18 kt
H18 critical nucleous embryo, crystal
H18 100 nm 10 But!
H18 µ 3 C 16π S γ J J 0 exp J 0 exp kt 3 µ kt µ
H18 VI
H18
H18 ρgh h γ cosθ r
H18 1 00mg
H18 Hen egg-white lysozyme s.964x10-6 m 3 γ 1.1X10-3 Jm - µ 1.381X10-3 X93.15X c.99x10-19 J C 16 π 3 S µ γ 3
H18
H18 Epitaxial
H18 G α 5 Jackson s α parameter α 3 α α 1 0 0.5 1 X Z α ' Z s R
H18 Volmer-Weber rank an der Merwe M VW
H18 A : µ < 0 C e B C B A B, B': µ > 0 C : µ > µ c > 0 µ kt ln C / Ce T
H18 γ SL γ WL > γ WS + γ SL rank an der Merwe Rsinθ O θ R θ γ WL γ WS γ WL + γ SL > γ WS > γ WL - γ SL Volmer Weber γ WS > γ WL + γ SL
H18
H18 Zone refining M
H18
H18 Maxwell-Boltzmann d kt m kt m d exp Pr / 3 π,,,, z z y y x x z y x d d d + + + N z y x z y x d d d,,,, z y x z y x f f f
H18 1,, 0 6 z y x x z z y y x x a f a f a f a a f ζ η ξ ζ η ξ + +,, z y x 1 6 ζ η ξ ζ η ξ a + +
H18 1 6 ζ η ξ ζ η ξ a + + 1 6 ζ η η ξ ζ η ξ ζ η ξ η ζ η ξ a + + + + + + η η, ξ 0 3 3 6 0 0 1 0 '0 0 '0 1 ' a a a f a a Q ξ ξ ξ
H18 N exp '0 ' 3 αξ ξ ξ α ξ ξ A a + + + + z y x z y x z y x z y x z y x z y x d d d A N d d d A d d d exp exp,, α α z y x z y x z y x z y x d d d N d d d N A d exp,, 1 exp 3 / 3 / + + α π α π α α π ξ αξ
H18 z y x z y x z y x z y x d d d N d d d exp,, 3/ + + α π α E α + + + + z y x z y x z y x d d d m N E exp 3 / α π α 5 / 0 4 3 / 0 0 0 5 / 3 / 0 3 / 8 3 exp 4 1 exp 1 exp exp 4 3 8 3 4 exp α π η αη η α π η αη η α π η αη π ξ ξ α α π π α π π α π α d d d d N m N m d m N E Q
H18 E RT 3 kt m α N m E 4α 3 N N A z y x z y x z y x z y x d d d kt m kt m N d d d exp,, 3/ + + π