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1

2 IMO/PSPC M ERR P ERR M P M P R R i

3 ERR R Bevel angle ERR ERR R R ii

4 OS IMO/PSC JSQS IMO/PSPC PSPC R IMO 2 PSPC 1

5 WG1 WG WG WG 2

6 WG WG WG WG 3

7 JSQS IMO/PSPC 1.2. IMO/PSPC Performance Standard for Protective Coatings for dedicated seawater ballast tanks on all new ships and double- side skin spaces of bulk carriers; PSPC, PSPC, IMO MSC IMO MSC PSPC 1-1 PSPC, 1-1 PSPC Requirement for Surface Preparation *1*2 Sa 2 1 / m *1 ISO (1988/Suppl: Preparation of steel substrate before application of paints and related products Visual assessment of surface cleanliness) *2 ISO /2 (1988. Preparation of steel substrate before application of paints and related products Surface roughness characteristics of blast cleaned steel substrates) *3,,,,,,, 2mm, *3 ISO (2001 (grade P2). Preparation of steel substrate before application of paints and related products - Visual assessment of surface cleanliness) 1.3., PSPC

8 , 1-2 Requests to Improve Coating Performance PSPC (1) PSPC, 1-1, 2mm,. 2mm,, PSPC PSPC (2),, 3, (3), PSPC, PSPC,, 5

9 1.4.2., ISO (1988/Suppl: Preparation of steel substrate before application of paints and related products Visual assessment of surface cleanliness) ISO /2 (1988. Preparation of steel substrate before application of paints and related products Surface roughness characteristics of blast cleaned steel substrates), Sa 2 1 /2, Sa 2 1 /2,,,, Standard for the Preparation of Steel Substrates for PSPC-2008(SPSS for PSPC) , ISO (2001 (grade P2). Preparation of steel substrate before application of paints and related products - Visual assessment of surface cleanliness),, JSQS,,, PSPC JSQS, 1.5. PSPC ) ISO (1988/Suppl: Preparation of steel substrate before application of paints and related products Visual assessment of surface cleanliness) 2) ISO /2 (1988. Preparation of steel substrate before application of paints and related products Surface roughness characteristics of blast cleaned steel substrates) 3) ISO (2001 (grade P2). Preparation of steel substrate before application of paints and related products - Visual assessment of surface cleanliness) 4) IACS Recommendation No.47 Shipbuilding and Repair Quality Standard (Rev.3, Nov.2006) 5) JSQS Japan Shipbuilding Quality Standard (Hull Part), The Society of Naval Architects of Japan Research Committee on Shipbuilding, ) Standard for the Preparation of Steel Substrates for PSPC-2008(SPSS for PSPC),,

10 R 3 R R R PSPC R 2R 3 Edge retention rate ERR 2.2. MIL-REF-23236C 1) ERR PSPC MIL-REF-23236C ERR,, PSPC 320 m m mm m 2.4 m

11 2-1 Automatic painting apparatus 2.3. M MIL-REF-23236C M ,20 20mm MIL-REF-23236C M 評価対象エッジ 43mm mm mm 20mm 20mm 15mm 8mm 28mm 120mm 20mm 25mm 10mm 10mm 20mm 90 33mm 15mm 25mm 15mm mm 33mm 2-2 Test specimen, Specimen's holder (M-Method) 8

12 2.3.2.,,, 3, 2-3,, 4 9% スプレー方向 スプレー方向 スプレー方向 2-3 Paint application (M-method) ERR ERR, (ElectoroPhysik MiniTest2100) (KEYENCE VH-800) 50 ( 30 ) 2-4 (2 ), R (2 ) R 5 3 (2 ) (2 ) (2 ) 7 ERR, (1) DFT ( edge ) % ERR = 100 (1) DFT ( flat ) DFT(edge) DFT(flat) P MIL-PRF-23236C 3 M,, 9

13 edge center R end R end Side Defective R, Composite R, R shape Side Side edge corner Side Center edge corner Edge center 3 pass shape Center ege corner Side edge corner Side 2-4 DFT edge measurement point,, ,12 30mm target edge 43mm mm mm 5mm 15mm 28mm 8mm 12mm 120mm 12mm 20mm mm 33mm mm mm 33mm 2-5 Test specimen, Specimen's holder (P-Method) ,,,

14 スプレー方向 スプレー方向 スプレー方向 2-6 Paint application (P-method),15, m, m ERR ERR,M,, M,,5 3,7, R, R R 5 3,, (2 ),, 7 ERR, (1), P, M,,,, (2) DFT ( edge ) % SideERR = 100 (2) DFT ( flat ) DFT(edge) DFT(flat) 2.5. M P R R=1.0,1.5,2.0mm 3 M P 11

15 R R shape edge R=1.0,1.5,2.0mm 2-7 edge shape (3pass, round shape) NOVA200QD 7%, 1.7Pa s 40 50cm/sec, - 37cm 30:1, MPa, MPa GRACO # , % , 56 58% Example of cross section views of specimens (M-method: Left: R shape(r=2.0mm), Right: 3pass) 12

16 2-9 Example of cross section views of specimens (P-method: Left: R shape(r=2.0mm), Right: 3pass) 2-8 M,,,, 2-9 P,,,R R,3,2,P ERR, 2-10 M 2-11 P M-method R shape - 3 pass(2008, 2009) ERR (%) R shape(2008) Ref.:3 pass(2008) R shape(2009) Ref.:3 pass(2009) R(mm) 2-10 M-method result 13

17 Side ERR (%) P-metod R shape - 3 pass (2008, 2009) R shape (2009) Ref.: 3 pass (2009) R shape (2008) Ref.: 3 pass (2008) R (mm) 2-11 P-method result R ERR, R ERR, 2, ,ERR,, ERR/ERR(3 pass mean) ERR/ERR(3 pass mean) R shape (2008) Ref.: 3 pass (2008) R shape (2009) Ref.: 3 pass (2009) R(mm) 2-12 Ratio of ERR/ERR(3pass mean), M-method 14

18 Side ERR/ Side ERR(3 pass mean) Side ERR/Side ERR(3 pass mean) 0.8 R shape (2009) 0.6 Ref.: 3 pass (2009) 0.4 R shape (2008) 0.2 Ref.: 3 pass (2008) R (mm) 2-13 Ratio of ERR/ERR(3pass mean), P-method M, P 3,,ERR,,,,, M P 2-8 R 3,,, R,3, 1,R 3,,1,, 2,,,3 1,,, R 3, R,P, ERR,, 2),P, R R P,3 15

19 2-14 Example of cross section views of P-method specimens (Left: 3pass, Right: 1pass, down: R shape) 2.6., ERR, 2 M, P ERR,,, M P, ERR ) MIL-PRF-23236C Standard, "Performance Specification: Coating Systems for Ship Structures", ) R,, H21, 2009, 16

20 3. R (PSPC),, 2R or 3-path grinding equivalence.r R, R, R, 2R or 3-path grinding equivalence, R,R R R R,2R, R 1) (Edge retention rate :ERR),2 R R R 3-1 R,d=0 R,d/R 3-1 d/r Bevel angle R 3-2 R R, R, / 90,( = 2 ) ) / 0, 1, 3-2, , 3pass R R=1.0mm, 1.5mm, 2.0mm 3-1 Cross section parameter of defective R shape d/r Bevel angle defective R shape 17

21 3-2 edge shape (mm)r(mm) (deg.) (mm) (mm) % % % % % % % 3-2 Featuring parameter of composite R shape % R R shape edge R=1.0,1.5,2.0mm 3-3 Composite R shape (test specimen) 3-4 Reference edge shape (3pass, round edge) ERR, MIL-REF-23236C 2) R R ERR, 1) ERR,, R R , NOVA200QD 7%, 1.7Pa s 40 50cm/sec, - 37cm 30:1, MPa, MPa GRACO #521 R , % R 14 15, 56 58% R, R 18

22 0m,, 1),R P, R M P,, 20 2 M 1, P, 3-6 M 3First spray First spray Second and Second spray Last spray Last spray m12mm target edge 20mm 20mm target edge 3-5 Paint application (P-method) 3-6 Paint application (M-method) ERR, (ElectoroPysik MiniTest2100) 4 4 (KEYENCE VH-800) 50 R,30,, 3-7 R R R R edge center R end R end Side Defective R, Composite R, R shape Side Side edge corner Side Center edge corner Edge center 3 pass shape Center ege corner Side edge corner Side 3-7 DFT edge measurement point P R, m, m 0.021, 0.021,M R,,139.3 m

23 3-4 Center ERR of Composite R shape edge Edge shape DFT DFT ERR ρ δ/δ(%) side(μm) edge(μm) (%) 3-8 Example of cross section views of defective R shape specimens (Left: defective R( ), Right: 3pass) 3-9 Example of cross section views of composite R shape specimens (Left: composite R( =1.0mm), Right: 3pass) 3-3 Side ERR of defective R shape edge Edge shape DFT DFT ERR Bevel angle θ( ) side (μm) edge (μm) (%) ρ=1.0mm 21.7 ρ=1.0mm 33.1 ρ=1.0mm 46.0 ρ=1.0mm 50.7 ρ=1.5mm 18.3 ρ=1.5mm 21.2 ρ=1.5mm 33.1 ρ=1.5mm pass R=1.0mm R=1.5mm R=2.0mm pass (157.5) R=1.0mm R=2.0mm ERR 3-8 R P 3-9 R M 20

24 1), ERR (1) ERR DFT ( edge ) % ERR = 100 (1) DFT ( flat ) DFT(edge) DFT(flat),R,R R,3,3 ERR R, R,3,2 ERR ERR R Bevel angle ERR R 3 R P R Bevel angle ERR ,3 ERR,Bevel angle R ERR,2R,R, ERR 1R,3 ERR, 2mm R,R Bevel angle 150 1R, 3 ERR Side ERR - Bevel angle θ Side ERR (%) Bevel angle θ ( ) Defective R Ref.: 3pass Ref.: 1R Ref.: 2R 3-10 Side ERR - Bevel angel (Defective R shape) 3.6. ERR R 3 R M ERR , R=2mm R, =1.5mm,,3 ERR ERR =1.0mm, 3 ERR R,1R<3 <1.5R<2R, R=2mm R, 21

25 =1.5mm, 3 ERR 140 Center ERR-Stick up parameter Center ERR (%) Stick up parameter δ/δ (%) ρ=1mm ρ=1.5mm Ref.:3pass Ref.:2R Ref.:1.5R Ref.:1R 3-11 Center ERR - Stick up parameter (Composite R shape) 3.7. R R R, 1) ERR,IMO/PSPC 2R or 3-path grinding equivalence, ERR,R R, ERR 2mm R, R Bevel angle mm R, 1.5mm, ),, H21, 2009, 2) MIL-PRF-23236C Standard, "Performance Specification: Coating Systems for Ship Structures",

26 IMO/PSPC IMO/PSPC (ERR: Edge Retention Ratio) ERR 4.2. ( 4-1) s z h(s, t) ( 1), 2), 3) ) σ 3μ h = h ( h + κ ) t sss s s t s (s) h 3 (1) ( (2)) ( (3)) 4-2 h( s,0) = h0 4-3 h ( t) h ( t) h ( L t) h ( L t) 0, = 0, =, =, = 0 s sss s sss 式 (1) からわかるように, 本論の計算は流体の蒸散や表面張力変化の影響は含まれていない. 4.3., IMO/PSPC R 4-1 (s) s R R R=0.20 cm, 0.15 cm, 0.10cm(R ) 3 R [R1=0.51cm, R2=0.02cm] [R1=0.32cm, R2=0.01cm] 2 (R1 R2 ) R 4-2 =30 dynes/cm = 1 pose t=1.0s 4-2 s=0.002cm t= s h0=0.02cm R [R1=0.317cm, R2=0.01cm] smin=0.0001cm t= s 23

27 (h/h0) s (s/l) L 4-3 s/l=1 s/l=0 ( )0.02cm ( 4-2 ) h = h0 4-3 h=h0 s (ERR) s/l= R-() R ( ) R1( )-R2( ) R ( ) ( 4-2 ) R (ERR), R=0.20cm 98%, R=0.15cm 93% R=0.10cm 87% R 85% R=0.20cm R ( 100%) R, [R1=0.51-R2=0.02] 72% [R1=0.32-R2=0.0] 91% [R1=0.51-R2=0.02] 4-2 ( ) (R2 ) [R1=0.32,R2=0.01] (R2 ) 90% R 4.5. (ERR) R ) L.W.SCHWARTZ and D.E.WEIDNER: Modeling of coating flows on curved surface, Journal of Engineering Mathematics, 29, 1995, pp ) J.A.Moriarty, L.W.Schwartz and E.O.Tuck: Unsteady spreading of thin liquid films with small surface tension, Phys.Fluids, A 3 (5), 1991, pp ) D.E.Weidner, L.W.Schwartz and R.R.Eley: Role of Surface Tension Gradients in Correcting Coating Defects in Corners, Journal of Colloid and Interface Science, 179, 1996, pp

28 R R 4-3 R R 25

29 5. R IMO MSC82 "Performance Standard for Protective Coatings" (IMO/PSPC) IMO/PSPC 2R 2mm 3 ( ) R R 2R 3 ( PJ ) R R PJ IMO/PSPC 5.2. R PJ 18 9 A B C D E F G H I FB IA UA LJ-G080 KS-Analyzer R R KS-Analyzer R R 1 R R R 3 R R 3 3 R 5-1 R R 2mm R 1 R 2mm R R 68 μ+σ μ σ 5-1 A, D, H R<2mm B, E, F R>2mm <2mm 26

30 C, G, I R>2mm >2mm R 5-2 R 2mm R 5-3 R>2mm R <2mm 5-4 R 2mm R R 10mm % (μ σ) 2.0mm 6 R R 5-5 R 2 R 5-2 R R ln Pr [ <1.5mm] 2.6% 68% 2.0mm R 1.5mm 3% R 2mm 1.5mm 2R 3 R 2.0mm IMO/PSPC 5.3. PJ R 2mm 2mm R 1)2) δ/δ 0 δ/δ =100% δ/δ ρ=1.0mm, 1.5mm δ/δ =18% 46% Ψ=30, 45, 60 deg

31 MIL-23236C 3) ERR%= DFT( edge) DFT( flat ) (1) ERR DFT(edge) DFT(flat) 3 DFT(edge) 5-10 DFT(edge) R =1.5mm R =1.0mm R ERR δ/δ 2mm R =1.5mm 3 2mm R =1.0mm δ/δ 20% 3 R 2mm 1.5mm R 2mm 1.5mm 3 IMO/PSPC R 2mm R 1.5mm 2 R 68% 2.0mm 5.5. R R IMO/PSPC 9 68% 2.0mm 3 2.0mm 28

32 R 2mm 1.5mm 3 IMO/PSPC R 2mm 1.5mm ),,, No. 8 (2009) 2) R,, No. 8 (2009) 3) MIL-PRF-23236C Standard, Performance Specification: Coatings Systems for Ship Structures (2003). 29

33 R (a) R (b) ρ 5-1Measurements of R and ρ. 5-1 Statistics on R and ρ for all makers. R (μm) ρ(μm) mean stdev μ-σ μ+σ mean stdev μ-σ A 社 B 社 C 社 D 社 E 社 F 社 G 社 H 社 I 社 R 5-2 Relationship between R and ρ for the case where most samples have R larger than 2mm (unit: μm). R ρ ρ 5-3 Relationship between R and ρ for the case where samples have R larger than 2mm but not a few samples have ρ smaller than 2mm. (unit: μm). 5-4 Relationship between R and ρ for the case where most samples have R and ρ larger than 2mm. (unit: μm). R (μm) ρ(μm) 5-5 Relationship between R and ρ for the cases where the lower bound of 68% confidence interval of R is larger than 2mm. (unit: μm). 5-2 Statistics on R and ρ for all makers for the cases where the lower bound of 68% confidence interval of R is larger than 2mm. R (μm) ρ(μm) mean stdev μ-σ μ+σ mean stdev μ-σ Frequency / total / bin width ρ 700x PDF of the fitted log-norm dist. 4 12x Statistical analysis of ρ for the cases where the lower bound of 68% confidence interval of R is larger than 2mm. 6 Min. radi ρ [μm] total num = 426 bin width = μm

34 Frequency / total / bin width 700x total num = 426 bin width = μm Statistical analysis of R for the cases where the lower bound of 68% confidence interval of R is larger than 2mm. 6 Radi R [μm] x Ideal 3-path grinding edge Side edge corner Side Center edge corner Edge center 3 pass shape Center ege corner Side edge corner Side 5-10 DFT measurement points of 3-path grinding edge ERR (%) Compound R shape ρ=1mm ρ=1.5mm 3 path δ/δ(%) 5-11 Comparison of edge retention ratios of compound R shape and 3-path grinding edges. 31

35 WG

14 FEM [1] 1992 [3] 1(a)(b) 1(c) [2] 2 ( 財 ) 日本海事協会 36 平成 14 年度 ClassNK 研究発表会

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