元素分析

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あいぞうやたけ
6 years ago
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1 : このマークが付してある著作物は第三者が有する著作物ですので同著作物の再使用同著作物の二次的著作物の創作等については著作権者より直接使用許諾を得る必要があります

2 (PET)

3 H He 1 2 Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Uub 113 Uuq 115 Uuh Lanthanoide (58-71) Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Actinoide (90-103) Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr Essential mineral elements Essential non mineral elements Beneficial Well known toxic elements

6 Shoot ( DE ABC!!"#!$ %&!$!'$ %& $!'$ %& (" )*)& )*& +, )*)& )*& -. )*& / 01 )*2 3) (1 & 4) 56 3 &)) 7 3 3) -# 2 &)) 8 2) & 9 /) 3 ($ :) 3 -; &34 4 < 34) &) + &))) &4 = /)))) /) > 3:)))?4) - 2@4)))?4)

7 制限資料 Shinano et al Photosynthetica 44(1), 1-10

11 C

15 10g 20mg

16 100mg mg 10mg

20 ICP-AES AAS ICP-MS AAS RNAA, INAA LA-ICP-AES XRF PGA LA-ICP-MS XMA(EPMA) PAA PIXE CPAA

21 ICP-AES AAS ICP-MS AAS RNAA, INAA LA-ICP-AES XRF PGA LA-ICP-MS XMA(EPMA) PAA PIXE CPAA

22 ICP-AES AAS ICP-MS AAS RNAA, INAA LA-ICP-AES XRF PGA LA-ICP-MS XMA(EPMA) PAA PIXE CPAA

23 ppt 1ppt DW g 10pg

25 20 200mg DW Limit 0.01

26 CN CNS CHONS 1 18 H He 1 2 Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Uub 113 Uuq 115 Uuh Lanthanoide (58-71) Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Actinoide (90-103) Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr

27 AAS mg DW ppt ppb x

28 LA-ICP-MS µm pg ICP-MS ppt ppb

29 X X XRF, XRF, XMA, PIXE) X X X

30 X 制限資料 Nakai, Terada, Itou, Sakuari, J. Synchrotron. Rad., 8, 1078 (2001).

31 XRF X 1 18 H He 1 2 Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Uub 113 Uuq 115 Uuh Lanthanoide (58-71) Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Actinoide (90-103) Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr

32 ppm 10 Si, Ti, Al, Fe, Mn, Mg, Ca, Na, K, P Sc, V, Cr, Co, Ni, Cu, Zn, Ga, Rb, Sr, Y, Zr, Nb, Ba, Cs, La, Ce, Pr, Nd, Sm, Gd, Dy, Er, Yb, Hf, W, Pb, Th, U

33 cm x10cm

34 X 制限資料 (1-10 ) 制限資料

35 PIXE Particle Induced X-ray Emission ppm, B, Li, F 制限資料制限資料

36 1 18 H He 1 2 Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Uub 113 Uuq 115 Uuh Lanthanoide (58-71) Actinoide (90-103) Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr

37 (RNAA INAA) Neutron Activation Analysis (PGA) (PAA) (CPAA) mg

38 Radiochemical NAA Instrumental NAA

39 1 18 NAA H He 1 2 Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Uub 113 Uuq 115 Uuh Lanthanoide (58-71) Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Actinoide (90-103) Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr !"#$%& '"#(%)

40 ppb

41 10mg 10sec 19min 5min γ 26min 14min γ 1g 6hr 3-6days 2-40hr γ 11-18days 25-70hr γ 21-39days hr γ BUNSEKI KAGAKU, 52, 325 (2003)

42 PGA (prompt γ-ray analysis) NAA H, B, Si, P, S Cd, Hg, B, Cd, Sm, Gd, Eu

43 PGA 1 18 H He 1 2 Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Uub 113 Uuq 115 Uuh Lanthanoide (58-71) Actinoide (90-103) Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr

44 PAA (Photon Activation Analysis) NAA NAA Mg, Ti, Ni, Y, Zr, Nb, I, Tl, Pb

45 CPAA (Charged Particle Activation Analysis) O, C, B, N

47 50-200mg DW

48 AAS ICP 230 C 105 C mg ml mg ml

51 制限資料

52 制限資料 (%) 36 70(60) (14) ca ,

53 制限資料 C HCl 80 HNO H2SO4 HF 230 ICP ,

54 PP PFA, PTFE, TFM x x HF HF 制限資料 Si, Na, K, B Si ,

55 制限資料 HCl HNO3 H2SO4 Ag, Hg, Pb Sb, Sn,W, Mo, Zr,Ti, B Ba, Pb, Cr, Sr Al, Ca, Mg, Nb,W, Mn, etc As, Sn, Se, etc. Ge, Si, etc. Cr 2006,

56 AAS µl ppt ppb ml ppb ppm x

57 AAS 1 18 H He 1 2 Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Uub 113 Uuq 115 Uuh Lanthanoide (58-71) Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Actinoide (90-103) Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr

58 Ca La 2000ppm (JIS), etc.

59 ICP-AES ICP-MS ICP ml ppm ml ppt ppm (ICP-MS

60 ICP-AES 1 18 H He 1 2 Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Uub 113 Uuq 115 Uuh Lanthanoide (58-71) Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Actinoide (90-103) Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr

61 ICP-MS 1 18 H He 1 2 Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Uub 113 Uuq 115 Uuh Lanthanoide (58-71) Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Actinoide (90-103) Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr

62 Li 14 N 2+ Na 46 Ca 2+ Al 54 Fe 2+ Si 14 N 14 N P 14 N 16 OH, 15 N 16 O S 16 O 16 O K 23 Na 16 O Ca 40 Ar, 40 K Cr 40 Ar 12 C Fe 40 Ar 16 O Se 40 Ar 40 Ar MS, etc.

63 Bi, Ho, In,Rh, Sc, Tb, Y

65 Cl Br ICP-MS XRF, 150mg + water 10ml with 0.1ml of 1% Tween min. 2-3 min.

66 ppm ppm 制限資料 H2PO4, F, Cl, NO2, Br, HNO3, SO4 30min/ IC-MS

69 B AAS ICP-AES ICP-MS XMA

70 Si HF AAS ICP-AES ICP-MS XMA

71 AAS (ICP-MS, XMA) 5 HNO 3 /trace /trace HF Al, As, Sb, Ba, B, Cd, Ca, Cs, Cr, Co, Cu, Ga, Ge, Fe, Pb, Li, Mg, Mn, Mo, Ni, P, K, Rb, Se, Si, Ag, Na, Sr, Sn, Ti, W, U, V, Zn, Zr 10μ /

72 NIST2709 San Joaquin Soil NIST2711 Montana Soil NIST 1570a Spinach Leaves BCR 679 White cabbage NCS DC07605 Tea NIST National Institute of Standards & Technology ( BCR Community Bureau of Reference NCS China National Analysis Center for Iron and Steel

73 ICP X GL-Science

74 < < XRF < ICP-AES AAS ICP-MS < AAS < < AAS < ICP XRF

75 < XRF AES < ICP-AES < ICP-MS AAS AAS < ICP AAS AAS < AAS LA-ICP XRF

76 AAS AAS XRF ICP-MS ICP-AES

78 Fin å web: rose.hucc.hokudai.ac.jp/~a11277/shinano.html

1 1 H Li Be Na M g B A l C S i N P O S F He N Cl A e K Ca S c T i V C Mn Fe Co Ni Cu Zn Ga Ge As Se B K Rb S Y Z Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb T e

No. 1 1 1 H Li Be Na M g B A l C S i N P O S F He N Cl A e K Ca S c T i V C Mn Fe Co Ni Cu Zn Ga Ge As Se B K Rb S Y Z Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb T e I X e Cs Ba F Ra Hf Ta W Re Os I Rf Db Sg Bh