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- よしたか あきくぼ
- 5 years ago
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1 Rb Rb Rb :
2 2
3 Rb Rb Rb FM
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5 Light-Induced Desorption LID LID LID LID Rb Rb Rb LID [1]Rb Rb Rb Rb LID Rb Rb LID Rb Rb 1.2 Rb Rb Rb LID 0.2 ev 0.9 ev 375 nm 170 mw 40 mm /s
6 6 1 XPS Rb Rb O Rb FM Rb Rb 1.3 Rb 1.1 Rb LID
7 7 2 Rb Rb Rb 2.1 Rb 375nm Rb Rb (Secondary Electron Multiplier SEM SEM Rb FM 2.2 Rb Rb (SiO 2 :81 B 2 O 3 :13 Na 2 O:4 ) [1] Rb (70 C4 h) 2.1 Rb
8 nm 2.1 Rb SiO 2 Rb φ20 mm 0.5 mm φ20 mm 30 mm φ6 mm Rb Rb 2.2 Rb Rb Rb Rb Rb 370 C 2 Rb Rb Rb Rb
9 2.2 Rb Rb 2.5 Rb
10 Rb Rb LID Rb Rb Rb 2 O= RbO 2 =) [2] 2RbO 2 + 2H 2 O 2RbOH + H 2 O 2 + O 2 (2.1) Rb 2 O + H 2 O 2RbOH (2.2) Rb 2Rb + 2H 2 O 2RbOH + H 2 (2.3) Rb Rb 2.3 Rb Rb 2.3.1
11 2.3 Rb 11 i + i 0 ( ) Φ Ei = Aexp kt (2.4) i + : i 0 : Φ: E i : Pt Pt Pt 5.0 A Pt SEM 0.05 [1] Pt Pt Rb Rb Rb nm D2 450 nm 1/2000 Rb
12 Pt A 2πL 2 = (2.5) APt =3.53 mm 2 L Pt =70 mm (0.05) /s 10 5 /s /s 2.5 FM Rb FM Rb nm AFG3102 Rb NEW FOCUS MHz
13 2.5 FM 13 SIGNAL RECOVER7270GDS-2064 Ch1 [Freq:150 khz, Amp:20 mv p p, :sin ]Ch2 [Freq:100 Hz, Amp:300 mv p p, :] T Ch1 Rb φ=30 mm 60 mm /cm 3 Rb Ch2 SN 1:1 Rb Rb Rb LID Rb Rb Rb Ch2 SN Rb Rb /cm 3 Rb.0/ #8:9<;4= &('*),+ -/.02143,5! #"%$'& $)(+*-, "!$# % ! #"%$'& $'()+*-,.0/ )9;:=<!#"%$'&)( &)*+!-,/ :9:;=<6>
14 SEM Pa Pt
15 Rb PG/PBN φ18 mm Rb C 24h 1.8 Ω 11.7 Ω
16 Pt SEM Pt 5.0 A SEM 2.0 kv Rb Pt 5.4 A SEM A121(AMPTEK ) PC121(AMPTEK ) V 3.9 SEM LabView AOUT 50 Ω Ground
17 nm LD nm 450 nm (Thorlabs DMLP567) f= mw 40 mm mw, φ3 mm 20 mw φ3 mm Rb LID Xe Xe 400 nm 350 mw Rb Xe Xe ND 1.41 mw Rb
18 Xe
19 Rb SENSITIVITY AC GAIN 24dB,DR28 INPUT LIMIT 180mV pk SENSITIVITY 2mV TIME CONSTANT 50µV REF PHASE INPUT COUPLING AC INPUT SHELL FLOAT INPUT MODE VOLTAGE INPUT CONNECTOR A INPUT DEVICE FET LINE NOTCH FILTER OFF AUTO AC GAIN OFF TIME CONSTANT 50µs SLOPE 12 db/oct SYNC THE CONSTANT OFF TIME CONSTANT MODE FAST 3.1
20 20 4 LID 4.1 Rb X LID 20 s nm nm C Rb 200 C 10 C Rb LID #$% &* #$% && #$%'&)( +-,.0/214365! " '&"($!"%$&$ )+*,.- /1032!"#$
21 LID Rb LID Rb Rb Rb 100 C /s at 100 C /s at 29 C Rb /s10 8 Rb 1/1000 Rb Rb! #" $!&%('*) "!$# C Rb LID 200 C Rb LID
22 22 4 1/2000 1/ s at 100 C s at 31 C 1/3 190 C Rb Pt "!$#&%"('*),+!#"$&%
23 s at 100 C s at 27 C 2 1 1/2 210 C 220 C 2 3 ±1 Rb Rb "! # %$'&)( Rb k k = A exp ( E ) a k B T A E a k B T 4.8 (4.1)
24 ( k = A 1 exp E ) ( a1 + A 2 exp E ) a2 k B T k B T 0 ) ) y = A 1 exp ( xτ1 + A 2 exp ( xτ2 (4.2) (4.3) (4.2),(4.3) ( ) kb E a1 = E a2 = τ 1 ( kb τ 2 ) (4.4) 4.1 τ 1 τ 2 (4.3) (A 1 A 2 ) #! "" #! # % #! %'" #! $&% (&)+*-, (&)/ :<;>=@? ACB DFECG H6I6J+KLH6INM E&O/P1Q ASRTDVU1G I-WXJ+KLHYUZM E&O/P1Q! "" " "$!#" %#&('*) %(&,+.- / *687:9<; =?>A@:BDC EGF*H(IJE.FLK B#MANGO =AP?@LQGC F*RGH(IJESQ<K B#MANGO
25 &$ %% & $ & ( &$ ( % &$ ')( *,+)-/. *, :9;5=<?>A@CB DFE GIHFJKH1L8M,NPO3LRQ H,S1T3U D1VWGXL/JKHFYXM,NPO3LRQ H,S1T3U #$ %%! "! "$#&%(')"$#+*-,.0/21435/(687:9<; =QST@-F(CEAQU-H$IKJLFNM)A&OQP-R !#"#$&%'!#")(+*,.-0/213-&46587:9 ;=< >0?0@BADCFE#GIHKJ:L'A#M)N0O ;QPR>KJF@ H0H0E#GIH+STL'A#M)N0O 4.13 Rb τ 1 τ E 1a (ev) E 2a (ev) 0.830± ± ± ± ± ±
26 Rb LID 2 Rb ev ev : [3] Cs Cs evsi Cs ev Cs Rb ev Si Rb ev Rb 16, Si Rb 4.17 Rb
27 : Rb [4] (RbO 2 :20 SiO 2 :80 ) Rb 0.8eV1.0eV Rb ev Rb Rb Rb Rb Rb ( Rb ) 4.3 Rb LID X X-ray photoelectron spectroscopy: XPS Rb LID Rb [5] Rb Rb Rb Rb
28
29 X LID XPS XPS X AlK α ev 5 nm XPS O Si Rb C OSiRb 4.24 O 4.25 Si
30 Rb Rb LID Rb Rb Rb 2728 O Si 2930 O Si Rb Rb O Si Rb Rb Rb O 2 Rb Rb Si XPS /cm 2 ) DFEHG:IKJ "! # $&% '"(&% ')+*,'-/.0), :<;<=?>A@ B<C?DAE FHGJI<KML! " # "!" " "! "$ %'& (*)'& (,+.-/(,021+/35460! O 4.29 Si
31 :9 ACBED=FHG "! #$"! #%'&(#)+*,%(-/.0) 132 "!$# "!%& ')( * +)( *&,.-/* 0213,/46570$8: O 4.31 Si XPS XPS Rb! #"%$&!('*),+! #"%$&!('*), Rb 4.33 Rb Rb C O Si C SiO 2 Rb
32 Rb V Xe Rb SENSITIVITY 500 µvrb 2.5 Rb 200 Rb 68729;:=<?>A@ B,CD #$ "! %'& (*),+.-'/0-'12( Rb 10 9 /cm 3 Rb 7.6 V SENSITIVITY 2 mv)20 mv SENSITIVITY 500 µvrb (10 6 /cm 3 ) /s Rb φ=20 mm 30 mm /cm /cm 3 1 Rb Rb Rb
33 Rb LID Rb Rb 10 8 /s 1015 LID Rb ev ev Rb XPS Rb Rb O Rb LID Rb Rb
34 LID LID Rb Rb Rb LID LID Rb
35 35 A A.1 V AC100V DC+5V A.1 5V AC100V AC6V AC DC +5V C2,C3 C1,C4 LED
36 36 A A.2 +5V A.3 +5V (DS-4354ML) DC5V +4.89V A.4 5V
37 37 [1] Rb Rb,,, (2013) [2] (2008) [3] Nuria Lopez, Francesc Illas, and Gianfranco PacchioniAdsorption of Cu, Pd, and Cs Atoms on Regular and Defect Sites of the SiO 2 Surface (1999).J. Am. Chem. Soc.1999,121, [4] NAROTTAM P.BANSAL, R.H.DOREMUS Handbook of Glass Properties (ACADEMIC PRESS, INC 1986) [5] ( 1979) [6] -- ( 1991)
38 38
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( ) () x C x = T T c T T c 4D ) ) Fe Ni Fe Fe Ni (Fe Fe Fe Fe Fe 462 Fe76 Ni36 4E ) ) (Fe) 463 4F ) ) ( ) Fe HeNe 17 Fe Fe Fe HeNe 464 Ni Ni Ni HeNe 465 466 (2) Al PtO 2 (liq) 467 4G ) Al 468 Al ( 468
1 1 1 1-1 1 1-9 1-3 1-1 13-17 -3 6-4 6 3 3-1 35 3-37 3-3 38 4 4-1 39 4- Fe C TEM 41 4-3 C TEM 44 4-4 Fe TEM 46 4-5 5 4-6 5 5 51 6 5 1 1-1 1991 1,1 multiwall nanotube 1993 singlewall nanotube ( 1,) sp 7.4eV
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6 2 T γ T B (6.4) (6.1) [( d nm + 3 ] 2 nt B )a 3 + nt B da 3 = 0 (6.9) na 3 = T B V 3/2 = T B V γ 1 = const. or T B a 2 = const. (6.10) H 2 = 8π kc2
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吸収分光.PDF
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9 1. (Ti:Al 2 O 3 ) (DCM) (Cr:Al 2 O 3 ) (Cr:BeAl 2 O 4 ) 2. 2.1 Ĥ ψ n (r) ω n Schrödinger Ĥ ψ n (r) = ω n ψ n (r), (1) ω i ψ (r, t) = [Ĥ + Ĥint (t)] ψ (r, t), (2) Ĥ int (t) = eˆxe cos ωt ˆdE cos ωt, (3)
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LLG-R8.Nisus.pdf
d M d t = γ M H + α M d M d t M γ [ 1/ ( Oe sec) ] α γ γ = gµ B h g g µ B h / π γ g = γ = 1.76 10 [ 7 1/ ( Oe sec) ] α α = λ γ λ λ λ α γ α α H α = γ H ω ω H α α H K K H K / M 1 1 > 0 α 1 M > 0 γ α γ =
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µ µ LT1398/LT1399 V IN A R G 00Ω CHANNEL A SELECT EN A R F 3Ω B C 97.6Ω CABLE V IN B R G 00Ω EN B R F 3Ω 97.6Ω V OUT OUTPUT (00mV/DIV) EN C V IN C 97.6Ω R G 00Ω R F 3Ω 1399 TA01 R F = R G = 30Ω f = 30MHz
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1906 R n m 1 = =1 1 R R= 8h ICP s p s HeNeArXe 1 ns 1 1 1 1 1 17 NaCl 1.3 nm 10nm 3s CuAuAg NaCl CaF - - HeNeAr 1.7(b) 2 2 2d = a + a = 2a d = 2a 2 1 1 N = 8 + 6 = 4 8 2 4 4 2a 3 4 π N πr 3 3 4 ρ = = =
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