(2- ) 2003 5
1. PVC PVC DEHP DEHP 2. 2.1 PVC PVC PVC 1930 1941 PVC 1943 37,000 1944 116 200500 PVC 1950 1,493 2000 268 2,596 PVC 2000 1,472 16% PVC 1948 190 2000 36 470 8% 80% DEHP 60% 50% DEHP PVC % 2.2 (2- :1-272 CAS 117-81-7 C 24 H 3 4-1 -
O CH 2 CH 3 C O CH 2 CH (CH 2 ) 3 CH 3 C O CH 2 CH (CH 2 ) 3 CH 3 O CH 2 CH 3 2.3 DEHP -50 385 0.00061.3g/L 2.4 DEHP 3 DEHP 2002 12 2003 3 3.1 3.1.1 DEHP 10,000mg DEHP LD 50 26,30033,900mg/kg DEHP DEHP Poon et al.(1997) 13 NOAEL 50ppm(3.7mg/kg/ ) Lamb et al.(1987) 106 NOAEL 0.1%14mg/kg/ in vitro IARC 2002 2 DEHP 2B 3 DEHP in vitro - 2 -
DEHP F1 AGD 3.1.2 DEHP DEHP (1997) (LC )74.8 mg/l Defoe et al.(1990) 90 NOEC > 0.502 mg/l NOEC Knowles et al.(1987)noec 0.158 mg/l NOEC Woin and Larsson(1987) 780 mg/kgdwt NOEC NOEC Larsson and Thuren(1987) 25mg/kgdry NOEC DEHP DEHP DEHP NOEC 3.2 DEHP 3.2-1 3.2-1 NTP EU EHC 3.2.1 NTP EU 1) Poon et al.(1997) 2) Lamb et al.(1987)) NTP EU 3) EU Moore (1996) Arcadi (1998) 3.2.2-3 -
1) Adams et al.(1995) Knowles et al.(1987) Defoe et al.(1990) (> 0.1 mg/l ) Adams et al.(1995) 2) Adams et al.(1995) (1997) Rhodes et al.(1995)passino and Smith(1987) Birge et al.(1979) Rhodes et al.(1995) (0.077 mg/l) PNEC 100 0.77g/L 3) EU NOEC PNEC Thompson et al.(1995)brown et al.1996 Solyom et al. (2001) Woin and Laesson (1987) Norrgren et al.(1999) Hüls Infracor (1999) Diefenbach (1998) Wood and Bitman (1980) Poon et al.(1997) 4) Springborn Bionomics (1984) (8 g/l) 5) EHC 4. 1997 DEHP DEHP DEHP 2002 8 2003 3 30 4.1DEHP 80% DEHP 60% 50% 4.1-1 1996 DEHP 31 2001 24 1996 68 2001 61% DEHP 23 4.1-1 - 4 -
4.1-1 4.1-1 2002 7 2 4.2 DEHP 13 6 4 19 5 4.2-1 20 2 1 5 2001 4.2-2 2 24 55% 81% DEHP ( ) 97% PVC96 3% DEHP 4.2-2 4.2-2 11.5% - 5 -
3% 2000 PVC 3 268 16% 4.2-1 PVC PVC PVC PVC 50% DEHP PVC 1996 2001 PVC PVC 1996 2001 PVC 43% 68% 4.2-3 DEHP 2001 DEHP 4.2-1 - 6 -
4.2-1 2001 DEHP - 7 -
- 8 -
2001 2001 DEHP DEHP 100-9 -
4.2-2 DEHP 1996 1997 1998 1999 2000 2001 4.2-2 DEHP 2002 7 2-10 -
4.2-3 PVC 2002 7 2 4.3 DEHP PVC 51%1999 PVC 31%(1991 ) PVC PVC 5. DEHP SPEED'98 (1998 5 2000 11 ) 65 1999 11 40 DEHP 4.2510 ng/m 3 1,100 ng/m 3 3,400 ng/m 3 0.21 g/l 42 0.050.5g/L 4.1g/L 0.051 g/l 9.2-11 -
0.051 g/l 36 25 g/kg 210 mg/kg 1999 22mg/kg(2000 )4mg/kg2001 4.3mg/kg(2002 ) 100 g/kg 5,200 25 g/kg 6,600 10 g/kg 1,100 0.25 g/l 0.5 g/l 68 g/l 2 0.2 0.5 g/l 0.5 7.7 g/l 11.9 25 g/kg 410 g/kg 25 g/kg 350 g/kg 25 g/kg 180 0.1 g/kg 180210 g/kg 0.3640g/kg 363 mg/kg 6. PRTR 2001 13 DEHP 46 651 5,400 1,180 6,580 82% 76%5,010 (6-1) 392 10 65% 65% 9 99% 60% 2846 12 DEHP - 12 -
6-1DEHP 7. DEHP PVC 1) PVC DEHP DEHP DEHP PVC 2000 6 14 2) DEHPDINP Mouthing 2002 8 2 2003 8 1 3) PVC DEHP DEHP DEHP 2002 10 17 DEHP PVC 8. 8.1 DEHP 8.1-1 DEHP - 13 -
DEHP 8.2 PRTR DEHP EU DEHP EU2001 DEHP 1976 8.2-1 8.2-1 4.2 DEHP 8.2-1 2001 ( /) / DEHP 0.004 0.02 0.8 PVC 180 0.001 1,000 PVC - - - - - - 20-170 ( 76-01 900 460,000 PVC 8 ) - 3.3-3.7 19-2 - - - 14 -
( DEHP 8.1-1 DEHP - 15 -
9. 9.1DEHP Simplified models DEHP 8.2 DEHP 2002 2006 2001 1970 2006 DEHP DEHP DEHP DEHP DEHP 9.1-1 9.1-1 DEHP DEHP DEHP DEHP DEHP DEHP DEHP DEHP DEHP DEHP DEHP 9.2DEHP 9.1 DEHP DEHP PRTR DEHP DEHP DEHP ADMER - 16 -
DEHP DEHP DEHP DEHP DEHP DEHP DEHP DEHP ADMER DEHP 10. DEHP 10.1 DEHP 194 10.1-1 DEHP 10.1-1 DEHP DEHP 91 46.9 47 24.2 31 16.0 12 6.2 10 5.3 3 1.5 10.2 101 10.2-1 (*1) (*2) DEHP 2 6 70% 10.2-1 % 35 35 *2 25 25 11 11 11 11 9 9 ISO14000 8 8 DEHP 3 3 (*1) DEHP - 17 -
(*2) 10.3 DEHP DEHP 133 10.3-1 10.3-2 DEHP 90 67.7% DINP 38 DIDP 2-43 32.3% 10.3-1 DEHP % 42 46.7 DINP38DIDP4 9 10.0 DOA3DINA2 2-8 8.9 5 4.4 7 7.8 2 3 3.3 16 17.8 10.3-2 % 10 23.2 16.3 5 11.7 5 11.7 4 9.3 12 27.9 10 2 10.4 82 59 72% 66 DEHP UP 44 DEHP 32 68.2% 12 31.8% 10.3-1 10.3-2 10.5 59 18 30.5% 15 25.4% 8 7 6 DEHP 5 23 DEHP DEHP 13 59% DEHP 5 22.7% 2 DEHP 2 10.6 DEHP DEHPPVC - 18 -
DEHP 11. 1998 10 5 SPEED'98 65 2000 67 2 1213 20 11.1 11.1.1 1998 7 SPEED 98 67 (2000 65 ) 11.1.2 DEHP 11.1.2-1 11.1.3 2002 14 DEHP 11.2 11.2.1 2001 13 20 1012 11 11.2.2 13 1013 11.2.2-1 11.2.3 (1) 40 1995 5-19 -
(2) - 20 -
11.1.2-1 2 1034 1517 020 05 2348 1919 ND17 ND7.8 ND ND ND4.9 7.240 934 1717 4160 6969 010 010 010 010 524 2949 4747 ND0.15 ND ND130 51.8592 ND0.5 ND1.9 5.331 534 1617 5960 135135 010 010 010 010 524 1621 2121 ND0.8 ND4.4 7.6300 152370 ND0.4 ND1.2 5.622 934 1617 4660 134135 614 88 88 ND5 ND5 1.829 ND1350 ND0.4 tr0.9 6.315-21 -
11.2.2-1 13 N.D. N.D. N.D. N.D. N.D. 3200 N.D. 130 19 N.D. N.D. N.D. N.D. N.D. N.D. 8300 N.D. 330 37 N.D. N.D. N.D. N.D. N.D. N.D. 7200 N.D. 230 93 N.D. N.D. N.D. N.D. N.D. N.D. 850 N.D. 55 N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1700 N.D. 220 N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1700 N.D. 49 N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1200 N.D. 48 N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1500 N.D. 51 N.D. N.D. N.D. N.D. N.D. N.D. N.D. 820 N.D. 52 N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1500 N.D. 41 N.D. N.D. 0.3 0.02 0.2 0.01 0.01 25 10 25 10 10-22 -
12. DEHP DEHP DEHP DEHP 1) DEHP DEHP PVC DEHP 2) PRTR DEHP DEHP DEHP 3) DEHP 4) - 23 -