THE CHEMICAL TIMES

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1 KANTO CHEMICAL CO., INC. çc

2 Decomposition of Chemical Compounds by Ultrasound and Development of Sonochemical Reactor KEIJI YASUDA (Associate Professor) Graduate School of Engineering, Nagoya University 20 khz khz1 MHz 1 m/s 1 2 OHH CO 2H 2O OH 2

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7 1:, pp.303, (1999) 2Adewuyi, Y. G.: Ind. Eng. Chem. Res., 40, 4681 (2001) 3Vajnhandl, S. et al.: Dyes Pigm., 65, 89 (2005) 4Mostafa, M. A. K. et al.: J. Polym. Sci., 33, 311 (1958) 5Basedow, A. M. et al.:ultrasonic Degradation of Polymers in Solution, Advances in Polymer Science, vol.22, p.83, Springer-Verlag (1977) 6:, 41, 739 (1984) 7Sivalingam, G. et al.: AIChE J., 50, 2258 (2004) 8Koda, S. et al.: Polymer, 35, 30 (1994) 9Okuyama, M. et al.: J. Appl. Poly. Sci., 7, 591 (1963) 10: 13, p.142 (2004) 11Sherba, G. et al.: Appl. Environ. Microbio., 57, 2079 (1991) 12Piyasena, P. et al.: Inter. J. Food Microbio., 87, 207 (2003) 13Oyame, I. et al.: Environ. Sci. Technol., 39, 7294 (2005) 14:p.844, (1974) 15Mason, T. J. et al.: Ultrasonics Sonochemistry, 3, S253 (1996) 16:, 15, 44(2003) 17:, 43, 259 (2002) 18:, 14, 124(2002) 19Koda, S. et al. : Ultrason. Sonochem., 10 (3), (2003) 20:, 27, 449 (2001) 21Asakura, Y. et al.: J. Chem. Eng. Jpn, 38, 1008 (2005) 22Asakura, Y. et al.: Chem. Eng. J., 135, 339 (2008) 23Feng, R. et al. : Ultrason. Sonochem., 9, 231 (2002) 24Yasuda, K. et al. : Ultrason. Sonochem., 14, 699 (2007) 25Mitome, H. et al. : Ultrasonics, 40, 683 (2002) 26Asakura, Y. et al. : Ultrason. Sonochem., 15, 244 (2008) 27Yasuda, K. et al. : J. Chem. Eng. Jpn, 32, (1999) 28Adewuyi, Y. G.: Environ. Sci. Tech., 39, 3409 (2005) 29Adewuyi, Y. G.: Environ. Sci. Tech., 39, 8557 (2005) 30Gogate, P. R. et al.: AIChE J., 50, 1051 (2004) 31Gogate, P. R. et al.: Advance Environ. Res., 8, 553 (2004) 32Hart, E. J. and A. Henglein : J. Phys. Chem., 90, 3061 (1986) 33Weavers, L. K. and M. R. Hoffmann : Environ. Sci. Technol., 32, 2727 (1998) 34Ince, N. H. and G. Tezcanli : Dyes Pigm., 49, 145 (2001) 35Shirgaonkar, I. Z. and A. B. Pandit : Ultrason. Sonochem., 5, 53 (1998) 36Naffrechoux, E. et al. : Ultrason. Sonochem., 7, 255 (2000) 37Rong, L. et al. : J. Chem. Eng. Japan, 36, 1045 (2003) 7

8 Novel fast photochromic molecules based on hexaarylbisimidazoles JIRO ABE (Associate Professor) ATSUSHI KIMOTO (Assistant Professor) School of Science and Engineering, Aoyama Gakuin University 1-8 9, ,5-12 PPG Industries Essilor InternationalTransitions OpticalTransitions

9 HABI HABI CN TPIR TPIRHABI P T TPIR HABI ESR HABI X 15,16 HABI K TPIR TPIR HABI11,8-bisTPI-naphthalene 18 1 X HABI CN1.494 Å HABITPIR 18TPIR HABITPIR 11R1,8-bisTPIRnaphthalene 253 K1R HABI 730 H S 44.5 kjmol JK -1 mol

10 18 2TPIR 20 HABI 21 HABI21-NDPI-8-TPI-naphthalene 400 nm1000 nm 530 nm 355 nm 2R1-NDPIR-8-TPIRnaphthalene1R R2R 2R H S 50.6 kjmol JK -1 mol -1 1R S 66 G = H T S 1R G 73.2 kjmol -1 2R69.6 kjmol -1 1R H G 2R HABI 2 UV-LED365 nm T HABI 10

11 HABITPIR [2.2] HABI 3 pseudogem-bisdpi[2.2]pc 25 X HABIC N1.488 Å3 500 nm1000 nm HABI3Rpseudogem-bisDPIR 2.2PC K 33 Eyring3R H S 59.8 kjmol JK -1 mol -1 HABI TPIR 2.2TPIR 3 1 PMMA 5 nsec4 mj/pulse1 3 HABI HABI HABI pseudogem-bisdpi2.2pc 11

12 HABI HABI HABI DyluxHABI HABI HABI HABI 1T. Kawai, Y. Nakashima, M. Irie, Adv. Mater., 17, 309 (2005). 2M. Irie, T. Fukaminato, T. Sasaki, N. Tamai, T. Kawai, Nature (London), 420, 759 (2002). 3K. Matsuda, M. Irie, J. Am. Chem. Soc., 122, 7195 (2000). 4Y. Yu, M. Nakano, T. Ikeda, Nature (London), 425, 145 (2003). 5M. Yamada, M. Kondo, J. Mamiya, Y. Yu, M. Kinoshita, C. Barrett, T. Ikeda, Angew. Chem. Int. Ed., 47, 4986 (2008). 6S. Kobatake, S. Takami, H. Muto, T. Ishikawa, M. Irie, Nature (London), 446, 778 (2007). 7B. L. Feringa, Molecular Switches; Wiley-VCH: Weinheim, Germany, (2001). 8A. Fernandez-Acebes, J.-M. Lehn, Adv. Mater., 10, 1519 (1998). 9J. C. Crano, R. J. Guglielmetti, Organic Photochromic and Thermochromic Compounds; Plenum Press: New York, (1999). 10H. Duerr, H. Bouas-Laurent, Photochromism: Molecules and Systems; Elsevier: Amsterdam, (2003). 11M. Tomasulo, S. Sortino, F. M. Raymo, Org. Lett., 7, 1109 (2005). 12S. Kawai, T. Nakashima, K. Atsumi, T. Sakai, M. Harigai, Y. Imamoto, H. Kamikubo, M. Kataoka, T. Kawai, Chem. Mater., 19, 3479 (2007). 13S. Jockusch, N. J. Turro, F. R. Blackburn, J. Phys. Chem. A, 106, 9236 (2002). 14T. Hayashi, K. Maeda, Bull. Chem. Soc. Jpn., 33, 565 (1960). 15M. Kawano, T. Sano, J. Abe, Y. Ohashi, J. Am. Chem. Soc., 121, 8106 (1999). 16J. Abe, T. Sano, M. Kawano, Y. Ohashi, M. M. Matsushita, T. Iyoda, Angew. Chem. Int. Ed., 40, 580 (2001). 17Y. Satoh, Y. Ishibashi, S. Ito, Y. Nagasawa, H. Miyasaka, H. Chosrowjan, S. Taniguchi, N. Mataga, D. Kato, A. Kikuchi, J. Abe, Chem. Phys. Lett., 448, 228 (2007). 18F. Iwahori, S. Hatano, J. Abe, J. Phys. Org. Chem., 20, 857 (2007). 19S. Hatano, J. Abe, J. Phys. Chem. A, 112, 6098 (2008). 20K. Fujita, S. Hatano, D. Kato, J. Abe, Org. Lett., 10, 3105 (2008). 21A. Kimoto, S. Niitsu, F. Iwahori, J. Abe, New J. Chem., in press. 22Supporting information of Ref Nature (London), 454, 4 (2008). 24C&EN, 86, 24 (2008). 25Y. Kishimoto, J. Abe, J. Am. Chem. Soc., in press. 12

13 Recent Technologies about Gold Plating Ryota Iwai Kazutaka Senda Central Research Laboratory, Kanto Chemical Co., Inc. 1, m 3, nm 13

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17 28, m 510m , Surtech2008 Surtech 1M.Kato: The Chemical Times,189,10(2003) 2K.Senda, M.Kato: The Chemical Times,205,7(2007) 3: 46(9), 815 (1995) 4:, 58(2), 92 (2007) 5,,, : 1181A-24, 24 (2008) 6,,, 48(4), 393 (1997) 7Y.Okinaka: Plating, 57, 914 (1970) 8R.Sard, Y.Okinaka, J.R.Rushton: Plating, 58, 893 (1971) 9,,, :, 42(7), 729 (1991) 10,,,,,,, :, 49(12), 1298 (1998) 11:, 32(10), 500 (1981) 12Y.Okinaka, M.Hoshino: Gold Bulletin, 31(1), 3 (1998) 13T.Osaka, M.Kato, J.Sato, K.Yoshizawa, T.Homma, Y.Okinaka, O.Yoshioka: Journal of The Electrochemical Society, 148 (10), C659 (2001) 14T.Osaka, T.Yokoshima: Corrosion Engineering, Science and Technology, 39(1), 121 (2004) 15:, 32(12), 649 (1981) 16, : 40(3)361 (1989) 17 (1982) 18N.Togasaki, Y.Okinaka, T.Homma and T.Osaka: Electrochim. Acta, 51, 884, (2005) 19M.Kato, K.Senda, Y.Musha, J.Sasano, Y.Okinaka, T.Osaka: Electrochim. Acta,53, 11 (2007) 21 17

18 New Series of My Paleontological Notes(5) Evolutional and Paleoecology of Extinct Giant Ground Sloth M.Dr. YOSHIO FUKUDA Edentates 5 2 V2b 20 18

19 19 Xenarthra X X X

20

21 / M.Kato, K.Senda, Y.Musha, J.Sasano, Y.Okinaka, T.Osaka: Extended Abstract of EPTM2005 International Symposium on Electrochemical Processing of Tailored Materials, 190 (2005) 21,,,,,, : 116,19B-9, 101 (2007) C-23 ( ) 23:, 23(12), 34 (2007) 24:, 16(2), 46 (2000) 25, :, 16(2), 32 (2000) 26:, 23(12), 58 (2007) 27,,,,,,,, : 18, 1B1-4, 51 (2008) 28, 23(12), 48 (2007) 29,,,,,, : 21, 14C-06, 69(2007) 21

22 Scientists and Engineers in German Stamps (25). Wilhelm Conrad Rontgen KAORU HARADA Professor Emeritus,University of Tsukuba. Wilhelm Conrad Rontgen, J. J. Joseph John Thomson, W. C. X1895 XW. C. Remscheid-Lennep A. August A. E. E. Kundt,

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