閨75, 縺5 [ ｨ ﾁ573, 縺 ｨ ｨ

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1 39ｨ , 7 86 ﾀ 縺48 縺 ﾀ5 縺473 ﾀ ｨ , ｨ , , 89573, ﾀ ｨ , ｨ PACS numbers: 34.8.Lx, q (73) (73) ｨ ﾀ ｨ (739). 3.. 縺 ｨ ｨ ﾁ ﾁ ｨ ｨ ﾀ ｨ ﾀ ｨ ﾀ ｨ ﾀ ｨ (749) ｨ ｨ 59 ｨ ｨ ﾀ ｨ ﾀ ｨ (757). 5.. ﾀ ｨ ｨ ﾀ ｨ 縺 ｨ ﾀ ｨ ﾁ , , , 閨 [email protected] , , /9, [email protected] ｨ (764) (764) ﾀ ｨ , 89573, ｨ ｨ ｨ ｨ 縺 ｨ ｨ , ｨ ｨ 9 ｨ ﾀ ｨ ｨ ﾁ ﾀ ｨ ﾁ ﾁ ﾀ ｨ ｨ 縺 ｨ ｨ ﾀ5854ｨ 59 ｨ 5ｨ 99 ｨ , ｨ 3ｨ ｨ , ｨ , ｨ ｨ ｨ ｨ , ｨ ｨ ｨ , ｨ , , , , 89575, , # ,

2 閨75, 縺5 [ ｨ ﾁ573, 縺 ｨ ｨ ｨ ﾀ5ｨ ｨ ｨ ｨ ｨ ｨ ｨ , ｨ 9 98 ｨ ｨ ﾀ ｨ [ 5 3] [4 5 ] ｨ ｨ [9, ], [9] , ｨ [9]. 縺 ｨ , ｨ ｨ V e R V e ﾀ ｨ ｨ ｨ ｨ ｨ ﾁ , 345 R , , 67595ｨ , [,, ]. 縺 縺 , ｨ ｨ ｨ ｨ 94574ｨ ﾁ499 ｨ C ｭr; R6 9 ｷ3 c ｭr; R6 9F ｭR6 9 ; ｭ: r ｨ , R , c ｭr; R6 9 ｨ ﾁ499, 5957ｨ R ｨ , F ｭR ﾁ ｨ , ｨ 45739ｨ e ｭR6 9 ｨ e ｭR6 9 ｷ3 E ｭR6 9 6ｦ ig ｭR6 9 ; ｭ: ｨ ｨ E ｭR G ｭR , 縺 ｨ ｨ ｨ e 6ｦ A! ｭA ｭ:36 9 V R R ｨ , ｨ ｨ ｨ ﾁ499 ｨ ｨ ｨ e ｨ 59754, A , ｭA , ｨ 5ｨ 95779ｨ , 67595ｨ ｭA 7 6 9, 縺 : t e 5 h G ; t e 5 o : ｭ: t e ｨ 59754, ho ｨ , 578ｨ ｭA , , ho ｨ 縺935993, hg 9 =o ｨ G ho, e

3 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 ﾁ , ｨ 59754, , , 67595ｨ ﾀ ｨ ｨ : e 6ｦ A! ｭA 7 6 9! e 6ｦ A : ｭ: ﾀ755887, 67595ｨ ｨ ﾀ ｨ ｨ ｨ ｨ e 6ｦ AB! ｭAB 7 6 9! e 6ｦ AB e 6ｦ AB ｭv6 9! ｭAB 7 6 9! e 6ｦ AB ｭv 6 9 e 6ｦ AB! ｭAB 7 6 9! A 7 6ｦ B A 7 6ｦ B! ｭAB 7 6 9! e 6ｦ AB e 6ｦ AB! ｭAB ; ｭAB ｦ C! AB 7 6ｦ C 5 ｨ ｨ ﾁ ﾁ ｨ , 9 ｨ ｨ ｨ ｨ e 6ｦ AB ｭv ｷ3 6 9! ｭAB 7 6 9! e 6ｦ AB ｭv6 9 ; ｭ: v ｨ , ｨ , (.3) ｨ , ｨ N ｨ ｨ ｨ , ｨ ｨ ｨ ﾁ ﾁ ｨ 45739ｨ ｨ ｨ ﾁ ﾁ ｨ ﾀ75588, ｨ ｨ , e 6ｦ XY! ｭXY 7 6 9! X 6ｦ Y 7 : ｭ: ｨ ｨ ﾀ ｨ ｭXY ｨ R, , R c ｨ ﾀ R > R c t R c 7 R v a c ; ｭ: R c 7 R A v a (49 ｨ ﾁ ) , 縺935993, 395 ｨ , (9. ) A 7 6ｦ B! ｭAB ; ｭAB ｦ C! AB 7 6ｦ C : ｭ: ｨ AB ｭAB 7 6 9, C. ﾀ5ｨ , , 578ｨ [] N, O 7 4 CO 7 3 CO 7 4 NO 7 CO O 7 H O O 7 ｭH O6 9 NO 7 H O Cl 7 H O Br 7 3 * T ｷ3 K.,3,3* 3 8 *,4 3* O He CO He He CO O He Ar O O NO NO Br 6 7,4,, 3,6,5,,5,,,7

4 閨75, 縺5 [ , ｨ , ｨ 5ｨ ﾀ ｨ e 6ｦ SF 6! ｭSF ! e 6ｦ SF 6 : ｭ: ｨ ｨ SF ; ; ｨ ｨ [ 5 ]. 縺 ｭSF ｨ ｨ , K , 589 ｨ , 67574ｨ 59, ｨ 5, , ｨ 縺935993, ｨ ｨ [] , ｨ ｨ ｨ ｨ , ｨ 8949ｨ ｨ ｨ ｨ , 578ｨ ｨ 縺 R m 54 ﾁ9-379ｨ 9457, ｨ 8 89 ｨ 59754, 9 R 7 54 ﾁ9379ｨ 9457, ｨ 5ｨ ｨ ｨ EA. 縺359445, 54 ﾁ R m ﾁ , ｨ ｨ e ｨ , ｨ EA 6ｦ e ｨ ｨ 45739ｨ 3557, ﾁ R m 45 R ｨ 95579ｨ RRKM ﾁ5735 [35] , ｨ ｨ ｨ 45739ｨ, t EA ｭR6 9> n ｭR6 9 dr t ｷ3 t ; n ｭR6 9 dr 6 7EA ｭR6 9< 345 n ｭR , t ﾁ 縺359445, 395 ｨ , 9.5. t ﾀ5858 t=t 8 7 9, ｨ ｨ 5ｨ 554: n ｭR m 6 9 t ｷ3 t n ｭR : 縺 , ﾁ ｨ ｨ , 59579, 85ｨ , ｨ , ｨ [36], o ｨ , ｨ p ｷ3 E= ｭho6 9, 345 E 6549 ｨ ﾀ n ｷ3 ｭp 6ｦ s 7 6 9! p! ｭs 7 6 9! ; t ( 75 8) , ｨ ｨ (N ｨ ) 355 N t 355 N t SF 4 SF 6 CH 3CO C 4F 6 c-c 4 F 6 C 6F 6 C 4F 8 c-c 4 F 8 C 6F 5Cl C 6F 5Br C 5F 8 c-c 5 F 8 C 6H 5CN C 6F 5CN C 6F 5CHO C 6H 5NO ,7 [3];,6 [4],5 [4, 5]; 6,8 [4];, [6], [4] 6,9 [7];,6 [8], [8], [7];,3 [9], [7]; 3, [8],5 [8, 3],8 [3], [3] 5 [7],7 [8],5 [3],7 [3] 3,6 [3] 4 [5]; 4,7 []; 4,9 [8];,8 [3] C 6D 5NO m-c 6 H 4 ClNO C 6H 3F NO C 7F 8 C 6F C 5F n-c 5 F C 6H 4CH 3NO C 6F n-c 6 F C F 8 C H 8 C D 8 C H 6O C 6H 3(CH 3) NO C 7F , [3] 4,7 [3] 4,7 [9], [7]; 3,8 [9] [7],3 [8] 3,4 [8] 3, [9] 4 [7] 4 [8] [3],8 [3];,7 [33],8 [3] 35 [34], [9] 79 [6]

5 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 s T ﾁ5735 ﾀ4 s p ｷ3 exp ho T 7 : p i p f , ｨ p i ho 6ｦ EA 6ｦ e ｷ3 p f ho : , ｨ ｨ e 9 EA ｨ 59754, 9.5. ｨ ｨ 縺98ｨ ｨ 95, p i 4 s; p f 4 s, , ｨ p i ho ｷ3 st, 9 ln t t 7 ｷ3 EA 6ｦ st sho ; p f ｷ3 s ln t 7 6ｦ p i : t , C 7 F EA ｷ3 ;7 ;3 ｨ 5 [37] t ｷ3 38 ( ) ho C 6 F EA ｷ3 ;4 ;3 ｨ 5 [37] t ｷ3 38 ( ), ho ｨ T ｷ3 3 K ｨ ｨ ｨ ｨ e ｷ ﾁ ﾁ t ｷ3 C exp T ho : ﾀ C 7 F 8 9 C 6 F ho 5 T , ｨ , K ｨ C 7 F C 6 F, ﾁ 縺935993, ｨ 縺 , 45 ｨ ｨ 45739ｨ 8989 ｨ ｨ , ｨ , , , , [38] K ｭ55p6 9 6ｦ CF 3 Cl! K 6ｦ 6ｦ CF 3 6ｦ Cl 7 ; K ｭ55p6 9 6ｦ CF Cl! K 6ｦ 6ｦ CF Cl 6ｦ Cl 7 : 534 ｨ , , Cl , Cl , , ﾀ CCl [39] ｨ ｨ , CCl CF 3 I [4] , ｨ ｨ ﾀ ｨ ｨ ( ). 縺 ｨ ﾀ ｨ ﾁ s cap ｭR6 9 ｷ3 ph m e e G ｭR6 9 e 7 E ｭR6 9 6ｦ G ｭR6 9=4 : ｭ: R ﾁ9379ｨ 9457, e ｨ ｨ , E ｨ ｨ , G 縺98ｨ ｨ ｨ ｨ k cap ｷ3 hvs cap i ｷ3 p p h G ｭR6 9 ｭ m 3= e Te 3= exp 7 e T de e G ｭR6 9 7 E ｭR6 9 6ｦ 4 7 ; ｭ: ｨ ﾁ , ｨ 縺359445, ｨ ｨ 9 83ｨ, 534 ｨ ｨ ｨ , ｨ E 5 T ｨ

6 閨75, 縺5 [ k cap ｷ3 p p h me 3= Te 3= ｭ G e 6ｦ G =4 exp 7 e de : T = p k cap ｷ3 h G ｭR6 9 ; G 5 T ; ｭ:3a6 9 m e T e k cap ｷ3 4 p p h ; G 4 T : ｭ:3b6 9 me 3= Te = 9573 (.3) ｨ ｨ ﾀ , , ｨ 9 ﾁ k cap ｷ ｨ , ｨ 縺935993, ｨ ｨ ｨ ﾀ ｨ ﾀ79 37 ｨ ｨ s ｨ ｨ ﾁ ﾁ ﾁ , ｨ s- ﾁ ｨ 59754: s cap ｷ3 ph m e e sin d c ; 345 d c ﾁ8 s , ｨ , ｨ ｨ s cap 4 ph m e e ｨ k cap 4 4 p p h ; me 3= Te = ｨ ﾁ5735 (.3), , ﾁ573 (.3) ｨ , 589 ｨ ｨ ｨ ｨ 95 ﾁ5735, ｨ , 99ｨ ｨ ﾀ A 6ｦ B! A 6ｦ 6ｦ B 7 : ｭ: A ( ) , (.4) ｨ ｨ B (.4) (.5) ｨ A. ﾀ x ｷ3 ade hv 4 ; ｭ: DE ｨ ｨ 59754, a ｨ , ｨ 989, v DE ｷ3 Ry=n 3, 345 n , Ry=3,6 ｨ , a n a ( l 5 n, 345 l ｨ 59754) , 679 v 4 e hn ｭ: ｨ ｨ , , , (.4) n , (.6), n (.4) ｨ B, 65ｨ ｨ ｨ ｨ 59754, [4 5 47] (.4) , 975 ｨ SF 6 9 CCl ｨ ｨ k chem ｭSF ｷ3 ｭ4; ; , k chem ｭCCl ｷ3 ｭ ﾀ (.5) 9 (.4) 78475, ｨ ｨ ( ) (.) A 6ｦ SF 6! A 6ｦ 6ｦ SF A 6ｦ CCl 4! A 6ｦ 6ｦ CCl ( l ｨ 59754) 3953 A * Xe( f) Rb(s) Rb(d) K(d) Na(p) K(d) K(p) Ne(s) k chem (SF 6) k chem (CCl 4) 687 4,,3 3,5,5 [4] 4,3,7 [4] 4,,4 [4] 4,,6 4,,5 [43] 4,4,4 [44] 4,5,5 7 [45] 4,,5 [46] 4 5 [47]

7 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 , ｨ t ｷ ﾁ (.) ｨ 59 94: C ｭR; t6 9 ｷ3 X f j F j ｭR6 9 exp 7 ie jt ; ｭ:76 9 h j 345 F j ｭR ﾁ499, ｨ - 59 j ｨ 9457, E j ｨ ｨ , R , f j ｨ j ｨ ﾁ [] f j ｷ3 p h m e e S j G= e 7 E j 6ｦ ig= : ｭ: e ｨ ｨ 59754, m e 388 ｨ 59754, E ｷ3, G , S j ﾁ ﾁ H ﾁ , , pjf j j ｨ ﾁ499, ｨ ﾁ573 (.8) f ｷ h G= p m e e e 7 E 6ｦ ig= ; ｭ: E ｨ ｨ ( ｨ ). 縺98ｨ ｨ s cap ｷ3 p G k ｭe 7 E6 9 6ｦ G =4 ; ｭ:6 9 p 345 k ｷ m e e=h ｨ (.5) ｨ : G ｷ3 G e 6ｦ G neg, 345 G e ｨ ｨ ｨ , G neg ｨ ｨ ｨ s at ｷ3 p G neg k ｭe 7 E6 9 6ｦ G =4 : ｭ: (.9), ｨ ｨ 545ｨ ﾁ49ｨ 53949ｨ , , ｨ , 9. 68, ｨ (.) , (.9) ﾁ573-5 (.) ｨ k at k chem k at k chem ｷ3 G neg G : ｭ:6 9 縺935993, ｨ ｨ , ｨ , ｨ ｨ 59754, ｨ ｨ ｨ ｨ ｨ ｨ ｨ , , n ｷ (.5) (.6) ｨ , 679 ｨ n ｨ SF 6 9 CCl , 縺 , ｨ SF ｨ ｨ e < 3ｨ 5, n ｨ ｨ ﾁ ﾁ n, ｨ ﾀ5854ｨ ｨ ｨ ｨ , 縺 ｨ ｨ ｨ ｨ ｨ ﾁ ﾁ59954, ﾀ5 ｨ ｨ ｨ ｨ ｨ

8 閨75, 縺5 [ , ｨ ｨ ｨ 5, , ｨ ﾁ ﾁ ｨ ｨ ﾀ5 ｨ ｨ ｨ ｨ 45739ｨ ｨ ｨ ｨ ﾁ ﾁ CO -8575, ｨ ｨ ｨ ｨ ﾁ ｨ [48] ｨ (.4), ｨ ﾀ5854ｨ ｨ ﾁ ﾁ ( , [49]), , ｨ h=g =o, 345 ho ｨ , 5957ｨ ｨ ﾁ49ｨ ｨ ｨ ﾁ49ｨ ﾁ5735 (.7) ﾁ ｨ 59754, ｨ s cap ｷ3 4p X F j ｭR6 9jC ｭR; t6 9 X ｷ3 4p jf j j ; ｭ:36 9 j j 345 F j ｭR ﾁ , R 縺 j k ｭR ｨ 545ｨ ﾁ49ｨ 3557, ﾁ C mol ｭR; t6 9 ｷ3 X f j S jk j k ｭR6 9 exp j;k 7 ie kt h ; ｭ: S jk ｷ3 hf j ｭR6 9jj k ｭR6 9i. 縺98ｨ k , t , s k ｭt6 9 ｷ3 4pjhj k ｭR6 9jC mol ｭR; t6 9ij ｷ3 ｷ3 4p X f j f j S jks j k j k ｭR6 9 exp 7 i ｭE j 7 E j 6 9t : h j; j ｭ: ﾁ573 (.5) t 45 t 6ｦ dt 745 G dt h exp 7 Gt h : 縺935993, G ﾁ ｨ 95 ﾁ5735 (.5), ｭ s k ｷ3 s k ｭt6 9 G dt h exp 7 Gt ｷ3 4p X f j f j h S jksj k j; j G G 6ｦ i ｭE j 7 E j 6 9 : ｭ: ﾁ (.8) ﾁ ｨ ｨ , 589 ｨ [48], s k ｷ3 ph X GS js jk m e e e 7 E j; j j 6ｦ ig= G G 6ｦ i ｭE j 7 E j 6 9 : GS j S j k e 7 E j 7 ig= ｭ: ｨ 9 ﾁ ﾁ57549ｨ ｨ ｨ 95 ﾁ , X S mj S jk ｷ3 X jm ｭR6 9jF j ｭR6 9 F j ｭR6 9jj k ｭR6 9 ｷ3 j j ｷ3 j m ｭR6 9jj k ｭR6 9 ｷ3 d mk ; ｨ ｨ 59754: s cap ｷ3 X k s k ｷ3 ph X m e e ｭe 7 E j 6 9 6ｦ G =4 ; G 4 DE ; j; j jgs jj ﾁ5735 (.3) DE G ﾁ , 9 395, G G 6ｦ i ｭE j 7 E j 6 97 ﾁ5735 (.8) d jj, ｨ 9 ﾁ s k ｷ3 ph X m e e j G js j j js jk j ｭe 7 E j 6 9 6ｦ G =4 ｷ3 X j s ｭj6 9 cap js jkj ; G 5 DE ; ｭ: s ｭj6 9 cap ｨ j j , ｨ ｨ , 9 9 ｨ ｨ , ﾁ 縺 R 94574ｨ , ｨ , 9 R j j , ｨ E ｭR j 6 9 ｷ3 e, 345 E ｭR

9 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 ｨ ｨ ﾁ [5] s ho F j ｭR6 9 ｷ3 E d ｭR 7 R j 6 9 ; ｭ:96 9 ｭR j E ｭR j ho ｨ 縺98ｨ s ho S j ｷ3 E j ｭR j 6 9 ｭR j 6 9 : , 395 dj ｷ3 de j = ｭho6 9 ｷ3 E ｭR j 6 9 dr j = ｭho6 9, ｨ ｨ ﾁ5737 (.7) [48]: s k ｷ3 ph m e e ｭ dr dr G 3 ｭR6 9j ｭR6 9j ｭR 6 9j k ｭR6 9j k ｭR 6 9 e 7 E ｭR6 9 6ｦ ig ｭR6 9= e 7 E ｭR ig ｭR 6 9= G ｭR6 9 6ｦ ie ｭR6 9 7 ie ｭR 6 9 : ｭ: ｨ 9 ﾁ (.3) , 598ｨ ｨ ｭ s cap ｷ3 ph drg ｭR6 9jj ｭR6 9j m e e e 7 E ｭR6 97 ｭ:36 9 6ｦ G ｭR6 9= ﾁ 縺 X j k ｭR6 9j k ｭR 6 9 ｷ3 d ｭR 7 R 6 9 ; k ﾁ49 fj k g , ｨ , ｨ , 395 ｨ ｨ ( 縺 ) 9 ｨ ﾁ ｨ ﾀ ﾁ ｨ ﾀ ｨ 縺 ｨ ﾀ ｨ : e 6ｦ AB! ｭAB 7 6 9! A 7 6ｦ B : ｭ3: ｨ ｨ ﾁ57339 (.), (.3): ｭ s cap ｷ3 ph drg ｭR6 9jj ｭR6 9j m e e e 7 E ｭR6 97 6ｦ G ｭR6 9=4 ; ｭ3: R , , R ; , ｨ 59754, ﾀ79 ｨ ｨ ﾀ ｨ ｨ 989, R c ﾀ5ｨ : G ｭR6 9 ｷ3 G e ｭR6 9 6ｦ G neg ｭR6 9, G e ｭR6 9 ｷ3 G ｭR6 9 7 exp 7 G neg ｭR6 9 ｷ3 G ｭR6 9 exp 7 ｭ Rc R ｭ Rc R G ｭR 6 9 dr hv R G ｭR 6 9 dr hv R ; : ｭ3: G e ｨ ｨ ｨ , G neg ｭR , , v R ｷ3 dr= dt ｨ exp ｭ G dt=h , ｨ ｨ ﾁ5737 (.). 縺 ｨ 縺 ﾁ5737 (.8), G ｭR ｨ 59754, (3.), ｭ s at ｷ3 ph G ｭR6 9jj dr ｭR6 9j m e e e 7 E ｭR6 97 6ｦ G ｭR6 9=4 ｭ Rc G ｭR 6 9 dr exp 7 ; ｭ3:46 9 R hv R 345 R ｨ 95 ﾁ ｭ s at e de ｷ3 p h ｭ Rc G ｭR 6 9 dr G ｭR6 9 exp 7 : m e R hv R ｭ3: R 89 ｨ ﾀ ﾁ573 (3.4) G 5 de dr DR ; ｭ3:66 9 3*

10 閨75, 縺5 [ DR ﾁ5735 (3.4) G ｭR6 9 p e 7 E ｭR6 97 ｷ3 d e 7 E ｭR6 97 ; 6ｦ G ｭR6 9=4 9 ｨ 9 ﾁ s at ｭe6 9 ｷ3 p h G ｭR e 6 9 m e e jj ｭR e 6 9j ｭ Rc de= dr exp G ｭR 6 9 dr 7 ; R e hv R ｭ3: e ｷ3 E ｭR e , ﾁ jj ｭR6 9j ｷ p exp 7 ｭR 7 R 6 9 p DR DR ; ｭ3: R , DR ﾀ (3.6) ﾁ573 (3.7) 459 s at ｭe6 9 ｷ3 s max exp 7 ｭe 7 e 6 9 ｭDR de= dr6 9 : ｭ3:9a ｨ ｨ e ｷ3 E ｭR s max ｷ3 p3= h G ｭR 6 9 m e e DR de= dr exp ｭ 7z6 9 ; ｭ3:9b z ｷ3 ｭ Rc R G ｭR6 9 dr hv R : ｭ3:9w , G R 9 E ｭR ﾁ E ｭR6 9 ｷ3 e ｷ3 de dr ｭR c 7 R ﾁ573 (3.9) 459 s max ｷ3 p3= h m e e 345 s m ｭR c 7 R 6 9 t ｷ3 de= dr G ｭR c 7 R 6 9 exp 7 Gt ; ｭ3:6 9 DR h 9 m ｨ R c , ｨ ｨ , (3.) ｨ G Gt ｷ p 3= h s max ｷ3 p e m me e 3= DR ｷ3 ;4h p m me e 3= DR : ｭ3:6 9 ﾀ5858 DR m 7=4, ﾁ s max m 7= e , ｨ ｨ , ｨ ｨ ｨ , ｨ (R c > R ) ﾁ , ﾁ4-95 ｨ ｨ 59754, ｨ (798., ) ﾁ5735 (3.5) ｨ G 5 T e : k at ｷ3 p = p T e p ｷ3 m e T e ｭ s e p 7 7 s at ｭe6 9 e exp 7 e de ｷ3 T e m e 3= h G ｭR6 9 exp 7 E ｭR6 9 7 z ; ｭ3:a6 9 T e ｨ ｨ E ｭR6 9 ｨ ER DR 4 T e ｨ 8 DR. 7534, G ｭR ｨ E ｭR6 9 T e, 98 ﾁ5737 (3.a) ｨ k at ｷ3 h p m e 3= Gj ｭR6 9 p exp ｭ 7z6 9 ; ｭ3:b6 9 T ee R 345 ｨ R , ﾁ ｨ 59754, ｨ ﾀ ｨ ｨ ﾁ ﾁ ｨ ﾀ ﾁ5737 4ｨ ｨ ｨ ｨ ﾁ ﾁ59, [5] [5]. ﾀ ﾁ95753, ﾁ5735 (3.4) , P ｷ3 exp ｭ 7z6 9 ; z ｷ3 ｭ Rc R G ｭR6 9 dr hv R : ｭ3: z m 7=, 345 m , p m P ｷ3 ｭP 6 9 =m : ｭ3:46 9

11 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 m ; m , P ; P ｨ ｨ ﾁ ﾁ , , ｨ ﾁ ﾁ , ｨ ｨ [ ] s at ｭH 6 9 ｷ3 ｷ3 ;6 7 83, s at ｭHD6 9 ｷ3 ; s at ｭD 6 9 ｷ3 ｷ 縺98ｨ z ｷ3 3;, ﾁ573 (3.4) s at ｭH 6 9=s at ｭHD6 9, z ｷ3 ; s at ｭH 6 9=s at ｭD z ｷ3 ; s at ｭHD6 9=s at ｭD ｨ s cap ｷ , 縺98ｨ ｨ 5, H ｭ S 6ｦ u 6 9 [ ], ｨ ｨ ｨ HX, 345 X , ｨ 959 ｨ ﾁ ﾁ59 855, ｨ ｨ ﾁ ﾁ ｨ z ﾁ5735 (3.9) s cap. 7 ﾁ ﾁ G eff ｷ3 6 7 s at ｭe6 9 de=s max. 9445, ｨ z 4975, , ｨ ﾁ ﾁ 縺935993, HI 9 DI ｨ ｨ , 9, , ﾁ5737 4ｨ ｨ ｭ3; ; ｭ; ; HI 9 DI [59] [5] ｨ HI T ｷ3 3 K 74 3; HBr 3; T ｷ3 55 K ﾀ ｨ HX 9 DX (X ), [54] 355 s max, A x, ｨ 5 A s cap, A z G ef, ｨ 5 NCl DCl HBr DBr HI DI,8, 4,, 3 4,78,6,,7 3,7,6,5, 7 76,5 5,,4,,9,6, ｨ ｨ ｨ ｨ ｨ ｨ ｨ ｨ 59 ｨ ﾀ898 m , m B (3.), e ｨ ｨ 5535 ｨ e 7 ｨ ｨ m e 7 D 6ｦ EA ｷ3 e 7 ; ｭ3:56 9 m 6ｦ m D ｨ AB 9 EA ｨ A ｨ (3.5) ｨ ( (83. [, ]).) ｨ , ｨ , ｨ (3.) ｨ ｨ e u ｨ x , ｨ ｭv 7 7 u x 6 9 6ｦ u r 7=, 345 u x, u r , ﾁ5735 (3.5) s ｭm 6ｦ m v 7 ｷ3 ｭe 7 D 6ｦ EA6 9 : mm v 4 u, ｨ ﾀ5ｨ ﾁ5735 r m 6ｦ m 7 f ｭu x 6 9 ｷ3 exp 7 ｭm 6ｦ m 76 9u x ; pt T 345 T , ｨ v ｷ3 v 7 7 u x, 598ｨ ｨ ｨ e 7 ｷ3 m 7 v = r m 7 f ｭv6 9 dv ｷ3 exp 7 ｭ p p e 7 7 e 6 9 pt T dv ; ｭ3: ﾁ e ｷ3 m 6ｦ m 7 ｭe 7 D 6ｦ EA6 9 m ｨ ｨ 縺7345 e 4 T 9 ﾁ p ﾁ e T, ｨ 9565ｨ ｨ 45739ｨ ﾁ ｨ ｨ , (3.), ｨ ｨ (3.5) , ｨ ｨ 59754, ｨ [6 5 64], ｨ ｨ [6 5 64] ｨ (3.) ｨ ｨ ｨ ｨ , ｨ 959

12 閨75, 縺5 [ ｨ ｨ , ｨ ｨ , ﾁ ｨ ｨ ｨ 64ｨ ｨ , e 6ｦ O! ｭO 7 6 9! O 7 6ｦ O ｭ3: , a b d e f c g h i ｨ 59754, ｨ 5 a O 7 =O j f 679 ｨ ｨ ｨ P g 9 P u. 89 ｨ ｨ , ｨ ｨ ｨ e ｨ s at ｨ s g 9 s u, 67595ｨ P g 9 P u [65] e, ｨ 5 s at s g s u 6934, b c d e g h j i 5,75 6,7 7,8 8,4 9, 3,7 5,7, ﾁ ｨ , (3.7). 5 ｨ ｨ [7, 8]. 縺 ｨ ﾁ , 5843ｨ 5ｨ, P g 9 P u. 655, ｨ ｨ O ｨ ｨ 59 ｨ ﾁ5735 (3.5), ﾀ5753 ｨ ｨ ｨ e ｷ3 3; 66 ｨ 5, ｨ D ｷ3 5; ｨ ｨ EA ｷ3 ; 46 ｨ ﾁ573, 8987ｨ ｨ , , , ｨ ｨ ｨ e max, ﾁ573 (3.5) G exp ｭ 7z6 9 ｷ3 m e e max p h ｭ s at ｭe6 9 de :,,,4,7 7,9,4 4,3,7 縺98ｨ ; 7 ｨ 5 G exp ｭ 7z6 9 ｷ3 ;9 3ｨ [66] 9 G exp ｭ 7z6 9 ｷ3 3; 3ｨ ｨ [67]. ﾀ (3.7) ｨ ｨ , O 7, ｨ 5 3,,5,,5,, , 38 DH a b c d e O ｭp 4 6 9, ｨ ｨ ﾁ ﾁ ﾁ ｨ ｨ O ｭs g s u p g p u 6 93 S g, s; p ｨ ｨ 588, g, u 5843ｨ ｨ ｨ ﾁ ｨ ｨ ｨ , f g h ｨ 59754, ｨ ﾀ ｨ : (a) ｨ O 7 ( ｨ ｨ 59754, ); () O 7 ; () ｨ O 7, , ﾁ499 ｨ ｨ i

13 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 縺 ｨ ｨ 5553 O 7 ｭs g s u p3 g p u 6 9 P g ｨ 9535 ｨ v ｨ , ｨ ｨ ｨ ｨ ｨ ｨ ｨ 5 4ｨ ｨ : e 6ｦ O ｭs g s u p g p u 6 93 S g! 7 O 7 ｭs g s u p g p3 u 6 9 P u!! O 7 ｭ P6 9 6ｦ O ｭ 3 P6 9 ; ｭ3:8a6 9 e 6ｦ O ｭs g s u p g p u 6 93 S g! 7 O 7 ｭs g s u p3 g p u 6 9 P g!! O 7 ｭ P6 9 6ｦ O ｭ 3 P6 9 : ｭ3:8b ｨ ｨ ｨ ｨ ｨ , 9 65ｨ ｨ , (3.8) 555 ｨ ﾁ ﾁ59954, (3.8). 縺 ｨ ｨ ｨ , , ｨ ｨ S 6ｦ g, S 6ｦ g s-ｨ 59754, ｨ ﾁ ｨ ｨ ｨ [68] , ｨ ｨ , , , ｨ , ｨ ｨ ｨ [69] ｨ , ｨ ﾁ499 ｨ ｨ [7]. 9445, ｨ ｨ 45739, ｨ ｨ ｨ [68, 7, 7]. ﾀ CO [7 5 74], ｨ ｨ ｨ K [75]. sat, 78 83,,75,5,5,,75,5 93 K 475 K 3 K T ｷ3 3 K ｨ ｨ [68] (l ｨ 59754, m ｨ 588, y ｨ ｨ ｨ 59754), e, ｨ H ( S 6ｦ g ) H ( S 6ｦ g ) O ( 3 S 7 g ) O ( S 6ｦ g ) O (A 3 S 6ｦ u ) H 7 ｭ S 6ｦ u 6 9 H 7 ｭ S 6ｦ g 6 9 O 7 ｭ P u 6 9 O 7 ｭ P u 6 9 O 7 ｭ P u ｨ l m ｨ ｨ 縺359445, , ｨ ｨ ｨ cos y const sin y sin y sin y ｨ ﾁ499 ｨ ｨ [7] , , ｨ , , ｨ ; 78 83, 縺935993, K 9585 % ｨ ｨ ｨ ｨ ｨ ﾁ ﾁ

14 閨75, 縺5 [ ｨ O ｭ D g , (3.8a) ｨ : e 6ｦ O ｭs g s u p g p u 6 9 D g! 7 O 7 ｭs g s u p g p3 u 6 9 P u!! O 7 ｭ P6 9 6ｦ O ｭ 3 P6 9 : ｭ3:9a6 9 縺935993, ﾁ93799 ｨ S g D g (3.9a) ｨ ｨ (3.8a) ｨ 5 (ｨ O ｭ D g 6 9) ｨ ｨ 59754, , (3.8a) [ ] , [78] ｨ ; ｨ ,7 ｨ ,7 ｨ 5. 縺98ｨ ﾁ5737 (3.5) hg exp ｭ 7z6 9i ｷ3 4 3ｨ ｨ 縺359445, , ｨ O ｭ D g 6 9, ｨ , ｨ 553 4: e 6ｦ O ｭs g s u p g p u 6 9 D g! 7 O 7 ｭs g s u p3 g p u 6 9 P g!! O 7 ｭ P6 9 6ｦ O ｭ 3 P6 9 : ｭ3:9b ｨ ｨ ｨ ｨ 8 (3.9) ｨ HCl 9 DCl ｨ ; ; [79] HCl 9 DCl 縺98ｨ , HCl 74 ; K ｨ [8] ｨ s max v. 縺 s max ｭv6 9, 65393, s max ｭv ｷ3 6 9=s max ｭv ｷ HCl 9 DCl s max ｭv ｷ3 6 9=s max ｭv ｷ ｨ 縺935993, v ｷ ｨ 59754, , R c , ｨ ｨ ﾀ ｨ , 395 ｨ ｨ , ｨ , ｨ ｨ , ｨ ｨ ﾁ ﾁ599473, ｨ , ｨ ﾀ ｨ ｨ ｨ , ｨ , , ｨ ﾁ ﾁ ｨ ｨ ｨ ｨ e 6ｦ HCl! ｭHCl 7 6 9! H 6ｦ Cl 7 ; ｭ3: ｨ [5 5 54, ] (3.) ;65 ;4 ｨ 5, ｨ ｨ ;78 ;8 ｨ ｨ ,6 ｨ 5 9 ｨ HCl 74 4,3 ｨ 5, ,69 ｨ ,69 ｨ ｨ ,6 A HCl R c , (3.) ｨ (3.), ｨ H 6ｦ Cl 7 9 H 7 6ｦ Cl S, S 9 P. 縺359445, 9585 ｨ S ｨ , E, ｨ 5 3 HCl 7 S 6ｦ S 7 S 6ｦ,,4,8 3, 3,6 HCl H+Cl 7 R, a ﾀ ｨ HCl 9 HCl 7, ｨ HCl [6].

15 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 S 6ｦ, ｨ ｨ s- ｨ S , , 595-3ｨ ｨ , ｨ HCl 74,37 ｨ 5, 65ｨ ｨ ﾁ ﾁ ｨ (3.) ｨ ｨ ｨ ｨ HCl 9 DCl [88] ｨ ﾁ ｨ ｭHCl HCl ｨ [85, 89] ｨ (3.), , ｨ ｨ ｨ ,5 ｨ ｭHCl [9], ｨ ｨ S ( ) ｨ (3.) H 7 6ｦ Cl! e 6ｦ HCl 74 9; [9]. ﾀ ｨ , ｨ [9] ｨ ｨ v ｷ HCl , HCl v ｷ3 9 v ｷ : , , ｨ ｨ HCl ｭHCl HCl, (3.). ﾀ ｨ X e 6ｦ X! ｭX 7 6 9! X 7 6ｦ X ｭ3:6 9 ｨ ｨ ｨ Cl ｨ Cl. 縺 Cl ｨ Cl ｭ P6 9 6ｦ Cl 7 ｭ S6 9, ｨ Cl S 6ｦ u, P g, P u, S 6ｦ g ｨ , Cl 7 6ｦ Cl ｨ ｭs g 6 9 ｭp4 u 6 9 ｭp4 g 6 9 ｭs u 6 9 E; ｨ P g S 6ｦ g P u Cl ｭ S 6ｦ g Cl ｨ ｨ Cl ｨ ｨ ｨ : S 6ｦ u, P g, P u, S 6ｦ g, 9 ｨ S 6ｦ u ｨ ｨ ｨ , ｨ , 8 98ｨ ﾁ957, [93]. 縺935993, 395, X S 6ｦ g, S 6ｦ u, S 6ｦ g s-ｨ 59754, p-ｨ ｨ P g, P u 679 S 6ｦ u Cl 7 R; A ﾀ ｨ Cl 9 Cl 7, ｨ [6] ﾀ ( 85) ( ｨ 5) , ｨ ｨ [93] 7573 F Cl Br I S 6ｦ u P g P u S 6ｦ g,9 (58977) 4 7,3 (58977),5 (,3) 5,5 (,),7 (58977),4 (,) 3,7 (,6),5 (58977),9 (,),5 (,7)

16 閨75, 縺5 [ ｨ ｨ , ｨ Cl, Br 9 I , F ｨ , ｨ (3.) kat, e + F 7! F 7 + F ｨ k at K EA ｭX 6 9 EA ｭX6 9 7 D, ｨ 5 k at, F Cl Br I 3,,4,5,5,,4,4,53 7 [88]; 3 [9] 37 [9];,9 [9, 94]; 3, [95];, [96] 3,3 [93];,8 [97]; [98]; [99], [9];,3 [97];,8 [],4 [97]; 4 [];,8 [] 9445, ｨ ｨ ﾁ ﾁ599-54, ｨ P g 縺 ｨ ﾁ499 ｨ ｨ ｨ ｨ ｨ Cl 7 ｭ S 6ｦ u , ｨ ﾁ P u,6,5 7,,, ｨ ﾁ495 ｨ ｨ , ｨ p ｨ e ｨ s at ｭe6 9 = 7 7 e ｨ [9] [] , [, ] G e l6ｦ= ; e, ｨ ｨ ﾁ : [3], & [9], o [4], 4 [5], ^ [6], [7] [8] ｨ l ｨ , G ｷ3 p C 7 jv jc mol c h q re ; sat; S 6ｦ g 3 P g,, ｨ 59754, ｨ 5,4 S 6ｦ g 345 C 7, C mol, c q ﾁ , ｨ , q ｨ 59754, V , ｨ , ｨ , r e ｨ ｨ ｨ q ﾁ ｨ c q d ｭq 7 q 6 9, c q q l, 345 l ｨ 59754, 9 r e q, [, ] ｨ ﾁ499 ｨ ｨ [94] Cl 7, ﾀ ｨ ｨ ﾁ499 ｨ ｨ , G q l6ｦ e l6ｦ= : ｭ3: , G ｨ 8 ｨ e ｨ ﾀ (3.) ﾁ573 (3.7), , ｨ ｨ s at ｭe6 9 p 7 7 : e ｭ3:3a6 9

17 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 縺 ｨ ｨ ｨ , , e 4 G ｨ , ｨ , 67937ｨ ｨ , ｨ G 縺 ｨ , ｨ ｨ , ｨ , , ｨ p 98 ﾁ5737 (3.a), G ｭe e. 5 ｨ ﾁ5735 (3.) k at ｷ3 p h p G= 7 7 e p 7 7 3= m E j ｭR6 9 ; e R ER DR 4 T p e 4 G ; G ｭe ｭ3:3b6 9 e : 5 ｨ ｨ , z ｷ3, ｨ (3.3a) ｨ , [8] F (3.3) ｨ ｨ e < 5 3ｨ ﾁ s at ｭe6 9 ｷ3 ; , ｨ ｨ ｨ ｨ ｨ ﾀ ｨ ｨ e 6ｦ AB 6ｦ M! AB 7 6ｦ M : ｭ3: ｨ M ｨ , ｨ , ｨ , AB ｨ K a , 578ｨ (3.4), d AB 7 7 ｷ3 K a N e AB7 M7 ; ｭ3:56 9 dt 345 N e ｨ , [Z] Z K a ｨ M. 5 ｨ , , K a k det K a ｭT6 9 ｷ3 ﾀ75588 e 6ｦ O 6ｦ He! O 7 6ｦ He e 6ｦ O 6ｦ Ne! O 7 6ｦ Ne e 6ｦ O 6ｦ Ar! O 7 6ｦ Ar e 6ｦ O 6ｦ Kr! O 7 6ｦ Kr e 6ｦ O 6ｦ Xe! O 7 6ｦ Xe e 6ｦ O 6ｦ H! O 7 6ｦ H e 6ｦ O 6ｦ D! O 7 6ｦ D e 6ｦ O 6ｦ N! O 7 6ｦ N e 6ｦ NO! NO 7 6ｦ NO e 6ｦ O 6ｦ H O! O 7 6ｦ H O e 6ｦ O 6ｦ CO! O 7 6ｦ CO e 6ｦ O 6ｦ H S! O 7 6ｦ H S e 6ｦ O 6ｦ NH 3! O 7 6ｦ NH 3 e 6ｦ O 6ｦ C H 4! O 7 6ｦ C H 4 g 7 g AB ph 3= EA k det ｭT6 9 exp : ｭ3:66 9 m e T T g 7, g AB AB AB ｨ 9 ｨ ｨ, EA ｨ ｨ , (ｨ , 355, ) T k det ｭT6 9 ﾁ5735 (3.6) s det ｭE AB M 679 ｨ E ﾁ5737 k det ｭT6 9 ｷ ｭ s E p p s p T 3 det ｭE6 9 E exp 7 E de ; m T K a, ,33 [];,3 [];,7 [3],3 [],5 [],5 [],85 [] 4,8 [4],4 [4],85 [];, [3];,6 [5];,6 [6];,78 [7];,5 [8],7 [9]; 8 [] 4 [, ]; 5 [3] 3 []; 3 [3] [3] 65 [3] 3 [, ]; 7 [3]; 3 [4] 345 m AB 9 M (3.4) ｨ ｨ , ｨ 4579 [5], e 6ｦ AB! ｭAB ; ｭAB ｦ M! AB 7 6ｦ M : ｭ3: ｨ ｨ , ｨ M. ﾀ5ｨ k q

18 閨75, 縺5 [ ﾁ5735 (3.6) K a ｭT6 9 ｷ3 g 7 ph 3= k q exp 7 E a ; ｭ3:86 9 g AB m e T T 345 E a ｨ , T , ｨ , 345 ﾁ ｨ ｨ ｨ ﾁ573 (3.8) ｨ [6] K a ｷ3 g 7 p h 3 k g AB me 3= q f ｭE a 6 9 ; ｭ3: ﾁ ｨ ｨ f ｭe ｭ p 7 7 e f ｭe6 9 de ｷ3 ; ｨ 59 ﾁ f ｭe6 9 ｷ3 p p exp 7 e ; T 3= T 345 T ｨ 縺 ｨ ｨ Ka, K 3 K T ｷ3 77 K 499 ﾁ573 (3.8) 9 (3.6) ﾀ5 ｨ , , ｨ (798. 8), ｨ ｭO ｦ O! O 6ｦ O ｨ ｨ (3.7) ｨ ｨ (3.), 67595ｨ , ｨ ﾁ ﾁ ｨ ﾀ5ｨ (3.7) , (3.) , ｨ , (3.7). ﾀ (3.7) , ｨ E a ｨ ｨ 45739ｨ ｨ , NO (798. 9) Ka, e + O 7! O 7 + O T; K,,4,,,4 e, ｨ Ka, K T ｷ3 3 K 5 K Ka, K,,,4,6,8 e, ｨ ｨ ﾁ499 ｨ ｨ 59754: () 649 ﾁ ｨ ｨ [, 7]; () 3545ｨ ｨ [6] ﾁ ｨ ｨ []. 3 T; K ｨ : a) : [4], [6], [7], & [5]; () 355 NO : [8], & [9].

19 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 , ｨ 3998, ﾁ ｨ ｨ 縺935993, (3.) 9 (3.7) ｨ O 7 ｭX P g 6 9, ｨ : v , E ｨ , G ﾀ ｨ O 7 ｭX P g 6 9 [4, ] v E, 3ｨ G, 3ｨ 5,4,36,,6,46,74, 4. ﾀ ｨ ｨ , , ｨ 縺 , ｨ - 59 ｨ ｨ ｨ ｨ ｨ 94574ｨ ﾀ5ｨ ｨ , , , 9, ｨ , ｨ R, ｨ 縺 ｨ , ｨ ｨ , 9 ｨ ｨ ｨ ｨ ｨ ｨ , ｨ ｨ 5ｨ , , , ｨ ｨ ﾀ ｨ , 89 ｨ ｨ ( ). 585 ｨ , 67595ｨ ｨ SF 6, ｨ ｨ , ｨ ｨ ｨ ｨ ｨ ｨ ｨ , , ｨ CX CX 7 4, 345 X ｨ ﾁ ﾁ ｨ ｨ CX , X ｨ ｨ 47, C ﾁ C ｷ3 X4 iｷ3 a i c i ; ｭ4: ｨ ﾁ499 c i , ｨ i X, 9 a i , ｨ ｨ ｨ X. ﾀ ｨ ｨ ﾁ937, 9597ｨ 47, , ｨ , ｨ X. 79 ﾁ , X ｨ p= ｨ , ｨ , ｨ ｨ , 縺 ｨ ｨ , ﾁ ｨ ﾁ5735 (4.) a ｷ3 a ｷ3 a 3 ｷ3 a CX ｨ , ﾁ ｨ ｨ 953. ﾀ ｨ , 37 8ｨ 353, 395 ｨ ｨ ,

20 閨75, 縺5 [ ｨ ｨ 47, 9.5. ｨ ｨ ｨ CX s-ｨ CX 7 4, p-ｨ ｨ , ｨ 59754, ｨ , ｨ CF 3 Cl, ｨ ﾀ C 5 Cl 5845, C 5 F, CF 3 Cl , CX , ｨ CF 3 Cl CF 3 7Cl 7 9 CF 7 3 7Cl ｨ F CF 3 Cl 7 578ｨ , ｨ 8989 C 5 Cl , CF 7 3 7Cl ｨ ｨ ｨ p= ﾁ ｨ CF 7 3 7Cl ｨ 9, F 578ｨ s-ｨ CF 3 Cl ｨ ｨ CF 3 7Cl ｨ CF 7 3 7Cl; ｨ p- ｨ 縺935993, ｨ CF 3 Cl ｨ CX 3 M ｨ X 7 9 M 7 : ｨ [, ] SF ｨ , ｨ ﾁ ﾁ , S 5 F 935ｨ ｨ 494, ﾁ ｨ 9 59ｨ , 5459 ﾁ , 85749ｨ 59 59ｨ p= ﾁ ｨ ｨ ｨ 9, ﾁ ｨ ｨ ｨ 9 ｨ ｨ , ｨ ｨ ｨ , ｨ , ｨ ｨ , ｨ ｨ , ｨ ﾁ , , ｨ , ｨ ｨ , , , ｨ ｨ 59 ｨ 5ｨ ｨ ｨ 59754, ( ) ｨ ｨ 59 ｨ , ｨ ｨ , ｨ 縺 ｨ ｨ , ｨ ﾁ , ｨ. ﾀ ｨ ｨ ﾁ ﾁ ﾁ5735 (3.7) ｨ ｨ 5ｨ 99, ﾁ573 (3.7) 945 s at ｭe6 9 ｷ3 p h m e e f ｭe6 9 ; 345 f ｭe6 9 ｷ3 G ｭR e 6 9 dw ｭR e6 9 exp ｭ 7z6 9 ; de z ｷ3 ｭ Rc R e G ｭR 6 9 dr hv R : ｭ4: R e , 5953ｨ ｨ 59754, 9.5. E ｭR e 6 9 ｷ3 e ｨ W ｭR e ﾁ R e z ｨ ﾁ5735 (3.5) ｭ s at e de ｷ3 p h G ｭR6 9 exp ｭ 7z6 9 ; ｭ4:36 9 m e ｨ ﾁ R ｨ , 59577, 85ｨ , ｨ ｨ ｨ ﾀ5ｨ , 6795, [7, 8], ｨ 5975-

21 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 , ﾁ , ﾁ , 578ｨ ｨ [38] ｨ ｨ , ｨ , ﾁ (CF 3, CF 7 3 ) ｨ ｨ ｨ e 6ｦ SF 6! ｭSF ! Produkty: ｭ4: ｨ ｨ ｨ ｨ ｨ ｨ ｨ (3.3) s at ｭe6 9 p 7 7 ; ｭ4:56 9 e 345 e ｨ ｨ p ｨ ｨ , 345 G 7 7 e, ｨ ｨ ｨ (4.4) a [39, 4] ｨ ｨ , , 3ｨ ｨ ｨ ｨ ﾁ , Cl 7 CCl 7 3 CCl 7 CCl 4 CFCl 3 CF Cl CF 3Cl 3 Cl 7 Cl 7 Cl , F , F 7 CCl 7 3 CFCl 7 CF Cl , F , CF 7 3 F 7 CF ｨ 59754, ｨ ｨ 59754, ｨ ｨ 59754, ｨ ｨ 59754, ｨ ｨ 59754, ｨ ｨ ( ) ﾁ499 ｨ ｨ [7, 8]: (a) CCl 4 ; () CFCl 3 ; () CF Cl ; (3) CF 3 Cl; (4) CF , b a c d e f g F 7 /CF , a b c d e f 6F 7 3 /CF 4 g h i k 6934, a b c e d f g h Cl 7 /CF 3Cl ｨ 59754, ｨ ｨ 59754, ｨ ｨ 59754, ｨ 5 d 6934, a b c d e f g 6934, a b c d e f g h i k 6934, a b c e f g h ｨ 59754, ｨ ｨ 59754, ｨ ｨ 59754, ｨ ｨ ｨ 59754: () e 6ｦ CF 4! F 7 6ｦ CF 3 ; () e 6ｦ CF 4! F 6ｦ CF 7 3 ; () e 6ｦ CF 3 Cl! Cl 7 6ｦ CF 3 [38] ｨ ｨ ｨ ｨ 59754,

22 閨75, 縺5 [ , 899ｨ SF 6, k chem ｷ3 ｭ4;3 ; sm 3 s 7 : ｭ4: , , 899ｨ ｨ , ｨ ｨ 59754, ｨ ｨ 9535 ｨ ｨ 縺935993, (4.6) ｨ ｨ , [39] ｨ ｨ (4.4) ｨ ｨ 99 ｨ ｨ SF ｨ , ﾁ573 (4.) ｨ 99 ｨ G ｷ3 const, 65353, ｨ ｨ ｨ 59754: s at ｷ3 A e ; ｭ4: ﾁ5735 (4.) Kat, , SF 6 7 e, 3ｨ 5 sat, 74 83,6, A ｷ3 p h m e dw de G exp ｭ 7z6 9 : ｭ4:96 9,8,4,,6, 35 [4, 4] ｨ [39, 4] ｨ , , ｨ ｨ , 9 ｨ , ﾁ ｨ ｨ , ｨ SF ｨ ｨ , 5 7 3ｨ 5. 閨 ｨ ｨ 59754, ｨ ｨ ｨ 59754, ｨ e < 3ｨ ｨ SF [39, 4] 74 (798. a) s e k at ｷ3 s at ｭe6 9 ｷ3 ｭ5;4 ; sm 3 s 7 : ｭ4:66 9 m e g > SF g ｷ3 ;, , 65ｨ ｨ SF ｨ (4.) 8 f ｷ3 ;77 (798. ) , ﾁ573 (4.) ｨ , e ｷ3 ;5 ｨ 5, s ｨ ｨ ｨ 59754,5 ｨ ｨ SF ｨ ｨ 縺 , ｨ , 589 ｨ ｨ ｨ ｨ ﾁ ﾁ , 675e, ｨ ｨ ｨ [39, 4] (a) [66] () ｨ SF SF A ｷ3 7; A ｨ [39, 4] 9 A ｷ3 5;8 A ｨ ｨ ｨ ,5 ｨ 5, ｨ [66] [43] z 5 9 G 74 ｨ ｨ ｨ ｨ 5898, SF ｨ e > ; ｨ 5. 5 ｨ ｨ ﾁ ｨ 45739, ｨ ｨ ｨ ｨ [66, 44, 45] g e s at ｷ3 s : ｭ4:6 9 e

23 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 ﾀ ｨ CCl g s, CH 3Br SF 6 C H 4O C 4H C 8H n-c H Br,3,3,84,,39,4,5,7.3,4,38 4, ,8 5,,3,4 [44] [45] [44] [66] [45] [66] [66] [45] [66] [44] [45] ｨ C 5 Cl a ｨ ｨ CF 3 Cl ﾀ C 5 Cl (4.), ｨ CF 3 Cl ﾀ , 9 ｨ ｨ ｨ ｨ ｨ , C 5 Cl, , ｨ 縺935993, ｨ ｨ ｨ ﾁ5735 (4.5), ｨ 9535 ｨ ｨ ｨ ｨ , ｨ ｨ ｨ 5 [46]. Cl 7 /CF 3 Cl T ｷ3 8 K ｨ CF 3Br CF Br CCl 3Br CH Br CH 3I CCl 4 CFCl 3 CF Cl k as, ,57* *,7* 6,* 7,* 3** 8**,36** * [46]. ** [47], , ﾁ573 (4.5) ｨ ｨ e ｷ3 3ｨ 5. 縺935993, ｨ ｨ ｨ ｨ , ｨ ｨ ﾁ49ｨ ｨ ｨ ｨ , , ｨ ﾁ ｨ ｨ ｨ 59754, ｨ , ｨ , , ﾀ79 ｨ , ｨ 8 ｨ , SF 6 ｨ ﾁ , e 6ｦ CF 3 Cl! ｭCF 3 Cl 7 6 9! CF 3 6ｦ Cl ｭ4: , V, ｨ 5 e, ｨ CF 3Cl R c CF 3 Cl 7 CF 3 + Cl s Cl 7 + CF 3 65 K 55 K 3 K ｨ 59754, ｨ 5 R(C 5 Cl) ｨ ｨ e 6ｦ CF 3 Cl! ｭCF 3 Cl 7 6 9! CF 3 6ｦ Cl [9] (a) (), ｨ , 9. 68, 7

24 閨75, 縺5 [ ｨ k at, CCl 4 CHCl 3 CH Cl CH 3Cl CFCl 3 CF Cl CF 3Cl CH 3Br CH Br CF 4 CH 3I CF 3Br CF 3I CF Br CCl 3Br 4 [99, ]; 36 [5]; 33 [5]; 9 [53, 54]; 5 [55]; 4 [98, 56, 57]; 43 [97]; 44 [58]; 38 [59]; 37 [6]; 8 [44]; 5 [6], [56];,49 [55];,38 [97, 53, 6];,44 [88];,6 [5];,4 [99, 49];,3 [6] 4;8 74 [99, 6]; ;7 74 [5]; ;5 73 [53] < 75 [99]; < 77 [63]; 7 78 [64] 6 [98]; 3 [64]; [53, 55]; [65, 66]; 8 [56]; 4 [59, 67,68]; 3 [6],3 [98];,4 [55];,3 [69];, [65];,7 [66];,6 [7];,6 [7];,4 [7];,7 [73] ; 75 [5, 6, 64, 66],7 [44];,5 [64, 74];, [75];,7 [63, 76];,4 [5];,6 [77] 9 [77, 78]; [46] < 78 [3] 9 [58]; [79, 77]; [78]; 7 [8],4 [53, 55];,9 [56];,5 [6];,6 [77] [56]; 7 [58]; 9 [8] 6 [53, 55] 4,9 [46]; 8, [79] 35, < 77 9, ; 75,7 < 78, ｨ , ｨ CF 3 I. 縺935993, , CF 3 6ｦ I 7, CF 7 3 6ｦ I. V, ｨ 5 CF. 3I 7 e, ｨ CF 3 I 7 CF 3 I R(C 5 I) CF 7 3 CF 3 + I CF I. ( P /) CF I CF 3 + I ｨ ﾀ ｨ ｨ ｨ ｨ ｨ ｨ ｨ ｨ ｨ ｨ I ﾀ ｨ , ｨ CF 3 I [9] ｨ ｨ , ｨ , ｨ , ｨ , ﾁ957 ｨ ｨ ｨ ﾁ [7]: D ｨ , ﾁ , e th ｨ ﾁ ｨ ｨ D ｭR 7 Cl6 9 e th ｭR 6ｦ Cl D ｭR 7 F6 9 e th ｭR 6ｦ F CCl 4 CFCl 3 CF Cl CF 3Cl CF 4 3,7, 3,7, 3,3, 3,74, 7,45, 7,45, 7,3, +,, 4,4, 4,77,3 5,33, 5,66,,,,37,3,93,,6, SF (4.4) ｨ ｭ;5 ; ｨ %. ﾀ75588 (4.4) ｨ 59754, 65ｨ ( ) ｨ SF 6 (e 6ｦ SF 6! SF6 7 ) k at,,,,3,4 687 [8] [8, 83] [6, 68, 84, 85] [56, 86, 87] [88] k at,5,6,7 5,8,8 3, 687 [89] [48, 5, 9 5 9] [66, 93] [97, 6, 94] [98, 95]

25 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 ｨ 5ｨ ﾀ ｨ ｨ ｨ ﾁ5735 (4.8) ｨ ｨ s k at ｷ3 hvs at i ｷ3 A : ｭ4:6 9 pm e T A SF 6, ｨ ｨ k at ｷ3 3; [39, 4] 9 k at ｷ3 ; [66] ｨ 縺359445, ｨ SF (4.6), ｨ ｨ 縺 [9] 835 SF k at ｭ3 K6 9 ｷ3 ; k at ｭ73 K6 9 ｷ3 ; ( , ｨ ). 縺 , ｨ , ｨ ｨ ｨ ﾀ ｨ ｨ 959 ｨ ﾁ ﾁ ｨ ｨ SF K [9], T ｷ3 7 K , ｨ SF , 395 ｨ SF ｨ SF 6, ｨ 縺 ｨ SF [98] ｨ SF ( ) 3,; 3,; 4,5; 4, , 3, K ｨ K , ｨ ｨ ﾁ5735 (4.8), , SF K ｨ A ﾁ5735 (4.8), ｨ 縺 [9], 45493, 395 ｨ 959 4* , K. 縺 ｨ , , [94] , K ,3, 3, 9, K ｨ A ﾁ5735 (4.8), ｨ [94] [98] , , ｨ ｨ ｨ ｭ I ｷ3 s at de : ｭ4: , ｨ ｨ ｨ 59754, ﾁ5735 (4.8), ｭ I ｷ3 s at de ｷ3 A ln e ; ｭ4:46 9 e 345 e, e ｨ ｨ (4.8). 577 e 3 3ｨ 5, e 3ｨ A, I ｷ3 ; ; A ｨ , [8] ｨ ｨ I 3555 SF K, , K A I ｨ 989,6 5, ｨ [8]. ﾀ ﾁ573 (4.8) A s at ｷ3 p e 6ｦ ; ｭ4:56 9 ee ﾁ573 (4.8) ｨ ｨ ｨ e k ｨ ｨ e ｷ3 A m e k : ｭ4: ﾁ5737 (4.6), (4.7) 49 k A, SF 6 e ｷ ｨ 5, [39, 4] ｨ ｨ 5. ﾀ ｨ , , , ｨ ｨ 9 83ｨ 798.,

26 閨75, 縺5 [ ｨ ﾁ ﾁ , ｨ SF 6, ｨ ｨ CF 3 Cl ( ). 5 ｨ ｨ ｨ ｨ ﾁ ﾁ CH 3 Br [75], K ｨ ｨ ; ; , ｨ ,6 ｨ 5 ｨ ｨ CHCl [98, 99, 49, 64, 96, 97] ｨ ｨ ｨ , ｨ 9 54 ﾁ , ｨ ｨ ｨ 縺935993, ｨ CH 3 Br K ｨ ｨ 59754,38 ｨ 5 [75] ｨ ｨ 45739, K ｨ ﾁ4-95 ｨ ｨ ｨ ｨ ﾁ ｨ ｨ ｨ , ﾁ , ｨ exp ｭ 7z ｨ 5ｨ 99 ( ) (SF 6, CF 3 Cl, CH 3 Br, CHCl 3 ) ﾁ , ｨ , ｨ 95, , , 83999, , jj ｭR6 9j jj ｭR6 9j exp 7 ho ｷ3 T R 7 R DR exp 7 ho : T ｭ4: j ｭR6 9, j ｭR ﾁ (83. ﾁ573 (3.8)), ho ｨ , T , , exp ｭ 7ho=T , 589 ho T, ｨ ﾀ ｨ , ｨ , ｨ ｨ SF ﾀ79 37 ｨ ｨ SF 7 6. ﾀ ｨ , 534 ｨ SF 6, e 6ｦ SF 6! ｭSF ! SF 7 5 6ｦ F ; ｭ4:86 9 e 6ｦ SF 6! ｭSF ! SF 5 6ｦ F 7 : ｭ4: ｨ ｨ ｭSF ﾀ ｨ ｨ ｭSF ｨ , 995 F 7, SF4 7, SF 3 7, SF 7, ｨ SF 6 [98, 99]. ﾀ ｨ ｨ (4.8), (4.9) ｨ (4.8), (4.9) ｨ ｨ ﾀ , , ｨ 45739ｨ (4.8), 縺 ﾁ ｨ , ｨ 縺 kat, , e + SF 6 7! SF F,, =T, ｨ ｨ SF SF 7 5 () 9 4 ｨ ｨ () [94]., 7 ﾀ75549 SF5

27 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 E a (4.8) E a, ｨ 5,,,,,5,43,4,,39,4,, 687- [] [] [96] [84] [94] [] [] (SF , ｨ 59 ｨ 5ｨ 99 ｨ ｨ ｨ , ｨ (SF6 76 9, (4.8) (SF ﾀ79 ｨ (SF , (SF ﾁ ｨ ｨ ｨ (SF 閨 , 78459ｨ 59 ｨ , ﾀ5ｨ ｨ , ｨ (4.8) ｨ ｨ , [] 49 ｨ EA ｭSF ｷ3 3;8 ;5 ｨ 5, EA ｭSF ｷ3 ;5 ;5 ｨ 5, 9 ｨ D ｭSF F6 9 ｷ3 ;35 ;5 ｨ 5. 縺98ｨ , 395 ｨ (4.9) 555,6 ｨ ｨ SF 5 5 F, : 3,4 ｨ 5 [], 3;9 ;5 ｨ 5 [3], 4; ;3 ｨ 5 [4] 9 4,35 ｨ 5 [5] ｨ , ｨ ｨ ｨ ｨ , ｨ , , , ｨ ﾀ ｨ ﾀ ｨ ｨ ｨ , ｨ ｨ , , ｨ ｨ , ｨ ｨ , , , ｨ ﾁ , ｨ ｨ [6 5 3]. 縺 ｨ e [, 3] , ｨ 3ｨ - 5ｨ ｨ , , ｨ ｨ , ｨ ｨ , 897ｨ 595 ｨ ﾀ ｨ ｨ 989 ｨ , ｨ , , 89 ｨ , , ｨ ﾀ57554 ｨ ｨ (ｨ ) 縺 ｨ ｨ ｨ ｨ , ｨ , ｨ ｨ e 6ｦ A 7Z n! 7 A 7 ｭZ6ｦ6 9 n ; ｭ5:a6 9 7 A 7 ｭZ6ｦ6 9 n 6ｦ M! A 7 ｭZ6ｦ6 9 n 6ｦ M ; ｭ5:b6 9 B 6ｦ 6ｦ A 7 ｭZ6ｦ6 9 n! B 6ｦ A 7Z n ; ｭ5:w A 7 ｭZ6ｦ6 9 n ｨ M. ﾀ ｨ ｨ ｨ , 49ｨ ｨ , 縺359445, , , ｨ 953

28 閨75, 縺5 [ , 縺7345 ｨ ｨ EA ｷ3 5 4 ｨ 5, I ｨ 5. ﾀ5ｨ ｨ , ｨ ｨ ｨ , ｨ ｨ , 49ｨ , ｨ , ｨ ｨ , ﾀ ｨ , ｨ , ｨ , ｨ ﾁ ﾁ ﾁ ｨ ｨ Ze, R J ｷ3 4pR dn 7 D 6ｦ dr 6ｦ K 6ｦEN e : ｭ5:6 9 ﾀ ﾁ ﾁ , ﾁ ｨ, N , D 6ｦ 9 K 6ｦ 5ｨ ﾁ ﾁ ﾁ ﾁ , e , ｨ 59754, E ｷ3 Ze =R ｨ , ｨ ﾁ ﾁ ﾁ ﾁ ｨ 9545 D 6ｦ ｷ3 ek 6ｦ =T, 345 T , dn J ｷ3 74pR D 6ｦ e Ze 7 N dr TR : ｭ5:36 9 ﾀ ｨ , 45493, R , N ｭr6 9 ｷ3, 345 r , 459 N ｭR6 9 ｷ3 ｷ3 J 4pD 6ｦ e ｭ R r JT 4pD 6ｦ Ze dr Ze ｭR 6 9 exp Ze exp Tr Ze 7 TR TR 7 Ze TR 7 ｷ3 : ﾀ R ｨ N 6ｦ ｨ ｨ : 4pD 6ｦ N 6ｦ Ze 3 J 6ｦ ｷ3 T exp Ze = ｭTr : ｭ5: ﾁ573 98, ﾀ ｨ pD 7 N 7 Ze 3 J 7 ｷ3 T ; ｭ5: exp 7Ze = ｭTr (5.4), Z! 7Z ｨ ﾀ ｨ ｨ T, Z (5.4), (5.5) Z ｷ3 rt e ln D 6ｦ : ｭ5:66 9 D , ｨ , , D 6ｦ < D 7. ﾀ ﾁ r 4 l ; r 4 e T ; ｭ5: l ｨ ｨ 683, ﾁ ｨ ｨ ﾁ ｨ ｨ 59 94: 4pK e N e Ze 3 J e ｷ3 7 exp 7Ze = ｭT e r6 97 ; ｭ5: ｨ ﾁ ﾁ5994ｨ ｨ T e T e ｷ3 ed e =K e K e 9 D e ｨ ﾁ ﾁ ﾁ ﾁ899 ｨ Z , ｨ ｨ ed e =K e ｨ 9544ｨ ｨ 45739ｨ ﾁ , ﾁ (5.5) Ze = ｭrT6 9 4 : J 6ｦ ｷ3 4pZe K 6ｦ N 6ｦ ; 345 N 6ｦ ﾀ ｨ N e ｷ3 N 6ｦ, Z ｷ3 r D e ek e ln K e K 6ｦ : ｭ5: ｨ 95 ﾁ Ze = ｭrT e 6 9 4, 345 T e ｨ ﾁ ﾁ59949 ｨ , ｨ ｨ ｨ , ｨ

29 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 , ｨ ｨ , ｨ , ｨ ｨ 38995, ﾁ57397ｨ r Z ｨ j ｷ3 Ze=r. 789 ej < EA, 345 EA ｨ , ｨ , ej > EA , ｨ ｨ , ｨ ｨ ｨ , Z ｷ3 r EA e : ｭ5: , 49 49ｨ r ｷ EA ｷ3 3 ｨ 5 ｨ Z ｷ3 3, ｨ 縺359445, , ｨ , , ｨ ｨ ｨ ｨ ﾀ ｨ , , ,3 33, , Z ｨ ｨ ｨ ｨ 縺 ｨ ｨ 5ｨ ｨ ｨ []: t exp ｭ 7S6 9 ; S ｷ3 ｭ Rc r r m e dr EA 7 V ｭr6 9 6ｦ V ｭR6 9 h : ｭ5: EA ｨ ｨ 59754, V ｭR6 9 ｷ3 Ze =R ｨ R , R c , 9.5. r R c ｷ3 ; 7 EA=e 9 e ｷ3 Ze =r s S ｷ3 p r m e e h : ｭ5:6 9 7 EA=e ﾀ539, 395 e , S r=a, 345 a 縺 , ｨ Z, ﾁ5735 (5.) , 45495ｨ 89 95ｨ ｨ ｨ E=N ｷ3 Td, ｨ ﾁ ﾁ ｨ ed e =K e ｷ3 4 ｨ ｨ ; 3 83 (5 8) Ar 6ｦ, ｨ K 6ｦ ｷ3 ;6 83 (5 8) 7. ﾀ79 ｨ ﾁ5735 (5.9) Z=r ｷ3 ; , ;8 4, (5.) Ze=r ｨ 縺935993, 395 ｨ (5.7), ｨ N , r ｷ3 33 ｨ N , ｨ , , ｨ ﾀ ｨ ﾀ ｨ , ｨ , ｨ 9 85ｨ 縺359445, , , ｨ , ｨ ｨ 縺 ｨ ｨ , ﾀ5ｨ ｨ ｨ ｨ , ｨ , ｨ , ｨ 3998, ｨ ｨ ｨ ｨ ｨ ,

30 閨75, 縺5 [ ｨ , ｨ ｭO 6 9 n [9, 4 5 7] ｨ ﾀ5 ｨ [7] ｨ O ｭO 6 9, ｨ ｨ ｨ ｭO , , ｨ 59754, ｨ ｨ 59 ｨ [9, 8], , 795ｨ , (), 3,5 93 () 9,5 93 () ﾀ ｭO ｨ ｨ , 5849ｨ , ｨ ｨ , e 6ｦ ｭO 6 9! O 7 6ｦ O : ｭ5:36 9 ﾀ ｨ ｨ O 7 ｭ P g ｨ O 7 O 7 O ｨ ｨ O 7, ｨ ﾁ ｨ , O ｭO n 578ｨ ｨ ｨ O ｨ ｭO O. 5 ｨ O 7 O. 縺 ｨ e 6ｦ O! ｭO 7 6 9! O 7 6ｦ O ; ｭ5: ｨ P g 9 P u. ﾀ5ｨ ｨ ｭO O 7 99 O 7 O ｨ [9] , ｨ O O 7 ｭO 6 9 n ｨ ﾁ ｨ , ｨ (3.7) ｨ - 59 ｨ s-ｨ p : e 6ｦ ｭO 6 9 n O ｭs g s u p g p u 6 9! ｭO 6 9 n O 7 ｭs gs u p4 g p u 6 9!! O 7 ｭO 6 9 m 6ｦ O ｭO 6 9 n 7m ; ｭ5:56 9 e 6ｦ ｭO 6 9 n O ｭs g s u p g p u 6 9! ｭO 6 9 n O 7 ｭs g s up 4 g p u 6 9!! O 7 ｭO 6 9 m 6ｦ O ｭO 6 9 n 7m : ｭ5:66 9 ﾀ75588 (5.5) S g, (5.6) S u ｨ ｨ ｨ ｨ 5, ｨ ｨ ｨ 5 [9, 5, 6] ﾁ9897ｨ O 7, O 7 ｭO , ｨ ｨ , ｨ ｨ (5.5), (5.6), ｨ ｨ ﾁ ﾁ [9, 9, ] ｭCF 3 Cl ｨ : e 6ｦ ｭCF 3 Cl6 9! CF 3 Cl 7 6ｦ CF 3 Cl ; ｭ5:76 9 e 6ｦ ｭCF 3 Cl6 9! Cl 7 CF 3 Cl 6ｦ CF 3 ; ｭ5: ｨ ｨ CF 3 Cl 縺 ｨ

31 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 CF 3 Cl ｨ ｨ 59754,5 ｨ ｭCF 3 Cl6 9, ｨ (5.7), (5.8) , ｨ , CF 3 Cl , ( ), ｭCF 3 Cl6 9 4ｨ ｨ ﾁ ﾁ ｨ ｨ ｨ ﾀ5ｨ ｨ ｨ 縺 , ｨ SF 6 N 9 O N [9,, ], ｨ ｨ , , ｨ , N ｭ P g ｨ ｨ ｨ ﾀ5ｨ ｨ e 7N [3, 4, 3, 4] ｨ , ｨ 59754, ｨ ｨ 59 ｨ , () : () [9, ] , ｨ ｭO SF 6 N SF ｨ ｨ ｨ 59 ｨ , , 935ｨ ｨ N 7 ｭ P g 6 9, , ｨ , ｨ , 85749ｨ , ﾀ5ｨ ｨ , ﾀ79 ｨ ｨ ｨ , 5849ｨ , , ｨ , , , ｨ 縺 ｨ ﾀ , ｨ , ｨ , ｨ , ｨ ﾀ ｨ ｨ , ｨ ｨ ｨ , ｨ ｨ ﾁ ｨ ｨ ｨ , ｨ , ML ( , ML ), ｨ ｨ ｨ. 縺7345 ｨ ｨ , ｨ 59754, ｨ 355-, , ｨ ｨ, 縺 ｨ ｨ ｨ 553. 縺 ｨ ( , , ﾁ583), ｨ (Ar, Kr, Xe),

32 閨75, 縺5 [ ﾀ585 ｨ ｨ , ｨ ﾁ85, , ｨ ｨ, ｨ , ｨ 59754, ｨ ｨ ｨ ｨ l (9.5. ｨ ), ｨ ﾁ ｨ ｨ De, : De ｷ3 e l ; ｭ5: e 8794 ｨ , ｨ ｨ , ｨ ｨ , ｨ ｨ ｨ ｨ ｨ 4445 ｨ , 縺935993, ｨ ｨ , ｨ ｨ ｨ , , (5.5), (5.6) [8 5 ] ｨ s- ｨ p , ﾁ85 ｨ ｨ 8 577ｨ ﾀ5 ｨ ｨ ﾁ , , ｨ CH 3 Cl [5] ｨ ｨ 59754,8 ｨ ｨ ｨ , ｨ ; ｨ ｨ 59754,5 ｨ 5 [5]. sat(ch3cl), sat(ch3cl), sat(ch3br), Kr, 3L 7,5 5,, Kr, 3L,,4,6,8,,, CH 3Cl, 3L ﾀ ｨ CH 3 Cl 9 CH 3 Br, , 59459ｨ 553 ｨ [5]: (a) ｨ ｨ CH 3 Cl Kr CH 3 Cl, ML, () ｨ ｨ CH 3 Br CH 3 Br, ML, () ｨ CH 3 Cl CH 3 Cl ML , ｨ ,,8,4, ｨ 59754, ｨ ｨ 59754, ｨ 5

33 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 CF ﾁ ｨ F 7 9 CF ｨ ｨ 59754, ｨ 4ｨ ｨ ｨ ,8 9 8 ｨ 5 [9, 6]. ﾀ ｨ F 7 9 CF3 7, ｨ F 7 [9, 6 5 8] (798. 9) ﾁ F ｨ [9, 6]. 縺935993, ｨ CF 4, 67595ｨ , ; [9, 3], ﾀ , ｨ , ﾀ5ｨ ｨ ｨ ﾁ ﾁ59 854ｨ CF ｨ F 7 99 F CF CF 3 9 CF ｨ ﾁ957. ﾀ5ｨ F ｨ CF 4, CF ｨ ｨ [9, 6]. ﾀ79 ｨ CF ｨ , 9 ｨ ｨ ﾁ ｨ ﾁ CF 3 I [9] ( ｨ ). 4ｨ ｨ ｨ ｨ ｨ ｨ 5 [9]. ﾀ ｨ I 7, ｨ CF3 7 9 F ﾁ , 5953ｨ ｨ I ｨ , F CF ﾁ I CF 7 3, ｨ ｨ ｨ ｨ F ｨ ﾀ5858 ｨ ｨ ｨ ﾁ (Ar, Kr, Xe) , ｨ 縺 , ｨ ｨ 9358ｨ 75459, (, 9 ) , ｨ ｨ , F 7 /CF 4 CF 7 3 /CF 4 F 7 /CF ｨ 59754, ｨ ｨ 59 ｨ CF (a), () () ﾁ8 [9, 6]. ﾀ ｨ ｨ 989 F 7 (a), () 9 CF3 7 () , ｨ ｨ 縺98ｨ , , ｨ ｨ ｨ 9 ｨ ｨ ｨ , 654, ｨ , ｨ ｨ ｨ ｨ 縺935993, 395 ｨ , ｨ , , CH 3 X, 345 X , C 5 X, ｨ ｨ 縺359445, ｨ ﾀ5ｨ 953, ｨ ML ( ), ｨ [3, 3]

34 閨75, 縺5 [ , , ｨ ﾀ ｨ ﾀ ｨ ｨ ｨ ｨ , ｨ ｨ ﾁｨ , ｨ , ｨ , , 85ｨ , 578ｨ ｨ ｨ ｨ , , , , , ｨ ﾀ ｨ ｨ ｨ ｨ [33, 34]. 5 ｨ ﾁ , ﾁ , , ﾁ ﾀ ﾁ99, ｨ ﾁ ﾁ , ｨ , ｨ , 345 ﾁ , ｨ , , ﾀ79 ｨ 953, , , , ｨ , , , , , ﾁ , , ｨ , 995, O, F, Cl, 99ｨ , , , , ｨ ｨ, ｨ ｨ ｨ [33]. ﾀ , ｨ , ﾀ ｨ AlCl 3, ﾀ5858 Cl 9 Cl ｨ 9 4 ﾁ , ｨ , CCl 4 99 CHCl 3 57, , ｨ , Cl 9 Cl Al , Cl, Cl 9 Al, ｨ , ｨ ｨ. 縺935993, ｨ , 355 CCl ｨ ｨ ﾀ ｨ , ｨ CCl ｨ ｨ , ｨ ｨ ｨ ｨ ｨ ｨ 5 ｨ ｨ , , ｨ 3ｨ , ﾀ5ｨ ｨ , , ﾀ ｨ ｨ ｨ , ｨ , , , ｨ Massey H S W Negative Ions (Cambridge, New York: Cambridge Univ. Press, 976). Smirnov B M Negative Ions (New York, London: McGraw Hill, 98) 3. Illenberger E, Momigny J Gaseous Molecular Ions: An Introduction to Elementary Processes Induced by Ionization (Darmstadt: Steinkopf Verlag, 99) 4. Schulz G J Rev. Mod. Phys (973) 5. Caledonia G E Chem. Rev (975) , (985) 7. Oster T, Ku6 hn A, Illenberger E Int. J. Mass Spectrom. Ion Proc. 89 (989)

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Phys. B 4 53 (97) 4. Allan M J. Electron. Spectrosc (989) 5. Ayotte P et al. J. Chem. Phys (997) 6. Weik F, Illenberger E J. Chem. Phys (995) 7. Illenberger E Chem. Phys. Lett (98) 8. Le Coat Y, Ziesel J-P, Guillotin J-P J. Phys. B (994) 9. Mann A, Linder F J. Phys. B (99) 3. Cristophorou L G, Olthoff J K, Rao M V S S J. Chem. Phys. Ref. Data 5 34 (996) 3. Marsh E P et al. J. Chem. Phys. 9 4 (99) 3. Rowntree P A, Scoles G, Ruiz-Suarez J C J. Phys. Chem (99) 33. Lieberman M A, Lichtenberg A J Principles of Plasma Discharges and Materials Processing (New York: Wiley, 994) 34. Plasma Science: from Fundamental Research to Technological Applications (Washington, D.C.: National Academy Press, 995) Electron attachment to atomic systems E. Illenberger Institut fu6r Physikalische und Theoretische Chemie, Freie Universita6t Berlin, Takustrasse 3, D-495 Berlin, Germany [email protected] B.M. Smirnov Institute of High Temperatures, ul. Izhorskaya 3/9, 74 Moscow, Russia [email protected] Electron attachment to diatomic and complex molecules, as well as to complexes, clusters, bulk particles, and surfaces is considered. The relevant theoretical concepts involving the formation of autodetachment states in negative ions, are presented. Experimental data on electron attachment parameters are analysed from a general theoretical viewpoint. PACS numbers: 34.8.Lx, q Bibliography 4 34 references Received 8 January 998