閨75, 縺5 [ ｨ ﾁ573, 縺 ｨ ｨ
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1 39ｨ , 7 86 ﾀ 縺48 縺 ﾀ5 縺473 ﾀ ｨ , ｨ , , 89573, ﾀ ｨ , ｨ PACS numbers: 34.8.Lx, q (73) (73) ｨ ﾀ ｨ (739). 3.. 縺 ｨ ｨ ﾁ ﾁ ｨ ｨ ﾀ ｨ ﾀ ｨ ﾀ ｨ ﾀ ｨ (749) ｨ ｨ 59 ｨ ｨ ﾀ ｨ ﾀ ｨ (757). 5.. ﾀ ｨ ｨ ﾀ ｨ 縺 ｨ ﾀ ｨ ﾁ , , , 閨 iln@chemie.fu-berlin.de , , /9, smirnov@termo.msk.su ｨ (764) (764) ﾀ ｨ , 89573, ｨ ｨ ｨ ｨ 縺 ｨ ｨ , ｨ ｨ 9 ｨ ﾀ ｨ ｨ ﾁ ﾀ ｨ ﾁ ﾁ ﾀ ｨ ｨ 縺 ｨ ｨ ﾀ5854ｨ 59 ｨ 5ｨ 99 ｨ , ｨ 3ｨ ｨ , ｨ , ｨ ｨ ｨ ｨ , ｨ ｨ ｨ , ｨ , , , , 89575, , # ,
2 閨75, 縺5 [ ｨ ﾁ573, 縺 ｨ ｨ ｨ ﾀ5ｨ ｨ ｨ ｨ ｨ ｨ ｨ , ｨ 9 98 ｨ ｨ ﾀ ｨ [ 5 3] [4 5 ] ｨ ｨ [9, ], [9] , ｨ [9]. 縺 ｨ , ｨ ｨ V e R V e ﾀ ｨ ｨ ｨ ｨ ｨ ﾁ , 345 R , , 67595ｨ , [,, ]. 縺 縺 , ｨ ｨ ｨ ｨ 94574ｨ ﾁ499 ｨ C ｭr; R6 9 ｷ3 c ｭr; R6 9F ｭR6 9 ; ｭ: r ｨ , R , c ｭr; R6 9 ｨ ﾁ499, 5957ｨ R ｨ , F ｭR ﾁ ｨ , ｨ 45739ｨ e ｭR6 9 ｨ e ｭR6 9 ｷ3 E ｭR6 9 6ｦ ig ｭR6 9 ; ｭ: ｨ ｨ E ｭR G ｭR , 縺 ｨ ｨ ｨ e 6ｦ A! ｭA ｭ:36 9 V R R ｨ , ｨ ｨ ｨ ﾁ499 ｨ ｨ ｨ e ｨ 59754, A , ｭA , ｨ 5ｨ 95779ｨ , 67595ｨ ｭA 7 6 9, 縺 : t e 5 h G ; t e 5 o : ｭ: t e ｨ 59754, ho ｨ , 578ｨ ｭA , , ho ｨ 縺935993, hg 9 =o ｨ G ho, e
3 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 ﾁ , ｨ 59754, , , 67595ｨ ﾀ ｨ ｨ : e 6ｦ A! ｭA 7 6 9! e 6ｦ A : ｭ: ﾀ755887, 67595ｨ ｨ ﾀ ｨ ｨ ｨ ｨ e 6ｦ AB! ｭAB 7 6 9! e 6ｦ AB e 6ｦ AB ｭv6 9! ｭAB 7 6 9! e 6ｦ AB ｭv 6 9 e 6ｦ AB! ｭAB 7 6 9! A 7 6ｦ B A 7 6ｦ B! ｭAB 7 6 9! e 6ｦ AB e 6ｦ AB! ｭAB ; ｭAB ｦ C! AB 7 6ｦ C 5 ｨ ｨ ﾁ ﾁ ｨ , 9 ｨ ｨ ｨ ｨ e 6ｦ AB ｭv ｷ3 6 9! ｭAB 7 6 9! e 6ｦ AB ｭv6 9 ; ｭ: v ｨ , ｨ , (.3) ｨ , ｨ N ｨ ｨ ｨ , ｨ ｨ ｨ ﾁ ﾁ ｨ 45739ｨ ｨ ｨ ﾁ ﾁ ｨ ﾀ75588, ｨ ｨ , e 6ｦ XY! ｭXY 7 6 9! X 6ｦ Y 7 : ｭ: ｨ ｨ ﾀ ｨ ｭXY ｨ R, , R c ｨ ﾀ R > R c t R c 7 R v a c ; ｭ: R c 7 R A v a (49 ｨ ﾁ ) , 縺935993, 395 ｨ , (9. ) A 7 6ｦ B! ｭAB ; ｭAB ｦ C! AB 7 6ｦ C : ｭ: ｨ AB ｭAB 7 6 9, C. ﾀ5ｨ , , 578ｨ [] N, O 7 4 CO 7 3 CO 7 4 NO 7 CO O 7 H O O 7 ｭH O6 9 NO 7 H O Cl 7 H O Br 7 3 * T ｷ3 K.,3,3* 3 8 *,4 3* O He CO He He CO O He Ar O O NO NO Br 6 7,4,, 3,6,5,,5,,,7
4 閨75, 縺5 [ , ｨ , ｨ 5ｨ ﾀ ｨ e 6ｦ SF 6! ｭSF ! e 6ｦ SF 6 : ｭ: ｨ ｨ SF ; ; ｨ ｨ [ 5 ]. 縺 ｭSF ｨ ｨ , K , 589 ｨ , 67574ｨ 59, ｨ 5, , ｨ 縺935993, ｨ ｨ [] , ｨ ｨ ｨ ｨ , ｨ 8949ｨ ｨ ｨ ｨ , 578ｨ ｨ 縺 R m 54 ﾁ9-379ｨ 9457, ｨ 8 89 ｨ 59754, 9 R 7 54 ﾁ9379ｨ 9457, ｨ 5ｨ ｨ ｨ EA. 縺359445, 54 ﾁ R m ﾁ , ｨ ｨ e ｨ , ｨ EA 6ｦ e ｨ ｨ 45739ｨ 3557, ﾁ R m 45 R ｨ 95579ｨ RRKM ﾁ5735 [35] , ｨ ｨ ｨ 45739ｨ, t EA ｭR6 9> n ｭR6 9 dr t ｷ3 t ; n ｭR6 9 dr 6 7EA ｭR6 9< 345 n ｭR , t ﾁ 縺359445, 395 ｨ , 9.5. t ﾀ5858 t=t 8 7 9, ｨ ｨ 5ｨ 554: n ｭR m 6 9 t ｷ3 t n ｭR : 縺 , ﾁ ｨ ｨ , 59579, 85ｨ , ｨ , ｨ [36], o ｨ , ｨ p ｷ3 E= ｭho6 9, 345 E 6549 ｨ ﾀ n ｷ3 ｭp 6ｦ s 7 6 9! p! ｭs 7 6 9! ; t ( 75 8) , ｨ ｨ (N ｨ ) 355 N t 355 N t SF 4 SF 6 CH 3CO C 4F 6 c-c 4 F 6 C 6F 6 C 4F 8 c-c 4 F 8 C 6F 5Cl C 6F 5Br C 5F 8 c-c 5 F 8 C 6H 5CN C 6F 5CN C 6F 5CHO C 6H 5NO ,7 [3];,6 [4],5 [4, 5]; 6,8 [4];, [6], [4] 6,9 [7];,6 [8], [8], [7];,3 [9], [7]; 3, [8],5 [8, 3],8 [3], [3] 5 [7],7 [8],5 [3],7 [3] 3,6 [3] 4 [5]; 4,7 []; 4,9 [8];,8 [3] C 6D 5NO m-c 6 H 4 ClNO C 6H 3F NO C 7F 8 C 6F C 5F n-c 5 F C 6H 4CH 3NO C 6F n-c 6 F C F 8 C H 8 C D 8 C H 6O C 6H 3(CH 3) NO C 7F , [3] 4,7 [3] 4,7 [9], [7]; 3,8 [9] [7],3 [8] 3,4 [8] 3, [9] 4 [7] 4 [8] [3],8 [3];,7 [33],8 [3] 35 [34], [9] 79 [6]
5 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 s T ﾁ5735 ﾀ4 s p ｷ3 exp ho T 7 : p i p f , ｨ p i ho 6ｦ EA 6ｦ e ｷ3 p f ho : , ｨ ｨ e 9 EA ｨ 59754, 9.5. ｨ ｨ 縺98ｨ ｨ 95, p i 4 s; p f 4 s, , ｨ p i ho ｷ3 st, 9 ln t t 7 ｷ3 EA 6ｦ st sho ; p f ｷ3 s ln t 7 6ｦ p i : t , C 7 F EA ｷ3 ;7 ;3 ｨ 5 [37] t ｷ3 38 ( ) ho C 6 F EA ｷ3 ;4 ;3 ｨ 5 [37] t ｷ3 38 ( ), ho ｨ T ｷ3 3 K ｨ ｨ ｨ ｨ e ｷ ﾁ ﾁ t ｷ3 C exp T ho : ﾀ C 7 F 8 9 C 6 F ho 5 T , ｨ , K ｨ C 7 F C 6 F, ﾁ 縺935993, ｨ 縺 , 45 ｨ ｨ 45739ｨ 8989 ｨ ｨ , ｨ , , , , [38] K ｭ55p6 9 6ｦ CF 3 Cl! K 6ｦ 6ｦ CF 3 6ｦ Cl 7 ; K ｭ55p6 9 6ｦ CF Cl! K 6ｦ 6ｦ CF Cl 6ｦ Cl 7 : 534 ｨ , , Cl , Cl , , ﾀ CCl [39] ｨ ｨ , CCl CF 3 I [4] , ｨ ｨ ﾀ ｨ ｨ ( ). 縺 ｨ ﾀ ｨ ﾁ s cap ｭR6 9 ｷ3 ph m e e G ｭR6 9 e 7 E ｭR6 9 6ｦ G ｭR6 9=4 : ｭ: R ﾁ9379ｨ 9457, e ｨ ｨ , E ｨ ｨ , G 縺98ｨ ｨ ｨ ｨ k cap ｷ3 hvs cap i ｷ3 p p h G ｭR6 9 ｭ m 3= e Te 3= exp 7 e T de e G ｭR6 9 7 E ｭR6 9 6ｦ 4 7 ; ｭ: ｨ ﾁ , ｨ 縺359445, ｨ ｨ 9 83ｨ, 534 ｨ ｨ ｨ , ｨ E 5 T ｨ
6 閨75, 縺5 [ k cap ｷ3 p p h me 3= Te 3= ｭ G e 6ｦ G =4 exp 7 e de : T = p k cap ｷ3 h G ｭR6 9 ; G 5 T ; ｭ:3a6 9 m e T e k cap ｷ3 4 p p h ; G 4 T : ｭ:3b6 9 me 3= Te = 9573 (.3) ｨ ｨ ﾀ , , ｨ 9 ﾁ k cap ｷ ｨ , ｨ 縺935993, ｨ ｨ ｨ ﾀ ｨ ﾀ79 37 ｨ ｨ s ｨ ｨ ﾁ ﾁ ﾁ , ｨ s- ﾁ ｨ 59754: s cap ｷ3 ph m e e sin d c ; 345 d c ﾁ8 s , ｨ , ｨ ｨ s cap 4 ph m e e ｨ k cap 4 4 p p h ; me 3= Te = ｨ ﾁ5735 (.3), , ﾁ573 (.3) ｨ , 589 ｨ ｨ ｨ ｨ 95 ﾁ5735, ｨ , 99ｨ ｨ ﾀ A 6ｦ B! A 6ｦ 6ｦ B 7 : ｭ: A ( ) , (.4) ｨ ｨ B (.4) (.5) ｨ A. ﾀ x ｷ3 ade hv 4 ; ｭ: DE ｨ ｨ 59754, a ｨ , ｨ 989, v DE ｷ3 Ry=n 3, 345 n , Ry=3,6 ｨ , a n a ( l 5 n, 345 l ｨ 59754) , 679 v 4 e hn ｭ: ｨ ｨ , , , (.4) n , (.6), n (.4) ｨ B, 65ｨ ｨ ｨ ｨ 59754, [4 5 47] (.4) , 975 ｨ SF 6 9 CCl ｨ ｨ k chem ｭSF ｷ3 ｭ4; ; , k chem ｭCCl ｷ3 ｭ ﾀ (.5) 9 (.4) 78475, ｨ ｨ ( ) (.) A 6ｦ SF 6! A 6ｦ 6ｦ SF A 6ｦ CCl 4! A 6ｦ 6ｦ CCl ( l ｨ 59754) 3953 A * Xe( f) Rb(s) Rb(d) K(d) Na(p) K(d) K(p) Ne(s) k chem (SF 6) k chem (CCl 4) 687 4,,3 3,5,5 [4] 4,3,7 [4] 4,,4 [4] 4,,6 4,,5 [43] 4,4,4 [44] 4,5,5 7 [45] 4,,5 [46] 4 5 [47]
7 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 , ｨ t ｷ ﾁ (.) ｨ 59 94: C ｭR; t6 9 ｷ3 X f j F j ｭR6 9 exp 7 ie jt ; ｭ:76 9 h j 345 F j ｭR ﾁ499, ｨ - 59 j ｨ 9457, E j ｨ ｨ , R , f j ｨ j ｨ ﾁ [] f j ｷ3 p h m e e S j G= e 7 E j 6ｦ ig= : ｭ: e ｨ ｨ 59754, m e 388 ｨ 59754, E ｷ3, G , S j ﾁ ﾁ H ﾁ , , pjf j j ｨ ﾁ499, ｨ ﾁ573 (.8) f ｷ h G= p m e e e 7 E 6ｦ ig= ; ｭ: E ｨ ｨ ( ｨ ). 縺98ｨ ｨ s cap ｷ3 p G k ｭe 7 E6 9 6ｦ G =4 ; ｭ:6 9 p 345 k ｷ m e e=h ｨ (.5) ｨ : G ｷ3 G e 6ｦ G neg, 345 G e ｨ ｨ ｨ , G neg ｨ ｨ ｨ s at ｷ3 p G neg k ｭe 7 E6 9 6ｦ G =4 : ｭ: (.9), ｨ ｨ 545ｨ ﾁ49ｨ 53949ｨ , , ｨ , 9. 68, ｨ (.) , (.9) ﾁ573-5 (.) ｨ k at k chem k at k chem ｷ3 G neg G : ｭ:6 9 縺935993, ｨ ｨ , ｨ , ｨ ｨ 59754, ｨ ｨ ｨ ｨ ｨ ｨ ｨ , , n ｷ (.5) (.6) ｨ , 679 ｨ n ｨ SF 6 9 CCl , 縺 , ｨ SF ｨ ｨ e < 3ｨ 5, n ｨ ｨ ﾁ ﾁ n, ｨ ﾀ5854ｨ ｨ ｨ ｨ , 縺 ｨ ｨ ｨ ｨ ｨ ﾁ ﾁ59954, ﾀ5 ｨ ｨ ｨ ｨ ｨ
8 閨75, 縺5 [ , ｨ ｨ ｨ 5, , ｨ ﾁ ﾁ ｨ ｨ ﾀ5 ｨ ｨ ｨ ｨ 45739ｨ ｨ ｨ ｨ ﾁ ﾁ CO -8575, ｨ ｨ ｨ ｨ ﾁ ｨ [48] ｨ (.4), ｨ ﾀ5854ｨ ｨ ﾁ ﾁ ( , [49]), , ｨ h=g =o, 345 ho ｨ , 5957ｨ ｨ ﾁ49ｨ ｨ ｨ ﾁ49ｨ ﾁ5735 (.7) ﾁ ｨ 59754, ｨ s cap ｷ3 4p X F j ｭR6 9jC ｭR; t6 9 X ｷ3 4p jf j j ; ｭ:36 9 j j 345 F j ｭR ﾁ , R 縺 j k ｭR ｨ 545ｨ ﾁ49ｨ 3557, ﾁ C mol ｭR; t6 9 ｷ3 X f j S jk j k ｭR6 9 exp j;k 7 ie kt h ; ｭ: S jk ｷ3 hf j ｭR6 9jj k ｭR6 9i. 縺98ｨ k , t , s k ｭt6 9 ｷ3 4pjhj k ｭR6 9jC mol ｭR; t6 9ij ｷ3 ｷ3 4p X f j f j S jks j k j k ｭR6 9 exp 7 i ｭE j 7 E j 6 9t : h j; j ｭ: ﾁ573 (.5) t 45 t 6ｦ dt 745 G dt h exp 7 Gt h : 縺935993, G ﾁ ｨ 95 ﾁ5735 (.5), ｭ s k ｷ3 s k ｭt6 9 G dt h exp 7 Gt ｷ3 4p X f j f j h S jksj k j; j G G 6ｦ i ｭE j 7 E j 6 9 : ｭ: ﾁ (.8) ﾁ ｨ ｨ , 589 ｨ [48], s k ｷ3 ph X GS js jk m e e e 7 E j; j j 6ｦ ig= G G 6ｦ i ｭE j 7 E j 6 9 : GS j S j k e 7 E j 7 ig= ｭ: ｨ 9 ﾁ ﾁ57549ｨ ｨ ｨ 95 ﾁ , X S mj S jk ｷ3 X jm ｭR6 9jF j ｭR6 9 F j ｭR6 9jj k ｭR6 9 ｷ3 j j ｷ3 j m ｭR6 9jj k ｭR6 9 ｷ3 d mk ; ｨ ｨ 59754: s cap ｷ3 X k s k ｷ3 ph X m e e ｭe 7 E j 6 9 6ｦ G =4 ; G 4 DE ; j; j jgs jj ﾁ5735 (.3) DE G ﾁ , 9 395, G G 6ｦ i ｭE j 7 E j 6 97 ﾁ5735 (.8) d jj, ｨ 9 ﾁ s k ｷ3 ph X m e e j G js j j js jk j ｭe 7 E j 6 9 6ｦ G =4 ｷ3 X j s ｭj6 9 cap js jkj ; G 5 DE ; ｭ: s ｭj6 9 cap ｨ j j , ｨ ｨ , 9 9 ｨ ｨ , ﾁ 縺 R 94574ｨ , ｨ , 9 R j j , ｨ E ｭR j 6 9 ｷ3 e, 345 E ｭR
9 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 ｨ ｨ ﾁ [5] s ho F j ｭR6 9 ｷ3 E d ｭR 7 R j 6 9 ; ｭ:96 9 ｭR j E ｭR j ho ｨ 縺98ｨ s ho S j ｷ3 E j ｭR j 6 9 ｭR j 6 9 : , 395 dj ｷ3 de j = ｭho6 9 ｷ3 E ｭR j 6 9 dr j = ｭho6 9, ｨ ｨ ﾁ5737 (.7) [48]: s k ｷ3 ph m e e ｭ dr dr G 3 ｭR6 9j ｭR6 9j ｭR 6 9j k ｭR6 9j k ｭR 6 9 e 7 E ｭR6 9 6ｦ ig ｭR6 9= e 7 E ｭR ig ｭR 6 9= G ｭR6 9 6ｦ ie ｭR6 9 7 ie ｭR 6 9 : ｭ: ｨ 9 ﾁ (.3) , 598ｨ ｨ ｭ s cap ｷ3 ph drg ｭR6 9jj ｭR6 9j m e e e 7 E ｭR6 97 ｭ:36 9 6ｦ G ｭR6 9= ﾁ 縺 X j k ｭR6 9j k ｭR 6 9 ｷ3 d ｭR 7 R 6 9 ; k ﾁ49 fj k g , ｨ , ｨ , 395 ｨ ｨ ( 縺 ) 9 ｨ ﾁ ｨ ﾀ ﾁ ｨ ﾀ ｨ 縺 ｨ ﾀ ｨ : e 6ｦ AB! ｭAB 7 6 9! A 7 6ｦ B : ｭ3: ｨ ｨ ﾁ57339 (.), (.3): ｭ s cap ｷ3 ph drg ｭR6 9jj ｭR6 9j m e e e 7 E ｭR6 97 6ｦ G ｭR6 9=4 ; ｭ3: R , , R ; , ｨ 59754, ﾀ79 ｨ ｨ ﾀ ｨ ｨ 989, R c ﾀ5ｨ : G ｭR6 9 ｷ3 G e ｭR6 9 6ｦ G neg ｭR6 9, G e ｭR6 9 ｷ3 G ｭR6 9 7 exp 7 G neg ｭR6 9 ｷ3 G ｭR6 9 exp 7 ｭ Rc R ｭ Rc R G ｭR 6 9 dr hv R G ｭR 6 9 dr hv R ; : ｭ3: G e ｨ ｨ ｨ , G neg ｭR , , v R ｷ3 dr= dt ｨ exp ｭ G dt=h , ｨ ｨ ﾁ5737 (.). 縺 ｨ 縺 ﾁ5737 (.8), G ｭR ｨ 59754, (3.), ｭ s at ｷ3 ph G ｭR6 9jj dr ｭR6 9j m e e e 7 E ｭR6 97 6ｦ G ｭR6 9=4 ｭ Rc G ｭR 6 9 dr exp 7 ; ｭ3:46 9 R hv R 345 R ｨ 95 ﾁ ｭ s at e de ｷ3 p h ｭ Rc G ｭR 6 9 dr G ｭR6 9 exp 7 : m e R hv R ｭ3: R 89 ｨ ﾀ ﾁ573 (3.4) G 5 de dr DR ; ｭ3:66 9 3*
10 閨75, 縺5 [ DR ﾁ5735 (3.4) G ｭR6 9 p e 7 E ｭR6 97 ｷ3 d e 7 E ｭR6 97 ; 6ｦ G ｭR6 9=4 9 ｨ 9 ﾁ s at ｭe6 9 ｷ3 p h G ｭR e 6 9 m e e jj ｭR e 6 9j ｭ Rc de= dr exp G ｭR 6 9 dr 7 ; R e hv R ｭ3: e ｷ3 E ｭR e , ﾁ jj ｭR6 9j ｷ p exp 7 ｭR 7 R 6 9 p DR DR ; ｭ3: R , DR ﾀ (3.6) ﾁ573 (3.7) 459 s at ｭe6 9 ｷ3 s max exp 7 ｭe 7 e 6 9 ｭDR de= dr6 9 : ｭ3:9a ｨ ｨ e ｷ3 E ｭR s max ｷ3 p3= h G ｭR 6 9 m e e DR de= dr exp ｭ 7z6 9 ; ｭ3:9b z ｷ3 ｭ Rc R G ｭR6 9 dr hv R : ｭ3:9w , G R 9 E ｭR ﾁ E ｭR6 9 ｷ3 e ｷ3 de dr ｭR c 7 R ﾁ573 (3.9) 459 s max ｷ3 p3= h m e e 345 s m ｭR c 7 R 6 9 t ｷ3 de= dr G ｭR c 7 R 6 9 exp 7 Gt ; ｭ3:6 9 DR h 9 m ｨ R c , ｨ ｨ , (3.) ｨ G Gt ｷ p 3= h s max ｷ3 p e m me e 3= DR ｷ3 ;4h p m me e 3= DR : ｭ3:6 9 ﾀ5858 DR m 7=4, ﾁ s max m 7= e , ｨ ｨ , ｨ ｨ ｨ , ｨ (R c > R ) ﾁ , ﾁ4-95 ｨ ｨ 59754, ｨ (798., ) ﾁ5735 (3.5) ｨ G 5 T e : k at ｷ3 p = p T e p ｷ3 m e T e ｭ s e p 7 7 s at ｭe6 9 e exp 7 e de ｷ3 T e m e 3= h G ｭR6 9 exp 7 E ｭR6 9 7 z ; ｭ3:a6 9 T e ｨ ｨ E ｭR6 9 ｨ ER DR 4 T e ｨ 8 DR. 7534, G ｭR ｨ E ｭR6 9 T e, 98 ﾁ5737 (3.a) ｨ k at ｷ3 h p m e 3= Gj ｭR6 9 p exp ｭ 7z6 9 ; ｭ3:b6 9 T ee R 345 ｨ R , ﾁ ｨ 59754, ｨ ﾀ ｨ ｨ ﾁ ﾁ ｨ ﾀ ﾁ5737 4ｨ ｨ ｨ ｨ ﾁ ﾁ59, [5] [5]. ﾀ ﾁ95753, ﾁ5735 (3.4) , P ｷ3 exp ｭ 7z6 9 ; z ｷ3 ｭ Rc R G ｭR6 9 dr hv R : ｭ3: z m 7=, 345 m , p m P ｷ3 ｭP 6 9 =m : ｭ3:46 9
11 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 m ; m , P ; P ｨ ｨ ﾁ ﾁ , , ｨ ﾁ ﾁ , ｨ ｨ [ ] s at ｭH 6 9 ｷ3 ｷ3 ;6 7 83, s at ｭHD6 9 ｷ3 ; s at ｭD 6 9 ｷ3 ｷ 縺98ｨ z ｷ3 3;, ﾁ573 (3.4) s at ｭH 6 9=s at ｭHD6 9, z ｷ3 ; s at ｭH 6 9=s at ｭD z ｷ3 ; s at ｭHD6 9=s at ｭD ｨ s cap ｷ , 縺98ｨ ｨ 5, H ｭ S 6ｦ u 6 9 [ ], ｨ ｨ ｨ HX, 345 X , ｨ 959 ｨ ﾁ ﾁ59 855, ｨ ｨ ﾁ ﾁ ｨ z ﾁ5735 (3.9) s cap. 7 ﾁ ﾁ G eff ｷ3 6 7 s at ｭe6 9 de=s max. 9445, ｨ z 4975, , ｨ ﾁ ﾁ 縺935993, HI 9 DI ｨ ｨ , 9, , ﾁ5737 4ｨ ｨ ｭ3; ; ｭ; ; HI 9 DI [59] [5] ｨ HI T ｷ3 3 K 74 3; HBr 3; T ｷ3 55 K ﾀ ｨ HX 9 DX (X ), [54] 355 s max, A x, ｨ 5 A s cap, A z G ef, ｨ 5 NCl DCl HBr DBr HI DI,8, 4,, 3 4,78,6,,7 3,7,6,5, 7 76,5 5,,4,,9,6, ｨ ｨ ｨ ｨ ｨ ｨ ｨ ｨ 59 ｨ ﾀ898 m , m B (3.), e ｨ ｨ 5535 ｨ e 7 ｨ ｨ m e 7 D 6ｦ EA ｷ3 e 7 ; ｭ3:56 9 m 6ｦ m D ｨ AB 9 EA ｨ A ｨ (3.5) ｨ ( (83. [, ]).) ｨ , ｨ , ｨ (3.) ｨ ｨ e u ｨ x , ｨ ｭv 7 7 u x 6 9 6ｦ u r 7=, 345 u x, u r , ﾁ5735 (3.5) s ｭm 6ｦ m v 7 ｷ3 ｭe 7 D 6ｦ EA6 9 : mm v 4 u, ｨ ﾀ5ｨ ﾁ5735 r m 6ｦ m 7 f ｭu x 6 9 ｷ3 exp 7 ｭm 6ｦ m 76 9u x ; pt T 345 T , ｨ v ｷ3 v 7 7 u x, 598ｨ ｨ ｨ e 7 ｷ3 m 7 v = r m 7 f ｭv6 9 dv ｷ3 exp 7 ｭ p p e 7 7 e 6 9 pt T dv ; ｭ3: ﾁ e ｷ3 m 6ｦ m 7 ｭe 7 D 6ｦ EA6 9 m ｨ ｨ 縺7345 e 4 T 9 ﾁ p ﾁ e T, ｨ 9565ｨ ｨ 45739ｨ ﾁ ｨ ｨ , (3.), ｨ ｨ (3.5) , ｨ ｨ 59754, ｨ [6 5 64], ｨ ｨ [6 5 64] ｨ (3.) ｨ ｨ ｨ ｨ , ｨ 959
12 閨75, 縺5 [ ｨ ｨ , ｨ ｨ , ﾁ ｨ ｨ ｨ 64ｨ ｨ , e 6ｦ O! ｭO 7 6 9! O 7 6ｦ O ｭ3: , a b d e f c g h i ｨ 59754, ｨ 5 a O 7 =O j f 679 ｨ ｨ ｨ P g 9 P u. 89 ｨ ｨ , ｨ ｨ ｨ e ｨ s at ｨ s g 9 s u, 67595ｨ P g 9 P u [65] e, ｨ 5 s at s g s u 6934, b c d e g h j i 5,75 6,7 7,8 8,4 9, 3,7 5,7, ﾁ ｨ , (3.7). 5 ｨ ｨ [7, 8]. 縺 ｨ ﾁ , 5843ｨ 5ｨ, P g 9 P u. 655, ｨ ｨ O ｨ ｨ 59 ｨ ﾁ5735 (3.5), ﾀ5753 ｨ ｨ ｨ e ｷ3 3; 66 ｨ 5, ｨ D ｷ3 5; ｨ ｨ EA ｷ3 ; 46 ｨ ﾁ573, 8987ｨ ｨ , , , ｨ ｨ ｨ e max, ﾁ573 (3.5) G exp ｭ 7z6 9 ｷ3 m e e max p h ｭ s at ｭe6 9 de :,,,4,7 7,9,4 4,3,7 縺98ｨ ; 7 ｨ 5 G exp ｭ 7z6 9 ｷ3 ;9 3ｨ [66] 9 G exp ｭ 7z6 9 ｷ3 3; 3ｨ ｨ [67]. ﾀ (3.7) ｨ ｨ , O 7, ｨ 5 3,,5,,5,, , 38 DH a b c d e O ｭp 4 6 9, ｨ ｨ ﾁ ﾁ ﾁ ｨ ｨ O ｭs g s u p g p u 6 93 S g, s; p ｨ ｨ 588, g, u 5843ｨ ｨ ｨ ﾁ ｨ ｨ ｨ , f g h ｨ 59754, ｨ ﾀ ｨ : (a) ｨ O 7 ( ｨ ｨ 59754, ); () O 7 ; () ｨ O 7, , ﾁ499 ｨ ｨ i
13 37. 68, 7] ﾀ599 ﾀ 縺43 65 縺4 縺 縺 縺 ｨ ｨ 5553 O 7 ｭs g s u p3 g p u 6 9 P g ｨ 9535 ｨ v ｨ , ｨ ｨ ｨ ｨ ｨ ｨ ｨ 5 4ｨ ｨ : e 6ｦ O ｭs g s u p g p u 6 93 S g! 7 O 7 ｭs g s u p g p3 u 6 9 P u!! O 7 ｭ P6 9 6ｦ O ｭ 3 P6 9 ; ｭ3:8a6 9 e 6ｦ O ｭs g s u p g p u 6 93 S g! 7 O 7 ｭs g s u p3 g p u 6 9 P g!! O 7 ｭ P6 9 6ｦ O ｭ 3 P6 9 : ｭ3:8b ｨ ｨ ｨ ｨ ｨ , 9 65ｨ ｨ , (3.8) 555 ｨ ﾁ ﾁ59954, (3.8). 縺 ｨ ｨ ｨ , , ｨ ｨ S 6ｦ g, S 6ｦ g s-ｨ 59754, ｨ ﾁ ｨ ｨ ｨ [68] , ｨ ｨ , , , ｨ , ｨ ｨ ｨ [69] ｨ , ｨ ﾁ499 ｨ ｨ [7]. 9445, ｨ ｨ 45739, ｨ ｨ ｨ [68, 7, 7]. ﾀ CO [7 5 74], ｨ ｨ ｨ K [75]. sat, 78 83,,75,5,5,,75,5 93 K 475 K 3 K T ｷ3 3 K ｨ ｨ [68] (l ｨ 59754, m ｨ 588, y ｨ ｨ ｨ 59754), e, ｨ H ( S 6ｦ g ) H ( S 6ｦ g ) O ( 3 S 7 g ) O ( S 6ｦ g ) O (A 3 S 6ｦ u ) H 7 ｭ S 6ｦ u 6 9 H 7 ｭ S 6ｦ g 6 9 O 7 ｭ P u 6 9 O 7 ｭ P u 6 9 O 7 ｭ P u ｨ l m ｨ ｨ 縺359445, , ｨ ｨ ｨ cos y const sin y sin y sin y ｨ ﾁ499 ｨ ｨ [7] , , ｨ , , ｨ ; 78 83, 縺935993, K 9585 % ｨ ｨ ｨ ｨ ｨ ﾁ ﾁ
14 閨75, 縺5 [ ｨ O ｭ D g , (3.8a) ｨ : e 6ｦ O ｭs g s u p g p u 6 9 D g! 7 O 7 ｭs g s u p g p3 u 6 9 P u!! O 7 ｭ P6 9 6ｦ O ｭ 3 P6 9 : ｭ3:9a6 9 縺935993, ﾁ93799 ｨ S g D g (3.9a) ｨ ｨ (3.8a) ｨ 5 (ｨ O ｭ D g 6 9) ｨ ｨ 59754, , (3.8a) [ ] , [78] ｨ ; ｨ ,7 ｨ ,7 ｨ 5. 縺98ｨ ﾁ5737 (3.5) hg exp ｭ 7z6 9i ｷ3 4 3ｨ ｨ 縺359445, , ｨ O ｭ D g 6 9, ｨ , ｨ 553 4: e 6ｦ O ｭs g s u p g p u 6 9 D g! 7 O 7 ｭs g s u p3 g p u 6 9 P g!! O 7 ｭ P6 9 6ｦ O ｭ 3 P6 9 : ｭ3:9b ｨ ｨ ｨ ｨ 8 (3.9) ｨ HCl 9 DCl ｨ ; ; [79] HCl 9 DCl 縺98ｨ , HCl 74 ; K ｨ [8] ｨ s max v. 縺 s max ｭv6 9, 65393, s max ｭv ｷ3 6 9=s max ｭv ｷ HCl 9 DCl s max ｭv ｷ3 6 9=s max ｭv ｷ ｨ 縺935993, v ｷ ｨ 59754, , R c , ｨ ｨ ﾀ ｨ , 395 ｨ ｨ , ｨ , ｨ ｨ , ｨ ｨ ﾁ ﾁ599473, ｨ , ｨ ﾀ ｨ ｨ ｨ , ｨ , , ｨ ﾁ ﾁ ｨ ｨ ｨ ｨ e 6ｦ HCl! ｭHCl 7 6 9! H 6ｦ Cl 7 ; ｭ3: ｨ [5 5 54, ] (3.) ;65 ;4 ｨ 5, ｨ ｨ ;78 ;8 ｨ ｨ ,6 ｨ 5 9 ｨ HCl 74 4,3 ｨ 5, ,69 ｨ ,69 ｨ ｨ ,6 A HCl R c , (3.) ｨ (3.), ｨ H 6ｦ Cl 7 9 H 7 6ｦ Cl S, S 9 P. 縺359445, 9585 ｨ S ｨ , E, ｨ 5 3 HCl 7 S 6ｦ S 7 S 6ｦ,,4,8 3, 3,6 HCl H+Cl 7 R, a ﾀ ｨ HCl 9 HCl 7, ｨ HCl [6].
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3379 3. 753 7, 3 86 ﾀ7 9 9989769 438 4 縺4775697 799 ﾀ 99897 ｨｬ 998 67547 4957 ｨ ﾁ ﾁ59 5. 967357 PACS numbers: 67.9.+z, 73.4.Hm (455589 599. 6953583, 4579 998 3.) 654577495. 5545495 (34).. 6357475 ｨ 59754475
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1
I II II 1 dw = pd = 0 1 U = Q (4.10) 1K (heat capacity) (mole heat capacity) ( dq / d ) = ( du d C = / ) (4.11) du = C d U = C d (4.1) 1 1 du = dq + dw dw = pd dq = du + pd (4.13) p dq = d( U + p ) p (4.14)
ｨ , 31, 02 2 (2001) ﾀ..0107ｨ
1301010200040905020009 ｨ 0205010907050409010000, 31, 02 2 (2001) ke@sci.lebedev.ru 05 http://ke.ioc.ac.ru 95 縺0408 縺05 020008050707 0002080907000105070509010901 090306000208080502 PACS 42.60.Fc; 42.65.Re;
Gmech08.dvi
145 13 13.1 13.1.1 0 m mg S 13.1 F 13.1 F /m S F F 13.1 F mg S F F mg 13.1: m d2 r 2 = F + F = 0 (13.1) 146 13 F = F (13.2) S S S S S P r S P r r = r 0 + r (13.3) r 0 S S m d2 r 2 = F (13.4) (13.3) d 2
V(x) m e V 0 cos x π x π V(x) = x < π, x > π V 0 (i) x = 0 (V(x) V 0 (1 x 2 /2)) n n d 2 f dξ 2ξ d f 2 dξ + 2n f = 0 H n (ξ) (ii) H
199 1 1 199 1 1. Vx) m e V cos x π x π Vx) = x < π, x > π V i) x = Vx) V 1 x /)) n n d f dξ ξ d f dξ + n f = H n ξ) ii) H n ξ) = 1) n expξ ) dn dξ n exp ξ )) H n ξ)h m ξ) exp ξ )dξ = π n n!δ n,m x = Vx)
(4) P θ P 3 P O O = θ OP = a n P n OP n = a n {a n } a = θ, a n = a n (n ) {a n } θ a n = ( ) n θ P n O = a a + a 3 + ( ) n a n a a + a 3 + ( ) n a n
3 () 3,,C = a, C = a, C = b, C = θ(0 < θ < π) cos θ = a + (a) b (a) = 5a b 4a b = 5a 4a cos θ b = a 5 4 cos θ a ( b > 0) C C l = a + a + a 5 4 cos θ = a(3 + 5 4 cos θ) C a l = 3 + 5 4 cos θ < cos θ < 4
9 1. (Ti:Al 2 O 3 ) (DCM) (Cr:Al 2 O 3 ) (Cr:BeAl 2 O 4 ) Ĥ0 ψ n (r) ω n Schrödinger Ĥ 0 ψ n (r) = ω n ψ n (r), (1) ω i ψ (r, t) = [Ĥ0 + Ĥint (
9 1. (Ti:Al 2 O 3 ) (DCM) (Cr:Al 2 O 3 ) (Cr:BeAl 2 O 4 ) 2. 2.1 Ĥ ψ n (r) ω n Schrödinger Ĥ ψ n (r) = ω n ψ n (r), (1) ω i ψ (r, t) = [Ĥ + Ĥint (t)] ψ (r, t), (2) Ĥ int (t) = eˆxe cos ωt ˆdE cos ωt, (3)
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1 No.1 5 C 1 I III F 1 F 2 F 1 F 2 2 Φ 2 (t) = Φ 1 (t) Φ 1 (t t). = Φ 1(t) t = ( 1.5e 0.5t 2.4e 4t 2e 10t ) τ < 0 t > τ Φ 2 (t) < 0 lim t Φ 2 (t) = 0
1 No.1 5 C 1 I III F 1 F 2 F 1 F 2 2 Φ 2 (t) = Φ 1 (t) Φ 1 (t t). = Φ 1(t) t = ( 1.5e 0.5t 2.4e 4t 2e 10t ) τ < 0 t > τ Φ 2 (t) < 0 lim t Φ 2 (t) = 0 0 < t < τ I II 0 No.2 2 C x y x y > 0 x 0 x > b a dx
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7 -a 7 -a February 4, 2007 1. 2. 3. 4. 1. 2. 3. 1 Gauss Gauss ɛ 0 E ds = Q (1) xy σ (x, y, z) (2) a ρ(x, y, z) = x 2 + y 2 (r, θ, φ) (1) xy A Gauss ɛ 0 E ds = ɛ 0 EA Q = ρa ɛ 0 EA = ρea E = (ρ/ɛ 0 )e z
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ω 0 m(ẍ + γẋ + ω0x) 2 = ee (2.118) e iωt x = e 1 m ω0 2 E(ω). (2.119) ω2 iωγ Z N P(ω) = χ(ω)e = exzn (2.120) ϵ = ϵ 0 (1 + χ) ϵ(ω) ϵ 0 = 1 +
2.6 2.6.1 ω 0 m(ẍ + γẋ + ω0x) 2 = ee (2.118) e iωt x = e 1 m ω0 2 E(ω). (2.119) ω2 iωγ Z N P(ω) = χ(ω)e = exzn (2.120) ϵ = ϵ 0 (1 + χ) ϵ(ω) ϵ 0 = 1 + Ne2 m j f j ω 2 j ω2 iωγ j (2.121) Z ω ω j γ j f j
18 I ( ) (1) I-1,I-2,I-3 (2) (3) I-1 ( ) (100 ) θ ϕ θ ϕ m m l l θ ϕ θ ϕ 2 g (1) (2) 0 (3) θ ϕ (4) (3) θ(t) = A 1 cos(ω 1 t + α 1 ) + A 2 cos(ω 2 t + α
18 I ( ) (1) I-1,I-2,I-3 (2) (3) I-1 ( ) (100 ) θ ϕ θ ϕ m m l l θ ϕ θ ϕ 2 g (1) (2) 0 (3) θ ϕ (4) (3) θ(t) = A 1 cos(ω 1 t + α 1 ) + A 2 cos(ω 2 t + α 2 ), ϕ(t) = B 1 cos(ω 1 t + α 1 ) + B 2 cos(ω 2 t
1/68 A. 電気所 ( 発電所, 変電所, 配電塔 ) における変圧器の空き容量一覧 平成 31 年 3 月 6 日現在 < 留意事項 > (1) 空容量は目安であり 系統接続の前には 接続検討のお申込みによる詳細検討が必要となります その結果 空容量が変更となる場合があります (2) 特に記載
1/68 A. 電気所 ( 発電所, 変電所, 配電塔 ) における変圧器の空き容量一覧 平成 31 年 3 月 6 日現在 < 留意事項 > (1) 空容量は目安であり 系統接続の前には 接続検討のお申込みによる詳細検討が必要となります その結果 空容量が変更となる場合があります (2) 特に記載のない限り 熱容量を考慮した空き容量を記載しております その他の要因 ( 電圧や系統安定度など ) で連系制約が発生する場合があります
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m(ẍ + γẋ + ω 0 x) = ee (2.118) e iωt P(ω) = χ(ω)e = ex = e2 E(ω) m ω0 2 ω2 iωγ (2.119) Z N ϵ(ω) ϵ 0 = 1 + Ne2 m j f j ω 2 j ω2 iωγ j (2.120)
2.6 2.6.1 mẍ + γẋ + ω 0 x) = ee 2.118) e iωt Pω) = χω)e = ex = e2 Eω) m ω0 2 ω2 iωγ 2.119) Z N ϵω) ϵ 0 = 1 + Ne2 m j f j ω 2 j ω2 iωγ j 2.120) Z ω ω j γ j f j f j f j sum j f j = Z 2.120 ω ω j, γ ϵω) ϵ
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1/3 A. 電気所 ( 発電所, 変電所, 配電塔 ) における変圧器の空き容量 覧 < 留意事項 > (1) 空容量は 安であり 系統接続の前には 接続検討のお申込みによる詳細検討が必要となります その結果 空容量が変更となる場合があります (2) 熱容量を考慮した空き容量を記載しております その他の要因 ( や系統安定度など ) で連系制約が発 する場合があります (3) 表 は 既に空容量がないため
2/8 一次二次当該 42 AX 変圧器 なし 43 AY 変圧器 なし 44 BA 変圧器 なし 45 BB 変圧器 なし 46 BC 変圧器 なし
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(1.2) T D = 0 T = D = 30 kn 1.2 (1.4) 2F W = 0 F = W/2 = 300 kn/2 = 150 kn 1.3 (1.9) R = W 1 + W 2 = = 1100 N. (1.9) W 2 b W 1 a = 0
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H 0 H = H 0 + V (t), V (t) = gµ B S α qb e e iωt i t Ψ(t) = [H 0 + V (t)]ψ(t) Φ(t) Ψ(t) = e ih0t Φ(t) H 0 e ih0t Φ(t) + ie ih0t t Φ(t) = [
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量子力学 問題
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Umgeleitetes Druckdokument von Remotedesktop
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