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1 15
2 Co-Pt X...11
3 Co-Pt Co-Pt Co/Pt Co Pt Co C0 Pt Co m S Hc S Co/Pt Co-Pt Co-Pt...24
4 Co-Pt m S Hc
5 ) Hc 1-1 1
6 (a) 1-2(b) (a) (b) 2
7 ) HDD GMR -3) 1-3 GMR GMR 3
8
9 ) ( ) 2Al 3H 2 O Al 2 O 3 6H 6e - (1-1) (ph5 7) ( ) 1-5 ( ) ( ) 1-5 Keller ( ) 1-7 Keller 5
10 1-2-2 ( ) ( ) nm nm m m 1-7 ( ) Fe Co ( ) 4) Al 2 O ) 2 (1) (2) (C) 1 (A) 1 (s) 1 1 Ag g 1g 1 (F) 1F= (Ah) I t m 1-2 m = I t e ( g) = k I t( g) (1-2) e 1g k 1 (Ah) 6
11 ) (1-3) RT a 0 n+ M E = E + ln (1-3) nf am E 0 R =8.31J K mol T F n a M n+ a M 1 0 E=E 0 E
12 ) 2 2 A B 1-8 A B - A B - V 1 A V B V 3 A i A A i B A B 1-8 A B ) ph (1) ph (2) (3) 8
13 1-4 Co-Pt Co Pt A B B A Co-Pt 7) Co (hexagonal close-packed hcp) Pt (face centered cubic fcc) Co-Pt 1-7 Co-Pt 8) Co 80%at. (hcp ) fcc 825 (facecentered tetragonal fct) AuCu (L1 0) A B (001) c/a ) fccco 50 Pt 50 fct CoPt c 10) 1-5 Fe Co Ni Fe Co 1-4 Co Pt 1 1 Co-Pt ( 1-9) CoPt Co Pt Co CoPt Co Pt 1 1 Co Pt Co-Pt
14 2 (V.S.M) X EPMA (Vibrating Sample Magnetometer V.S.M) 2-1 M x z a A(x y z) S N x-y E =2 f E = KafM j t + exp ω π (2-1) 2 K NSx K = 3 (2-2) 2r 3 N S (2-1) a f M E M 2-1 V.S.M (1) z (2) (3) 80Hz 10kOe 10
15 X X 2-2 X X X Bragg 2-2 X X d a (h k l) 1 2 d = h + k + l 2 a (2-3) X 2-2 Bragg λ = 2d sinθ (2-4) 2 (2-3) (2-4) 2θ = 2sin 1 λ 2 h + k + l 2 a (2-5) 1 4 h + k + l = 2 2 d 3 a l + c 2 2 (2-6) 11
16 2 2θ = 2sin 1 λ 2 4 h + k + l 2 3 a l c 2 2 (2-7) X Cu-K (40kV 40mA) = (2-8) (2-5) (2-7) Co a c ) Co a ) Co-Pt a ) CoPt :a c ) Pt a ) ) X Co hkl a [ ] c [ ] 10.0 hcp [deg.] Co fcc CoPt3 fcc CoPt fct Pt fcc
17 2-3 (Electron Probe Micro Analyzer) EPMA 2-3 X X X
18 3 Co-Pt % mm 25 15mm 15 15mm mol/l 30 50V mol/l 40V 2V 8 2V 2 14
19 3-2 Co-Pt Co-Pt Co Pt 3-2 Pt Pt Co-Pt off-time 15mm 15mm 10mm 10mm
20 4 Co/Pt 4-1 Co Co 0.4mol/l Co Co 2 ph on-time 10ms T 150ms N 400 V 8V 12V H (a) (c) 4-2(a) (c) 4-1 ( ) 4-2 ( ) m s Hc 1kOe ph Co Co Co 16
21 X (a) (c) 4-4(a) (c) 2 =38.5 Al(111) Co 2 =41.6 Co(10.0) 2 =44.2 Co(00.2) Co Co Co 4-3 X 4-4 X 4-2 Pt Co g/l Pt Pt Co Co Pt on-time 10ms T 150ms N 400 8V 9V Co Pt Co Pt Co on-time 10ms T 150ms N 400 V 8V 15V 4-5 Pt 8V 4-6 Pt 9V Pt Co Co 17
22 Pt Pt m s Pt Pt 8V 9V Pt Pt Co Co 4-5 (Pt 8V) 4-6 (Pt 9V) X Pt 8V 4-8 Pt 9V Pt Pt Pt Pt(111) Co Co 2 =41.7 Co(10.0) Co(10.0) Co 18
23 4-7 X (Pt 8V) 4-8 X (Pt 9V) 19
24 4-3 Co Pt Co m s Co Pt 8V 9V 2 Co 4-9 Co Pt 8V Co Pt 9V Co 11V Pt 12V Co Co Hc Co Pt 8V 9V 2 Co 4-10 Co Pt 8V Co Pt 9V Co Pt Pt Co(hcp) 10V Co Pt Pt
25 4-3-3 S Co Pt 8V 9V 2 Co 4-11 Co Pt 8V Co Pt 9V Co Co 0.5 Pt Pt 8V 0.6 Pt 9V 0.7 Co Co/Pt g/ Pt Pt Co Co Co Pt CoPt Torr (a) (d) 4-12(a) (b) Pt 8V 4-12(c) (d) Pt 9V 21
26 4-12 (a) (b) Pt 8V (c) (d) Pt 9V Co Co Co X 4-13(a) (c) 4-13(a) (b) Pt 8V 4-13(c) (d) Pt 9V X X Pt(111) 4-13 (b) (d) 2 =41 CoPt(111) Co/Pt CoPt 22
27 4-13 X (a) (b) Pt 8V (c) (d) Pt 9V 23
28 5 Co-Pt 5-1 Co-Pt Co Pt Co-Pt (fct )CoPt Co Pt Co-Pt Co Pt Co-Pt N 400 Co Pt=5 1 on-time/ T 50ms/300ms 40ms/300ms 30ms/300ms Co Pt=4 1 on-time/ T 30ms/300ms 30ms/150ms 20ms/150ms V 8V 12V 5-2 Co Pt Co-Pt Co 5 1 Co Co Pt 4 1 Co 40% Co Pt 5 1 Co 50% 5-1 Co-Pt 5-3 N 400 Co Pt=5 1 on-time/ T 50ms/300ms 40ms/300ms 30ms/300ms Co Pt=4 1 on-time/ T 30ms/300ms 30ms/150ms 20ms/150ms V 8V 12V Co-Pt 5-2(a) (f) 5-3(a) (f) 5-2 Co Pt= Co Pt=5 1 24
29 5-2 (Co Pt=4 1) 25
30 5-3 (Co Pt=5 1) 26
31 Co-Pt Hc 1kOe X 5-4(a) (f) 5-5(a) (f) 5-4 Co Pt= Co Pt= X (Co Pt=4 1) 27
32 5-5 X (Co Pt=5 1) 28
33 5-4 Co-Pt m s 5-6 Co Pt 4 1 Co-Pt on-time/ T=30ms/300ms Co-Pt on-time/ T=30ms/150ms Co-Pt on-time/ T=20ms/150ms Co-Pt 5-6 Co Pt 4 1 on-time/ T=30ms/300ms on-time/ T=30ms/150ms Co-Pt on-time/ T=20ms/150ms Co-Pt 9V Co-Pt on-time/ T 5-6 (Co Pt=4 1) 29
34 5-7 Co Pt 5 1 Co-Pt on-time/ T=30ms/300ms CoPt on-time/ T=40ms/300ms CoPt on-time/ T=50ms/300ms CoPt Co Pt 4 1 Co-Pt 5-7 (Co Pt=5 1) Hc 5-8 Co Pt 4 1 Co-Pt on-time/ T=30ms/300ms CoPt on-time/ T=30ms/150ms CoPt on-time/ T=20ms/150ms CoPt 1kOe 5-8 (Co Pt=4 1) 30
35 5-9 Co Pt 5 1 Co-Pt on-time/ T=30ms/300ms Co-Pt on-time/ T=40ms/300ms Co-Pt on-time/ T=50ms/300ms Co-Pt Co Pt on-time 1.0kOe 5-9 (Co Pt=5 1) Co-Pt Torr N 400 Co Pt=5 1 on-time/ T 50ms/300ms 40ms/300ms 30ms/300ms Co Pt=4 1 on-time/ T 30ms/300ms 30ms/150ms 20ms/150ms V 8V 12V 5-10(a) (f) 5-11(a) (f) Co Pt V 5-10(b) 12V on-time/ T=30ms/300ms Co Pt
36 5-10 ( N 400) (Co Pt=4 1) 32
37 5-11 ( N 400) (Co Pt=5 1) 33
38 Co Pt 4 1 Co-Pt (a) on-time/ T=30ms/300ms 5-12(b) on-time/ T=30ms/150ms 5-12(c) on-time/ T=20ms/150ms Co 1.2kOe (a) 12V Co-Pt 5-12 (Co Pt=4 1) 34
39 Co Pt 5 1 Co-Pt (a) on-time/ T=40ms/300ms 5-13(b) on-time/ T=50ms/300ms Co 1.2kOe (Co Pt=5 1) X 5-14(a) (f) 5-15(a)Co Pt (f) 5-14 Co Pt Co Pt V on-time/ T=30ms/300ms Co-Pt 2 =41.7 fct Co-Pt(101) fct CoPt 2 =40.5 Co-Pt Co-Pt(111) Co Pt 5 1 Co-Pt(111) fct Co-Pt(101) fct Co-Pt 35
40 5-14 X (Co Pt=4 1) 36
41 5-15 X (Co Pt=5 1) 37
42 6 ( ) 2kOe CoPt CoPt Co-Pt Co Pt Co % mm mol/l 50V mol/l 2V 0.675mA/cm 2 2V 10 Co Co-Pt Pt Co-Pt Co Pt=4 1 Co Pt=5 1 2 Co 0.4M Pt 5g/l Co/Pt Pt Co Pt N 400 on-time 10ms T 150ms 8V 9V Co N 400 on-time 10ms T 150ms 8V 15V Co Pt Co Pt Pt Co(hcp) Pt Co-Pt Co Pt 4 1 Co-Pt Co 40% Co Pt 5 1 Co-Pt Co 50% N V on-time 20ms 50ms T 150ms 300ms on-time Co-Pt 1kOe Co 38
43 Co-Pt Torr Co Pt=4 1 12V ontime/ T=30ms/300ms 0.9kOe 1.8kOe X CoPt(111) fct CoPt 1 1 Co Pt Co-Pt 39
44 1) 1998 pp ) 1997 p.44 3) ) 21 pp ) 2001 p p ) 1971 p.19 7) p.471 8) R. M. Bozorth Ferromagnetism IEEE PRESS 1993 p.413 9) 1993 pp ) O. Kitakami N. Kikuchi S. Okamoto Y. Shimada K. Oikawa Y. Otani K. Fukamichi J Magn Magn Mater. 202 pp
45 41
CoPt 17
CoPt 17 1...1 1.1...1 1.2...1 1.2.1...1 1.2.2...1 1.2.3...2 1.3...3 1.4 CoPt...3 1.5...4 2...6 2.1...6 2.1.1...6 2.1.2...6 2.2...7 2.2.1 X...7 2.2.2...7 2.3...8 2.3.1...8 2.3.2...9 3 CoPt...10 3.1...10
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