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1 15

2 Co-Pt X...11

3 Co-Pt Co-Pt Co/Pt Co Pt Co C0 Pt Co m S Hc S Co/Pt Co-Pt Co-Pt...24

4 Co-Pt m S Hc

5 ) Hc 1-1 1

6 (a) 1-2(b) (a) (b) 2

7 ) HDD GMR -3) 1-3 GMR GMR 3

8

9 ) ( ) 2Al 3H 2 O Al 2 O 3 6H 6e - (1-1) (ph5 7) ( ) 1-5 ( ) ( ) 1-5 Keller ( ) 1-7 Keller 5

10 1-2-2 ( ) ( ) nm nm m m 1-7 ( ) Fe Co ( ) 4) Al 2 O ) 2 (1) (2) (C) 1 (A) 1 (s) 1 1 Ag g 1g 1 (F) 1F= (Ah) I t m 1-2 m = I t e ( g) = k I t( g) (1-2) e 1g k 1 (Ah) 6

11 ) (1-3) RT a 0 n+ M E = E + ln (1-3) nf am E 0 R =8.31J K mol T F n a M n+ a M 1 0 E=E 0 E

12 ) 2 2 A B 1-8 A B - A B - V 1 A V B V 3 A i A A i B A B 1-8 A B ) ph (1) ph (2) (3) 8

13 1-4 Co-Pt Co Pt A B B A Co-Pt 7) Co (hexagonal close-packed hcp) Pt (face centered cubic fcc) Co-Pt 1-7 Co-Pt 8) Co 80%at. (hcp ) fcc 825 (facecentered tetragonal fct) AuCu (L1 0) A B (001) c/a ) fccco 50 Pt 50 fct CoPt c 10) 1-5 Fe Co Ni Fe Co 1-4 Co Pt 1 1 Co-Pt ( 1-9) CoPt Co Pt Co CoPt Co Pt 1 1 Co Pt Co-Pt

14 2 (V.S.M) X EPMA (Vibrating Sample Magnetometer V.S.M) 2-1 M x z a A(x y z) S N x-y E =2 f E = KafM j t + exp ω π (2-1) 2 K NSx K = 3 (2-2) 2r 3 N S (2-1) a f M E M 2-1 V.S.M (1) z (2) (3) 80Hz 10kOe 10

15 X X 2-2 X X X Bragg 2-2 X X d a (h k l) 1 2 d = h + k + l 2 a (2-3) X 2-2 Bragg λ = 2d sinθ (2-4) 2 (2-3) (2-4) 2θ = 2sin 1 λ 2 h + k + l 2 a (2-5) 1 4 h + k + l = 2 2 d 3 a l + c 2 2 (2-6) 11

16 2 2θ = 2sin 1 λ 2 4 h + k + l 2 3 a l c 2 2 (2-7) X Cu-K (40kV 40mA) = (2-8) (2-5) (2-7) Co a c ) Co a ) Co-Pt a ) CoPt :a c ) Pt a ) ) X Co hkl a [ ] c [ ] 10.0 hcp [deg.] Co fcc CoPt3 fcc CoPt fct Pt fcc

17 2-3 (Electron Probe Micro Analyzer) EPMA 2-3 X X X

18 3 Co-Pt % mm 25 15mm 15 15mm mol/l 30 50V mol/l 40V 2V 8 2V 2 14

19 3-2 Co-Pt Co-Pt Co Pt 3-2 Pt Pt Co-Pt off-time 15mm 15mm 10mm 10mm

20 4 Co/Pt 4-1 Co Co 0.4mol/l Co Co 2 ph on-time 10ms T 150ms N 400 V 8V 12V H (a) (c) 4-2(a) (c) 4-1 ( ) 4-2 ( ) m s Hc 1kOe ph Co Co Co 16

21 X (a) (c) 4-4(a) (c) 2 =38.5 Al(111) Co 2 =41.6 Co(10.0) 2 =44.2 Co(00.2) Co Co Co 4-3 X 4-4 X 4-2 Pt Co g/l Pt Pt Co Co Pt on-time 10ms T 150ms N 400 8V 9V Co Pt Co Pt Co on-time 10ms T 150ms N 400 V 8V 15V 4-5 Pt 8V 4-6 Pt 9V Pt Co Co 17

22 Pt Pt m s Pt Pt 8V 9V Pt Pt Co Co 4-5 (Pt 8V) 4-6 (Pt 9V) X Pt 8V 4-8 Pt 9V Pt Pt Pt Pt(111) Co Co 2 =41.7 Co(10.0) Co(10.0) Co 18

23 4-7 X (Pt 8V) 4-8 X (Pt 9V) 19

24 4-3 Co Pt Co m s Co Pt 8V 9V 2 Co 4-9 Co Pt 8V Co Pt 9V Co 11V Pt 12V Co Co Hc Co Pt 8V 9V 2 Co 4-10 Co Pt 8V Co Pt 9V Co Pt Pt Co(hcp) 10V Co Pt Pt

25 4-3-3 S Co Pt 8V 9V 2 Co 4-11 Co Pt 8V Co Pt 9V Co Co 0.5 Pt Pt 8V 0.6 Pt 9V 0.7 Co Co/Pt g/ Pt Pt Co Co Co Pt CoPt Torr (a) (d) 4-12(a) (b) Pt 8V 4-12(c) (d) Pt 9V 21

26 4-12 (a) (b) Pt 8V (c) (d) Pt 9V Co Co Co X 4-13(a) (c) 4-13(a) (b) Pt 8V 4-13(c) (d) Pt 9V X X Pt(111) 4-13 (b) (d) 2 =41 CoPt(111) Co/Pt CoPt 22

27 4-13 X (a) (b) Pt 8V (c) (d) Pt 9V 23

28 5 Co-Pt 5-1 Co-Pt Co Pt Co-Pt (fct )CoPt Co Pt Co-Pt Co Pt Co-Pt N 400 Co Pt=5 1 on-time/ T 50ms/300ms 40ms/300ms 30ms/300ms Co Pt=4 1 on-time/ T 30ms/300ms 30ms/150ms 20ms/150ms V 8V 12V 5-2 Co Pt Co-Pt Co 5 1 Co Co Pt 4 1 Co 40% Co Pt 5 1 Co 50% 5-1 Co-Pt 5-3 N 400 Co Pt=5 1 on-time/ T 50ms/300ms 40ms/300ms 30ms/300ms Co Pt=4 1 on-time/ T 30ms/300ms 30ms/150ms 20ms/150ms V 8V 12V Co-Pt 5-2(a) (f) 5-3(a) (f) 5-2 Co Pt= Co Pt=5 1 24

29 5-2 (Co Pt=4 1) 25

30 5-3 (Co Pt=5 1) 26

31 Co-Pt Hc 1kOe X 5-4(a) (f) 5-5(a) (f) 5-4 Co Pt= Co Pt= X (Co Pt=4 1) 27

32 5-5 X (Co Pt=5 1) 28

33 5-4 Co-Pt m s 5-6 Co Pt 4 1 Co-Pt on-time/ T=30ms/300ms Co-Pt on-time/ T=30ms/150ms Co-Pt on-time/ T=20ms/150ms Co-Pt 5-6 Co Pt 4 1 on-time/ T=30ms/300ms on-time/ T=30ms/150ms Co-Pt on-time/ T=20ms/150ms Co-Pt 9V Co-Pt on-time/ T 5-6 (Co Pt=4 1) 29

34 5-7 Co Pt 5 1 Co-Pt on-time/ T=30ms/300ms CoPt on-time/ T=40ms/300ms CoPt on-time/ T=50ms/300ms CoPt Co Pt 4 1 Co-Pt 5-7 (Co Pt=5 1) Hc 5-8 Co Pt 4 1 Co-Pt on-time/ T=30ms/300ms CoPt on-time/ T=30ms/150ms CoPt on-time/ T=20ms/150ms CoPt 1kOe 5-8 (Co Pt=4 1) 30

35 5-9 Co Pt 5 1 Co-Pt on-time/ T=30ms/300ms Co-Pt on-time/ T=40ms/300ms Co-Pt on-time/ T=50ms/300ms Co-Pt Co Pt on-time 1.0kOe 5-9 (Co Pt=5 1) Co-Pt Torr N 400 Co Pt=5 1 on-time/ T 50ms/300ms 40ms/300ms 30ms/300ms Co Pt=4 1 on-time/ T 30ms/300ms 30ms/150ms 20ms/150ms V 8V 12V 5-10(a) (f) 5-11(a) (f) Co Pt V 5-10(b) 12V on-time/ T=30ms/300ms Co Pt

36 5-10 ( N 400) (Co Pt=4 1) 32

37 5-11 ( N 400) (Co Pt=5 1) 33

38 Co Pt 4 1 Co-Pt (a) on-time/ T=30ms/300ms 5-12(b) on-time/ T=30ms/150ms 5-12(c) on-time/ T=20ms/150ms Co 1.2kOe (a) 12V Co-Pt 5-12 (Co Pt=4 1) 34

39 Co Pt 5 1 Co-Pt (a) on-time/ T=40ms/300ms 5-13(b) on-time/ T=50ms/300ms Co 1.2kOe (Co Pt=5 1) X 5-14(a) (f) 5-15(a)Co Pt (f) 5-14 Co Pt Co Pt V on-time/ T=30ms/300ms Co-Pt 2 =41.7 fct Co-Pt(101) fct CoPt 2 =40.5 Co-Pt Co-Pt(111) Co Pt 5 1 Co-Pt(111) fct Co-Pt(101) fct Co-Pt 35

40 5-14 X (Co Pt=4 1) 36

41 5-15 X (Co Pt=5 1) 37

42 6 ( ) 2kOe CoPt CoPt Co-Pt Co Pt Co % mm mol/l 50V mol/l 2V 0.675mA/cm 2 2V 10 Co Co-Pt Pt Co-Pt Co Pt=4 1 Co Pt=5 1 2 Co 0.4M Pt 5g/l Co/Pt Pt Co Pt N 400 on-time 10ms T 150ms 8V 9V Co N 400 on-time 10ms T 150ms 8V 15V Co Pt Co Pt Pt Co(hcp) Pt Co-Pt Co Pt 4 1 Co-Pt Co 40% Co Pt 5 1 Co-Pt Co 50% N V on-time 20ms 50ms T 150ms 300ms on-time Co-Pt 1kOe Co 38

43 Co-Pt Torr Co Pt=4 1 12V ontime/ T=30ms/300ms 0.9kOe 1.8kOe X CoPt(111) fct CoPt 1 1 Co Pt Co-Pt 39

44 1) 1998 pp ) 1997 p.44 3) ) 21 pp ) 2001 p p ) 1971 p.19 7) p.471 8) R. M. Bozorth Ferromagnetism IEEE PRESS 1993 p.413 9) 1993 pp ) O. Kitakami N. Kikuchi S. Okamoto Y. Shimada K. Oikawa Y. Otani K. Fukamichi J Magn Magn Mater. 202 pp

45 41

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