Ryoji KANNO: Crystal Structure and Properties of Materials for Lithium Battery Electrode materials for rechargeable lithium batteries are reviewed fro
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1 Ryoji KANNO: Crystal Structure and Properties of Materials for Lithium Battery Electrode materials for rechargeable lithium batteries are reviewed from the viewpoint of crystal structures, phase relationships, and electrode properties. Following a brief description of lithium battery, major electrode materials, LiCoO2, LiNiO2, and LiMn2O4 are discussed. Materials design for the electrodes based on the crystal structures are important for future materials developments.
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3 (Crystal structures based on the cubic closed packed oxide ion array. (a) Rocksalt type, (b) Y LiFeO2 type, (c) Layered rocksalt (ƒ -NaFeO2) type, (d) Zig-zag layered (ƒà-namno2) type, (e) Spinel type.)
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6 tween the synthesis temperature and the compositions in Li1-XNi1+XO2. ( Z ND: neutron, œ XRD: X-ray diffraction, determined from the intensity ratio of several X-ray diffraction peaks)).
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[1-1] 1970p.13. [1-2] 1982p.174. [1-3] 2001p.321. [1-4] D. Guerard, A. Herold, Carbon, 13, 337 (1975). [1-5] A. N. Dey, B. P. Sullivan, J. Electrochem. Soc., 117, 222 (1970). [1-6] 57-208079 (1982). [1-7]
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