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- みがね ももき
- 5 years ago
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7 (SIL) 7
8 (ODS) 8
9 (ODS) (Octyl) 9
10 (STR ODS) 10
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12 ULTRON ES-OVM Arotinolol -blockers Alprenolol Mobile Phase: 20 mm KH 2 PO 4 (ph 6.0) / CH 3 CN = 100 / 5 Temperature: 25 Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 5.5) / CH 3 CN = 100 / 10 Temperature: 25 -blockers Bunitrolol Oxprenolol Mobile Phase: 20 mm KH 2 PO 4 (ph 6.0) / C 2 H 5 OH = 100 / 3 Temperature: 25 Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 6.0) / CH 3 CN = 100 / 10 Flow Rate: 1.2 ml/min Temperature: 25 12
13 ULTRON ES-OVM Pindolol -blockers Propranolol Mobile Phase: 20 mm KH 2 PO 4 (ph 5.5) / C 2 H 5 OH = 100 / 30 Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 6.8) / CH 3 CN = 100 / 30 Temperature: 25 Bay k 8644 Calcium Antagonists Prenylamine Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / C 2 H 5 OH = 100 / 25 Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 5.0) / CH 3 CN = 100 / 15 Temperature: 25 13
14 ULTRON ES-OVM Calcium Antagonists Verapamil Antiparkinsons Biperiden Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / C 2 H 5 OH = 100 / 5 Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / C 2 H 5 OH = 100 / 10 Temperature: 25 Profenamine () Antiparkinsons Trihexyphenidyl Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / C 2 H 5 OH = 100 / 25 Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / C 2 H 5 OH = 100/ 10 Temperature: 25 14
15 ULTRON ES-OVM Flurbiprofen Antiinflammatoryies Ibuprofen Mobile Phase: 20 mm KH 2 PO 4 (ph 3.0) / CH 3 CN = 100 / 10 Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 3.0) / CH 3 CN = 100 / 5 Temperature: 25 Ketoprofen Antiinflammatoryies Pranoprofen Mobile Phase: 20 mm KH 2 PO 4 (ph 3.0) / CH 3 CN = 100 / 10 Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 3.0) / CH 3 CN = 100 / 8 Temperature: 25 15
16 ULTRON ES-OVM Antiinflammatoryies Zaltoprofen Antihistamines () Alimemazine Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 3.0) / CH 3 CN = 87 / 13 Flow Rate: 1.2 ml/min Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / C 2 H 5 OH = 100 / 25 Temperature: 25 Chlorpheniramine Antihistamines () Dimethindene Maleate Mobile Phase: 20 mm KH 2 PO 4 (ph 5.0) / CH 3 CN = 100 / 5 Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 100 / 9 Temperature: 25 16
17 ULTRON ES-OVM Antihistamines () Homochlorcyclizine Promethazine Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / C 2 H 5 OH = 100 / 20 Flow Rate: 1.2 ml/min Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 3.0) / CH 3 CN = 100 / 5 Temperature: 25 Acetylpheneturide Anticonvulsants Mephobarbital Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / C 2 H 5 OH = 100 / 7.5 Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / C 2 H 5 OH = 100 / 10 Temperature: 25 17
18 ULTRON ES-OVM Tranquilizers () Hydroxyzine Skeletal Muscle Relaxants () Chlormezanone Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 100 / 10 Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 100 / 10 Temperature: 25 Chlorphenesin Skeletal Muscle Relaxants () Eperisone Mobile Phase: 20 mm KH 2 PO 4 (ph 5.5) Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 5.5) / C 2 H 5 OH = 100 / 5 Temperature: 25 18
19 ULTRON ES-OVM Skeletal Muscle Relaxants () Tolperisone Antidepressants () Trimipramine maleate Mobile Phase: 20 mm KH 2 PO 4 (ph 5.5) / C 2 H 5 OH = 100 / 10 Temperature: 25 Central nervous system stimulants () Methylphenidate Mobile Phase: 20 mm KH 2 PO 4 (ph 4.5) / C 2 H 5 OH = 100 / 30 Temperature: 25 Drugs used in Vertigo () Meclizine Mobile Phase: 20 mm KH 2 PO 4 (ph 5.7) Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / C 2 H 5 OH = 100 / 35 Temperature: 25 19
20 ULTRON ES-OVM Glutethimide Hypnotics () Hexobarbital Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / C 2 H 5 OH = 100 / 10 Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 6.0) / C 2 H 5 OH = 100 / 5 Temperature: 25 Glycopyrronium bromaide Anticholinergics () Mepenzolate bromaide Mobile Phase: 20 mm KH 2 PO 4 (ph 5.5) / C 2 H 5 OH = 100 / 2 Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) Temperature: 25 20
21 ULTRON ES-OVM Local Anesthetics () Bupivacaine Antidysrhythmics () Disopyramid Mobile Phase: 20 mm KH 2 PO 4 (ph 5.5) / CH 3 CN = 100 / 10 Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 5.5) / C 2 H 5 OH = 100 / 10 Temperature: 25 Benproperine Antitussives () Cloperastin Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / C 2 H 5 OH = 100 / 20 Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / C 2 H 5 OH = 100 / 15 Temperature: 25 21
22 ULTRON ES-OVM Diuretics () Ethiazide Oral anticoagulants () Warfarin Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 3.0) / CH 3 CN = 100 / 15 Flow Rate: 0.1 ml/min Temperature: 25 Detection: UV-305 nm Bronchodilators () Clorprenaline Drugs in peptic ulcer () Proglumide Mobile Phase: 20 mm KH 2 PO 4 (ph 5.5) / C 2 H 5 OH = 100 / 3 Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / C 2 H 5 OH = 100 / 20 Temperature: 25 22
23 ULTRON ES-OVM 1,2-Diphenylethylamine Others () Flavanone Mobile Phase: 20 mm KH 2 PO 4 (ph 5.5) Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 100 / 30 Temperature: 25 Detection: UV-254 nm (1S,2R)-1-Methyl-cis-1,2,3,6-tetrahydrophthalate Others () Benzoin Mobile Phase: 20 mm KH 2 PO 4 (ph 4.0) / CH 3 CN = 100 / 5 Temperature: 25 Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / C 2 H 5 OH = 100 / 10 Temperature: 25 Detection: UV-2 nm 23
24 ULTRON ES-OVM Thyroxine Others () Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 100 / 20 Flow Rate: 1.2 ml/min Temperature: 15 24
25 ULTRON ES-PEPSIN Alprenolol -blockers Atenolol Column: ULTRON ES-PEPSIN Mobile Phase: 20 mm KH 2 PO 4 (ph 5.0) / C 2 H 5 OH = 95 / 5 Temperature: 25 Column: ULTRON ES-PEPSIN Mobile Phase: 20 mm KH 2 PO 4 (ph 6.0) / C 2 H 5 OH = 99 / 1 Temperature: 25 -blockers Bunitrolol Bronchodilators () Terbutaline Column: ULTRON ES-PEPSIN Mobile Phase: 20 mm KH 2 PO 4 (ph 5.0) / C 2 H 5 OH = 95 / 5 Temperature: 25 Column: ULTRON ES-PEPSIN Mobile Phase: 20 mm KH 2 PO 4 (ph 6.0) Temperature: 25 25
26 ULTRON ES-BSA Ibuprofen Antiinflammatoryies Column: ULTRON ES-BSA Mobile Phase: 20 mm KH 2 PO 4 (ph 7.0) / 1-Propanol / Caprylic Acid = 98 / 2 / 0.08 Temperature: 25 Antiinflammatoryies Pranoprofen Oral anticoagulants () Warfarin Column: ULTRON ES-BSA Mobile Phase: 20 mm KH 2 PO 4 (ph 7.0) / 1-Propanol / Caprylic Acid = 98 / 2 / 0.01 Temperature: Column: ULTRON ES-BSA Mobile Phase: 20 mm KH 2 PO 4 (ph 7.0) / 1-Propanol / Caprylic Acid = 98 / 2 / 0.01 Temperature: 25
27 ULTRON ES-CD Alimemazine Antihistamines () Chlorpheniramine Column: ULTRON ES-CD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 5.0) / CH 3 CN = 70 / 30 Flow Rate: 1.2 ml/min Temperature: 25 Column: ULTRON ES-CD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 83 / 17 Temperature: 15 Anticonvulsants Mephobarbital Skeletal Muscle Relaxants () Chlormezanone Column: ULTRON ES-CD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 80 / 20 Flow Rate: 0.6 ml/min Temperature: 25 Column: ULTRON ES-CD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 93 / 7 Flow Rate: 1.2 ml/min Temperature: 25 27
28 ULTRON ES-CD Eperisone Skeletal Muscle Relaxants () Tolperisone Column: ULTRON ES-CD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 80 / 20 Flow Rate: 0.6 ml/min Temperature: 25 Antidepressants () Trimipramine maleate Column: ULTRON ES-CD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 85 / 15 Flow Rate: 1.2 ml/min Temperature: 7 Central nervous system stimulants () Methylphenidate Column: ULTRON ES-CD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 75 / 25 Flow Rate: 1.2 ml/min Temperature: 25 Column: ULTRON ES-CD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 6.0) / CH 3 CN = 90 / 10 Flow Rate: 1.2 ml/min Temperature: 25 28
29 ULTRON ES-CD Antipsychotic drug () Thioridazine Hypnotics () Hexobarbital Column: ULTRON ES-CD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 75 / 25 Flow Rate: 1.2 ml/min Temperature: 25 Column: ULTRON ES-CD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 83 / 17 Flow Rate: 1.2 ml/min Temperature: 25 Clorprenaline Bronchodilators () Terbutaline Column: ULTRON ES-CD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 94 / 6 Flow Rate: 1.2 ml/min Temperature: 25 Column: ULTRON ES-CD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 6.0) / CH 3 CN = 99 / 1 Flow Rate: 1.2 ml/min Temperature: 25 29
30 ULTRON ES-CD Diuretics () Ethiazide Others () Benzoin Column: ULTRON ES-CD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 92.5 / 7.5 Flow Rate: 1.2 ml/min Temperature: 25 Column: ULTRON ES-CD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 88 / 12 Flow Rate: 1.2 ml/min Temperature: 25 Others () Flavanone PTH-Valine PTH- Column: ULTRON ES-CD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 80 / 20 Flow Rate: 1.2 ml/min Temperature: 25 Column: ULTRON ES-CD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 3.0) / CH 3 CN Flow Rate: 1.2 ml/min Temperature: 25 30
31 ULTRON ES-PhCD Alprenolol -blockers Arotinolol Column: ULTRON ES-PhCD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 80 / 20 Flow Rate: 1.2 ml/min Temperature: 25 Column: ULTRON ES-PhCD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 75 / 25 Flow Rate: 1.2 ml/min Temperature: 25 Atenolol -blockers Bunitrolol Column: ULTRON ES-PhCD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 6.0) / CH 3 CN = 90 / 10 Flow Rate: 0.6 ml/min Temperature: 25 Column: ULTRON ES-PhCD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 70 / 30 Flow Rate: 1.2 ml/min Temperature: 25 31
32 ULTRON ES-PhCD Pindolol -blockers Propranolol Column: ULTRON ES-PhCD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 90 / 10 Flow Rate: 1.2 ml/min Temperature: 25 Column: ULTRON ES-PhCD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 60 / 40 Flow Rate: 1.2 ml/min Temperature: 25 Local Anesthetics () Bupivacaine Anticonvulsants Acetylpheneturide Column: ULTRON ES-PhCD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 80 / 20 Flow Rate: 1.2 ml/min Temperature: 25 Column: ULTRON ES-PhCD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 76 / 24 Flow Rate: 1.2 ml/min Temperature: 25 32
33 ULTRON ES-PhCD Skeletal Muscle Relaxants () Chlormezanone Chlorphenesin Column: ULTRON ES-PhCD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 70 / 30 Flow Rate: 0.6 ml/min Temperature: 9 Column: ULTRON ES-PhCD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 70 / 30 Flow Rate: 0.6 ml/min Temperature: 9 Skeletal Muscle Relaxants () Eperisone Others () 1,1 -Bi-2-Naphthol Column: ULTRON ES-PhCD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 70 / 30 Flow Rate: 1.2 ml/min Temperature: 9 Column: ULTRON ES-PhCD Size: 1 mm x 6.0 mm I.D. Mobile Phase: Hexane / Dichloromethane/ Methanol = 75 / 25 / 5 Flow Rate: 1.2 ml/min Temperature: 25 Detection: UV-254 nm 33
34 ULTRON ES-PhCD Others () N-(3,5-Dinitrobenzoyl)--Methylbenzylamine (N-(3,5-)--) Flavanone Column: ULTRON ES-PhCD Size: 1 mm x 6.0 mm I.D. Mobile Phase: Hexane / Ethanol = 85 / 15 Temperature: 25 Detection: UV-254 nm Column: ULTRON ES-PhCD Size: 1 mm x 6.0 mm I.D. Mobile Phase: Hexane / Ethanol = 99 / 1 Temperature: 25 Detection: UV-254 nm Others () -Phenylethyl alcohol -Phenylethylamine Column: ULTRON ES-PhCD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 90 / 10 Flow Rate: 0.6 ml/min Temperature: 15 Column: ULTRON ES-PhCD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 95 / 5 Flow Rate: 0.6 ml/min Temperature: 15 34
35 Others () The relationship between flow ratio and capacitor ratio (k') of column temperature, optics recognition ability () ( (k )() ) -Phenylethylamine ULTRON ES-PhCD Column: ULTRON ES-PhCD Size: 1 mm x 6.0 mm I.D. Mobile Phase: 20 mm KH 2 PO 4 (ph 4.6) / CH 3 CN = 90 / 10 Others () trans-stilben Oxide Column: ULTRON ES-PhCD Size: 1 mm x 6.0 mm I.D. Mobile Phase: Hexane / Methanol = 99.9 / 0.1 Temperature: 25 Detection: UV-254 nm 35
36 ULTRON PS-80H Elution position of the aliphatic organic acid Citric Acid () Tartaric Acid () Glyoxylic Acid () Malic Acid () Malonic Acid () Succinic Acid () Glycolic Acid () Formic Acid () Lactic Acid () Acetic Acid () Fumaric Acid () Levulinic Acid () Adipic Acid () Pyroglutamic Acid () Propionic Acid () Acrylic Acid () Pivalic Acid () Methacrylic Acid () Crotonic Acid () Column: ULTRON PS-80H Size: 300 mm x 8.0 mm I.D. Mobile Phase: HClO 4 aq. (ph2.1) Temperature: 60 Detection: UV-210 nm Elution position of the aromatic organic acid Citric Acid () Tartaric Acid () Malonic Acid () Succinic Acid () Lactic Acid () Acetic Acid () Gallic Acid () Propionic Acid () o-phthalic Acid (o-) Phenoxyacetic Acid () m-hydroxybenzoic Acid (m-) p-hydroxybenzoic Acid (p-) Vanilic Acid () Sorbic Acid () Caffeic Acid () Benzoic Acid () o-hydroxybenzoic Acid (o-) Column: ULTRON PS-80H Size: 300 mm x 8.0 mm I.D. Mobile Phase: 10 % CH3CN addition HClO4aq. (ph2.1) Temperature: 60 Detection: UV-210 nm 36
37 ULTRON PS-80H Alcohols Aldehydes Alcohols Formaldehyde () Acetaldehyde () Ethanol () Ethylene Glycol () Diethylene Glycol () Methanol () Ethanol () Isopropyl Alcohol ( ) Column: ULTRON PS-80H Size: 300 mm x 8.0 mm I.D. + mm x 8.0 mm I.D. Mobile Phase: HClO 4 aq (ph 2.1) Temperature: 60 Pressure: 25 kgf/cm 2 Detection: RI, 32x10-6 RIUFS Uronic Acid, acetylation amino sugar Glucuronic Acid () N-Acetylglucosamine (N-) N-Acetylgalactosamine (N-) Column: ULTRON PS-80H Size: 300 mm x 8.0 mm I.D. Mobile Phase: H 2 O Temperature: 60 Pressure: 25 kgf/cm 2 Detection: RI, 32x10-6 RIUFS Inj. Vol.: 6.0 ul (10 mg/ml) Analysis of the soy sauce Citric Acid () Tartaric Acid () Malic Acid () Succinic Acid () Lactic Acid () Acetic Acid () Pyroglutamic Acid () Column: ULTRON PS-80H Size: 300 mm x 8.0 mm I.D. + mm x 8.0 mm I.D. Mobile Phase: HClO 4 aq (ph 2.1) Temperature: 60 Pressure: 25 kgf/cm 2 Detection: UV-210 nm Column: ULTRON PS-80H Size: 300 mm x 8.0 mm I.D. Mobile Phase: HClO 4 aq (ph 2.1) Temperature: 60 Detection: UV-210 nm 37
38 ULTRON PS-80H Analysis of aliphatic organic acid Citric Acid () Tartaric Acid () Maleic Acid () Malonic Acid () Succinic Acid () Glycolic Acid () Lactic Acid () Fumaric Acid () Acetic Acid () Adipic Acid () Propionic Acid () Methacrylic Acid () Crotonic Acid () (min) Column: ULTRON PS-80H Size: 2 mm x 2.0 mm I.D. Mobile Phase: HClO 4 aq (ph 2.1) Flow Rate: 0.05 ml/min Temperature: 60 Press.:0.7 MPa Injection amount: 2.5 ul Detection: UV-210 nm Mass chromatograms obtained by TIC of 11 carboxylic acids. 9.22e e e e e e e Ketoglutaric Acid 9.58 Malonic Acid Glycolic Acid 8.40 Succinic Acid 8.77 Fumaric Acid 8.81 L-(+)-Lactic Acid m/z=145 DL-2-Hydroxy-n-butyric Acid m/z=103 m/z=75 m/z=117 m/z=115 m/z= Glutaric Acid m/z=131 Column : ULTRON PS-80H Dimensions : 2 mm L 2.0 mm I.D. Mobile phase : 0.1 Formic Acid (ph 2.3) Flow rate : 0.07 ml/min Temperature : 55 Detection : ESI positive and negative, range: m/z e4 Acetic Acid 9.82 m/z= e e4 0 Propionic Acid n-butyric Acid m/z=92 m/z= (min) 38
39 ULTRON PS-80N PS-80C PS-80P Elution Position of Sugar and Sugar Alcohol for PS-80N Dextran T-10 ( T-10) Raffinose () Lactose () Glucose () Galactose () Arabinose () Ethanol () Column: ULTRON PS-80N Size: 300 mm x 8.0 mm I.D. Mobile Phase: H 2 O Temperature: 60 Detection: RI, 16x10-5 RIUFS Sample: ea. 15 mg/ml, ethanol ul/ml Elution Position of Sugar and Sugar Alcohol for PS-80C Dextran T-10 ( T-10) Raffinose () Sucrose () Glucose () Galactose () Fructose () Adonitol () Glycerol () Ethanol + Mannitol ( + ) Xylitol +Sorbitol ( + ) Column: ULTRON PS-80C Size: 300 mm x 8.0 mm I.D. Mobile Phase: H 2 O Temperature: 80 Detection: RI, 16x10-5 RIUFS Sample: ea. 10 ul/ml 39
40 ULTRON PS-80N PS-80C PS-80P Elution Position of Sugar and Sugar Alcohol for PS-80P Dextran T-10 ( T-10) Raffinose () Sucrose () Lactose () Glucose () Xylose () Galactose () Arabinose () Fructose () Ethanol () Glycerol () Mannitol () Xylitol () Sorbitol () Column: ULTRON PS-80P Size: 300 mm x 8.0 mm I.D. Mobile Phase: H 2 O Temperature: 80 Detection: RI, 16x10-5 RIUFS Sample: ea. 10 ul/ml Retention Index of the Standard Sample Ethanol () Ethylene glycol () Diethylene glycol () Glycerol () Arabinose () Xylitol () Inositol () Fructose () Xylose () Mannose () Galactose () Sorbitol () Adonitol () Mannitol () Glucose () Lactose () Maltose () Sucrose () Maltotriose () Raffinose () Dextran T-10 ( T-10) Sorbitol () Xylitol () Diethylene glycol () Ethanol () Mannitol () Ethylene glycol () Glycerol () Adonitol () Arabinose () Inositol () Fructose () Mannose () Galactose () Xylose () Glucose () Lactose () Maltose () Sucrose () Maltotriose () Raffinose () Dextran T-10 T-10) Sorbitol () Xylitol () Diethylene glycol () Mannitol () Adonitol () Inositol () Glycerol () Ethylene glycol () Ethanol () Fructose () Mannose () Arabinose () Galactose () Xylose () Glucose () Lactose () Maltose () Sucrose () Maltotriose () Raffinose () Dextran T-10 ( T-10) 40
41 ULTRON PS-80N PS-80C PS-80P Sugar and Sugar Alcohol Sucrose () Lactose () Glucose () Xylosel () Galactose () Fructose () Inositol () Column: ULTRON PS-80P Size: 300 mm x 8.0 mm I.D mm x 8.0 mm I.D. Mobile Phase: H 2 O Temperature: 80 Pressure: 20 kgf/cm 2 Detection: RI, 16x10-5 RIUFS Comparison of retention between PS-80N 300 mm 8.0 mm and 0 mm 8.0 mm Dextran T-10 ( T-10) Maltotriose () Maltose () Glucose () Galactose () Inositol () Ethanol () Column: ULTRON PS-80N Size: 300 mm x 8.0 mm I.D. Mobile Phase: H 2 O Pressure: 20 kgf/cm 2 Column: ULTRON PS-80NL Size: 0 mm x 8.0 mm I.D. Mobile Phase: H 2 O Pressure: 35 kgf/cm 2 41
42 ULTRON PS-80N PS-80C PS-80P Sake Starch syrup Maltotriose () Maltose () Glucose () Glycerol () Ethanol () Oligosaccharide () Maltotriose () Maltose () Glucose () Column: ULTRON PS-80N Size: 300 mm x 8.0 mm I.D. Mobile Phase: H 2 O Temperature: 60 Pressure: 22 kgf/cm 2 Detection: RI, 16x10-5 RIUFS Injection vol.: 10 ul Column: ULTRON PS-80N Size: 300 mm x 8.0 mm I.D. Mobile Phase: H 2 O Temperature: 60 Pressure: 22 kgf/cm 2 Detection: RI, 16x10-5 RIUFS Injection vol.: 5 ul(25 mg/ml) Separation of stachyose and raffinose Stachyose () Raffinose () Glucose () Yoghurt drink Sucrose () Lactose () Glucose () Galactose () Fructose () Column: ULTRON PS-80N Size: 300 mm x 8.0 mm I.D. Mobile Phase: H 2 O Temperature: 60 Pressure: 25 kgf/cm 2 Detection: RI, 128x10-6 RIUFS Injection vol.: 10 ul(2 mg/ml) Column: ULTRON PS-80C Size: 300 mm x 8.0 mm I.D. Mobile Phase: H 2 O Flow Rate: 0.5 ml/min Temperature: 80 Pressure: 20 kgf/cm 2 Detection: RI, 8x10-5 RIUFS Injection vol.: 10 ul 42
43 ULTRON CI CL Inositol in health drink () Health drink R Health drink RS Inositol Inositol Inositol Column: ULTRON CI Size: 200 mm x 4.6 mm I.D. Mobile Phase: CH 3 CN / H 2 O = 60 / 40 Temperature: 40 Detection: RI Glucuronic acid in health drink L-sodium glutaminate, Glucuronolactone Health drink C Column: ULTRON CL Size: 1 mm x 4.0 mm I.D. Mobile Phase: Flow Rate: 0.8 ml/min Temperature: 70 Detection: UV-210 nm 43
44 ULTRON VX-SIL Female sex hormone Estrone () Estradiol () Estriol () The fat-soluble vitamins Vitamin A Palmitate (A) Vitamin K 1 (K1) Vitamin K 2 (K2) Vitamin A Acetate (A) Vitamin E (E) Column: ULTRON VX-SIL Mobile Phase: n-hexane / Ethanol = 90 / 10 Temperature: ambient Detection: UV-280 nm Column: ULTRON VX-SIL Mobile Phase: n-hexane / Dichloromethane = 90 / 10 Temperature: ambient Detection: UV-254 nm 44
45 ULTRON VX-ODS Pyridine, Phenol test Pyridine () Phenol () Acidic compounds p-hydroxybenzoic Acid (p-) m-hydroxybenzoic Acid (m-) Phenol () Acetylsalicylic Acid () Benzoic Acid () Salicylic Acid () Column: ULTRON VX-ODS Mobile Phase: CH 3 CN / H 2 O = 30 / 70 Temperature: 30 Detection: UV-254 nm Column: ULTRON VX-ODS Mobile Phase: 10 mm (NH 4 ) 3 PO 4 ph 2.5/ CH 3 CN = 80 / 20 Temperature: 30 Detection: UV-254 nm Separation of the steroid The water-soluble vitamin Predonisone () Cortisone () Hydrocortisone () Cortisone Acetate () Hydrocortisone Acetate () Nicotinic Acid () Nicotinic Acid Amide ((PP)) Calcium Pantothenate ((B3)) Pyridoxine Hydrochloride ( (B6)) Riboflavin Phosphate () Thiamine ((B1)) Folic Acid ((Bc)) Biotin ((H)) Riboflavin ((B2)) Column: ULTRON VX-ODS Mobile Phase: H 2 O / CH 3 OH / THF = 70 / 10 / 20 Temperature: 40 Detection: UV-254 nm Column: ULTRON VX-ODS Mobile Phase: 20 mm H 3 PO 4 / 5 mm CH 3 (CH 2 ) 5 SO 3 Na= 91 / 9 Temperature: 45 Detection: UV-210 nm 45
46 ULTRON VX-ODS The synthetic antibacterial medicine simultaneity analysis ( Amprolium () Sulfamerazine () Sulfadimidine () Thiamphenicol () Furazolidone () Oxytetracycline () Sulfamonomethoxine () Oxolinic Acid () Sulfadimethoxine () Sulfaquinoxaline () Column: ULTRON VX-ODS 5 µm Mobile Phase: 10 mm TFA B CH 3 CN Temperature: 40 Synthetic antibacterial medicine repeat test ( Amprolium () Sulfamerazine () Sulfadimidine () Thiamphenicol () Furazolidone () Oxytetracycline () Sulfamonomethoxine () Oxolinic Acid () Sulfadimethoxine () Sulfaquinoxaline () Column: ULTRON VX-ODS 5 µm Mobile Phase: 10 mm TFA B CH 3 CN Temperature: 40 Detection: UV-254 nm 46
47 ULTRON VX-ODS Chromatogram of the repeat test ( Amprolium () Sulfamerazine () Sulfadimidine () Thiamphenicol () Furazolidone () Oxytetracycline () Sulfamonomethoxine () Oxolinic Acid () Sulfadimethoxine () Sulfaquinoxaline () Column: ULTRON VX-ODS 5 µm Mobile Phase: A 10 mm TFA B CH 3 CN Temperature: 40 Detection: UV-254 nm Naphthalene Pyridine, Phenol test Naphthalene Phenol Pyridine Column: ULTRON VX-ODS Size: 1 mm x 2.1 mm I.D. Mobile Phase: CH 3 CN/H 2 O=70/30 Flow Rate: 0.2 ml/min Temperature: ambient Detection: UV-254nm,0.16AUFS Pressure: 66 MPa Column: ULTRON VX-ODS Size: 1 mm x 2.1 mm I.D. Mobile Phase: CH 3 CN/H 2 O=30/70 Flow Rate: 0.2 ml/min Temperature: ambient Detection: UV-254nm,0.16AUFS Pressure: 44 MPa 47
48 ULTRON VX-Octyl Life Test in Acidic Solution ( Lot 70 % 60 % MeOH, 0.1 % TFA (ph 2.2) 1.0 ml/min, 40 Comparison of alkylbenzene in VX-Octyl and VX-ODS Column: ULTRON VX-Octyl 5 µm Mobile Phase: CH 3 OH/H 2 O Temperature: 40 Detection: UV-254 nm 48
49 STR ODS- Nucleic acid base, Nucleoside ( Cytosine Uracil Guanine Adenine Cytidine Uridine Thymine Adenosine Guanosine Thymidine Nucleoside, Nucleotide Cytidine 5'-Monophosphate Uridine 5'-Monophosphate Guanosine 5'-Monophosphate Adenosine 5'-Triphosphate Cytidine Uridine Adenosine 5'-Monophosphate Inosine Guanosine Column: STR ODS- Mobile Phase: 0.1 M-Phosphate Buffer (ph2.1) 0.2 M NaClO 4 Temperature: Detection: UV-260 nm (0.32 AUFS) Column: STR ODS- Mobile Phase: 0.1 M KH 2 PO 4 (ph5.8) 0.2 mm Na 2 SO 4 Temperature: ambient Detection: UV-254 nm (0.32 AUFS), NADH Catecholamine Nicotinamide Adenine Dinucleotide oxidized Nicotinamide Adenine Dinucleotide Reduced Norepinephrine Epinephrine Normetanephrine 3,4-Dihydroxyphenylacetic Acid Dopamine 5-Hydroxyindole-3-acetic Acid Isoproterenol Homovanilic Acid 5-Hydroxytryptamine Column: STR ODS- Mobile Phase: 10 mm NH 4 H 2 PO 4 (ph 2.6) Temperature: 40 Detection: UV-260 nm (0.04 AUFS) Column: STR ODS- Mobile Phase: 0.1M Citric Acid, 0.1M Sodium acetate(ph4) / 17% CH 3 OH 1-Octane sodium sulphonate 160mg/L EDTA 5mg/L Temperature: 25 Detection: ECD, 800 mv, 10 na
50 STR ODS- Bile Acid Hippuric Acid Cholic Acid Glucocholic Acid Taurocholic Acid Chenodeoxycholic Acid Glucochenodeoxycholic Acid Deoxycholic Acid Taurochenodeoxycholic Acid Taurodeoxycholic Acid Hippuric Acid o-methyl Hippuric Acid p-methyl Hippuric Acid m-methyl Hippuric Acid Column: STR ODS- Mobile Phase: CH 3 CN/30 mm (NH 4 ) 2 HPO 4 (ph 7.2 NH 4 H 2 PO 4 ) A = 10/90, B = / 30 % B 85 % B (55 min) Temperature: 40 Detection: UV-217 nm (0.02 AUFS) Column: STR ODS- Mobile Phase: 20 mm-phosphate Buffer (ph2.5) 8 10 mm -Cyclodextrin CH 3 CN 1 Temperature: Detection: UV-260 nm (0.02 AUFS) Analysis of the PTC Amino Acid Aspartic Acid Glutamic Acid Serine Glycine Histidine Arginine Threonine Alanine Proline Tyrosine Valine Methionine Cysteinecysteine Isoleucine Leucine Phenylalanine Lysine Column: STR ODS- Mobile Phase: A: Sodium acetate (ph 6.5) / CH 3 CN (93:7) B: CH 3 CN / H 2 O (4:1) 0 % B 34 % B (18 min) 100 % B (18.01 min) 100 % B (23 min) Temperature: 40 Detection: UV-254 nm (0.04 AUFS)
51 STR ODS- The water-soluble vitamin The water-soluble vitamin Nicotinic Acid Nicotinamide Pantothenic Acid Pyridoxine Riboflavin Phosphate Thiamine Caffeine Folic Acid Biotin Riboflavin Pyridoxal Pyridoxine Pyridoxamine Column: STR ODS- Mobile Phase: 100 mm-phosphate Buffer (ph2.1) mm Octane sodium sulphonate CH 3 CN 1 Temperature: 40 Detection: UV-210 nm (0.16 AUFS) Column: STR ODS- Mobile Phase: 100 mm-phosphate Buffer (ph2.1) 9 mm Hexane sodium sulphonate CH 3 CN 1 Temperature: 45 Detection: UV-210 nm (0.04 AUFS) Fat-soluble vitamin The freshness K value Vitamin A Vitamin D2 Vitamin D3 Vitamin E Tocopherol Acetate Hypoxanthine Inosine 5'-Monophosphate Adenosine 5'-Diphosphate Adenosine 5'-Monophosphate Inosine Adenosine 5'-Triphosphate Column: STR ODS- Mobile Phase: 100 % CH 3 CN Temperature: 40 Detection: UV-280 nm (0.08 AUFS) Column: STR ODS- Mobile Phase: 24mM 2-Diethylaminoethanol is contained 16mM Citric Acid aqueous solution Flow Rate: 2.0 ml/min Temperature: 40 Detection: UV-2 nm (0.04 AUFS) 51
52 STR ODS- Organic Acids Saccharin, Aspartame, Benzoic Acid, Sorbic Acid Tartaric Acid Malic Acid Malonic Acid Acetic Acid Citric Acid Succinic Acid Malic Acid Degradate Propionic Acid Saccharin Aspartame Benzoic Acid Sorbic Acid Column: STR ODS- Mobile Phase: 5M NH 4 H 2 PO 4 (ph 2.4) Temperature: 40 Detection: UV-210 nm (0.08 AUFS) The phenolic system antioxidant (it is added to the edible oil of the marketing) Prostaglandin 2,4,5-Trihydroxybutyrophenone Nordihydroguaiaretic Acid Butyl Hydroxy Anisol Octyl Gallate 2,6-Di-t-Butyl-4-Hydroxy-Methylphenol Lauryl Gallate 2,6-Di-t-Butylhydroxytoluene Column: STR ODS- Mobile Phase: 40 mm Acetate buffer (ph4.0) 3 CH 3 OH 1 Temperature: 40 Detection: UV-2 nm (0.16 AUFS) Paraben (it is added to the soy sauce of the marketing) Methyl Paraben Ethyl Paraben Isopropyl Paraben Propyl Paraben Isobutyl Paraben Butyl Paraben Column: STR ODS- Mobile Phase: A: 10 mm-phosphate Buffer (ph2.6) B: CH 3 CN 30 % B 30 % B (4 min) 63 % B (4.01 min) 63 % B (10 min) 90 % (10.01 min ) 90 % B (16 min) 30 % B (16.01 min) 30 % B (25 min) Temperature: 40 Detection: SPD-10A, 280 nm 2AU/V, AT = 7 Column: STR ODS- Mobile Phase: 10 mm-phosphate Buffer (ph2.6) CH 3 OH Flow Rate: 1.5 ml/min Temperature: 40 Detection: SPD-10A, 270 nm 2AU/V, AT = 6 52
53 STR ODS- The component of the anti-inflammatory agent Salicylic Acid Diphenhydramine Methyl Salicylate -Camphor Thymol Anticonvulsant analysis Ethosuximide Primidone Phenobarbital Phenytoin Carbamazepine Column: STR ODS- Mobile Phase: 10 mm-phosphate Buffer (ph2.6) 3 20 mm Heptane sodium sulphonate CH 3 OH 2 CH 3 CN 2 Temperature: 45 Detection: UV-210 nm (0.08 AUFS) Column: STR ODS- Mobile Phase: 100 mm Phosphoric Acid buffer (ph4.0) / CH 3 OH / CH 3 CN (4 / 2 / 1) Temperature: 40 Detection: UV-2 nm (0.16 AUFS) The component of the cold remedy Methylephedrine Hydrochloride Noscapine Thiamine Dextromethorphan Carbinoxamine Maleate The component of the cold remedy Acetaminophen Caffeine Riboflavin Phenol Potassium Guaiacol-4-Sulfonate Column: STR ODS- Mobile Phase: CH 3 CN 510 H 2 O 0 H 3 PO % Sodium dodecyl sulfate Temperature: Detection: UV-210 nm (0.04 AUFS) Column: STR ODS- Mobile Phase: H 2 O 15 CH 3 CN 2 mm Tetrabutylammonium 1 (It is adjusted at ph=6 in the phosphoric Acid) Temperature: Detection: UV-280 nm (0.01 AUFS) 53
54 STR ODS- Oxine copper Thiuram Oxine-copper Thiuram Column: STR ODS- Mobile Phase: mm-phosphate Buffer (ph2.2) 95 CH 3 CN 5 Temperature: 40 Detection: UV-240 nm (0.04 AUFS) Column: STR ODS- Mobile Phase: CH 3 CN H 2 O Temperature: 40 Detection: UV-280 nm (0.01 AUFS) Asulam Iprodione, Bensulide Asulam Iprodione Bensulide Column: STR ODS- Mobile Phase: mm-phosphate Buffer (ph3.3) 90 CH 3 CN 10 Temperature: 40 Detection: UV-270 nm (0.01 AUFS) Column: STR ODS- Mobile Phase: CH 3 CN 60 H 2 O 40 Temperature: 40 Detection: UV-230 nm (0.02 AUFS) 54
55 STR ODS- Arbutin in the Bearberry Leaf end Berberine in the Coptis end Arbutin Unknow Hydroquinone Gallic Acid Berberine Column: STR ODS- Mobile Phase: 100 mm-phosphate Buffer (ph2.1) 40 CH 3 OH 1 Flow Rate: 0.9 ml/min Temperature: 35 Detection: UV-280 nm (0.16 AUFS) Column: STR ODS- Mobile Phase: The result of dissolving potassium dihydrogenphosphate 3.4g and sodium lauryl sulfate 1.7g at water 1L/CH 3 CN=1 / 1 Flow Rate: 0.5 ml/min Temperature: 40 Detection: UV-345 nm (0.16 AUFS) Glycyrrhizin in the licorice end Glycyrrhetic Acid Propyl Paraben Paeoniflorin in the peony end Paeoniflorin Column: STR ODS- Mobile Phase: 15 times dilution acetic Acid aqueous solution 3 CH 3 CN 2 Flow Rate: 0.7 ml/min Temperature: ambient Detection: UV-254 nm (0.08 AUFS) Column: STR ODS- Mobile Phase: 10 mm Sodium acetate (ph 4.8) 5 Ch 3 CN 1 Flow Rate: 0.5 ml/min Temperature: 40 Detection: UV-230 nm (0.64 AUFS) 55
56 STR ODS- Strychnine in nux vomica Scopolamine and Hyoscyamus niger thiamine in the Rohto extract Strychnine Scopolamine Hyoscyamine Brucine Column: STR ODS- Mobile Phase: (The result of dissolving potassium dihydrogenphosphate 6.8g in water 1000mL) / Acetonitrile/Triethylamine=45/5/1 The result of adjusting at ph=3 in the phosphoric acid Flow Rate: 0.5 ml/min Temperature: 40 Detection: UV-210 nm (0.16 AUFS) Column: STR ODS- Mobile Phase: The liquid by adding water after it dissolved potassium dihydrogenphosphate 6.8g at water 900 ml and added triethylamine 10 ml, and after it adjusted it in the phosphoric acid in ph3.5 as 1000mL/CH 3 CN=9/1 Flow Rate: 0.8 ml/min Temperature: ambient Detection: UV-210 nm (0.16 AUFS) 56
57 STR ODS-M Nucleoside, Nucleotide Cytidine 5-Diphosphate Cytidine 5-Monophosphate Uridine 5-Monophosphate Guanosine 5-Monophosphate Adenosine 5-Triphosphate Gytidine Uridine Adenosine 5-Monophosphate Inosine Guanosine Adenosine 5-Monophosphate Adenosine 5-Diphosphate Adenosine 5-Triphosphate Column: STR ODS-M Mobile Phase: 0.1 M KH 2 PO 4, 20 mm Na 2 SO 4 (ph 5.8) Temperature: 30 Detection: UV-254 nm Column: STR ODS-M Mobile Phase: 30 mm 2-Diethylaminoethanol is contained 20 mm Citric Acid aqueous solution Flow Rate: 0.8 ml/min Temperature: 40 Detection: UV-260 nm The freshness K value The water-soluble vitamin Hypoxanthine Inosine 5-Monophosphate Adenosine 5-Monophosphate Adenosine 5-Diphosphate Adenosine 5-Triphosphate Isosine Nicotinic Acid Nicotinamide Pantothenic Acid Pyridoxine Riboflavin Phosphate Thiamine Caffeine Biotin Riboflavin Column: STR ODS-M Mobile Phase: 24 mm 2-Diethylaminoethanol is contained 16 mm Citric Acid aqueous solution Flow Rate: 2.0 ml/min Temperature: 40 Detection: UV-2 nm Column: STR ODS-M Mobile Phase: 100 mm-phosphate Buffer (ph2.1) mm Octane sodium sulphonate CH 3 CN 1 Temperature: 40 Detection: UV-210 nm 57
58 STR ODS-M Organic Acids Caffeine and Catechin Tartaric Acid Malic Acid Malonic Acid Acetic Acid Citric Acid Succinic Acid Malic Acid Degradate Propionic Acid Epigallocatechin Catechin Caffeine Epigallocatechin Gallate Epicatechin Epicatechin Gallate Column: STR ODS-M Mobile Phase: 10 mm NH 2 PO 4 (It is adjusted at ph=2.3 in the phosphoric acid) Temperature: 40 Detection: UV-210 nm Saccharin, Aspartame, Benzoic Acid, Sorbic Acid Column: STR ODS-M Mobile Phase: A: 10 mm-phosphate Buffer (ph2.6) B: CH 3 CN 7 % B 7 % B (30 min) 12 % B (30.01 min) 12 % B (45 min) % B (45.01 min ) % B ( min) 7 % B (.01 min) 7 % B (80 min) Temperature: 45 Detection: UV-280 nm (0.64 AUFS) Anticonvulsant analysis Saccharin Aspartame Benzoic Acid Sorbic Acid Ethosuximide Primidone Phenobarbital Phenytoin Carbamazepine Column: STR ODS-M Mobile Phase: 40 mm Acetate buffer (ph4.0) 3 CH 3 OH 1 Temperature: 40 Detection: UV-2 nm (0.32 AUFS) Column: STR ODS-M Mobile Phase: 100 mm-phosphate Buffer (ph2.1) 4 CH 3 OH 2 CH 3 CN 1 Temperature: 40 Detection: UV-205 nm 58
59 STR ODS-M Nicarbazin Ethopabate Nicarbazin Ethopabate Column: STR ODS-M Mobile Phase: 10 mm-phosphate Buffer (ph2.6) 30 CH 3 CN 70 Flow Rate: 0.8 ml/min Temperature: 40 Detection: UV-340 nm Column: STR ODS-M Mobile Phase: H 2 O 70 CH 3 CN 30 Flow Rate: 0.7 ml/min Temperature: 40 Detection: UV-270 nm Berberine Berberine Column: STR ODS-M Mobile Phase: The result of dissolving potassium dihydrogenphosphate 3.4g and sodium lauryl sulfate 1.7g at water 1L / CH3CN=1 / 1 Flow Rate: 0.6 ml/min Temperature: 40 Detection: UV-345 nm Column: STR ODS-M Mobile Phase: 10 mm-phosphate Buffer (ph 2.6) mm NaClO 4 CH 3 CN 3 Temperature: 40 Detection: UV-345 nm 59
60 STR ODS-M Scopolanime, Hyoscyamine Scopolanime Hyoscyamine Brucine Column: STR ODS-M Column: STR ODS-M Mobile Phase: The liquid by adding water after it dissolved potassium dihydrogenphosphate Mobile Phase: 10 mm-phosphate Buffer (ph 2.6) 3 6.8g at water 900 ml and added triethylamine 10 ml, and after it adjusted it in the phosphoric 200 mm NaClO 4 CH 3 CN 1 acid in ph3.5 as 1000 ml / CH 3 CN = 9 / 1 Flow Rate: 0.8 ml/min Temperature: ambient Temperature: 40 Detection: UV-210 nm Detection: UV-210 nm Arbutin Arbutin Hydroquinone Gallic Acid Column: STR ODS-M Mobile Phase: H 2 O / CH 3 OH / 0.1N-HCl = 94 / 5 / 1 Flow Rate: 0.8 ml/min Temperature: ambient Detection: UV-280 nm Column: STR ODS-M Mobile Phase: 100 mm-phosphate Buffer (ph 2.1) / CH 3 OH = 40 / 1 Flow Rate: 0.8 ml/min Temperature: 40 Detection: UV-280 nm 60
61 STR ODS-M AldehydeAldehydes (1.3-Cyclohexanedione derivatives) Formaldehyde Acetaldehyde Column: STR ODS-M Mobile Phase: CH 3 CN / H 2 O = 35 / 65 Flow Rate: 0.8 ml/min Temperature: 40 Detection: RF-535 Ex = 360 nm Em = 440 nm 61
62 INDEX Acetaldehyde Acetaminophen Acetic Acid N-Acetylgalactosamine N-Acetylglucosamine Acetylpheneturide Acetylsalicylic Acid Acrylic Acid Adenine Adenosine Adenosine 5 -Diphosphate Adenosine 5 -Monophosphate Adenosine 5 -Triphosphate Adipic Acid Adonitol Alanine Alimemazine Alkylbenzene Alprenolol Amprolium Arabinose Arbutin Arginine Arotinolol Aspartame Aspartic Acid Asulam Atenolol Benproperine Bensulide Benzoic Acid Benzoin Berberine 1,1 -Bi-2-naphthol Biotin Biperiden Brucine Bunitrolol Bupivacaine Butyl Hydroxy Anisol A N- N- 5'- 5'- 5'- B 1, , , 37, 38, 52, , , 57, 51, 57, 51, 57 36, 38 39, 40 16, , 25, 31 46, 47 39, 40 55, 60 12, 31 52, , , 45, 52, 58 23, 30 55, , 51, , 60 12, 25, 31 21,
63 INDEX Butyl Paraben n-butyric acid Caffeic Acid Caffeine Calcium Pantothenate -Camphor Carbamazepine Carboxylic acids Catechin Chenodeoxycholic Acid Chlormezanone Chlorphenesin Chlorpheniramine Cholic Acid Citric Acid Cloperastin Clorprenaline Cortisone Cortisone Acetate Crotonic Acid Cysteine Cytidine ytidine Cytidine 5 -Diphosphate Cytidine 5 -Monophosphate B n- C , 53, 57, , , 27, 33 18, 33 16, 27 36, 37, 38, 52, , , , 57 Cytosine D Deoxycholic Acid Dextran T-10 Dextromethorphan 2,6-Di-t-Butyl-4-Hydroxy-Methylphenol 2,6-Di-t-Butylhydroxytoluene Diethylene Glycol 3,4-Dihydroxyphenylacetic Acid Dimethindene Maleate N-(3,5-Dinitrobenzoyl)--Methylbenzylamine Diphenhydramine 1,2-Diphenylethylamine Disopyramid Dopamine T-10 2,6--t--4-2,6--t--4-3,4- N-(3,5-)-- 1,2-39, 40, ,
64 INDEX Eperisone Epicatechin Epicatechin Gallate Epigallocatechin Epigallocatechin Gallate Epinephrine Estradiol Estriol Estrone Ethanol Ethiazide Ethopabate Ethosuximide Ethyl Paraben Ethylene Glycol Flavanone Flurbiprofen Folic Acid Formaldehyde Formic Acid Fructose Fumaric Acid Furazolidone Galactose Gallic Acid Glucose Glucuronic Acid Glutamic Acid -Glutamic Acid Monosodium Salt Glutaric acid Glutethimide Glycerol Glycine Glycochenodeoxycholic Acid Glycocholic Acid Glycolic Acid Glycopyrronium bromaide Glycyrrhetic Acid E F (Bc) G - 18, 28, , 39, 40, 41, 42 22, , , 40 23, 30, , 51 37, , 40, 41, 42 36, 38 46, 47 39, 40, 41, 42 36, 55, 60 39, 40, 41, 42 37, , 40 36,
65 INDEX Glyoxylic Acid Guanine Guanosine Guanosine 5 -Monophosphate Hexobarbital Hippuric Acid Histidine Homochlorcyclizine Homovanilic Acid Hydrocortisone Hydrocortisone Acetate Hydroquinone m-hydroxybenzoic Acid p-hydroxybenzoic Acid o-hydroxybenzoic Acid 5-Hydroxyindole-3-acetic Acid 5-Hydroxytryptamine Hydroxyzine Hyoscyamine Hypoxanthine Ibuprofen Inosine Inosine 5 -Monophosphate Inositol Iprodione Isobutyl Paraben Isoleucine Isopropyl Alcohol Isopropyl Paraben Isoproterenol G H m- p- o I 5'- 36, 57, 57 20, , 60 36, 45 36, , 60 51, 57 15, 26, 51, 57 51, 57 40, 41, Isosine K 57 2-Ketoglutaric acid Ketoprofen Lactic Acid Lactose Lauryl Gallate Leucine 2- L , 37, 38 39, 40, 41,
66 INDEX Levulinic Acid L 36 Lysine M Maleic acid Malic Acid Malonic Acid Maltose Maltotriose Mannitol Mannose Meclizine Mepenzolate bromaide Mephobarbital Methacrylic Acid Methanol Methionine o-methyl Hippuric Acid p-methyl Hippuric Acid m-methyl Hippuric Acid Methyl Paraben Methyl Salicylate Methylephedrine Hydrochloride Methylphenidate (1S,2R)-1-Methyl-cis-1,2,3,6-tetrahydrophthalate Naphthalen Nicarbazin Nicotinamide Nicotinamide Adenine Dinucleotide oxidized Nicotinamide Adenine Dinucleotide Reduced Nicotinic Acid Nicotinic Acid Amide Nordihydroguaiaretic Acid Norepinephrine Normetanephrine Noscapine Octyl Gallate Oligosaccharide Oxine-copper Oxolinic Acid o- p- m- (1S,2R)-1--cis-1,2,3,6- N (PP) O 38 36, 37, 52, 58 36, 38, 52, 58 40, 41, 42 40, 41, 42 39, , 27 36, , , 57 45, 51, , 47 66
67 INDEX Oxprenolol Oxytetracycline Paeoniflorin Pantothenic Acid Phenobarbital Phenol Phenoxyacetic Acid Phenylalanine -Phenylethyl alcohol -Phenylethylamine Phenytoin o-phthalic Acid Pindolol Pivalic Acid Potassium Guaiacol-4-Sulfonate Pranoprofen Predonisone Prenylamine Primidone Profenamine Proglumide Proline Promethazine Propionic Acid Propranolol Propyl Paraben Prostaglandin PTH-Valine Pyridine Pyridoxal Pyridoxamine Pyridoxine Pyridoxine Hydrochloride Pyroglutamic Acid Raffinose Riboflavin Riboflavin Phosphate Saccharin - - o- PTH- (B6) (B2) O P R S 12 46, , 57 53, 58 45, 47, , 35 53, , , , , 38, 52, 58 13, 32 52, , , , 37 39, 40, 42 45, 51, 53, 57 45, 51, 57 52, 58 67
68 INDEX Salicylic Acid Scopolamine Scopolamine Serine Sorbic Acid Sorbitol Stachyose trans-stilben Oxide Strychnine Succinic Acid Sucrose Sulfadimethoxine Sulfadimidine Sulfadimidine Sulfamerazine Sulfamonomethoxine Sulfaquinoxaline Tartaric Acid Taurochenodeoxycholic Acid Taurocholic Acid Taurodeoxycholic Acid Terbutaline Thiamine Thiamphenicol Thioridazine Thiuram Threonine Thymidine Thymine Thymol Thyroxine Tocopherol Acetate Tolperisone Trihexyphenidyl Trimipramine maleate Tyrosine Uracil Uridine Uridine 5 -Monophosphate S trans- T (B1) U 45, , 52, 58 39, , 37, 38, 52, 58 39, 40, 41, 42 46, 47 46, 47 46, 47 46, 47 46, 47 46, 47 36, 37, 38, 52, 58 25, 29 45, 51, 53, 57 46, , , 28, 57, 57 68
69 INDEX Valine Vanilic Acid Verapamil Vitamin A Vitamin A Acetate Vitamin A Palmitate Vitamin D2 Vitamin D3 Vitamin E Vitamin K1 Vitamin K2 Warfarin Xylitol Xylose Zaltoprofen V A A A D2 D3 E K1 K2 W X Z , , 26 39, 40 40,
70 INDEX N- N- 5'- 5'- 5'- 5'- Acetaldehyde Acrylic Acid Adipic Acid Asulam Aspartic Acid Aspartame N-Acetylgalactosamine N-Acetylglucosamine Acetylsalicylic Acid Acetylpheneturide Acetaminophen Adenine Adenosine Adenosine 5 -Diphosphate Adenosine 5 -Triphosphate Adenosine 5 -Monophosphate Atenolol Adonitol Alanine Arabinose Alimemazine Arginine Alkylbenzene Arbutin Alprenolol Arotinolol Benzoic Acid Amprolium Isosine Isobutyl Paraben Isoproterenol Isopropyl Alcohol Isopropyl Paraben Isoleucine Inositol Inosine Inosine 5 -Monophosphate Ibuprofen Iprodione 37, , , , , 57, 51, 57, 51, 57 25, 31 39, 40 39, 40 16, , 60 12, 25, 31 12, 31 36, 45, 52, 58 46, , 41, 43, 51, 57 51, 57 15,
71 INDEX (B6) 5- Uracil Uridine Uridine 5 -Monophosphate Estradiol Estriol Estrone Ethanol Ethiazide Ethyl Paraben Ethylene Glycol Ethosuximide Ethopabate Epicatechin Epicatechin Gallate Epigallocatechin Epigallocatechin Gallate Epinephrine Eperisone Pyridoxine Hydrochloride Methylephedrine Hydrochloride 5-Hydroxyindole-3-acetic Acid Oxytetracycline Oxine-copper Oxolinic Acid Oxprenolol Octyl Gallate Oligosaccharide Catechin Caffeine Caffeic Acid Galactose Carbamazepine Carboxylic acids Formic Acid Xylitol Xylose, 57, , 39, 40, 41, 42 22, , 40 53, , 28, , , , 53, 57, , 40, 41, 42 53, , 40 40, 41 71
72 INDEX - 2- Guanine Guanosine Guanosine 5 -Monophosphate Potassium Guaiacol-4-Sulfonate Citric Acid Glyoxylic Acid Glycochenodeoxycholic Acid Glycocholic Acid Glycopyrronium bromaide Glycyrrhetic Acid Glycine Glycerol Glucuronic Acid Glucose Glycolic Acid Glutamic Acid -Glutamic Acid Monosodium Salt Glutaric acid Glutethimide Crotonic Acid Cloperastin Chlorpheniramine Chlorphenesin Clorprenaline Chlormezanone 2-Ketoglutaric acid Ketoprofen Chenodeoxycholic Acid Cholic Acid Succinic Acid Cortisone Acetic Acid Cortisone Acetate Tocopherol Acetate Hydrocortisone Acetate Saccharin Methyl Salicylate, 57, , 37, 38, 52, , 40 37, 43 39, 40, 41, 42 36, , , 27 18, 33 22, 29 18, 27, , 37, 38, 52, , 37, 38, 52, ,
73 INDEX 3,4- N-(3,5-)-- 1,2-2,6--t--4-2,6--t trans- Salicylic Acid Zaltoprofen Sulfaquinoxaline Sulfadimidine Sulfadimidine Sulfadimethoxine Sulfamerazine Sulfamonomethoxine Diethylene Glycol 3,4-Dihydroxyphenylacetic Acid Cysteine Disopyramid Cytidine ytidine Cytidine 5 -Monophosphate Cytidine 5 -Diphosphate Cytosine N-(3,5-Dinitrobenzoyl)--Methylbenzylamine 1,2-Diphenylethylamine Diphenhydramine 2,6-Di-t-Butylhydroxytoluene 2,6-Di-t-Butyl-4-Hydroxy-Methylphenol Tartaric Acid -Camphor Sucrose Scopolamine Scopolamine Stachyose trans-stilben Oxide Strychnine Serine Sorbitol Sorbic Acid Taurochenodeoxycholic Acid Taurocholic Acid Taurodeoxycholic Acid 73 45, , 47 46, 47 46, 47 46, 47 46, 47 46, 47 37, , , 37, 38, 52, , 40, 41, , 40 36, 52, 58
74 INDEX (B1) T-10 (PP) Thiamine Thiamphenicol Thiuram Thioridazine Thymidine Thymine Thymol Thyroxine Tyrosine Deoxycholic Acid Dextran T-10 Dextromethorphan Terbutaline Dopamine Trihexyphenidyl Tolperisone Threonine Nicarbazin Naphthalen Nicotinamide Nicotinamide Adenine Dinucleotide Reduced Nicotinamide Adenine Dinucleotide oxidized Nicotinic Acid Nicotinic Acid Amide Lactic Acid Noscapine Norepinephrine Nordihydroguaiaretic Acid Normetanephrine Hippuric Acid Vanilic Acid Valine Calcium Pantothenate Pantothenic Acid 45, 51, 53, 57 46, , 40, , , , 57 45, 51, , 37, , 57 74
75 INDEX 1, PTH- A A A D2 D3 E K1 K2 5- m- p- o- - - o- 1,1 -Bi-2-naphthol PTH-Valine Hyoscyamine Biotin Histidine Vitamin A Vitamin A Acetate Vitamin A Palmitate Vitamin D2 Vitamin D3 Vitamin E Vitamin K1 Vitamin K2 Hydroxyzine 5-Hydroxytryptamine m-hydroxybenzoic Acid p-hydroxybenzoic Acid o-hydroxybenzoic Acid Hydroquinone Hydrocortisone Pivalic Acid Biperiden Hypoxanthine Pyridine Pyridoxal Pyridoxamine Pyridoxine Pyroglutamic Acid Pindolol Phenytoin Phenylalanine -Phenylethylamine -Phenylethyl alcohol Phenol Phenoxyacetic Acid Phenobarbital o-phthalic Acid Butyl Paraben Butyl Hydroxy Anisol Bunitrolol , 60 45, 51, , , 45 36, , , 57 45, , 57 36, 37 13, 32 53, 58 34, , 47, , , 25, 31 75
76 INDEX Bupivacaine Fumaric Acid Furazolidone Pranoprofen Flavanone Primidone Fructose Brucine Flurbiprofen Predonisone Prenylamine Proglumide Prostaglandin Propionic Acid Propyl Paraben Profenamine Propranolol Promethazine Proline Paeoniflorin Hexobarbital Verapamil Berberine Bensulide Benzoin Benproperine Homochlorcyclizine Homovanilic Acid Formaldehyde Maltose Maltotriose Maleic acid Dimethindene Maleate Trimipramine maleate Malonic Acid Mannitol Mannose 21, 32 36, 38 46, 47 15, 26 23, 30, 34 53, 58 39, 40, 41, 42 56, , 38, 52, 58 52, , , , , , 61 40, 41, 42 40, 41, , 28 36, 38, 52, 58 39,
77 INDEX (1S,2R)-1--cis-1,2,3,6- o- p- m- (Bc) n- (B2) Meclizine Methacrylic Acid Methanol Methionine (1S,2R)-1-Methyl-cis-1,2,3,6-tetrahydrophthalate o-methyl Hippuric Acid p-methyl Hippuric Acid m-methyl Hippuric Acid Methyl Paraben Methylphenidate Mepenzolate bromaide Mephobarbital Gallic Acid Folic Acid Lauryl Gallate n-butyric acid Lactose Raffinose Lysine Riboflavin Malic Acid Riboflavin Phosphate Levulinic Acid Leucine Warfarin 19 36, , , 27 36, 55, 60 45, , 40, 41, 42 39, 40, 42 45, 51, 53, 57 36, 37, 52, 58 45, 51, , 26 77
78 LN1002A
COSMOSIL.indd
Column: 5C 18 -MS-II Column size: 4.6mmI.D.-150mm Mobile phase: Methanol/ H 2 = 60/40 Detection: UV254nm Sample: 1; Acetophenone (0.05μg) 2; Methyl Benzoate (0.5μg) 3; Benzene (2.0μg) 4; Toluene (2.0μg)
Agilent Infinity ELSD ELSD ( ) ( ºC ) W x D x H mm LED ELSD ELSD ELSD UV UV LC/MS RSD % Column: Agilent Pursuit C8, x.6 mm, µm Eluent: Water: Acetonit
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スローフードとその網羅的分析法 (slow food) ジエルサイエンス ( 株 ) ジーエルサイエンス ( 株 ) 宮川浩美 スローフードを攻めの農業の一つに ~ フレーバー ( 広義では香りと味 ) と機能 ~ グルコバニリン 糖 糖 脂質 前駆体 アミノ酸 生体 3MH-S-cys 3MH-S-glutS TCA 回路 3-MH( メルカフ トヘキサノール ) 香り 酵素唾液 味 舌ざわり 官能試験
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Adenosine Triphosphate Adenosine Monophosphate min min Fig.2 Chromatograms of Nucleotides Peak
Hydrocortisone Sodium Phosphate 3.5 1.0 0.5 1 μg/ml 3.0 2.5 25 ng/ml 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0 min 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0 min Fig.1 Chromatograms of Hydrocortisone
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~ミックスモードカラム ~ DS との違い 移動相の考え方 TCI Chromatography Department 逆相とミックスモード : 充填剤の違い DS カラムに用いる充填剤 オクタデシル基をシリカゲルに化学結合 ミックスモードカラムに用いる充填剤 オクタデシル基とイオン交換基両方を有する試薬をシリカゲルに化学結合 弊社製品は DS とイオン交換の充填剤を混ぜることはしておりません 疎水性部分
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Hydrocortisone Sodium Phosphate 3.5 1.0 0.5 1 μg/ml 3.0 2.5 25 ng/ml 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0 min 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0 min Fig.1 Chromatograms of Hydrocortisone
Adenosine Triphosphate Adenosine Monophosphate min Fig.2 Chromatograms of Nucleotides min Peak
Adenosine Triphosphate Adenosine Monophosphate 0.0 1.0 2.0 3.0 4.0 5.0 6.0 min Fig.2 Chromatograms of Nucleotides 0.0 1.0 2.0 3.0 4.0 5.0 6.0 min Peak Asymmetry Peak 1 Peak 2 1.39 1.14 5.10 1.49 Instrument
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LAAN-C-XX011A Lifescience O HO O MS 1 MS 2 C 14 H 16 N 10 HO HO O MS 3 Application Note No.10 Application Note No.10 Application Note No.10 Intensity (x100,000,000) 7.5 5 5.0 2.5 1 2 3 4 6 7 8 9 10 +:TIC
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2,2-2,2 -Iminodiethanol Diethanol amine CAS 111-42-2 C 4 H 11 NO 2 105.1356-105.0790-28 C 1) 1.0881 g/cm 3 1)
平成26年度 化学物質分析法開発報告書
2,2-2,2 -Iminodiethanol Diethanol amine CAS 111-42-2 C 4 H 11 NO 2 105.1356-105.0790-28 C 1) 1.0881 g/cm 3 1)
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2017 5 26 350 Restek time time time increasing time μ = = k = t r t o t o = t r ' t o van Deemter Equation H A B H = height equivalent theoretical plate (HETP) A = Eddy diffusion term B = Molecular diffusion
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64 Shimadzu GLC Ltd.PLCカラム0 Synergi TM 基材として粒子径 4µm 細孔径 80A のシリカ粒子を使用しています 粒子径 3µm のカラムに近いカラム効率が得られます 粒子径 5µm のカラムと同様のカラム圧で分析可能です 基材として高純度シリカ (99.99%) を用いることで キレートの原因となる金属不純物が減少し 中性移動相条件下でも残存シラノール基の活性を抑えることが可能です
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29.18 カルボン酸 ( 他の酸素官能基を有するものに限る ) 並びにその酸無水物 酸ハロゲン化物 酸過酸化物及び過酸並びにこれらのハロゲン化誘導体 スルホン化誘導体 ニトロ化誘導体及びニトロソ化誘導体 (Carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids;
Mastro -リン酸基含有化合物分析に対する新規高耐圧ステンレスフリーカラムの有用性について-
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Tl Thallium CAS 7440-28-0 CH 3 COOTl Thallium Acetate CAS 563-68-8 Tl 2 CO 3 Thallium Carbonate CAS 6533-73-9 Tl 2 SO 4 Thallium Sulfate CAS 7446-18-6 TlNO 3 Thallium Nitrate CAS 10102-45-1 TlClO 3 Thallium
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カ9 ラム順相系用分析用順相カラムの種類と特長 順相クロマトグラフィーは 逆相では分離が難しい位置異性体の分離などに有用です ワイエムシィの順相カラムには シリカゲルカラムのほか極性基で修飾した充填剤を充填したカラムがあります ラインナップ 製品名 細孔径粒子径 (nm)(μm) 使用 ph 範囲
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Title 数種の中国産甘草サポニン成分の化学的研究 Author(s) 堀, 一之 Citation Issue Date Text Version ETD URL https://doi.org/10.11501/3070540 DOI 10.11501/3070540 rights 0 0 II C 0 COOR COOK OH HOH COOR 0 OH HOO H H3 16
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Alkane n 2n+2 () 4 4 10 ( 2 6 5 12 ( 3 8 6 14 ( Alkane n 2n+2 () 4 4 10 ( Methane 2 2 Butane 2-Methylpropane 2 6 5 12 ( Ethane 2 2 2 Pentane 3 8 2 Propane 2,2-Dimethylpropane 2 2-Methylbutane 6 14 ( 2
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1 2 3 4 5 (written by Dr. ) Stock Solution (one liter) in 4 Buffer A: 0.05 M glucose 20% (1.1 M) glucose 22.7 ml 0.025 M Tris-Cl ph8 1 M Tris (ph8.0) 12.5 ml 0.01 M EDTA 0.5 M EDTA 10 ml Buffer B: 5 M
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Accucore HPLC Thermo Scientific TM Accucore TM HPLC HPLC Accucore HPLC 2.6 µm UHPLC 2 µm Accucore HPLC Accucore HPLC 5 Å Accucore XL HPLC Accucore XL
Thermo Scientific Accucore HPLC Accucore HPLC Thermo Scientific TM Accucore TM HPLC HPLC Accucore HPLC 2.6 µm UHPLC 2 µm Accucore HPLC Accucore HPLC 5 Å Accucore XL HPLC Accucore XL 4 µm HPLC 5 µm4 µm3
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N,N- N,N-Dimethylacetamide Acethyldimethylamine CAS 127-19-5 C 4 H 9 NO 87.12 ~ 87.14 87.68413 163-165 C 1) - 18.59 C 2) 1 mg/l 25 C 3) 3.3 hpa 2 C 4) log P ow -.77 2).9429 2/4 C 1) 3.1 4) 1.31E - 8 atm-m
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次世代型シリカモノリスカートリッジカラム MonoTower TM C18 次世代型シリカモノリスカートリッジカラム MonoTower TM C18 MonoTower TM C18 モノリスカートリッジを連結することで高い理論段数を低圧力で実現 粒子充填型 ODS カラム (3 μm, 250 3.0 mm I.D.) 15.5 MPa 分離不充分 (500 3.0 mm I.D.) 14.5
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56 Shimadzu GLC Ltd.H Luna R 社独自の技術をもとに 優れた ph 安定性と再現性を持つ逆相系カラムです ph1.5-9.0( ) の ph 領域において 酸性 塩基性および両性化合物の分析が可能です ph1.5-9.0( ) の領域において 1,000 時間以上安定してお使いいただけます 多種の粒子径やカラムサイズ 固定相を取り揃えております ガードカラムを除くすべてのカラムに基材品質保証書
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酸素官能のアミノ化合物 (xygen-function amino-compounds.) (A) アミノアルコール並びにそのエーテル及びエステル並びにこれらの塩 (Amino-alcohols, their ethers and esters, salts thereof) (1) モノエタノールアミン (Monoethanolamine) (2) ジエタノールアミン (Diethanolamine)
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極性化合物の分離に! ILIC,C8 C8-SC の 基礎と上手な使い方! 一般の C8 では分離が難しい極性化合物に適した ILIC とlanol ctivity Controlled C8 の活用法について説明いたしますいたします 7/8/ :-: - 会場於 : アパホテル & リゾート東京ベイ幕張ホール クロマニックテクノロジーズ Chromai Technologies Inc. TEL:
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効率的な HPLC メソッドの開発手法 基礎から最新手法まで アジレント テクノロジー ( 株 ) Page 1 HPLC メソッド開発の流れ メソッドのゴールを決める メソッドのパラメータをスクリーニングする カラム - 固定相の選択 移動相 - 有機溶媒 緩衝液と ph 組成 グラジエント条件 カラム温度 検出条件 スクリーニング結果をもとにメソッドを最適化 メソッドの頑健性を評価 メソッドバリデーション
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2,4- (2,4-Dichlorophenoxy) acetic acid 2,4-D 2,4-PA OH O O C A S 94-75-7 C 8 H 6 Cl 2 O 3 Cl Cl ( ) 221. (219.9694) 1) (g/cm 3 ) (25 C) 2) ( C) (.4 mm Hg) 2) ( C) 2) (mmhg) (2 C) 2) (mg/l) (25 C) log P
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